CN108117779A - A kind of generation negative oxygen ion environmental protection coating material and preparation method thereof - Google Patents
A kind of generation negative oxygen ion environmental protection coating material and preparation method thereof Download PDFInfo
- Publication number
- CN108117779A CN108117779A CN201711392769.2A CN201711392769A CN108117779A CN 108117779 A CN108117779 A CN 108117779A CN 201711392769 A CN201711392769 A CN 201711392769A CN 108117779 A CN108117779 A CN 108117779A
- Authority
- CN
- China
- Prior art keywords
- acid salt
- urocanic acid
- ethyl ester
- parts
- conditions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
- C07D233/58—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/24—Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D235/26—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/24—Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D235/28—Sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention is related to a kind of generation negative oxygen ion environmental protection coating material, including following raw material components：2 sulfydryl benzos（Ethyl ester）Urocanic acid salt, 2 hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, methyl-propyl urocanic acid salt, modified verdelite, ZX X1011 antifoaming agent, 819 photoinitiators, 2 sulfydryl benzos（Ethyl ester）Urocanic acid salt is reacted by 2 mercaptobenzimidazoles, ethyl acrylate and maleic acid to be made, 2 hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt is reacted by 2 hydroxybenzimidazoles, hydroxy-ethyl acrylate, hydroxypropyl acrylate and acrylic acid to be made, methyl-propyl urocanic acid salt is reacted by methylimidazole, propyl acrylate, acrylamide and ethyl methacrylate to be made, and modified verdelite reacts obtained by tourmaline, acrylic acid, 550 silane coupling agents of KH, 03 cationic gemini emulsifiers of HL, 801 novel environment-friendly anion surfactants of AS and BYK 1150.The invention has excellent adhesive force and releasing negative oxygen ion performance.
Description
Technical field
The invention is related to a kind of generation negative oxygen ion environmental protection coating material and preparation method thereof.
Background technology
Acrylic coating is one of common synthetic paint.Acrylic coating has excellent weatherability, chemical-resistant resistance
The performances such as property, colour retention, gloss retention, anti-corrosive properties.Acrylic coating is widely used in automobile, mechanical equipment, ship, mine smelting
The fields such as gold, furniture, instrument and meter, terrace, outdoor advertising.
At present, acrylic coating needs further to be promoted in adhesive force and releasing negative oxygen ion performance.The invention uses 2-
Sulfydryl benzo（Ethyl ester）Urocanic acid salt, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, methyl-propyl urocanic acid
Salt, modified verdelite, ZX-X1011 antifoaming agent, 819 photoinitiators are prepared for generating negative oxygen ion environmental protection coating material, prepared by this method
The negative oxygen ion environmental protection coating material of generating there is excellent adhesive force and releasing negative oxygen ion performance.
The content of the invention
The invention is designed to provide a kind of preparation method for generating negative oxygen ion environmental protection coating material, and this method passes through change
Reactant feed and technology mode, the material of preparation have excellent adhesive force and releasing negative oxygen ion performance.
To achieve these goals, the technical solution of the invention is as follows.
A kind of generation negative oxygen ion environmental protection coating material and preparation method thereof, specifically includes following steps：(1), by tourmaline and
Acrylic acid is 80 according to quality parts ratio：25~31 are added in hydrothermal reaction kettle, maintain hydrothermal temperature as 45 DEG C of reactions
25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product and matter
It is 0.5~1 to measure portion rate：0.7~1.6：0.6~1.4：0.4~1 KH-550 silane coupling agents, HL-03 cationic geminis breast
Agent, AS-801 novel environment-friendlies anion surfactant and BYK-1150 are added in grinder, grinding rate for 300~
390r/min reacts 10~25min under the conditions of 35~44 DEG C of maintenance system temperature, and product washs 4 times through 1L EtOH Sonicates, in
75 DEG C, -0.07MPa vacuum drying 6min, obtain modified verdelite；(2), by methylimidazole, propyl acrylate, acrylamide and
Ethyl methacrylate is 53 according to quality parts ratio：58~66：2~6：4~9 are added in reaction kettle, mixing speed 85
~98r/min reacts 2~6h under the conditions of 123~135 DEG C of reduced-pressure backflows of maintenance system temperature, temperature of reaction kettle is risen to 120
DEG C, continue vacuum distillation reaction 1h under the conditions of -0.07MPa, obtain methyl-propyl urocanic acid salt；(3), by 2- hydroxy benzos
Imidazoles, hydroxy-ethyl acrylate, hydroxypropyl acrylate and acrylic acid are according to quality parts ratio 70：75~83：7~15：3~7 add in
Into reaction kettle, mixing speed be 80~93r/min, 99~110 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflow conditions
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxyls by 2~6h of lower reaction
Base benzo（Hydroxyl ethyl ester）Urocanic acid salt；(4), by 2-mercaptobenzimidazole, ethyl acrylate and maleic acid according to matter
Measure portion rate 60：87~96：4~9 are added in hydrothermal reaction kettle, under the conditions of 135~150 DEG C of maintenance system temperature react 2~
5h, product is through continuing vacuum distillation reaction 1h to get to 2- sulfydryl benzos under the conditions of 115 DEG C, -0.07MPa（Ethyl ester）Imidazoles third
Olefin(e) acid salt；(5), by 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, methyl
Propyl imidazole acrylates, modified verdelite, ZX-X1011 antifoaming agent, 819 photoinitiators are according to quality parts ratio 45：36~
49：25~33：23~36：0.2~0.5：0.4~1 is added in reaction kettle, mixing speed be 72~85r/min, maintenance system
Under the conditions of 33~40 DEG C of temperature react 22~40min to get to generate negative oxygen ion environmental protection coating material.
