CN108130024A - A kind of graphene pastes waterproof roll rubber powder - Google Patents
A kind of graphene pastes waterproof roll rubber powder Download PDFInfo
- Publication number
- CN108130024A CN108130024A CN201711321774.4A CN201711321774A CN108130024A CN 108130024 A CN108130024 A CN 108130024A CN 201711321774 A CN201711321774 A CN 201711321774A CN 108130024 A CN108130024 A CN 108130024A
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- Prior art keywords
- rubber powder
- parts
- waterproof roll
- powder
- graphene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of graphenes to paste waterproof roll rubber powder, is made of following components and parts by weight：75 85 parts of acrylic acid rubber powder, 17 22 parts of graphene nanometer sheet, 0.02 0.05 parts of defoaming powder, 35 parts of starch ether, 35 parts of powder hydrophober, glass are chopped 25 parts of silk, 0.5 1 parts of filler material.Rubber powder product of the present invention has very good adhesion strength, tensile strength and elongation at break.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of graphene pastes waterproof roll rubber powder.
Background technology
Redispersible latex powder be by polymer emulsion by adding in the substances such as protecting colloid, it is spray-dried to form,
Lotion can be re-formed using water as decentralized medium, the polymer powder with redispersible.It is general can be in dispersed latex
Powder can be divided into III type of I types of RDP, II types of RDP and RDP with reactive agent material type.
Redispersable latex powder can be used as the additive of concrete material, for increasing the viscosity of concrete material；Also may be used
For the additive of plastering mortar, for increasing the adhesive force of plastering mortar；Glue for tile or gap-filling glue are can also be used for, for bonding
Ceramic wall and floor bricks or for filling cracks；It can also be used to paste waterproof roll, the binding agent as waterproof roll.
When binding agent of the dispersable adhesive powder as waterproof roll, often require that it with good adhesion strength, drawing
Stretch intensity and elongation at break.
To meet the requirement of GB/T29545-2013, existing dispersibility latex powder does not require adhesion strength,
And generally it is required of tensile strength and elongation at break.Such as III types of RDP, tensile strength is general >=5.0MPa, fracture
Elongation is generally >=300%.
Due to the particularity of waterproof roll, it is different from concrete material and plastering mortar, for bonding waterproof roll
Redispersable latex powder requires have higher adhesion strength, and can specifically show needs higher tensile strength and extension at break
Rate.Therefore, general rubber powder, glue for tile or the gap-filling glue for being used for mixed mud material or plastering mortar is not to be suitable for waterproof volume
The rubber powder of material is based on different adhesion strength requirements.
Pitch class or high score subclass waterproof material are immersed on carcass, the waterproof material product being fabricated to, with coiled material shape
Formula provides, referred to as waterproof roll.Waterproof roll needs to have certain adhesion strength, excellent tensile strength and extension at break
Rate makes waterproof roll have adhesive property and bears a constant load, stress or not broken property under conditions of certain deformation
Energy.It can show on adhesion strength, tensile strength and elongation at break.
Rubber powder for pasting waterproof roll also needs to form one with the performance of waterproof roll, so as to caking property
Energy, tensile strength and elongation at break have more special requirement.
Invention content
In order to meet the requirement, inventor is made that experiment many times, tests many kinds of different components and dosage,
Creative work has been paid, has just obtained the present invention.
The purpose of the present invention is to provide a kind of graphite with good adhesive property, tensile strength and elongation at break
Alkene pastes waterproof roll rubber powder.
Used technical solution is：
A kind of graphene pastes waterproof roll rubber powder, is made of following components and parts by weight：
In the technical solution of the present invention, it is as a kind of rubber powder product, each component that graphene, which pastes waterproof roll rubber powder,
It has been mixed to form a kind of product that rubber powder form is presented on the whole.
Wherein, acrylic acid rubber powder is used as top quality redispersable latex powder.The acrylic acid rubber powder has relatively strong
Adhesive force, it is flexible, the adhesion strength as rubber powder product basic need is met, in tensile strength and extension at break
The requirement of GB/T29545-2013 is also complied in rate.
Graphene nanometer sheet also has excellent adhesion strength in itself, and graphene nanometer sheet is with Van der Waals force and acrylate glue
The polymer molecule of powder is connected, meanwhile, the addition of graphene nanometer sheet can make the friendship of the polymer molecule of acrylate glue powder
Connection degree increases, the active force enhancing between the polymer molecule of acrylic acid rubber powder, so as to the bonding of notable acrylic acid rubber powder
Intensity, tensile strength and elongation at break.So as on the one hand the addition of graphene nanometer sheet can reduce making for acrylic acid rubber powder
With；On the other hand it plays and acts synergistically with acrylic acid rubber powder again, the adhesion strength of product entirety, tensile strength can be improved and break
Split elongation.
Glass is chopped silk as reinforcing material, can further increase the tensile strength and elongation at break of product.
Powder hydrophober has good waterproof effect, when for pasting waterproof roll, is formed on waterproof roll surface
Thin waterproof glued membrane, prevents the entrance of water.
Starch ether is used to improve the internal structure of rubber powder product, and has good compatibility, Ke Yijin with other components
One step increases adhesion strength, tensile strength and the elongation at break of product, and improves applying when product pastes waterproof roll
Work performance.
