CN108131563A - A kind of hydride hydrogen-storing cylinder with helical structure - Google Patents
A kind of hydride hydrogen-storing cylinder with helical structure Download PDFInfo
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- CN108131563A CN108131563A CN201711172735.2A CN201711172735A CN108131563A CN 108131563 A CN108131563 A CN 108131563A CN 201711172735 A CN201711172735 A CN 201711172735A CN 108131563 A CN108131563 A CN 108131563A
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- Prior art keywords
- hydrogen
- helical structure
- alloy powder
- bearing alloy
- structure part
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/012—Hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
The invention discloses a kind of hydride hydrogen-storing cylinder with helical structure, including tank body, gas-guide tube, helical structure part, hydrogen-bearing alloy powder etc..By setting helical structure part in tank body, it can effectively enhance the heat transfer of hydrogen-bearing alloy powder bed body in hydride hydrogen-storing cylinder first, improve the discharge charge hydrogen performance of hydride hydrogen-storing cylinder;Secondly, when hydrogen-bearing alloy powder loads, helical structure part can make hydrogen-bearing alloy powder full and uniform, during hydride hydrogen-storing cylinder use, helical structure part plays hydrogen-bearing alloy powder fixed supporting role again, the localized clusters of hydrogen storing alloy powder are prevented, avoids hydride hydrogen-storing cylinder local stress excessive and excessive plastic deformation occurs and even ruptures, to improve the safety of hydride hydrogen-storing cylinder and service life.
Description
Technical field
The invention belongs to the hydrogen storage technology fields of Hydrogen Energy, particularly, are related to a kind of metal hydride with helical structure
Hydrogen container.
Background technology
At present, with the aggravation of energy crisis and the reinforcement of environmental consciousness, the utilization of Hydrogen Energy is more and more widely closed
Note, the storage of wherein hydrogen is one of major technology bottleneck in Hydrogen Energy in practical process
In the prior art there are mainly three types of more practical hydrogen storage modes:High-pressure bottle hydrogen storage (such as steel cylinder), low temperature liquid hydrogen
Storage tank (cooled cryostat tank) and metal hydride solid-state hydrogen storage.Metal hydride solid-state hydrogen storage technology therein is to utilize hydrogen
With the storage reacted to realize hydrogen of hydrogen bearing alloy, compared with other hydrogen storage modes, with hydrogen-storage density height, pressure is low, pacifies
The advantages that good perfection, high hydrogen purity is an important directions of hydrogen storage technology development.
But also there are following technical bottlenecks for metal hydride solid-state hydrogen storage technology at present:
1) dusting, which occurs, for hydrogen bearing alloy influences the heat transfer property of hydrogen container.Hydrogen bearing alloy generates amount of heat when inhaling hydrogen, puts
Amount of heat need to be absorbed from outside during hydrogen, and temperature then seriously affects suction/hydrogen discharging rate of hydrogen bearing alloy;In addition hydrogen bearing alloy exists
Violent lattice dilatation/contraction can be occurred in the process by inhaling/put hydrogen so that dusting occurs for hydrogen bearing alloy, hydrogen storage is caused to be closed after dusting
The heat transfer property of gold is very poor (its efficient thermal conductivity is about 1W/m/K or so) so that the hydrogen storage inside hydride hydrogen-storing cylinder is closed
The heat transfer of bronze end bed body is one of principal element for influencing hydrogen container performance.
2) localized clusters of hydrogen-bearing alloy powder easily cause hydrogen container safety accident.In hydrogen bearing alloy expansion/contraction and again
Under the action of power so that hydrogen-bearing alloy powder can be settled gradually, this will cause hydrogen-bearing alloy powder certain in hydrogen container
Position is gathered, and the hydrogen bearing alloy of aggregation can apply great stress when inhaling hydrogen-expansion to tank body, tank body will be caused to occur excessive
Plastic deformation even ruptures, and causes safety accident.