The preparation method of generation negative oxygen ion environmental protection coating material described in the invention, comprises the following steps：
(1), it is 80 according to quality parts ratio by tourmaline and acrylic acid：25~31 are added in hydrothermal reaction kettle, maintain hydro-thermal
Reaction temperature is 45 DEG C of reaction 25min, and product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, dry through 120 DEG C
Product and quality parts ratio are 0.5~1 by dry 15min：0.7~1.6：0.6~1.4：0.4~1 KH-550 is silane coupled
Agent, HL-03 cationic geminis emulsifier, AS-801 novel environment-friendlies anion surfactant and BYK-1150 are added to grinding
In machine, grinding rate is 300~390r/min, and 10~25min, product warp are reacted under the conditions of 35~44 DEG C of maintenance system temperature
1L EtOH Sonicates wash 4 times, in 75 DEG C, -0.07MPa vacuum drying 6min, obtain modified verdelite；The KH-550 silane
The purpose of coupling agent, HL-03 cationic geminis emulsifier and AS-801 novel environment-friendly anion surfactants is in order to improve
The compatibility and dispersion stabilization of electrical powder and storeroom；The purpose of the acrylic acid is in order to improve the surface defect of tourmaline
Rate.
(2), it is 53 according to quality parts ratio by methylimidazole, propyl acrylate, acrylamide and ethyl methacrylate：
58~66：2~6：4~9 are added in reaction kettle, mixing speed be 85~98r/min, 123~135 DEG C of maintenance system temperature
2~6h is reacted under the conditions of reduced-pressure backflow, temperature of reaction kettle is risen to 120 DEG C, continues vacuum distillation reaction under the conditions of -0.07MPa
1h obtains methyl-propyl urocanic acid salt；The purpose of the methylimidazole is in order to improve methyl-propyl urocanic acid salt
Ion and charge conductibility.
(3), by 2- hydroxybenzimidazoles, hydroxy-ethyl acrylate, hydroxypropyl acrylate and acrylic acid according to quality parts ratio
70：75~83：7~15：3~7 are added in reaction kettle, mixing speed be 80~93r/min, maintenance system temperature 99~110
DEG C, 2~6h is reacted under the conditions of -0.06MPa reduced-pressure backflows, temperature of reaction kettle is risen to 115 DEG C, continues to subtract under the conditions of -0.07MPa
Distillation reaction 1h is pressed to get to 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt；The purpose of the 2- hydroxybenzimidazoles
In order to improve 2- hydroxy benzos（Hydroxyl ethyl ester）The ion of urocanic acid salt and the conductibility of charge.
(4), by 2-mercaptobenzimidazole, ethyl acrylate and maleic acid according to quality parts ratio 60：87~96：4
~9 are added in hydrothermal reaction kettle, under the conditions of 135~150 DEG C of maintenance system temperature react 2~5h, product through 115 DEG C ,-
Continue vacuum distillation reaction 1h under the conditions of 0.07MPa to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；The 2- mercaptos
The purpose of base benzimidazole is in order to improve 2- sulfydryl benzos（Ethyl ester）The ion of urocanic acid salt and the conductibility of charge.
(5), by 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, first
Base propyl imidazole acrylates, modified verdelite, ZX-X1011 antifoaming agent, 819 photoinitiators are according to quality parts ratio 45：36~
49：25~33：23~36：0.2~0.5：0.4~1 is added in reaction kettle, mixing speed be 72~85r/min, maintenance system
Under the conditions of 33~40 DEG C of temperature react 22~40min to get to generate negative oxygen ion environmental protection coating material.
