CN108130500A - A kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material and its application method - Google Patents

A kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material and its application method Download PDF

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Publication number
CN108130500A
CN108130500A CN201711210144.XA CN201711210144A CN108130500A CN 108130500 A CN108130500 A CN 108130500A CN 201711210144 A CN201711210144 A CN 201711210144A CN 108130500 A CN108130500 A CN 108130500A
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consolidant
aluminium oxide
agent
composite coating
oxide ceramics
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CN201711210144.XA
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宋鹏
李乔磊
吕凯月
陈榕
陆建生
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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Priority to CN201711210144.XA priority Critical patent/CN108130500A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/12Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

The present invention relates to a kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material and its application methods, belong to ceramic wear-resistant coating technical field.The thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, material is prepared using the following raw material, 40 ~ 65 parts by weight of hardening agent, 30 ~ 40 parts by weight of raising agent, 5 ~ 20 parts by weight of consolidant, wherein hardening agent is alumina powder, and raising agent is copper, NiAl or NiCr, and consolidant is Zirconium dioxide powder.Hardening agent, raising agent and consolidant are sieved respectively, then hardening agent and consolidant are uniformly mixed, it is respectively fed to again with raising agent in two powder feeders, powder feeding carries out thermal spraying to spraying matrix, and resistance to crack extension aluminium oxide ceramics composite coating material is obtained in spraying matrix surface.Present invention seek to address that the problem of being also easy to produce micro-crack in the high crisp low tough, spraying process of alumina-based ceramic heat spray coating layer material.