Occurs the above problem in order to prevent, first should improve the heat exchange property of hydrogen-bearing alloy powder bed body, to ensure metal
The quick progress of hydrogen is inhaled/put to hydride hydrogen storage tank;Second should prevent localized clusters of the hydrogen-bearing alloy powder in hydrogen container, with true
It protects hydrogen-bearing alloy powder to be uniformly distributed in tank body, prevents stress is excessive from leading to tank body excessive deformation, ensure safety in utilization
And the service life.
Invention content
To solve the above problems, the object of the present invention is to provide a kind of hydride hydrogen-storing cylinders with helical structure.
The hydride hydrogen-storing cylinder is internally provided with helical structure part, which primarily serves effective work of two aspects
With:1) effect of heat exchange structure is played, the heat transfer property of hydrogen-bearing alloy powder bed body is improved, improves hydride hydrogen-storing cylinder
Discharge charge hydrogen performance;2) when hydrogen-bearing alloy powder loads, by rotating helical structure part, it is sufficiently stirred hydrogen-bearing alloy powder,
Ensure distributing homogeneity of the hydrogen-bearing alloy powder during filling, during hydrogen container use, helical structure part can rise again
To the fixation supporting role of hydrogen-bearing alloy powder, prevent from leading to the part of hydrogen storing alloy powder due to expansion/contraction when inhaling/put hydrogen
Aggregation, makes hydrogen-bearing alloy powder be always maintained at uniform distribution, avoids hydride hydrogen-storing cylinder due to local stress is excessive
Excessively plastic deformation even ruptures for generation, safety and service life during guarantee hydride hydrogen-storing cylinder long-time service.
The technical solution adopted by the present invention is a kind of hydride hydrogen-storing cylinder with helical structure, including tank body 2,
Gas-guide tube 3, hydrogen-bearing alloy powder 1, filter 5 and valve 6, which is characterized in that the hydrogen container further includes helical structure part 4.
Preferably, the gas-guide tube 3 is axially arranged on 2 inner hub location of tank body, for ensureing hydrogen in the storage
It is unimpeded in hydrogen alloy powder 1;The helical structure part 4 is placed in inside the tank body 2, is set along the gas-guide tube 3 is axial, described
Helical structure part 4 is set in horizontal direction on the whole, and fixed supporting role is played to the hydrogen-bearing alloy powder 1;The hydrogen storage
Alloy powder 1 is filled between the helical structure part 4 and the tank body 2.
Preferably, the tank body 2 is welded by stainless steel seamless pipe and end socket, outer diameter 90-110mm;Wall thickness 3-
4mm;The long 400-600mm of straight drum part;Overall length is 480-680mm.
Preferably, the outer diameter of the helical structure part 4 is 80-100mm, and is set smaller than the internal diameter of tank body 2.
Preferably, the outer diameter of the gas-guide tube 3 is 10-15mm;Wall thickness is 2-5mm;Filtering accuracy is 2-3 μm.
Preferably, the central diameter of the helical structure part 4 is 10-15mm, and is arranged to the outer diameter with the gas-guide tube 3
Unanimously.
Preferably, metal of the material of the helical structure part 4 for high heat conductance, thickness 1-2mm, screw pitch 40-
60mm。
Preferably, the material of the helical structure part 4 is aluminium, copper, aluminium alloy or copper alloy.
Preferably, the hydrogen-bearing alloy powder 1 be Rare Earth AB5 types, titanium system AB types, titanium system AB2 types or titanium vanadium solid solution,
The total weight of the hydrogen-bearing alloy powder 1 is 10-15kg.
Preferably, 5 thickness of filter is 0.8-1.2mm;Filtering accuracy is 0.4-0.5 μm.
