CN108130712A - A kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent - Google Patents
A kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent Download PDFInfo
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- CN108130712A CN108130712A CN201711492605.7A CN201711492605A CN108130712A CN 108130712 A CN108130712 A CN 108130712A CN 201711492605 A CN201711492605 A CN 201711492605A CN 108130712 A CN108130712 A CN 108130712A
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- fermentation
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 33
- 239000000675 fabric finishing Substances 0.000 title claims abstract description 27
- 238000009962 finishing (textile) Methods 0.000 title claims abstract description 27
- 239000002028 Biomass Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 48
- 238000000855 fermentation Methods 0.000 claims abstract description 45
- 230000004151 fermentation Effects 0.000 claims abstract description 45
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 28
- 239000010936 titanium Substances 0.000 claims abstract description 28
- 239000000701 coagulant Substances 0.000 claims abstract description 17
- 239000000706 filtrate Substances 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- 230000001954 sterilising effect Effects 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 230000010355 oscillation Effects 0.000 claims description 14
- 238000004659 sterilization and disinfection Methods 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229910001220 stainless steel Inorganic materials 0.000 claims description 11
- 239000010935 stainless steel Substances 0.000 claims description 11
- 235000011201 Ginkgo Nutrition 0.000 claims description 9
- 241000218628 Ginkgo Species 0.000 claims description 9
- 235000008100 Ginkgo biloba Nutrition 0.000 claims description 9
- 244000068988 Glycine max Species 0.000 claims description 9
- 235000010469 Glycine max Nutrition 0.000 claims description 9
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 8
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 8
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 7
- 229960000583 acetic acid Drugs 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 240000006365 Vitis vinifera Species 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 17
- 239000004744 fabric Substances 0.000 abstract description 16
- 150000001413 amino acids Chemical class 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- -1 polyphenol compound Chemical class 0.000 abstract description 4
- 235000013824 polyphenols Nutrition 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 239000012620 biological material Substances 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 239000002105 nanoparticle Substances 0.000 abstract description 2
- 230000002688 persistence Effects 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 description 7
- 241000219095 Vitis Species 0.000 description 6
- 210000003491 skin Anatomy 0.000 description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 108010022355 Fibroins Proteins 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 235000003846 Ricinus Nutrition 0.000 description 1
- 241000322381 Ricinus <louse> Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to the preparation methods that a kind of biomass ferment is modified Anti-ultraviolet true silk fabric finishing agent, belong to fabric finishing agent preparing technical field.The present invention uses tetra-n-butyl titanate to prepare monocrystalline Detitanium-ore-type TiO using the synthesis technology of colloidal sol hydro-thermal as titanium source presoma2The coagulant liquid of nano particle, then the biological material rich in polyphenol compound and amino acid is selected, greenhouse is put into after being pulverized and mixed, naturally it is mouldy in the environment of high temperature and humidity, again mouldy object and water-stop are fermented to obtain ferment filtrate, ferment filtrate is recycled to carry out fermentation modification to titania gel liquid, finally obtained Silk Fabric Finishing agent, biomass ferment produced by the present invention, which is modified Anti-ultraviolet true silk fabric finishing agent, has splendid UVResistant effect, and the adhesion-tight degree between finishing agent and fabric is high, it still will not fall off after washing repeatedly, still there is splendid UVResistant effect, and uvioresistant persistence is high, it has broad application prospects.
Description
Technical field
The present invention relates to the preparation methods that a kind of biomass ferment is modified Anti-ultraviolet true silk fabric finishing agent, and it is whole to belong to fabric
Manage agent preparing technical field.
Background technology
Silk refers generally to silk, including mulberry silk, tussah silk, ricinus silk, cassava silkwormsilk etc..Silk is referred to as " fiber
Queen " is favored with its unique glamour by people through the ages.Silk belongs to protein fibre, contains 18 kinds in fibroin
The amino acid beneficial to human body can help skin to maintain the metabolism of surface adipose membrane, therefore skin can be made to keep moist, light
It is sliding.Real silk fabric can enhance the vigor of skin surface cell, promote the metabolism of Skin Cell, fibroin fiber enrichment
Many amidos（-CHNH）, amino（-NH2）Hydrophilic radicals are waited, and due to its porosity, be easy to water diffusion, so it
Moisture can be absorbed in air or distribute moisture, and keep certain moisture.Under normal temperature, it can help skin to possess
Certain moisture does not make skin excessively dry；It is worn in summer, and the sweat and heat that can discharge human body distribute rapidly, make
People feels nice and cool incomparable.Just because of this performance, make silk fabric more suitable for being in direct contact with human skin, real silk fabric
With excellent skin-friendly.