Description

A kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material and its use Method
Technical field
The present invention relates to a kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material and its application methods, belong to Ceramic wear-resistant coating technical field.
Background technology
Aluminium oxide thermal Sperayed Ceramic Coatings are because of its low-density, high temperature resistant, corrosion-resistant, high rigidity, wear-resistant, chemical stability Preferably the advantages that, is widely used in the fields such as aerospace, mechano-electronic, medical treatment and chemical industry.But alumina ceramic material is brilliant Body structure belongs to corundum type, by the ionic bond and Covalent bonding together of highly directive, leads to its own with high brittleness low tenacity, high Micro-crack is easily generated during temperature spraying, this characteristic constrains the practical application of alumina ceramic material.
There is zirconium oxide heating to shrink, the phase transformation volume change characteristic for the expansion that cools down.During heating zirconium dioxide from monocline to Four directions conversion, absorbs heat, there is apparent volume contraction(5%), and when cooling down(Four directions is converted as monocline)Generate volume expansion (8%).Zirconium oxide monocline to cubic conversion temperature usually between 1100 DEG C ~ 1200 DEG C, and four direction monocline conversions when cooling down, Since monocline cenotype nucleus forms difficulty, thus transition temperature is between 860 DEG C ~ 980 DEG C.
The characteristics of for micro-crack is also easy to produce in the high crisp low tough, spraying process of aluminium oxide, domestic and international research worker does A large amount of research improves this characteristic of alumina ceramic material, propose alumina-based ceramic material yttria stabilizator, Stratiform toughening, it is crystal whisker toughened the methods of.The method of the type in temperature-fall period zirconium oxide due to the constraint of surrounding ceramic particle, It cannot undergo phase transition, inhibit the volume expansion of zirconium oxide, limited compression be generated in coat inside, although inhibiting to a certain extent The generation and extension of crackle, but toughening effect is limited, so as to which the requirement of alumina ceramic material cannot be fully met.
Therefore the problem of above-mentioned is directed to, needs a kind of inexpensive, simple for process, crackle that can eliminate the side of crackle after generating The method that method quickly and easily prepares green and healthy, inexpensive thermal spraying resistance to crack extension aluminium oxide ceramics composite coating.
Invention content
For the above-mentioned prior art there are the problem of and deficiency, the present invention a kind of thermal spraying resistance to crack extension aluminium oxide is provided Ceramics material used for preparing coated and its application method.Present invention seek to address that alumina-based ceramic heat spray coating layer material is high crisp low The problem of micro-crack being also easy to produce in tough, spraying process.The invention is realized by the following technical scheme.
A kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, material are prepared using the following raw material, are strengthened 40 ~ 65 parts by weight of agent, 30 ~ 40 parts by weight of raising agent, 5 ~ 20 parts by weight of consolidant, wherein hardening agent are alumina powder, loose Agent is copper, NiAl or NiCr, and consolidant is Zirconium dioxide powder.
A kind of application method of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, by hardening agent, raising agent It is sieved with consolidant, is then uniformly mixed hardening agent and consolidant respectively, then be respectively fed in two powder feeders with raising agent, Powder feeding carries out thermal spraying to spraying matrix, and resistance to crack extension aluminium oxide ceramics composite coating material is obtained in spraying matrix surface.
Above-mentioned application method, detailed process are:
Matrix surface to be sprayed is carried out the rough processing of sandblasting and cleaning treatment by step 1;
Hardening agent, raising agent and consolidant are crushed and cross 325 mesh sieve by step 2, are then mixed hardening agent and consolidant equal It is even, then be respectively fed in two powder feeders with raising agent, powder feeding thermal spraying is carried out in the substrate surface of step 1, obtains anti-crack Extend aluminium oxide ceramics composite coating material(Close to substrate surface be raising agent deposition adhesive layer, one layer of outside be strengthen The ceramic coating that agent and consolidant mixed powder are formed).
Matrix carries out blasted rough processing in above-mentioned steps 1, and then sand blasted surface is carried out at cleaning using dry air It manages, the grains of sand material used in during blasted rough is:Fused alumina zirconia, white fused alumina or Brown Alundum, granularity are 15 ~ 30 μm.
Above-mentioned thermal spraying is expanded using thermal spraying anti-crack on even application the methods of plasma spraying, supersonic flame spraying Open up aluminium oxide ceramics composite coating material.
Consolidant and the adhesive layer of raising agent deposition are added in the coating material of the present invention.
(1)Consolidant is zirconium oxide, and phase transformation caused by temperature change can cause volume, is sprayed in cooling procedure, oxidation The opposite monoclinic phase conversion in four directions occurs for zirconium, leads to volume expansion, and zirconium oxide volume increases the crackle that healing aluminium oxide generates, so as to It realizes the purpose of spraying process crack healing, and certain compression is generated in coat inside.
(2)In the case where coat inside is there are compression, the raising agent with preferable toughness can flow, near filling Crackle, while raising agent reserves space for consolidant volume change.
(3)In thermal spray process, it is ensured that material is rapidly heated, and reduces volume caused by monocline is converted to four directions and receives Contracting;And subsequent slow cooling contributes to tetragonal phase of zirconia to change completely to monoclinic phase, so as to reach 8% volume expansion.
The beneficial effects of the invention are as follows:Manufacturing cost is relatively low, simple for process, which makes full use of four direction of zirconium oxide single Tiltedly the volume expansion of conversion phase transformation carrys out self-healing coating, can preferably solve in pyrolytic coating process aluminium oxide ceramic coating layer Micro-crack.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
The thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, material are prepared using the following raw material, hardening agent 65g, Raising agent 30g, wherein consolidant 5g, hardening agent are alumina powder, and raising agent is copper, and consolidant is Zirconium dioxide powder.
