CN108129135A - 烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法 - Google Patents
烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法 Download PDFInfo
- Publication number
- CN108129135A CN108129135A CN201810028753.1A CN201810028753A CN108129135A CN 108129135 A CN108129135 A CN 108129135A CN 201810028753 A CN201810028753 A CN 201810028753A CN 108129135 A CN108129135 A CN 108129135A
- Authority
- CN
- China
- Prior art keywords
- expanded perlite
- parts
- nsulation
- sintering
- engineering spoir
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010451 perlite Substances 0.000 title claims abstract description 66
- 235000019362 perlite Nutrition 0.000 title claims abstract description 66
- 238000005245 sintering Methods 0.000 title claims abstract description 49
- 238000005034 decoration Methods 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000009413 insulation Methods 0.000 claims abstract description 32
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004088 foaming agent Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000006260 foam Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 8
- 239000003086 colorant Substances 0.000 claims abstract description 7
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 229910001947 lithium oxide Inorganic materials 0.000 claims abstract description 6
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 5
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims description 11
- 238000007664 blowing Methods 0.000 claims description 9
- 238000010276 construction Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000001238 wet grinding Methods 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 5
- 239000002689 soil Substances 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229920002748 Basalt fiber Polymers 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229910052863 mullite Inorganic materials 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 238000009412 basement excavation Methods 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000002910 solid waste Substances 0.000 abstract description 6
- 238000004321 preservation Methods 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract description 3