However, cocoon fiber is to sunlight UV radiation-sensitive, although itself has faint uvioresistant performance, so
And under sunlight irradiation, real silk fabric will be by irreversible damage.Modern society for silk needs not only
It is limited to indoor wear, as a large amount of silk dress ornaments use outdoors, people seem more for the efficient uvioresistant performance of silk
Urgently.In order to overcome this problem, many methods have been used to influence the anti-ultraviolet property of silk.
Nano-TiO2As a kind of important N-type semiconductor material, since its special performance causes it in various fields,
Such as catalysis, solar cell, chemical sensor, UV absorption and opto-electronic device etc. have a wide range of applications.But it passes
Nano-titanium dioxide surface-active functional group's quantity of system is few, easily reunites between each other, bad dispersibility, and and real silk fabric
Between compatibility it is poor, adhesion-tight degree is low, and washability is poor, easily comes off, and uvioresistant timeliness is caused to be lower, and therefore, invention is a kind of
Good dispersion and compatibility is good between real silk fabric, the high novel Silk Fabric Finishing agent of uvioresistant timeliness have positive meaning
Justice.
Invention content
Present invention mainly solves the technical issues of, arranged for current titanium dioxide as most common anti-UV fabric
Agent, surface-active functional group's quantity is few, easily reunites between each other, bad dispersibility, and the compatibility between real silk fabric
Difference, adhesion-tight degree is low, easily comes off, the defects of uvioresistant timeliness is caused to be lower, provide a kind of biomass ferment be modified it is anti-
The preparation method of ultraviolet Silk Fabric Finishing agent.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent, it is characterised in that specific preparation process
For：
（1）Sonic oscillation instrument is poured into after tetra-n-butyl titanate and absolute ethyl alcohol are mixed, sonic oscillation handles 3~5min and obtains titanium
Source liquid adjusts pH to 2~3 with glacial acetic acid again after mixing deionized water and absolute ethyl alcohol, obtains mixed liquor；
（2）Above-mentioned mixed liquor is fitted into the three-necked flask with blender and dropping funel, then adds in and mixes into dropping funel
The isometric titanium source liquid of liquid is closed, starts blender and is stirred with the rotating speed of 400~500r/min, while stirring to by titanium source liquid
It instills in mixed liquor dropwise, continues 40~50min of stirring after titanium source liquid is added dropwise, obtain coagulant liquid, it is spare；
（3）It weighs tealeaves, ginkgo, Fructus Forsythiae and soybean and crushes 20~30min, obtain crushed material, crushed material and grape wine are mixed
After be laid in stainless steel pallet, stainless steel pallet is put into greenhouse, stand mouldy 5~6 days, obtain mouldy object；
（4）It is fitted into fermentation tank after mouldy object and deionized water are mixed, is sealed by fermentation, is separated by filtration is sent out after fermentation
Ferment filtrate is again loaded into clean fermentation tank after immediately mixing ferment filtrate and spare coagulant liquid, continues to be sealed by fermentation；
（5）Treat it is above-mentioned take out tunning after fermentation, be put into high-temperature sterilization furnace, high-temperature sterilization, sterilizing and is gone product
30~40min of ultrasonic disperse after ionized water mixing, discharges and is modified Anti-ultraviolet true silk fabric finishing agent up to biomass ferment.
Step（1）Described in tetra-n-butyl titanate and absolute ethyl alcohol mass ratio be 1:3, the frequency of sonic oscillation processing
For 25~30kHz, the volume ratio of deionized water and absolute ethyl alcohol is 1:3.
Step（3）Described in tealeaves, ginkgo, Fructus Forsythiae and the mass ratio of soybean be 5:3:2:1, crushed material and grape wine
Mass ratio is 3:1, the temperature in greenhouse is 40~45 DEG C, and relative air humidity is 60~70%.
Step（4）Described in mouldy object and deionized water mass ratio be 1:3, the temperature of sealing and fermenting is 35~45
DEG C, the time of sealing and fermenting is 7~9 days, and the mass ratio of ferment filtrate and coagulant liquid is 1:5, continue be sealed by fermentation temperature be
30~35 DEG C, it is 2~3 days to continue the time being sealed by fermentation.