The application method of the thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, by hardening agent, raising agent and Consolidant is sieved respectively, is then uniformly mixed hardening agent and consolidant, then is respectively fed in two powder feeders with raising agent, send Powder carries out thermal spraying to spraying matrix, and resistance to crack extension aluminium oxide ceramics composite coating material is obtained in spraying matrix surface.
Above-mentioned application method, detailed process are:
Step 1, by matrix to be sprayed(Copper alloy)Surface carries out the rough processing of sandblasting and cleaning treatment;Matrix carries out blasted rough Then processing carries out cleaning treatment, the grains of sand material used in during blasted rough using dry air to sand blasted surface For:Fused alumina zirconia, granularity are 15 μm;
Alumina powder hardening agent 65g, copper raising agent 30g and Zirconium dioxide powder consolidant 5g are crushed and are crossed 325 by step 2 Mesh sieves, and is then uniformly mixed hardening agent and consolidant, then be respectively fed in two powder feeders with raising agent, in the base of step 1 Material surface carries out powder feeding thermal spraying, obtains resistance to crack extension aluminium oxide ceramics composite coating material.
Embodiment 2
The thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, material are prepared using the following raw material, hardening agent 40g, Raising agent 40g, wherein consolidant 20g, hardening agent are alumina powder, and raising agent is copper, and consolidant is Zirconium dioxide powder.
The application method of the thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, by hardening agent, raising agent and Consolidant is sieved respectively, is then uniformly mixed hardening agent and consolidant, then is respectively fed in two powder feeders with raising agent, send Powder carries out thermal spraying to spraying matrix, and resistance to crack extension aluminium oxide ceramics composite coating material is obtained in spraying matrix surface.
Above-mentioned application method, detailed process are:
Step 1, by matrix to be sprayed(Copper alloy)Surface carries out the rough processing of sandblasting and cleaning treatment;Matrix carries out blasted rough Then processing carries out cleaning treatment, the grains of sand material used in during blasted rough using dry air to sand blasted surface For:Fused alumina zirconia, granularity are 15 μm;
Alumina powder hardening agent 40g, copper raising agent 40g and Zirconium dioxide powder consolidant 20g are crushed and are crossed 325 by step 2 Mesh sieves, and is then uniformly mixed hardening agent and consolidant, then be respectively fed in two powder feeders with raising agent, in the base of step 1 Material surface carries out powder feeding thermal spraying, obtains resistance to crack extension aluminium oxide ceramics composite coating material.
Embodiment 3
The thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, material are prepared using the following raw material, hardening agent 60g, Raising agent 32g, wherein consolidant 8g, hardening agent are alumina powder, and raising agent NiAl, consolidant is Zirconium dioxide powder.
The application method of the thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, by hardening agent, raising agent and Consolidant is sieved respectively, is then uniformly mixed hardening agent and consolidant, then is respectively fed in two powder feeders with raising agent, The substrate surface of step 1 carries out powder feeding thermal spraying, obtains resistance to crack extension aluminium oxide ceramics composite coating material.
Above-mentioned application method, detailed process are:
Step 1, by matrix to be sprayed(Cast iron)Surface carries out the rough processing of sandblasting and cleaning treatment;Matrix is carried out at blasted rough Reason, then carries out cleaning treatment using dry air to sand blasted surface, and the grains of sand material used in during blasted rough is: White fused alumina, granularity are 30 μm;
Step 2, by alumina powder hardening agent 60g, NiAl raising agent 32g and Zirconium dioxide powder consolidant 8g is crushed and mistake 325 mesh sieve, and are then uniformly mixed hardening agent and consolidant, then be respectively fed in two powder feeders with raising agent, in step 1 Substrate surface carries out powder feeding thermal spraying, obtains resistance to crack extension aluminium oxide ceramics composite coating material.
Embodiment 4
The thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, material are prepared using the following raw material, hardening agent 55g, Raising agent 35g, wherein consolidant 10g, hardening agent are alumina powder, and raising agent NiCr, consolidant is Zirconium dioxide powder.
The application method of the thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, by hardening agent, raising agent and Consolidant is sieved respectively, after hardening agent and consolidant are uniformly mixed, then is respectively fed in two powder feeders with raising agent, powder feeding Thermal spraying is carried out to spraying matrix, resistance to crack extension aluminium oxide ceramics composite coating material is obtained in spraying matrix surface.
Above-mentioned application method, detailed process are:
Step 1, by matrix to be sprayed(Cast iron)Surface carries out the rough processing of sandblasting and cleaning treatment;Matrix is carried out at blasted rough Reason, then carries out cleaning treatment using dry air to sand blasted surface, and the grains of sand material used in during blasted rough is: Brown Alundum, granularity are 25 μm;
Step 2, by alumina powder hardening agent 55g, NiCr raising agent 35g and Zirconium dioxide powder consolidant 10g is crushed and mistake 325 mesh sieve, and are then uniformly mixed hardening agent and consolidant, then be respectively fed in two powder feeders with raising agent, in step 1 Substrate surface carries out powder feeding thermal spraying, obtains resistance to crack extension aluminium oxide ceramics composite coating material.
The resistance to crack extension aluminium oxide ceramics composite coating material that embodiment 1 to 4 is obtained carries out micro-crack incidence, hard The data of the index tests such as degree, brittleness load, and the conventional coatings with being added without raising agent and consolidant are compared, and compare knot Fruit is as shown in table 1.
Table 1
Note 1:Using GB/T25995-2010 fine ceramics density and apparent porosity test method.
Note 2:Brittleness payload is tested using Vickers hardness indentation method.
The resistance to crack extension aluminium oxide ceramics composite coating material that the application is prepared as can be seen from Table 1 and tradition Coating compare have less micro-crack incidence, have higher hardness, have more smaller brittleness, alumina-based ceramic The problem of being also easy to produce micro-crack in the high crisp low tough, spraying process of heat spray coating layer material obtains a degree of solution.
The specific embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party Formula within the knowledge of a person skilled in the art, can also be made under the premise of present inventive concept is not departed from Go out various change.

