CN108149387A - A kind of hydrogel filament mask substrate - Google Patents

A kind of hydrogel filament mask substrate Download PDF

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Publication number
CN108149387A
CN108149387A CN201810044901.9A CN201810044901A CN108149387A CN 108149387 A CN108149387 A CN 108149387A CN 201810044901 A CN201810044901 A CN 201810044901A CN 108149387 A CN108149387 A CN 108149387A
Authority
CN
China
Prior art keywords
mask substrate
shell
solution
hydrogel filament
filament
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810044901.9A
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Chinese (zh)
Inventor
明津法
宁新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao University
Original Assignee
Qingdao University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao University filed Critical Qingdao University
Priority to CN201810044901.9A priority Critical patent/CN108149387A/en
Publication of CN108149387A publication Critical patent/CN108149387A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/11—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
    • D01F4/02—Monocomponent artificial filaments or the like of proteins; Manufacture thereof from fibroin
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/04—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
    • D04H3/045—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles for net manufacturing

Abstract

The invention discloses a kind of hydrogel filament mask substrates, and base fabric is regenerated silk fibroin hydrogel filament, through vertical bidirectional lapping, spun lacing machine-shaping.Hydrogel filament mask substrate provided by the invention has hydrogel absorbing and holding water property, has the ability of high load skin maintenance liquid, meanwhile, mask substrate is simple in structure, is easy to make, highly practical, has great market popularization value.