Step（5）Described in high-temperature sterilization temperature for 120~130 DEG C, the time of high-temperature sterilization is 10~15min,
Sterilizing product and the mass ratio of deionized water are 1:3, the power of ultrasonic disperse is 200~300W.
The beneficial effects of the invention are as follows：
The present invention uses tetra-n-butyl titanate that it is sharp to prepare monocrystalline using the synthesis technology of Sol-Hydrothermal as titanium source presoma
Titanium ore type TiO2The coagulant liquid of nano particle then selects the biological material rich in polyphenol compound and amino acid, by it
Greenhouse is put into after being pulverized and mixed, it is naturally mouldy in the environment of high temperature and humidity, then mouldy object and water-stop are fermented
Filtrate recycles ferment filtrate to carry out fermentation modification to titania gel liquid, finally obtained Silk Fabric Finishing agent, wherein originally
It is all the organic matter rich in a large amount of polyphenol compounds and amino acid to invent biomass tealeaves, ginkgo, Fructus Forsythiae and the soybean selected,
It degrades first with mould microorganism to the polyphenol compound in biomass and amino acid, it is a large amount of free so as to generate
Property aromatic group, amino group and other active groups are dissolved in ferment filtrate, these free property aromatic group, amino groups
Nano-silica in coagulant liquid can be introduced in later stage of other active groups in fermentation under the self-crosslinking in microorganism again
Change the surface of titanium particle, so that titanium dioxide granule surface aromatic group, amino group and other work that fermentation is modified
Property radical amount increase, wherein aromatic group is introduced into titanium dioxide surface as non-polar group can reduce titanium dioxide
Surface polarity, so as to reduce titanium dioxide surface energy, in addition the preliminary agglomeration for reducing nano-titanium dioxide also has a large amount of living
Property group introducing, these groups, which introduce, can increase the steric hindrance on nano-titanium dioxide surface, reduce nanometer two again
The agglomeration of titanium oxide, additionally, due to cocoon fiber surface enrichment many amino and hydroxyl, the application introduce these
With the amino and hydroxyl on cocoon fiber surface Hydrogen Binding Adsorption and other Chemical bondings can also occur for active group, so as to make
The cohesive force obtained between finishing agent and cocoon fiber of the invention is improved, and is knitted so as to greatly improve finishing agent in silk
The adhesion-tight degree on object surface, washability is good, and the amino and the amino on real silk fabric surface that nano-titanium dioxide surface introduces
Compatibility is extremely strong, therefore also improves the compatibility between fabric finishing agent and real silk fabric simultaneously, before having wide application
Scape.
Specific embodiment
It is 1 in mass ratio:3 will pour into sonic oscillation instrument after tetra-n-butyl titanate and absolute ethyl alcohol mixing, with 25~30kHz
3~5min of frequency ultrasound oscillation treatment obtain titanium source liquid, be 1 by volume by deionized water and absolute ethyl alcohol:After 3 mixing again
PH to 2~3 is adjusted with glacial acetic acid, obtains mixed liquor；Mixed liquor is fitted into the three-necked flask with blender and dropping funel,
The isometric titanium source liquid of mixed liquor is added in into dropping funel again, starts blender and is stirred with the rotating speed of 400~500r/min
It mixes, is instilled in mixed liquor dropwise to by titanium source liquid while stirring, continue 40~50min of stirring after titanium source liquid is added dropwise, obtain
It is spare to coagulant liquid；It is 5 in mass ratio:3:2:1, which weighs tealeaves, ginkgo, Fructus Forsythiae and soybean, is put into tissue pulverizer and crushes 20
~30min, obtains crushed material, is 3 in mass ratio by crushed material and grape wine:It is laid in stainless steel pallet after 1 mixing, it will not
It is 40~45 DEG C that rust steel tray, which is put into temperature, and relative air humidity is in 60~70% greenhouse, stands mouldy 5~6 days, obtains
Mouldy object；It is 1 in mass ratio by mouldy object and deionized water:It is fitted into fermentation tank after 3 mixing, tank mouth is sealed, at 35~45 DEG C
It is lower to be sealed by fermentation 7~9 days, it is separated by filtration to obtain ferment filtrate after fermentation, immediately by ferment filtrate and spare coagulant liquid
It is 1 in mass ratio:It is again loaded into clean fermentation tank after 5 mixing, continues sealing and fermenting at 30~35 DEG C 2~3 days；It waits to ferment
After, tunning is taken out, is put into high-temperature sterilization furnace, 10~15min of high-temperature sterilization at 120~130 DEG C, sterilizing is produced
Object and deionized water are 1 in mass ratio:It discharges after 30~40min of ultrasonic disperse under the power of 200~300W after 3 mixing to obtain the final product
Biomass ferment is modified Anti-ultraviolet true silk fabric finishing agent.