- 230000006835 compression Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- 229910001562 pearlite Inorganic materials 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000012774 insulation material Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 210000003195 fascia Anatomy 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- -1 poly- ammonia Ester Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000004795 extruded polystyrene foam Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical group 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 239000007783 nanoporous material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1328—Waste materials; Refuse; Residues without additional clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/02—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/522—Oxidic
- C04B2235/5228—Silica and alumina, including aluminosilicates, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/522—Oxidic
- C04B2235/5232—Silica or silicates other than aluminosilicates, e.g. quartz
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
- Building Environments (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开了一种烧结工程弃土膨胀珍珠岩保温装饰一体化板,由保温基层和装饰面层组成,其中保温基层由工程弃土50~80份,膨胀珍珠岩50~80份,粘结剂5~10份,发泡剂0.5~1份,稳泡剂2~6份,增强纤维6~8份,助熔剂0.2~0.3,水30~50份烧制而成;装饰面层由二氧化硅20~70份,氧化锌30~80份,氧化硼5~8份,氧化铝2~4份,氧化锂0.5~2份,着色剂0.5~3份,分散剂0.2~0.3份,消泡剂0.1~0.4份,水20~40份烧制而成。本发明高效利固体废弃物的同时,制备的烧结工程弃土膨胀珍珠岩保温板还兼具防火、保温、装饰一体化功能。
Description
技术领域
本发明属于建筑材料领域,具体为一种烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法。
背景技术
建筑耗能已经超过社会总耗能的1/3。提高建筑围护结构的保温隔热性能是降低建筑能耗的有效手段。建筑中常用的有机保温材料如聚苯板(EPS)、挤塑聚苯板(XPS)、聚氨酯板(PU)等虽然导热系数低,保温性能好,但是由于其较差的防火性和耐久性已经无法满足建筑防火和安全的发展需求。无机保温材料如岩棉、膨胀珍珠岩、膨胀蛭石等具有良好的防火性能、化学稳定性和耐久性,已经成为传统有机保温材料的理想替代品。
膨胀珍珠岩保温板是建筑节能领域常用的一种无机保温板材。传统膨胀珍珠岩保温板采用粘结剂与膨胀珍珠岩混合,然后压制成型。为了提高板材强度,制备膨胀珍珠岩保温板时需要大量粘结剂并提高保温板的压缩比,这无疑会增加了保温板的导热系数,降级了保温板的保温性能。另外,传统采用水玻璃为粘结剂直接压制成型的膨胀珍珠岩保温板还具有耐水性差、固化时间长、易受潮返碱等缺点。由于上述原因导致膨胀珍珠岩保温板在建筑节能领域中的应用和推广受到了限制。
发明专利申请CN 104860703 A公开了一种以工程弃土为原料的泡沫砖的制备方法。但是由于该发明申请制备的泡沫砖导热系数仍然偏高,这将限制其在建筑节能领域的推广应用。
发明专利CN103553397B公开了一种具有高强度的膨胀珍珠岩外墙保温板材及其制备方法。发明专利CN 103570328 B公开了一种结合法制造的建筑外墙保温材料的方法。发明专利CN103553544B公开了一种具有低导热系数的膨胀珍珠岩外墙保温板材及其制备方法。这三个发明专利均涉及到采用烧结方法制备膨胀珍珠岩外墙板。但是他们明显的缺点是:(1)采用压制成型制备膨胀珍珠岩板坯,这导致膨胀珍珠岩破碎而影响板的保温性能;(2)未经发泡的无机粘结剂在烧结过程中进一步增加了板的密实度,导致板的导热系数进一步增加;(3)不具备保温装饰一体效果,板材上墙之后还需要抹面、装饰,导致施工工艺繁琐,成本增加。
发明内容