The advantageous effect of present invention is that:
1) hydrogen container of the invention is simple in structure, manufactures handling ease;
2) the helical structure part of hydrogen container of the invention plays the role of enhancing heat transfer, can effectively improve hydrogen-bearing alloy powder
The heat transfer efficiency of bed body improves the discharge charge hydrogen performance of hydrogen container;
3) hydrogen container of the invention passes through helical structure part clockwise/counterclockwise during hydrogen-bearing alloy powder filling
Be alternately rotated, it is ensured that hydrogen-bearing alloy powder is uniformly distributed;
4) in use, helical structure part plays hydrogen-bearing alloy powder fixed support and makees hydrogen container of the invention
With hydrogen-bearing alloy powder is made to be always maintained at uniform distribution, avoids its localized clusters, avoids hydrogen container excessive because of local stress
And excessive plastic deformation occurs and even ruptures, ensure safety and service life.
Description of the drawings
Fig. 1 is a kind of cross-sectional view of the structure of hydride hydrogen-storing cylinder with helical structure of the present invention;
Fig. 2 is the helical structure part and gas-guide tube of a kind of hydride hydrogen-storing cylinder with helical structure of the present invention
Structure diagram;
Fig. 3 is the preferred embodiment and the prior art of a kind of hydride hydrogen-storing cylinder with helical structure of the present invention
In without the hydride hydrogen-storing cylinder of helical structure be flushed with hydrogen curve comparison figure;
Fig. 4 is the preferred embodiment and the prior art of a kind of hydride hydrogen-storing cylinder with helical structure of the present invention
In without helical structure hydride hydrogen-storing cylinder strain curve comparison diagram;
Wherein reference numeral is in figure:
1- hydrogen-bearing alloy powders, 2- tank bodies, 3- gas-guide tubes, 4- helical structure parts, 5- filters, 6- valves.
Specific embodiment
To make the purpose, technical scheme and advantage that the present invention is implemented clearer, below in conjunction in the embodiment of the present invention
Attached drawing, the technical solution in the embodiment of the present invention is further described in more detail.In the accompanying drawings, identical from beginning to end or class
As label represent same or similar element or the element with same or like function.Described embodiment is the present invention
Part of the embodiment, instead of all the embodiments.The word of embodiment and directionality below with reference to attached drawing description
It is exemplary, it is intended to for explaining the present invention, and be not considered as limiting the invention.Based on the implementation in the present invention
Example, those of ordinary skill in the art's all other embodiments obtained without creative efforts, belongs to
The scope of protection of the invention.
In the broad embodiment of the present invention, a kind of hydride hydrogen-storing cylinder with helical structure, including tank
Body, gas-guide tube, helical structure part, hydrogen-bearing alloy powder, filter and valve etc., wherein,
Tank body is axially extending conventional structure;
Gas-guide tube is axially arranged on tank interior center, for ensureing that hydrogen is unimpeded in hydrogen-bearing alloy powder;
Helical structure part is placed in tank interior, is axially set along gas-guide tube, helical structure part is set in horizontal direction on the whole
It puts, fixed supporting role is played to hydrogen-bearing alloy powder;
Hydrogen-bearing alloy powder is filled between helical structure part and tank body;
Filter is arranged on the top exit position of tank body, for hydrogen-bearing alloy powder to be avoided to flow out hydrogen container with hydrogen;
Valve is arranged on outside tank body, for controlling the hydrogen of disengaging gas-guide tube.
Below in conjunction with the accompanying drawings to a preferred embodiment of the present invention will be described in detail.
As illustrated in fig. 1 and 2, a kind of hydride hydrogen-storing cylinder with helical structure, including tank body 2, gas-guide tube 3, spiral
Structural member 4, hydrogen-bearing alloy powder 1, filter 5 and valve 6 etc..Wherein,
Tank body 2 is welded by stainless steel seamless pipe and end socket, outer diameter 90-110mm, it is therefore preferable to 108mm;Wall thickness 3-
4mm, it is therefore preferable to 3.5mm;The long 400-600mm of straight drum part, it is therefore preferable to 500mm;Overall length is 480-680mm, it is therefore preferable to
580mm。
Gas-guide tube 3 is axially arranged on 2 inner hub location of tank body, outer diameter 10-15mm, it is therefore preferable to 12mm;Wall thickness is
2-5mm, it is therefore preferable to 3mm;Filtering accuracy is 2-3 μm, it is therefore preferable to 2.5 μm.