Example 1
It is 1 in mass ratio:3 will pour into sonic oscillation instrument after tetra-n-butyl titanate and absolute ethyl alcohol mixing, be surpassed with the frequency of 25kHz
Sound oscillation processing 3min obtains titanium source liquid, is 1 by volume by deionized water and absolute ethyl alcohol:Again with glacial acetic acid tune after 3 mixing
PH to 2 is saved, obtains mixed liquor；Mixed liquor is fitted into the three-necked flask with blender and dropping funel, then to dropping funel
It is middle to add in the isometric titanium source liquid of mixed liquor, start blender and be stirred with the rotating speed of 400r/min, while stirring to by titanium
Source liquid is instilled in mixed liquor dropwise, is continued to stir 40min after titanium source liquid is added dropwise, is obtained coagulant liquid, spare；In mass ratio
It is 5:3:2:1, which weighs tealeaves, ginkgo, Fructus Forsythiae and soybean, is put into tissue pulverizer and crushes 20min, obtains crushed material, will crush
Object and grape wine are 3 in mass ratio:It is laid in stainless steel pallet after 1 mixing, it is 40 DEG C that stainless steel pallet is put into temperature, empty
Gas relative humidity is in 60% greenhouse, stands mouldy 5 days, obtains mouldy object；It is 1 in mass ratio by mouldy object and deionized water:
It is fitted into fermentation tank after 3 mixing, seals tank mouth, be sealed by fermentation 7 days at 35 DEG C, be separated by filtration to obtain fermentation filter after fermentation
Ferment filtrate and spare coagulant liquid are immediately 1 in mass ratio by liquid:It is again loaded into clean fermentation tank after 5 mixing, at 30 DEG C
Under continue be sealed by fermentation 2 days；It treats after fermentation, to take out tunning, be put into high-temperature sterilization furnace, high temperature goes out at 120 DEG C
Sterilizing product and deionized water are 1 in mass ratio by bacterium 10min:After 3 mixing under the power of 200W after ultrasonic disperse 30min
It discharges and is modified Anti-ultraviolet true silk fabric finishing agent up to biomass ferment.
Example 2
It is 1 in mass ratio:3 will pour into sonic oscillation instrument after tetra-n-butyl titanate and absolute ethyl alcohol mixing, be surpassed with the frequency of 28kHz
Sound oscillation processing 4min obtains titanium source liquid, is 1 by volume by deionized water and absolute ethyl alcohol:Again with glacial acetic acid tune after 3 mixing
PH to 3 is saved, obtains mixed liquor；Mixed liquor is fitted into the three-necked flask with blender and dropping funel, then to dropping funel
It is middle to add in the isometric titanium source liquid of mixed liquor, start blender and be stirred with the rotating speed of 450r/min, while stirring to by titanium
Source liquid is instilled in mixed liquor dropwise, is continued to stir 45min after titanium source liquid is added dropwise, is obtained coagulant liquid, spare；In mass ratio
It is 5:3:2:1, which weighs tealeaves, ginkgo, Fructus Forsythiae and soybean, is put into tissue pulverizer and crushes 25min, obtains crushed material, will crush
Object and grape wine are 3 in mass ratio:It is laid in stainless steel pallet after 1 mixing, it is 43 DEG C that stainless steel pallet is put into temperature, empty
Gas relative humidity is in 65% greenhouse, stands mouldy 5 days, obtains mouldy object；It is 1 in mass ratio by mouldy object and deionized water:
It is fitted into fermentation tank after 3 mixing, seals tank mouth, be sealed by fermentation 8 days at 40 DEG C, be separated by filtration to obtain fermentation filter after fermentation
Ferment filtrate and spare coagulant liquid are immediately 1 in mass ratio by liquid:It is again loaded into clean fermentation tank after 5 mixing, at 33 DEG C
Under continue be sealed by fermentation 2 days；It treats after fermentation, to take out tunning, be put into high-temperature sterilization furnace, high temperature goes out at 125 DEG C
Sterilizing product and deionized water are 1 in mass ratio by bacterium 13min:After 3 mixing under the power of 250W after ultrasonic disperse 35min
It discharges and is modified Anti-ultraviolet true silk fabric finishing agent up to biomass ferment.