本发明目的是提供一种烧结膨胀珍珠岩保温板及其制备方法,以解决膨胀珍珠岩保温板现有技术的不足。
本发明是通过如下技术方案实现的:
一种烧结工程弃土膨胀珍珠岩保温装饰一体化板,由保温基层和装饰面层组成。
其中,保温基层按以下原材料的重量份数烧制而成:工程弃土50~80份,膨胀珍珠岩50~80份,粘结剂5~10份,发泡剂0.5~1份,稳泡剂2~6份,增强纤维6~8份,助熔剂0.2~0.3份,水30~50份。
装饰面层按以下原材料的重量份数烧制而成:二氧化硅20~70份,氧化锌30~80份,氧化硼5~8份,氧化铝2~4份,氧化锂0.5~2份,着色剂0.5~3份,分散剂0.2~0.3份,消泡剂0.1~0.4份,水20~40份。
上述烧结工程弃土膨胀珍珠岩保温装饰一体化板制备方法如下:
(1)、将工程弃土采用球磨机湿磨0.5~1h,然后105℃烘干至恒重,过200目筛;
(2)、将步骤(1)获得的工程弃土与粘结剂、发泡剂、稳泡剂、增强纤维、助熔剂、水按比例混合,通过化学发泡方式或物理发泡方式获得发泡浆料;
(3)、将步骤(2)的发泡浆料与膨胀珍珠岩均匀混合、包裹,直接注模成型或入模振动成型,固化2~24h,然后拆模获得发泡保温基层板坯;
(4)、将二氧化硅、氧化锌、氧化硼、氧化铝、氧化锂、着色剂、分散剂、消泡剂及水按比例混合,采用球磨机湿磨3~12h,获得装饰面层釉浆;
(5)采用步骤(4)获得的釉浆在步骤(3)获得的保温基层板坯表面施釉;
(6)将步骤(5)获得的板坯入高温炉烧结,烧结温度750~850℃,烧结时间0.5~1h,然后快速降温至500℃,保温0.5h,最后退火至常温,获得烧结工程弃土膨胀珍珠岩保温装饰一体化板。
工程弃土为城市建设中开挖土方无法回填和利用的工程废弃土,包括砂、黄土、粉土、黏土等中的一种或几种混合土。
膨胀珍珠岩还可以是球形闭孔膨胀珍珠岩,玻化微珠,纳米膨胀珍珠岩中的一种,粒径0.1~15mm。其中,纳米膨胀珍珠岩是指通过在膨胀珍珠岩孔洞填充气凝胶复合而合成的纳米多孔材料。
粘结剂为水泥、水玻璃、磷酸、聚乙烯醇中的一种。
物理发泡方式采用的发泡剂是植物发泡剂、动物发泡剂中的一种或两种复合;化学发泡方式采用的发泡剂为双氧水。
稳泡剂可以是明胶、聚丙烯酸钠或者蛋白质稳泡剂。
增强纤维可以是玻璃纤维、莫来石纤维和玄武岩纤维中的一种。
助熔剂可以是玻璃粉,氧化钠,菱镁矿,赤泥中的一种。
着色剂为根据不同的呈色选择金属氧化物和颜料复配。
在实验中发现,本发明具有如下有益效果:传统工艺通过粘结剂粘结、压制并烘干制备的膨胀珍珠岩保温板抗压强度一般在0.3~0.5MPa,导热系数一般在0.045~0.07W/(m·K)。而本发明制备的烧结工程弃土膨胀珍珠岩保温装饰一体化板导热系数≤0.042W/(m·K),抗压强度≥0.60MPa,吸水率≤5%。此外,与现有烧结的膨胀珍珠岩保温外墙板相比,本发明制备的烧结工程弃土膨胀珍珠岩保温装饰一体化板大量利用固体废弃物,并且兼具保温装饰功能,应用于外墙保温可以一次安装完成,省去二次抹灰和装饰施工,经济效益和社会效益显著。产生上述有益效果的原因主要包括以下五个方面:
第一、烧结工程弃土膨胀珍珠岩保温装饰一体化板中工程弃土等固体废弃物占比达50~80%,固废利用率高,充分利用城市建设中开挖而无法回填的工程弃土。
第二、通过发泡注浆成型或入模振动成型技术,避免传统膨胀珍珠岩板由于压制成型带来的大量膨胀珍珠岩破损问题,这会显著减低膨胀珍珠岩保温板的密度和导热系数。
第三、通过预发泡技术获得发泡的保温基层板坯,然后进行烧结,使得膨胀珍珠岩粒间间隙充满高温烧结而成的高强度闭孔陶瓷气泡,这不仅提高了保温板的强度,而且闭孔气泡有效地限制了空气的对流,显著降低基层膨胀珍珠保温板的导热系数。
第四、采用高温烧结技术,使得膨胀珍珠岩颗粒表面玻化,粒间形成闭孔气泡,装饰面层形成釉面,这都会显著降低保温板的吸水率,提高保温板的耐久性。
第五、通过复合玻璃纤维、莫来石纤维和玄武岩纤维,有效提高板材的抗压强度、抗折强度和抗冲击性能。
第六、采用低温釉烧结技术,在烧结前施釉,保温基层和装饰面层一次烧结完成,提高制备效率,降低生产成本。
本发明设计合理,高效利固体废弃物的同时,制备的烧结工程弃土膨胀珍珠岩保温板还兼具防火、保温、装饰一体化功能,具有很好的市场应用及推广价值。
具体实施方式
下面对本发明的具体实施例进行详细说明。
一种烧结工程弃土膨胀珍珠岩保温装饰一体化板,具体实施例见表1、表2、表3和表4所示。
表1所示为各实施例对应的保温基层原材料。表2所示为各实施例对应的保温基层原材料的重量份数。表3所示为各实施例对应的装饰面层原材料的重量份数。表4所示为各实施例对应的烧结温度、烧结时间,以及试验测得的烧结工程弃土膨胀珍珠岩保温装饰一体化板抗压强度和导热系数。
各实施例中烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法具体步骤如下:
(1)、将工程弃土采用球磨机湿磨0.5~1h,然后105℃烘干至恒重,过200目方孔筛;
(2)、将步骤(1)获得的工程弃土与粘结剂、发泡剂、稳泡剂、增强纤维、助熔剂、水按比例混合,通过物理发泡方式,高速搅拌获得发泡浆料;
(3)、将步骤(2)的发泡浆料与膨胀珍珠岩均匀混合、包裹,直接注模成型,固化2~24h,然后拆模获得发泡保温基层板坯;
(4)、将二氧化硅、氧化锌、氧化硼、氧化铝、氧化锂、着色剂、分散剂、消泡剂和水按比例混合,采用球磨机湿磨3~12h,获得装饰面层釉浆;