Helical structure part 4 is placed in inside tank body 2, is set, is set in horizontal direction on the whole, spiral along gas-guide tube 3 is axial
The material of structural member 4 is the high heat conductivity metals such as aluminium, copper, aluminium alloy, copper alloy, it is therefore preferable to fine aluminium;Thickness is 1-2mm, excellent
Selection of land is 1.5mm;Screw pitch is 40-60mm, it is therefore preferable to 50mm;Outer diameter is 80-100mm, it is therefore preferable to 100mm, helical structure
The outer diameter of part 4 is arranged to the internal diameter of slightly smaller than tank body 2;Central diameter is 10-15mm, it is therefore preferable to which 12mm ensures and gas-guide tube 3
It is fitted close.
Hydrogen-bearing alloy powder 1 is filled between helical structure part 4 and tank body 2, it is therefore preferable to Rare Earth AB5 types, titanium system AB
Type, titanium system AB2 types, titanium vanadium solid solution etc., wherein titanium system AB2 types preferably (TiZr) 1 (VFeCrMn) 2, hydrogen-bearing alloy powder
1 total weight is 10-15kg, it is therefore preferable to 14kg.
5 thickness of filter is 0.8-1.2mm, it is therefore preferable to 1mm;Filtering accuracy is 0.4-0.5 μm, it is therefore preferable to 0.5 μm.
It should be recognized that the above-mentioned dimensional parameters in relation to tank body 2, gas-guide tube 3, helical structure part 4 and filter 5 are only to show
Example, and it is not construed as any limitation of the invention.
It is test helical structure part to the beneficial effect of hydride hydrogen-storing cylinder, to the present invention with helical structure
The preferred embodiment of the hydride hydrogen-storing cylinder hydride hydrogen-storing cylinder without helical structure identical with size therewith
It is flushed with hydrogen maximum strain amount of the centre position of performance and tank body during being repeatedly flushed with hydrogen and has carried out contrast test, respectively as schemed
Shown in 3 and Fig. 4.
Fig. 3 is to be flushed with hydrogen curve comparison schematic diagram.
In the contrast test, two hydrogen containers are flushed with hydrogen that condition is identical, and it is 4.2Mpa that maximum, which is flushed with hydrogen pressure, in phase
With being flushed with hydrogen under pressure condition, the speed that is flushed with hydrogen of the hydride hydrogen-storing cylinder with helical structure of the invention is significantly greater than same ruler
The very little hydride hydrogen-storing cylinder without helical structure illustrates that the helical structure part can effectively improve hydride hydrogen-storing
The performance of tank, this is primarily due to the addition of helical structure part, improves the heat transfer property of hydrogen-bearing alloy powder bed body in hydrogen container.
Fig. 4 is the maximum strain correlation curve schematic diagram during being flushed with hydrogen at first 10 times.
In the contrast test, two hydrogen containers are flushed with hydrogen that condition is identical, and it is 4.2MPa that maximum, which is flushed with hydrogen pressure, in phase
With being flushed with hydrogen under pressure condition, the strain with the hydride hydrogen-storing cylinder tank body without helical structure of size becomes larger, this
Hydrogen-bearing alloy powder is primarily due to during inhaling/putting hydrogen because expansion/contraction leads to further dusting, while in the work of gravity
With lower gradually lower aggregation, increase so as to cause strain, and the hydride hydrogen-storing cylinder tank with helical structure of the present invention
The strain of body is kept approximately constant during being flushed with hydrogen for several times, illustrates that helical structure part plays centainly hydrogen-bearing alloy powder
Fixed supporting role can make hydrogen-bearing alloy powder be always maintained at initial uniform distribution, therefore should disappearing of being subject to of tank body
There is apparent increase.
It is last it is to be noted that:The present invention is described in detail above, its object is to allow be familiar with this field skill
The personage of art can understand present disclosure and be implemented, and it is not intended to limit the scope of the present invention, and this hair
Bright to be not limited to the above embodiments, the equivalent change or modification that all Spirit Essences according to the present invention are made should all cover at this
Within the protection domain of invention.