Example 3
It is 1 in mass ratio:3 will pour into sonic oscillation instrument after tetra-n-butyl titanate and absolute ethyl alcohol mixing, be surpassed with the frequency of 30kHz
Sound oscillation processing 5min obtains titanium source liquid, is 1 by volume by deionized water and absolute ethyl alcohol:Again with glacial acetic acid tune after 3 mixing
PH to 3 is saved, obtains mixed liquor；Mixed liquor is fitted into the three-necked flask with blender and dropping funel, then to dropping funel
It is middle to add in the isometric titanium source liquid of mixed liquor, start blender and be stirred with the rotating speed of 500r/min, while stirring to by titanium
Source liquid is instilled in mixed liquor dropwise, is continued to stir 50min after titanium source liquid is added dropwise, is obtained coagulant liquid, spare；In mass ratio
It is 5:3:2:1, which weighs tealeaves, ginkgo, Fructus Forsythiae and soybean, is put into tissue pulverizer and crushes 30min, obtains crushed material, will crush
Object and grape wine are 3 in mass ratio:It is laid in stainless steel pallet after 1 mixing, it is 45 DEG C that stainless steel pallet is put into temperature, empty
Gas relative humidity is in 70% greenhouse, stands mouldy 6 days, obtains mouldy object；It is 1 in mass ratio by mouldy object and deionized water:
It is fitted into fermentation tank after 3 mixing, seals tank mouth, be sealed by fermentation 9 days at 45 DEG C, be separated by filtration to obtain fermentation filter after fermentation
Ferment filtrate and spare coagulant liquid are immediately 1 in mass ratio by liquid:It is again loaded into clean fermentation tank after 5 mixing, at 35 DEG C
Under continue be sealed by fermentation 3 days；It treats after fermentation, to take out tunning, be put into high-temperature sterilization furnace, high temperature goes out at 130 DEG C
Sterilizing product and deionized water are 1 in mass ratio by bacterium 15min:After 3 mixing under the power of 300W after ultrasonic disperse 40min
It discharges and is modified Anti-ultraviolet true silk fabric finishing agent up to biomass ferment.
Reference examples
Not make modified nano-titanium dioxide Silk Fabric Finishing agent as reference examples
Performance detection is carried out to the fabric finishing agent in Silk Fabric Finishing agent produced by the present invention and reference examples, testing result is such as
Shown in table 1：
Test method
1st, the standard according to as defined in GB/T 18830 surveys the uvioresistant performance of real silk fabric in textile LJV protection factors
Try instrument（Labsphere UV-1000F）The uvioresistant performance of real silk fabric is tested.
2nd, the washing fastness of the real silk fabric after arrangement is tested according to GB/T 3921-2008 standards.
1 performance test results of table
Biomass ferment produced by the present invention is modified Anti-ultraviolet true silk fabric finishing agent it can be seen from the detection data in upper table
With splendid UVResistant effect, and the adhesion-tight degree between finishing agent and fabric is high, still will not fall off after washing repeatedly,
Still there is splendid UVResistant effect, and uvioresistant persistence is high, has broad application prospects.
Claims (5)
1. a kind of biomass ferment is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent, it is characterised in that specific preparation process
For：
（1）Sonic oscillation instrument is poured into after tetra-n-butyl titanate and absolute ethyl alcohol are mixed, sonic oscillation handles 3~5min and obtains titanium
Source liquid adjusts pH to 2~3 with glacial acetic acid again after mixing deionized water and absolute ethyl alcohol, obtains mixed liquor；
（2）Above-mentioned mixed liquor is fitted into the three-necked flask with blender and dropping funel, then adds in and mixes into dropping funel
The isometric titanium source liquid of liquid is closed, starts blender and is stirred with the rotating speed of 400~500r/min, while stirring to by titanium source liquid
It instills in mixed liquor dropwise, continues 40~50min of stirring after titanium source liquid is added dropwise, obtain coagulant liquid, it is spare；
（3）It weighs tealeaves, ginkgo, Fructus Forsythiae and soybean and crushes 20~30min, obtain crushed material, crushed material and grape wine are mixed
After be laid in stainless steel pallet, stainless steel pallet is put into greenhouse, stand mouldy 5~6 days, obtain mouldy object；
（4）It is fitted into fermentation tank after mouldy object and deionized water are mixed, is sealed by fermentation, is separated by filtration is sent out after fermentation
Ferment filtrate is again loaded into clean fermentation tank after immediately mixing ferment filtrate and spare coagulant liquid, continues to be sealed by fermentation；
（5）Treat it is above-mentioned take out tunning after fermentation, be put into high-temperature sterilization furnace, high-temperature sterilization, sterilizing and is gone product
30~40min of ultrasonic disperse after ionized water mixing, discharges and is modified Anti-ultraviolet true silk fabric finishing agent up to biomass ferment.