During preparation, each component of formula is mixed evenly, you can rubber powder product is made.
The shape of this rubber powder product is powdery；Smell is non-toxic and tasteless；Dissolubility be slightly soluble in it is most of organic molten
Agent, it is water-soluble.
This rubber powder product, can be according to user's technology requirement practical at that time or prevailing circumstances when pasting waterproof roll
Use demand, freely to adjust the quality proportioning of this rubber powder product and water and cement, after mixing be Pasting.
The beneficial effects of the present invention are：
By test of many times, a kind of graphite with good adhesion strength, tensile strength and elongation at break has been obtained
Alkene pastes waterproof roll rubber powder.
Specific embodiment
Technical scheme of the present invention is further described, but only enumerated from the numerous experiments of inventor with reference to embodiment
Section Example, the present invention claims protection domain be not limited thereto.
Embodiment 1
The graphene of the present embodiment pastes waterproof roll rubber powder, is made of following components and parts by weight：
Embodiment 2
The graphene of the present embodiment pastes waterproof roll rubber powder, is made of following components and parts by weight：
Embodiment 3
The graphene of the present embodiment pastes waterproof roll rubber powder, is made of following components and parts by weight：
Embodiment 4
The graphene of the present embodiment pastes waterproof roll rubber powder, is made of following components and parts by weight：
Embodiment 5
The graphene of the present embodiment pastes waterproof roll rubber powder, is made of following components and parts by weight：
Graphene made from above each embodiment is pasted into waterproof roll rubber powder, performance detection is carried out to it, obtains following table：
As can be known from the above table, graphene of the invention, which pastes waterproof roll rubber powder, has very good adhesion strength, stretching
Intensity and elongation at break, compared to common waterproof roll rubber powder, in the low of adhesion strength, tensile strength and elongation at break
In the increasing degree of limit value, expection is had exceeded, achieves unexpected technique effect.
Claims (1)
1. a kind of graphene pastes waterproof roll rubber powder, which is characterized in that it is made of following components and parts by weight：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711321774.4A CN108130024A (en) | 2017-12-12 | 2017-12-12 | A kind of graphene pastes waterproof roll rubber powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711321774.4A CN108130024A (en) | 2017-12-12 | 2017-12-12 | A kind of graphene pastes waterproof roll rubber powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108130024A true CN108130024A (en) | 2018-06-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711321774.4A Pending CN108130024A (en) | 2017-12-12 | 2017-12-12 | A kind of graphene pastes waterproof roll rubber powder |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337593A (en) * | 2018-10-09 | 2019-02-15 | 芜湖融汇化工有限公司 | Two-sided composite of water-proof coiled material construction glue of polyvinyl chloride and preparation method thereof |
| CN110204983A (en) * | 2019-06-13 | 2019-09-06 | 厦门东顺涂料有限公司 | A kind of antirust interfacial agents |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320056A (en) * | 2013-07-11 | 2013-09-25 | 中国科学院宁波材料技术与工程研究所 | Binder for laminated wood |
| CN103396055A (en) * | 2013-07-19 | 2013-11-20 | 北京东方雨虹防水技术股份有限公司 | Special cement adhesive for waterproof backing TPO coils and preparation method thereof |
| CN104479591A (en) * | 2014-12-03 | 2015-04-01 | 厦门力嘉诚防水工程有限公司 | Adhesive powder for sticking waterproof rolls |
| US20160177147A1 (en) * | 2014-12-23 | 2016-06-23 | Samsung Sdi Co., Ltd. | Adhesive film and display member including the same |
| CN106381104A (en) * | 2016-10-20 | 2017-02-08 | 北京林业大学 | Water-based adhesive and preparation method thereof |
-
2017
- 2017-12-12 CN CN201711321774.4A patent/CN108130024A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320056A (en) * | 2013-07-11 | 2013-09-25 | 中国科学院宁波材料技术与工程研究所 | Binder for laminated wood |
| CN103396055A (en) * | 2013-07-19 | 2013-11-20 | 北京东方雨虹防水技术股份有限公司 | Special cement adhesive for waterproof backing TPO coils and preparation method thereof |
| CN104479591A (en) * | 2014-12-03 | 2015-04-01 | 厦门力嘉诚防水工程有限公司 | Adhesive powder for sticking waterproof rolls |
| US20160177147A1 (en) * | 2014-12-23 | 2016-06-23 | Samsung Sdi Co., Ltd. | Adhesive film and display member including the same |
| CN106381104A (en) * | 2016-10-20 | 2017-02-08 | 北京林业大学 | Water-based adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 周文英等: "《导热高分子材料》", 30 April 2014, 国防工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337593A (en) * | 2018-10-09 | 2019-02-15 | 芜湖融汇化工有限公司 | Two-sided composite of water-proof coiled material construction glue of polyvinyl chloride and preparation method thereof |
| CN110204983A (en) * | 2019-06-13 | 2019-09-06 | 厦门东顺涂料有限公司 | A kind of antirust interfacial agents |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180608 |
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| RJ01 | Rejection of invention patent application after publication |