Claims (2)

1. a kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material, it is characterised in that:Material uses the following raw material It prepares, 40 ~ 65 parts by weight of hardening agent, 30 ~ 40 parts by weight of raising agent, 5 ~ 20 parts by weight of consolidant, wherein hardening agent are aluminium oxide Powder, raising agent are copper, NiAl or NiCr, and consolidant is Zirconium dioxide powder.
2. a kind of user of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material according to claim 1 Method, it is characterised in that:Hardening agent, raising agent and consolidant are sieved respectively, are then uniformly mixed hardening agent and consolidant, then It is respectively fed in two powder feeders with raising agent, powder feeding carries out thermal spraying to spraying matrix, and cracking resistance is obtained in spraying matrix surface Line extends aluminium oxide ceramics composite coating material.
CN201711210144.XA 2017-11-28 2017-11-28 A kind of thermal spraying resistance to crack extension aluminium oxide ceramics composite coating material and its application method Pending CN108130500A (en)

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CN109112460A (en) * 2018-08-30 2019-01-01 昆明理工大学 A kind of preparation method of thermal spraying refractory ceramics coating
CN109266992A (en) * 2018-08-30 2019-01-25 昆明理工大学 A kind of preparation method of high-temperature wearable aluminium oxide ceramics base composite coating
CN109987947A (en) * 2019-04-19 2019-07-09 中国科学院上海硅酸盐研究所 Utilize the thermally conductive method with mechanical property of in-situ stress induced transformation Synchronous fluorimetry aluminum oxide coating layer
CN110129715A (en) * 2019-05-14 2019-08-16 昆明理工大学 A kind of in-situ nano metal-ceramic composite coatings and preparation method thereof
CN114804838A (en) * 2022-04-01 2022-07-29 东南大学 Nano composite ceramic material and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109112460A (en) * 2018-08-30 2019-01-01 昆明理工大学 A kind of preparation method of thermal spraying refractory ceramics coating
CN109266992A (en) * 2018-08-30 2019-01-25 昆明理工大学 A kind of preparation method of high-temperature wearable aluminium oxide ceramics base composite coating
CN109987947A (en) * 2019-04-19 2019-07-09 中国科学院上海硅酸盐研究所 Utilize the thermally conductive method with mechanical property of in-situ stress induced transformation Synchronous fluorimetry aluminum oxide coating layer
CN110129715A (en) * 2019-05-14 2019-08-16 昆明理工大学 A kind of in-situ nano metal-ceramic composite coatings and preparation method thereof
CN114804838A (en) * 2022-04-01 2022-07-29 东南大学 Nano composite ceramic material and application thereof

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Application publication date: 20180608