Description

A kind of hydrogel filament mask substrate
Technical field
The invention belongs to beauty product fields, provide a kind of hydrogel filament mask substrate, the mask substrate water suction of preparation Good water-retaining property, it is degradable, it is environmentally safe.
Background technology
Facial mask is a kind of using extensive beauty product, is mainly made of base fabric and beautifying liquid, base fabric is as a kind of carrier Beautifying liquid is passed into human skin, very important role is played the part of in facial mask.
Mask substrate is generally prepared using non-woven material, by the porosity of non-woven material and the suction of used fiber Wet moisture retention and functionality, so as to reach beauty functions.
Before this patent, a kind of natural silk mask substrates of Chinese invention patent CN104762756A and its preparation side Silk is deoiled, sofening treatment, is adhesively fixed to form mask substrate by silk gum by method.Chinese invention patent CN104611838A It is a kind of with silk cocoon production silk mask base fabric method and silk mask, by wash cocoon, wetting, caustic dip, decatize, cleaning, shell cocoon, Networking, sizing are prepared into silk mask base fabric.A kind of systems of tussah non-woven fabrics facial mask of Chinese invention patent CN104674355A Make method, by succinct technique and degumming tech etc., prepare tussah non-woven fabrics facial mask.Chinese invention patent CN104593945A A kind of high water absorption silk non-woven fabric production technology, using hydrophilic agent solution under the conditions of various concentration, temperature and time, to silk Fiber or silk non-woven fabric are sprayed, impregnated or are padded, and greatly improve silk fiber water imbibition.Chinese utility model patent CN206589406U one kind contains natural true silk mask base fabric, and mask substrate is built using impervious barrier, liquid storage level mulberry silk layer.In State's utility model patent CN202822173U silk non-woven fabric facial masks, including nonwoven layer and pearly-lustre film layer.
Fibroin albumen, natural macromolecular material is nontoxic, nonirritant, and there is good biocompatibility and biology can drop Xie Xing.Gelation occurs under certain condition for silk fibroin protein solution, and gelation process is mainly by solution concentration, temperature, pH, gold Belonging to the factors such as ion influences.Its hydrogel can be promoted to be formed by changing its gelation influence factor.Chinese invention patent CN106310380A discloses a kind of nanofiber Silk fibroin gel and preparation method thereof, molten using salt/formic acid lysate Boiled silk is solved, directly injection forms gel.A kind of silk fibroin gels of Chinese invention patent CN106866996A it is fast Fast preparation method quickly prepares silk extract gel using weak electric field.
Silk fibroin hydrogel has the function of water-absorbing-retaining well because of unique spacial framework.It is special by its Regenerated silk fibroin hydrogel filament is applied to make mask substrate by the water-absorbing-retaining function of pore structure, the present invention.
Invention content
It is an object of the present invention to provide a kind of hydrogel filament mask substrates.
In order to achieve the above objectives, the technical solution adopted by the present invention is：A kind of hydrogel filament mask substrate, including walking as follows Suddenly：
A kind of hydrogel filament mask substrate, which is characterized in that the long filament is regenerated silk fibroin hydrogel filament, and long filament is straight Diameter is at 5-500 μm.
In above-mentioned technical proposal, the preparation process of hydrogel filament mask substrate includes the following steps：
(1) boiled silk is dissolved in solion, be stirred at room temperature, be prepared into gellike shape solution.
(2) step (1) solution is poured into spinning liquid bath, spinning solution constant speed from spinneret orifice squeezes out, in coagulating bath directly It is prepared into hydrogel filament.
(3) the direct lapping of hydrogel filament, spun lacing, formation mask substrate.
In above-mentioned technical proposal, the boiled silk dissolution system solion is acid/shell solution；Acid is formic acid, phosphorus Acid etc.；Shell is one kind or more in the sea shells such as pearl shell, scallop shell, CONCHA MERETRICID SEU CYCLINAE, mussel shell, oyster shell, conch shell Kind.
In above-mentioned technical proposal, the mass fraction of shell is 0.1%-30% in the acid/shell solution；Silk in spinning solution Fibroin mass fraction is 5%-40%；The extruded velocity of spinning solution is 0.1mL/min-10mL/min；Spinneret orifice (endoporus) is straight Diameter is 0.1-1.0mm.
In above-mentioned technical proposal, the coagulating bath is water.
In above-mentioned technical proposal, the lapping mode is vertical bidirectional lapping；10-100 grams/square of mask substrate grammes per square metre Rice.
Compared with prior art, the advantages and positive effects of the present invention are：
Inventive gel long filament mask substrate using gel absorbing and holding water property, solves high beauty treatment fluid load well The problem of, while hydrogel filament mask substrate provided by the invention is simple in structure, is easy to make, and it is highly practical, have great Market popularization value.
Description of the drawings：
Long filament shape appearance figure in 1 mask substrate of attached drawing
Specific embodiment
The present invention is further described with reference to embodiment：
Embodiment one
1. take 10g shell room-temperature dissolutions in formic acid solution, be prepared into formic acid/shell that 100g mass fractions are 10% from Sub- solution.
2. boiled silk 20g is taken to be dissolved in formic acid/shell solion, it is prepared into silk fibroin protein solution.
3. silk fibroin protein solution is poured into spinning liquid bath, using 0.5mL/min by solution from spinneret orifice (internal diameter 0.5mm) Constant speed squeezes out, and aqueous solution is used directly to be prepared into hydrogel filament for coagulating bath.
4. hydrogel filament straight forming, and the direct lapping of vertical bidirectional in aqueous solution, then spun lacing, directly forms gel Long filament mask substrate.
Embodiment two
1. take 20g shell room-temperature dissolutions in phosphoric acid solution, be prepared into formic acid/shell that 100g mass fractions are 20% from Sub- solution.
2. boiled silk 30g is taken to be dissolved in phosphoric acid/shell solion, it is prepared into silk fibroin protein solution.
3. silk fibroin protein solution is poured into spinning liquid bath, using 1.0mL/min by solution from spinneret orifice (internal diameter 0.9mm) Constant speed squeezes out, and aqueous solution is used directly to be prepared into hydrogel filament for coagulating bath.
4. hydrogel filament straight forming, and the direct lapping of vertical bidirectional in aqueous solution, then spun lacing, directly forms gel Long filament mask substrate.
Embodiment three
1. taking 5g shell room-temperature dissolutions in formic acid solution, it is prepared into formic acid/shell ion that 50g mass fractions are 10% Solution.
2. boiled silk 15g is taken to be dissolved in formic acid/shell solion, it is prepared into silk fibroin protein solution.
3. silk fibroin protein solution is poured into spinning liquid bath, using 0.5mL/min by solution from spinneret orifice (internal diameter 0.9mm) Constant speed squeezes out, and aqueous solution is used directly to be prepared into hydrogel filament for coagulating bath.
4. hydrogel filament straight forming, and the direct lapping of vertical bidirectional in aqueous solution, then spun lacing, directly forms gel Long filament mask substrate.
Fig. 1 is the scanning electron microscope (SEM) photograph of long filament in hydrogel filament mask substrate in embodiment, it can be seen from the figure that long filament Even thickness, surface is more smooth, because spun lacing is processed, long filament mutually tangles, it is therefore prevented that mask substrate long filament in use It comes off.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to etc. to replace or change, and should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of hydrogel filament mask substrate, which is characterized in that the long filament be regenerated silk fibroin hydrogel filament, filament diameter At 5-500 μm.
2. hydrogel filament mask substrate according to claim 1, which is characterized in that preparation process includes the following steps：
(1) boiled silk is dissolved in solion, be stirred at room temperature, be prepared into gellike shape solution.
(2) step (1) solution is poured into spinning liquid bath, spinning solution constant speed from spinneret orifice squeezes out, and is directly prepared in coagulating bath Into hydrogel filament.
(3) the direct lapping of hydrogel filament, spun lacing, formation mask substrate.
3. hydrogel filament mask substrate according to claim 2, which is characterized in that the boiled silk dissolution system ion Solution is acid/shell solution；Acid is formic acid, phosphoric acid etc.；Shell for pearl shell, scallop shell, CONCHA MERETRICID SEU CYCLINAE, mussel shell, oyster shell, It is one or more in the sea shells such as conch shell.
4. hydrogel filament mask substrate according to claim 2, which is characterized in that shell in the acid/shell solution Mass fraction is 0.1%-30%；Fibroin albumen quality score is 5%-40% in spinning solution；The extruded velocity of spinning solution is 0.1mL/min-10mL/min；Spinneret orifice (endoporus) a diameter of 0.1-1.0mm.
5. hydrogel filament mask substrate according to claim 2, which is characterized in that the coagulating bath is water.
6. hydrogel filament mask substrate according to claim 2, which is characterized in that the lapping mode is spread for vertical bidirectional Net；10-100 grams/m of mask substrate grammes per square metre.
CN201810044901.9A 2018-01-17 2018-01-17 A kind of hydrogel filament mask substrate Pending CN108149387A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810044901.9A CN108149387A (en) 2018-01-17 2018-01-17 A kind of hydrogel filament mask substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810044901.9A CN108149387A (en) 2018-01-17 2018-01-17 A kind of hydrogel filament mask substrate

