CN108117848A - A kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane - Google Patents
A kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane Download PDFInfo
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- CN108117848A CN108117848A CN201711402545.5A CN201711402545A CN108117848A CN 108117848 A CN108117848 A CN 108117848A CN 201711402545 A CN201711402545 A CN 201711402545A CN 108117848 A CN108117848 A CN 108117848A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
- C09J2301/208—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being constituted by at least two or more adjacent or superposed adhesive layers, e.g. multilayer adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/20—Presence of organic materials
- C09J2400/26—Presence of textile or fabric
- C09J2400/263—Presence of textile or fabric in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2463/00—Presence of epoxy resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2495/00—Presence of bitume
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane, including upper surface layer, upper chemically-resistant adhesive layer, the upper self-adhesion asphalt adhesive bed of material, carcass, the lower self-adhesion asphalt adhesive bed of material, lower chemically-resistant adhesive layer and the lower surface isolation film set gradually from top to bottom.Chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane uses multi-layer compound structure, pass through the combination of physical and chemical performance between layers of material, the physical and chemical performance for changing self-adhesive glue layer is not had to not only, the excellent high temperature performance of conventional self-adhered polymer modified bitumen waterproofing membrane, tensile strength and elongation at break are made it have, while also has to corrosivity such as high salinity chloride permeabilities and excellent keeps out effect.
Description
Technical field
The present invention relates to waterproof roll technical fields, change in particular to a kind of chemically-resistant type self-adhering polymer
Property asphalt water-proof coiled material.
Background technology
Since the coastal contour persistent problem of varieties in saline-alkali areas waterproof of domestic and international waterproofing work bound pair is paid close attention to for a long time, do big
The experimental study of amount, many researchers also constantly deepen the durability awareness of waterproof material.
The thinking of mainstream is still the component improved inside waterproof material at present, then improves the saline-alkali tolerant of waterproof material
Property.But waterproof material, high temperature performance are mass produced with this thinking, tensile strength and fracture elongation do not ensure that and
Waterproof roll used in common area is equally excellent, this thinking, which will enter practice, still to have a long way to go.
I takes charge of a large amount of needs for this current problem and coastal contour varieties in saline-alkali areas, has changed a kind of thinking, from
Master has developed a kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane.
The content of the invention
It is a primary object of the present invention to provide a kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane, have
The excellent high temperature performance of conventional self-adhered polymer modified bitumen waterproofing membrane, tensile strength and elongation at break, while to height
The corrosivity such as saline and alkaline chloride permeability, which also have, excellent keeps out effect.
To achieve these goals, the present invention provides a kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane,
Upper surface layer, upper chemically-resistant adhesive layer, the upper self-adhesion asphalt adhesive bed of material, carcass, lower self-adhesion including setting gradually from top to bottom drip
Blue or green compound layer, lower chemically-resistant adhesive layer and lower surface isolation film；Upper surface layer is PE isolation films, PET isolation films, PET aluminium films
In any one；Upper chemically-resistant adhesive layer is identical with the material of lower chemically-resistant adhesive layer, is made of epoxy resin；Upper self-adhesion
The asphalt adhesive bed of material is identical with the material of the lower self-adhesion asphalt adhesive bed of material, is made of following ingredient according to mass fraction：No. 10 drips
Green grass or young crops is more than or equal to 30 parts and is less than or equal to 50 parts, and heavy traffic paving asphalt is more than or equal to 30 parts and is less than or equal to 50 parts, and modifying agent is more than or equal to 3 parts
Less than or equal to 8 parts；Tackifier are more than or equal to 1 part and are less than or equal to 3 parts, and filler is more than or equal to 10 parts and is less than or equal to 12 parts, softening oil
It is less than or equal to 5 parts more than or equal to 3 parts；Lower surface isolation film is linear saturated polyester's resin；Carcass is polyester blank, glass fiber blank, glass
Any one in fiber reinforced polyester felt.
Further, the needle penetration of heavy traffic paving asphalt is 60-100.
Further, filler is precipitated calcium carbonate, in powdered whiting, mountain flour, pulverized limestone, flyash, talcum powder, carbon black
One or more mixtures.
Further, softening oil is one or more miscella groups by mineral oil, synthetic oil, semi synthetic base oils or vegetable oil
Into.
Further, tackifier are C5-C9 Petropols, alkyl phenol resin, liquid rosin resin, terpene resin, hydrogenation
One or more mixtures in rosin glyceride, phenolic resin, epoxy resin, polyisobutene.
Further, modifying agent is made of following ingredient according to mass fraction：Polybutene is more than or equal to 8 parts and is less than or equal to 10
Part, epoxy resin is more than or equal to 4 parts and is less than or equal to 7 parts, and aluminium oxide is more than or equal to 1 and is less than or equal to 3 parts, and silica nanometer powder is big
In equal to 1 part be less than or equal to 2 parts.