2. a kind of biomass ferment according to claim 1 is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent,
It is characterized in that：Step（1）Described in tetra-n-butyl titanate and absolute ethyl alcohol mass ratio be 1:3, the frequency of sonic oscillation processing
Rate is 25~30kHz, and the volume ratio of deionized water and absolute ethyl alcohol is 1:3.
3. a kind of biomass ferment according to claim 1 is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent,
It is characterized in that：Step（3）Described in tealeaves, ginkgo, Fructus Forsythiae and the mass ratio of soybean be 5:3:2:1, crushed material and grape wine
Mass ratio be 3:1, the temperature in greenhouse is 40~45 DEG C, and relative air humidity is 60~70%.
4. a kind of biomass ferment according to claim 1 is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent,
It is characterized in that：Step（4）Described in mouldy object and deionized water mass ratio be 1:3, the temperature of sealing and fermenting is 35~45
DEG C, the time of sealing and fermenting is 7~9 days, and the mass ratio of ferment filtrate and coagulant liquid is 1:5, continue be sealed by fermentation temperature be
30~35 DEG C, it is 2~3 days to continue the time being sealed by fermentation.
5. a kind of biomass ferment according to claim 1 is modified the preparation method of Anti-ultraviolet true silk fabric finishing agent,
It is characterized in that：Step（5）Described in high-temperature sterilization temperature for 120~130 DEG C, the time of high-temperature sterilization is 10~15min,
Sterilizing product and the mass ratio of deionized water are 1:3, the power of ultrasonic disperse is 200~300W.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108483897A (en) * | 2018-04-09 | 2018-09-04 | 徐冬 | A kind of preparation method of ceramic pigment nano-powder |
| CN108841361A (en) * | 2018-05-15 | 2018-11-20 | 王雪峰 | A kind of preparation method of rancid object sizing heat-storing material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251388A (en) * | 2011-06-22 | 2011-11-23 | 西安工程大学 | Method for carrying out modification on real-silk fabrics by using butyl titanate |
| CN103451914A (en) * | 2013-08-06 | 2013-12-18 | 苏州三和开泰花线织造有限公司 | Production method of antibacterial silk fabric |
| CN106120316A (en) * | 2016-07-19 | 2016-11-16 | 雷春生 | The preparation method of one Plant Extracts modification uvioresistant gel fabric finishing agent |
| CN106243892A (en) * | 2016-08-05 | 2016-12-21 | 陈毅忠 | A kind of preparation method of the automatically cleaning dining table that sterilizes |
| CN106868628A (en) * | 2017-03-09 | 2017-06-20 | 桂林融通科技有限公司 | A kind of method that utilization sludge prepares cotton like fabric |
-
2017
- 2017-12-30 CN CN201711492605.7A patent/CN108130712A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251388A (en) * | 2011-06-22 | 2011-11-23 | 西安工程大学 | Method for carrying out modification on real-silk fabrics by using butyl titanate |
| CN103451914A (en) * | 2013-08-06 | 2013-12-18 | 苏州三和开泰花线织造有限公司 | Production method of antibacterial silk fabric |
| CN106120316A (en) * | 2016-07-19 | 2016-11-16 | 雷春生 | The preparation method of one Plant Extracts modification uvioresistant gel fabric finishing agent |
| CN106243892A (en) * | 2016-08-05 | 2016-12-21 | 陈毅忠 | A kind of preparation method of the automatically cleaning dining table that sterilizes |
| CN106868628A (en) * | 2017-03-09 | 2017-06-20 | 桂林融通科技有限公司 | A kind of method that utilization sludge prepares cotton like fabric |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108483897A (en) * | 2018-04-09 | 2018-09-04 | 徐冬 | A kind of preparation method of ceramic pigment nano-powder |
| CN108483897B (en) * | 2018-04-09 | 2020-08-25 | 佛山意达加精密陶瓷科技有限公司 | Preparation method of ceramic pigment nano powder |
| CN108841361A (en) * | 2018-05-15 | 2018-11-20 | 王雪峰 | A kind of preparation method of rancid object sizing heat-storing material |
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Application publication date: 20180608 |