Publications (1)

Publication Number Publication Date
CN108149387A true CN108149387A (en) 2018-06-12

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CN201810044901.9A Pending CN108149387A (en) 2018-01-17 2018-01-17 A kind of hydrogel filament mask substrate

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113186659A (en) * 2021-04-23 2021-07-30 中国纺织科学研究院有限公司 Preparation method and equipment of cellulose filament non-woven fabric

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5937977A (en) * 1982-08-25 1984-03-01 伊藤忠商事株式会社 Silk bedding cotton
CN102560902A (en) * 2012-01-12 2012-07-11 天津工业大学 Method for producing viscose cellulose spun-laid nonwoven
CN103173882A (en) * 2013-04-11 2013-06-26 大连海事大学 Method for preparing graphene/ silk composite fiber
CN104436285A (en) * 2014-12-12 2015-03-25 苏州大学 Regenerated silk fibroin gel mask and preparation method thereof
CN104611840A (en) * 2015-02-13 2015-05-13 上海特安纶纤维有限公司 Flocculus made of mixed polymer fiber containing aromatic polyamide and polyarylsulfone and preparation method thereof
CN105437667A (en) * 2016-01-08 2016-03-30 清华大学 Preparation method of composite base material for facial masks
CN106726681A (en) * 2016-12-15 2017-05-31 浙江大学 A kind of method that sericin prepares mask sheet
CN106928729A (en) * 2017-03-27 2017-07-07 广西科技大学 A kind of nanometer silver antimicrobial regenerated silk fibroin material and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5937977A (en) * 1982-08-25 1984-03-01 伊藤忠商事株式会社 Silk bedding cotton
CN102560902A (en) * 2012-01-12 2012-07-11 天津工业大学 Method for producing viscose cellulose spun-laid nonwoven
CN103173882A (en) * 2013-04-11 2013-06-26 大连海事大学 Method for preparing graphene/ silk composite fiber
CN104436285A (en) * 2014-12-12 2015-03-25 苏州大学 Regenerated silk fibroin gel mask and preparation method thereof
CN104611840A (en) * 2015-02-13 2015-05-13 上海特安纶纤维有限公司 Flocculus made of mixed polymer fiber containing aromatic polyamide and polyarylsulfone and preparation method thereof
CN105437667A (en) * 2016-01-08 2016-03-30 清华大学 Preparation method of composite base material for facial masks
CN106726681A (en) * 2016-12-15 2017-05-31 浙江大学 A kind of method that sericin prepares mask sheet
CN106928729A (en) * 2017-03-27 2017-07-07 广西科技大学 A kind of nanometer silver antimicrobial regenerated silk fibroin material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113186659A (en) * 2021-04-23 2021-07-30 中国纺织科学研究院有限公司 Preparation method and equipment of cellulose filament non-woven fabric

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Application publication date: 20180612

RJ01 Rejection of invention patent application after publication