It applies the technical scheme of the present invention, chemically-resistant type self-adhered polymer modified asphalt membrane includes upper successively from top to bottom
Superficial layer, upper chemically-resistant adhesive layer, the upper self-adhesion asphalt adhesive bed of material, carcass, the lower self-adhesion asphalt adhesive bed of material, lower chemically-resistant adhesive layer with
And lower surface every, using multi-layer compound structure, by the combination of physical and chemical performance between layers of material, do not have to not only to change from
The physical and chemical performance of adhesive-layer, make it have the excellent high temperature performance of conventional self-adhered polymer modified bitumen waterproofing membrane,
Tensile strength and elongation at break, while also have to corrosivity such as high salinity chloride permeabilities and excellent keep out effect.
Description of the drawings
The accompanying drawings which form a part of this application are used for providing a further understanding of the present invention, and of the invention shows
Meaning property embodiment and its explanation do not constitute improper limitations of the present invention for explaining the present invention.In the accompanying drawings：
Fig. 1 shows the structure diagram of the chemically-resistant type self-adhered polymer modified asphalt membrane of the present invention.
Wherein, above-mentioned attached drawing is marked including the following drawings：
10th, upper surface layer；20th, upper chemically-resistant adhesive layer；30th, the upper self-adhesion asphalt adhesive bed of material；40th, carcass；50th, lower self-adhesion asphalt adhesive
The bed of material；60th, lower chemically-resistant adhesive layer；70、；Lower surface isolation film.
Specific embodiment
It should be noted that in the case where there is no conflict, the feature in embodiment and embodiment in the application can phase
Mutually combination.The present invention will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.It is unless another
It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field
The identical meanings of understanding.
In the present invention, in the case where not making explanation on the contrary, the noun of locality such as " upper and lower, top, bottom " used is typically pin
For direction shown in the drawings or for component in itself on vertical, vertical or gravity direction for；Equally
Ground for ease of understanding and describes, and " inside and outside " refers to the inside and outside of the profile compared with each component in itself, but the above-mentioned noun of locality is not
For limiting the present invention.
As shown in Figure 1, chemically-resistant type self-adhered polymer modified asphalt membrane from top to bottom successively include upper surface layer 10, on
Chemically-resistant adhesive layer 20, the upper self-adhesion asphalt adhesive bed of material 30, carcass 40, the lower self-adhesion asphalt adhesive bed of material 50, lower chemically-resistant adhesive layer 60
And lower surface isolation film 70.
The upper surface layer 10 is any one in PE isolation films, PET isolation films, PET aluminium films.
The upper chemically-resistant adhesive layer 20 is identical with the structure of lower chemically-resistant adhesive layer 60, is made of epoxy resin.
The upper self-adhesion asphalt adhesive bed of material 30 is identical with the structure of the lower self-adhesion asphalt adhesive bed of material 50, by as follows into
Divide and formed according to mass fraction：No. 10 pitches are more than or equal to 30 parts and are less than or equal to 50 parts, and heavy traffic paving asphalt is less than more than or equal to 30 parts
Equal to 50 parts, modifying agent is more than or equal to 3 parts and is less than or equal to 8 parts；Tackifier are more than or equal to 1 part less than or equal to 3 parts, and filler is more than etc.
It is less than or equal to 12 parts in 10 parts, softening oil is more than or equal to 3 parts and is less than or equal to 5 parts.Wherein, the needle penetration of the heavy traffic paving asphalt（It is single
Position 0.1mm）For 60-100.The filler is precipitated calcium carbonate, powdered whiting, mountain flour, pulverized limestone, flyash, talcum powder, charcoal
One or more mixtures in black.The softening oil be by mineral oil, synthetic oil, semi synthetic base oils or vegetable oil one kind or
A variety of miscella compositions.The tackifier are C5-C9 Petropols, alkyl phenol resin, liquid rosin resin, terpene resin, hydrogen
Change one or more mixtures in rosin glyceride, phenolic resin, epoxy resin, polyisobutene.For improving tack
With bonding persistence.The modifying agent is mixed using following ingredient：Polybutene is more than or equal to 8 parts and is less than or equal to 10 parts, ring
Oxygen resin is more than or equal to 4 parts and is less than or equal to 7 parts, and aluminium oxide is more than or equal to 1 less than or equal to 3 parts, and silica nanometer powder is more than etc.
It is less than or equal to 2 parts in 1 part so that self-adhesion asphalt adhesive bed of material deformability is high, and low-temperature resistance cracking ability is strong.
The lower surface isolation film 70 is linear saturated polyester's resin；Lower surface isolation film 70 has wax on one side, on one side without wax,
The one side and adhesive layer for having wax fit together.
The carcass 40 is any one in polyester blank, glass fiber blank, fiberglass reinforcing polyester felt.