(5)采用步骤(4)获得的釉浆在步骤(3)获得的保温基层板坯表面施釉;
(6)将步骤(5)获得的板坯入高温炉烧结,烧结温度750~850℃,烧结时间0.5~1h,然后以10℃/min快速降温至500℃,保温0.5h,最后退火至常温,获得烧结工程弃土膨胀珍珠岩保温装饰一体化板。
表1各实施例对应的保温基层原材料
注:*膨胀珍珠岩也可以为球形闭孔膨胀珍珠岩、玻化微珠、纳米膨胀珍珠岩中的一种。
表2 实施例对应的保温基层原材料重量份数
表3 施例对应的装饰面层原材料重量份数
表4 烧结膨胀珍珠岩保温板烧结温度、烧结时间及物理力学性能
由表4可知,本实施例制备的烧结煤废膨胀珍珠岩保温装饰一体化板导热系数≤0.042W/(m·K),抗压强度≥0.60MPa,吸水率≤5%。其中,实施例1、实施例4、实施例5制备的保温装饰一体化板性能相对更好;而且,实施例5制备的保温装饰一体化板的导热系数为0.034W/(m·K),抗压强度达到0.9MPa,吸水率低至0.9%,综合性能最优。
本发明实施例制备的烧结工程弃土膨胀珍珠岩保温装饰一体化板采用物理发泡注浆和直接注模成型,结合高温烧结相结合的工艺,显著提高了自身保温性能、力学性能和耐久性,高效利用固体废弃物的同时,还兼具防火、保温、装饰一体化的功能特点。
最后所应说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照本发明实施例进行了详细说明,本领域的普通技术人员应当理解,对本发明的技术方案进行修改或者等同替换,都不脱离本发明的技术方案的精神和范围,其均应涵盖权利要求保护范围中。
Claims (10)
1.一种烧结工程弃土膨胀珍珠岩保温装饰一体化板,其特征在于:由保温基层和装饰面层组成;
其中,保温基层按以下原材料的重量份数烧制而成:工程弃土50~80份,膨胀珍珠岩50~80份,粘结剂5~10份,发泡剂0.5~1份,稳泡剂2~6份,增强纤维6~8份,助熔剂0.2~0.3份,水30~50份;
装饰面层按以下原材料的重量份数烧制而成:二氧化硅20~70份,氧化锌30~80份,氧化硼5~8份,氧化铝2~4份,氧化锂0.5~2份,着色剂0.5~3份,分散剂0.2~0.3份,消泡剂0.1~0.4份,水20~40份。
2.根据权利要求1所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:包括如下步骤:
(1)、将工程弃土采用球磨机湿磨0.5~1h,然后105℃烘干至恒重,过200目筛;
(2)、将步骤(1)获得的工程弃土与粘结剂、发泡剂、稳泡剂、增强纤维、助熔剂、水按比例混合,通过化学发泡方式或物理发泡方式获得发泡浆料;
(3)、将步骤(2)的发泡浆料与膨胀珍珠岩均匀混合、包裹,直接注模成型或入模振动成型,固化2~24h,然后拆模获得发泡保温基层板坯;
(4)、将二氧化硅、氧化锌、氧化硼、氧化铝、氧化锂、着色剂、分散剂、消泡剂和水按比例混合,采用球磨机湿磨3~12h,获得装饰面层釉浆;
(5)、采用步骤(4)获得的釉浆在步骤(3)获得的保温基层板坯表面施釉;
(6)、将步骤(5)获得的板坯入高温炉烧结,烧结温度750~850℃,烧结时间0.5~1h,然后快速降温至500℃,保温0.5h,最后退火至常温,获得烧结工程弃土膨胀珍珠岩保温装饰一体化板。
3.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述工程弃土为城市建设中开挖土方无法回填和利用的工程废弃土。
4.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述膨胀珍珠岩由球形闭孔膨胀珍珠岩、玻化微珠或者纳米膨胀珍珠岩替换。
5.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述粘结剂为水泥、水玻璃、磷酸或者聚乙烯醇。
6.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述物理发泡方式采用的发泡剂是植物发泡剂、动物发泡剂中的一种或两种复合;所述化学发泡方式采用的发泡剂为双氧水。
7.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述稳泡剂是明胶、聚丙烯酸钠或者蛋白质稳泡剂。
8.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述增强纤维是玻璃纤维、莫来石纤维或者玄武岩纤维。
9.根据权利要求2所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述助熔剂是玻璃粉、氧化钠、菱镁矿或者赤泥。
10.根据权利要求3所述的烧结工程弃土膨胀珍珠岩保温装饰一体化板的制备方法,其特征在于:所述纳米膨胀珍珠岩是指通过在膨胀珍珠岩孔洞填充气凝胶复合而合成的纳米多孔材料。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810028753.1A CN108129135B (zh) | 2018-01-12 | 2018-01-12 | 烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810028753.1A CN108129135B (zh) | 2018-01-12 | 2018-01-12 | 烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108129135A true CN108129135A (zh) | 2018-06-08 |