Claims (10)
1. a kind of hydride hydrogen-storing cylinder with helical structure, including tank body (2), gas-guide tube (3), hydrogen-bearing alloy powder
(1), filter (5) and valve (6), which is characterized in that the hydrogen container further includes helical structure part (4).
2. hydrogen container according to claim 1, which is characterized in that the gas-guide tube (3) is axially arranged in tank body (2)
Portion center, for ensureing that hydrogen is unimpeded in the hydrogen-bearing alloy powder (1);The helical structure part (4) is placed in described
Tank body (2) is internal, is axially set along the gas-guide tube (3), the helical structure part (4) is set in horizontal direction on the whole, right
The hydrogen-bearing alloy powder (1) plays fixed supporting role;The hydrogen-bearing alloy powder (1) is filled in the helical structure part
(4) between the tank body (2).
3. hydrogen container according to claim 1, which is characterized in that the tank body (2) is welded by stainless steel seamless pipe and end socket
It connects, outer diameter 90-110mm;Wall thickness 3-4mm;The long 400-600mm of straight drum part;Overall length is 480-680mm.
4. hydrogen container according to claim 3, which is characterized in that the outer diameter of the helical structure part (4) is 80-100mm,
And it is set smaller than the internal diameter of tank body (2).
5. hydrogen container according to claim 1, which is characterized in that the outer diameter of the gas-guide tube (3) is 10-15mm;Wall thickness
For 2-5mm;Filtering accuracy is 2-3 μm.
6. hydrogen container according to claim 5, which is characterized in that the central diameter of the helical structure part (4) is 10-
15mm, and be arranged to consistent with the outer diameter of the gas-guide tube (3).
7. the hydrogen container according to claim 4 or 6, which is characterized in that the material of the helical structure part (4) is highly thermally conductive
The metal of rate, thickness 1-2mm;Screw pitch is 40-60mm.
8. hydrogen container according to claim 7, which is characterized in that the material of the helical structure part (4) is aluminium, copper, aluminium
Alloy or copper alloy.
9. hydrogen container according to claim 1, which is characterized in that the hydrogen-bearing alloy powder (1) for Rare Earth AB5 types,
Titanium system AB types, titanium system AB2 types or titanium vanadium solid solution, the total weight of the hydrogen-bearing alloy powder (1) is 10-15kg.
10. hydrogen container according to claim 1, which is characterized in that filter (5) thickness is 0.8-1.2mm;Filtering
Precision is 0.4-0.5 μm.
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CN201711172735.2A CN108131563B (en) | 2017-11-22 | 2017-11-22 | Metal hydride hydrogen storage tank with spiral structure |
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CN201711172735.2A CN108131563B (en) | 2017-11-22 | 2017-11-22 | Metal hydride hydrogen storage tank with spiral structure |
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CN108131563B CN108131563B (en) | 2020-05-26 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111195808A (en) * | 2020-02-18 | 2020-05-26 | 扬州大学 | Method for manufacturing metal hydride hydrogen storage tank |
CN112066242A (en) * | 2020-08-07 | 2020-12-11 | 太原科技大学 | Solid hydrogen source device for hydrogen fuel |
CN113277467A (en) * | 2021-04-26 | 2021-08-20 | 山东大学 | Hydrogen storage alloy reaction bed device and using method and application thereof |
CN117006401A (en) * | 2023-07-07 | 2023-11-07 | 惠州市华达通气体制造股份有限公司 | Solid hydrogen storage member, apparatus and method for manufacturing solid hydrogen storage member |
CN117267611A (en) * | 2023-09-27 | 2023-12-22 | 广东佳邑新能源科技有限公司 | Efficient and uniform reaction metal hydride hydrogen storage bottle and use method thereof |
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CN117267611A (en) * | 2023-09-27 | 2023-12-22 | 广东佳邑新能源科技有限公司 | Efficient and uniform reaction metal hydride hydrogen storage bottle and use method thereof |
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