In conclusion the chemically-resistant type self-adhered polymer modified asphalt membrane includes upper surface layer successively from top to bottom
10th, upper chemically-resistant adhesive layer 20, the upper self-adhesion asphalt adhesive bed of material 30, carcass 40, the lower self-adhesion asphalt adhesive bed of material 50, lower chemically-resistant gluing
Layer 60 and lower surface isolation.The present invention is using multi-layer compound structure, by the combination of physical and chemical performance between layers of material,
Do not have to the physical and chemical performance for changing self-adhesive glue layer not only, it is excellent to make it have conventional self-adhered polymer modified bitumen waterproofing membrane
High temperature performance, tensile strength and elongation at break, while also have excellent support to corrosivity such as high salinity chloride permeabilities
Gear acts on.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root
According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singulative
It is also intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " bag
Include " when, indicate existing characteristics, step, work, device, component and/or combination thereof.
It should be noted that term " comprising " and " tool in the description and claims of this application and above-mentioned attached drawing
Have " and their any deformation, it is intended that cover it is non-exclusive include, for example, containing series of steps or unit
Process, method, system, product or equipment are not necessarily limited to those steps or unit clearly listed, but may include without clear
It is listing to Chu or for the intrinsic other steps of these processes, method, product or equipment or unit.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, for the skill of this field
For art personnel, the invention may be variously modified and varied.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should all be included in the protection scope of the present invention.
Claims (6)
1. a kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane, which is characterized in that including setting gradually from top to bottom
Upper surface layer（10）, upper chemically-resistant adhesive layer（20）, the upper self-adhesion asphalt adhesive bed of material（30）, carcass（40）, lower self-adhesion asphalt adhesive
The bed of material（50）, lower chemically-resistant adhesive layer（60）And lower surface isolation film（70）；The upper surface layer（10）For PE isolation films,
Any one in PET isolation films, PET aluminium films；The upper chemically-resistant adhesive layer（20）With lower chemically-resistant adhesive layer（60）Material
Matter is identical, is made of epoxy resin；The upper self-adhesion asphalt adhesive bed of material（30）With the lower self-adhesion asphalt adhesive bed of material（50）'s
Material is identical, is made of following ingredient according to mass fraction：No. 10 pitches are more than or equal to 30 parts and are less than or equal to 50 parts, hand over again
Pitch is more than or equal to 30 parts and is less than or equal to 50 parts, and modifying agent is more than or equal to 3 parts and is less than or equal to 8 parts；Tackifier are more than or equal to 1 part small
In equal to 3 parts, filler is more than or equal to 10 parts and is less than or equal to 12 parts, and softening oil is more than or equal to 3 parts and is less than or equal to 5 parts；The following table
Face isolation film（70）For linear saturated polyester's resin；The carcass（40）For in polyester blank, glass fiber blank, fiberglass reinforcing polyester felt
Any one.
2. chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane according to claim 1, which is characterized in that described heavy
The needle penetration for handing over pitch is 60-100.
3. chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane according to claim 1, which is characterized in that described to fill out
Expect for one or more mixing in precipitated calcium carbonate, powdered whiting, mountain flour, pulverized limestone, flyash, talcum powder, carbon black
Object.
4. chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane according to claim 1, which is characterized in that described soft
Carburetion is made of one or more miscellas of mineral oil, synthetic oil, semi synthetic base oils or vegetable oil.
5. chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane according to claim 1, which is characterized in that the increasing
Stick for C5-C9 Petropols, alkyl phenol resin, liquid rosin resin, terpene resin, hydrogenated rosin glyceride, phenolic resin,
One or more mixtures in epoxy resin, polyisobutene.
6. chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane according to claim 1, which is characterized in that described to change
Property agent is made of following ingredient according to mass fraction：Polybutene is more than or equal to 8 parts and is less than or equal to 10 parts, and epoxy resin is more than or equal to
4 parts are less than or equal to 7 parts, and aluminium oxide is more than or equal to 1 and is less than or equal to 3 parts, and silica nanometer powder is more than or equal to 1 part and is less than or equal to 2
Part.
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| CN201711402545.5A CN108117848A (en) | 2017-12-22 | 2017-12-22 | A kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane |
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| CN201711402545.5A CN108117848A (en) | 2017-12-22 | 2017-12-22 | A kind of chemically-resistant type self-adhered polymer modified bitumen waterproofing membrane |
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|---|---|---|---|---|
| CN109504301A (en) * | 2018-10-31 | 2019-03-22 | 山东清池防水材料股份有限公司 | A kind of prespreading waterproof roll and preparation method thereof |
| CN109627798A (en) * | 2018-12-29 | 2019-04-16 | 东莞东交沥青有限公司 | A kind of enhancing blending type butadiene-styrene rubber modified emulsifying asphalt and preparation method thereof |
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| CN109627798A (en) * | 2018-12-29 | 2019-04-16 | 东莞东交沥青有限公司 | A kind of enhancing blending type butadiene-styrene rubber modified emulsifying asphalt and preparation method thereof |
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