CN108129135B CN108129135B (zh) | 2021-03-02 |
Family
ID=62399609
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810028753.1A Active CN108129135B (zh) | 2018-01-12 | 2018-01-12 | 烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108129135B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108689603A (zh) * | 2018-06-20 | 2018-10-23 | 桐乡市乌镇内利仿古园林建设有限公司 | 用于古建筑琉璃瓦的干法生产工艺 |
CN111153710A (zh) * | 2020-01-13 | 2020-05-15 | 山东晟世达科技有限公司 | 一种高强低导热发泡陶瓷和使用该发泡陶瓷的复合板及其制备方法 |
CN113480291A (zh) * | 2021-08-11 | 2021-10-08 | 信阳科美新型材料有限公司 | 一种脱玻化珍珠岩制备的陶瓷透水砖及其制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1072664A (zh) * | 1991-11-29 | 1993-06-02 | 中国建筑材料科学研究院高技术陶瓷研究所 | 低温烧成、低膨胀性釉料 |
CN104513041A (zh) * | 2013-09-29 | 2015-04-15 | 佛山市顺德区北航先进技术产业基地有限公司 | 一种无机纤维增强隔热保温板 |
CN104529301A (zh) * | 2014-12-23 | 2015-04-22 | 太原理工大学 | 含纳米珍珠岩的建筑保温混凝土及其制备方法 |
WO2015056138A1 (de) * | 2013-10-14 | 2015-04-23 | Adt Aero Dämm Technik Gmbh | Stabile formkörper oder platten aus leichtbaumaterail zur wärmedämmung und zur verwendung als brandschutz, das verfahren zu ihrer herstellung, ihre verwendung und ein damit augerüstetes bauwerk |
CN104860703A (zh) * | 2015-05-04 | 2015-08-26 | 深圳市士高岩土技术工程有限公司 | 一种以工程弃土为原料的泡沫砖的制备方法 |
CN105669173A (zh) * | 2016-01-11 | 2016-06-15 | 信阳科美新型材料有限公司 | 一种综合利用珍珠岩废弃物生产的保温装饰陶瓷板及其生产方法 |
CN106082830A (zh) * | 2016-06-25 | 2016-11-09 | 张莘蔓 | 一种保温砖 |
-
2018
- 2018-01-12 CN CN201810028753.1A patent/CN108129135B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1072664A (zh) * | 1991-11-29 | 1993-06-02 | 中国建筑材料科学研究院高技术陶瓷研究所 | 低温烧成、低膨胀性釉料 |
CN104513041A (zh) * | 2013-09-29 | 2015-04-15 | 佛山市顺德区北航先进技术产业基地有限公司 | 一种无机纤维增强隔热保温板 |
WO2015056138A1 (de) * | 2013-10-14 | 2015-04-23 | Adt Aero Dämm Technik Gmbh | Stabile formkörper oder platten aus leichtbaumaterail zur wärmedämmung und zur verwendung als brandschutz, das verfahren zu ihrer herstellung, ihre verwendung und ein damit augerüstetes bauwerk |
CN104529301A (zh) * | 2014-12-23 | 2015-04-22 | 太原理工大学 | 含纳米珍珠岩的建筑保温混凝土及其制备方法 |
CN104860703A (zh) * | 2015-05-04 | 2015-08-26 | 深圳市士高岩土技术工程有限公司 | 一种以工程弃土为原料的泡沫砖的制备方法 |
CN105669173A (zh) * | 2016-01-11 | 2016-06-15 | 信阳科美新型材料有限公司 | 一种综合利用珍珠岩废弃物生产的保温装饰陶瓷板及其生产方法 |
CN106082830A (zh) * | 2016-06-25 | 2016-11-09 | 张莘蔓 | 一种保温砖 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108689603A (zh) * | 2018-06-20 | 2018-10-23 | 桐乡市乌镇内利仿古园林建设有限公司 | 用于古建筑琉璃瓦的干法生产工艺 |
CN111153710A (zh) * | 2020-01-13 | 2020-05-15 | 山东晟世达科技有限公司 | 一种高强低导热发泡陶瓷和使用该发泡陶瓷的复合板及其制备方法 |
CN111153710B (zh) * | 2020-01-13 | 2022-04-29 | 山东晟世达科技有限公司 | 一种高强低导热发泡陶瓷和使用该发泡陶瓷的复合板及其制备方法 |
CN113480291A (zh) * | 2021-08-11 | 2021-10-08 | 信阳科美新型材料有限公司 | 一种脱玻化珍珠岩制备的陶瓷透水砖及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN108129135B (zh) | 2021-03-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102877614B (zh) | 一种具有装饰性能的隔热保温陶瓷复合板的生产方法 | |
CN101239837B (zh) | 蜂窝混凝土及其制备方法 | |
CN103342578B (zh) | 利用铁尾矿制备的多孔保温装饰材料及其制备方法 | |
CN106542843B (zh) | 一种利用固体废弃物制备轻质保温墙体材料的方法 | |
CN101705741B (zh) | 相变自调温外墙保温饰面砖及其制作方法 | |
CN105418149A (zh) | 一种石材面蜂孔双层再生材料 | |
CN107586102A (zh) | 一种花岗岩废石粉泡沫陶瓷及其制备方法 | |
CN103011882A (zh) | 一种具有三级孔结构的无机保温材料及其制备方法 | |
CN111410513B (zh) | 一种高致孔率的薄型微孔复合陶板及其制备方法 | |
CN108129132A (zh) | 烧结煤废膨胀珍珠岩保温装饰一体化板及其制备方法 | |
CN108129135A (zh) | 烧结工程弃土膨胀珍珠岩保温装饰一体化板及其制备方法 | |
CN108546034A (zh) | 一种隔音保温的混凝土组合物 | |
CN110616862A (zh) | 一种轻质安全保温装饰一体板及其制备方法 | |
CN112025971A (zh) | 一种保温装饰一体化外墙的制备方法及外墙 | |
CN204418481U (zh) | 一种利用尾砂生产的微晶发泡墙体砌块 | |
CN112028649A (zh) | 一种节能环保的耐火砖及其制备方法 | |
CN108358659A (zh) | 一种隔音、保温型空心砖及其制备方法 | |
CN103979862B (zh) | 一种节能环保材料、制备方法及其在建筑***中的应用 | |
CN109133862A (zh) | 利用铁尾矿制备的多孔保温装饰材料及其制备方法 | |
CN107935624A (zh) | 一种自保温轻骨料砌块及其制备方法 | |
CN101134657A (zh) | 环保型复合保温砂浆 | |
CN201459966U (zh) | 建筑物自保温墙体结构 | |
CN105622158A (zh) | 一种微晶面蜂孔双层再生材料 | |
CN102229490A (zh) | 一种水泥板材及其制备方法 | |
CN110158849B (zh) | 一种建筑砖块 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20210202 Address after: Room 649, building 4, science and technology innovation incubation base, 11 Kangshou street, Tanghuai Park, Taiyuan City, Shanxi comprehensive reform demonstration zone Applicant after: Shanxi Shengke Microbial Building Materials Technology Co.,Ltd. Address before: 030000 2402, unit 1, building 9, Xinghewan 2 Park, Xiaodian District, Taiyuan City, Shanxi Province Applicant before: Li Zhu |
|
TA01 | Transfer of patent application right | ||
GR01 | Patent grant | ||
GR01 | Patent grant |