The advantageous effect of the invention is：
1st, acrylic acid can carry out microcorrosion to tourmaline surface, improve the specific surface area of tourmaline, and it is negative to improve tourmaline release
The performance of oxonium ion；KH-550 silane coupling agents, HL-03 cationic geminis emulsifier and AS-801 novel environment-friendly anion tables
Face activating agent is surface modified by the tourmaline after modifying acrylic acid, can be improved compatible between tourmaline and unclassified stores
Property, scattered and storage stability；Finally, modified verdelite can improve the releasing negative oxygen ion performance of coating；
2nd, addition reaction can occur for methylimidazole and propyl acrylate, ethyl methacrylate, generate methyl-propyl imidazoles propylene
Hydrochlorate ionic liquid, methyl-propyl urocanic acid salt can improve the conductibility of ion and charge, can improve the negative oxygen of coating release
The performance and adhesive force of ion；
3rd, addition reaction can occur for 2- hydroxybenzimidazoles and hydroxy-ethyl acrylate, hydroxypropyl acrylate, generate 2- hydroxy benzos
（Hydroxyl ethyl ester）Urocanic acid ionic liquid, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt can improve ion and charge
Conductibility can improve the performance and adhesive force of coating releasing negative oxygen ion；
4th, addition reaction can occur for 2-mercaptobenzimidazole and ethyl acrylate, generate 2- sulfydryl benzos（Ethyl ester）Urocanic acid
Ionic liquid, 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt can improve the conductibility of ion and charge, can improve coating and release
Put the performance and adhesive force of negative oxygen ion；
5th, in 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, methyl-propyl
Under urocanic acid salt, modified verdelite, ZX-X1011 antifoaming agent, 819 photoinitiators synergistic effect, assign and generate negative oxygen ion
The excellent adhesive force of environmental protection coating material and releasing negative oxygen ion performance.
Specific embodiment
The specific embodiment of the invention is described with reference to embodiment, to be better understood from the invention.
Embodiment 1
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 27 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.5 part of KH-550 silane coupling agent, 0.8 part of HL-03 cationic geminis emulsifier, 0.9 part of AS-801 novel environment-friendly anion
Surfactant, 0.5 part of BYK-1150 are added in grinder, grinding rate 340r/min, 37 DEG C of items of maintenance system temperature
15min is reacted under part, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified electricity
Gas stone；
(2), 53 parts of methylimidazoles, 60 parts of propyl acrylates, 2.5 parts of acrylamides and 5.5 parts of ethyl methacrylate are weighed to add
Enter into reaction kettle, mixing speed 90r/min, 2.5h is reacted under the conditions of 130 DEG C of reduced-pressure backflows of maintenance system temperature, it will be anti-
Kettle temperature degree is answered to rise to 120 DEG C, continue vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 78 parts of hydroxy-ethyl acrylates, 8 parts of hydroxypropyl acrylates and 5 parts of acrylic acid are weighed to add
Enter into reaction kettle, mixing speed 85r/min, reacted under the conditions of 105 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos by 3h（Hydroxyl
Ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 90 parts of ethyl acrylates and 5.5 parts of maleic acids are weighed and are added to hydro-thermal reaction
In kettle, 3h is reacted under the conditions of 143 DEG C of maintenance system temperature, product is anti-through continuing vacuum distillation under the conditions of 115 DEG C, -0.07MPa
1h is answered to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 39 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 28 portions of methyl-propyl urocanic acid salt, 30 parts of modified verdelites, 0.3 part of ZX-X1011 antifoaming agent, 0.5 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 75r/min, and 250min is reacted under the conditions of 36 DEG C of maintenance system temperature to get to production
Raw negative oxygen ion environmental protection coating material.
Embodiment 2
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 25 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.5 part of KH-550 silane coupling agent, 0.7 part of HL-03 cationic geminis emulsifier, 0.6 part of AS-801 novel environment-friendly anion
Surfactant, 0.4 part of BYK-1150 are added in grinder, grinding rate 300r/min, 35 DEG C of items of maintenance system temperature
25min is reacted under part, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified electricity
Gas stone；
(2), 53 parts of methylimidazoles, 58 parts of propyl acrylates, 2 parts of acrylamides and 4 parts of ethyl methacrylate are weighed to be added to
In reaction kettle, mixing speed 85r/min reacts 6h under the conditions of 123 DEG C of reduced-pressure backflows of maintenance system temperature, will react kettle temperature
Degree rises to 120 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 75 parts of hydroxy-ethyl acrylates, 7 parts of hydroxypropyl acrylates and 3 parts of acrylic acid are weighed to add
Enter into reaction kettle, mixing speed 80r/min, reacted under the conditions of 99 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos by 6h（Hydroxyl
Ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 87 parts of ethyl acrylates and 4 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 5h is reacted under the conditions of 135 DEG C of maintenance system temperature, product is through continuing vacuum distillation reaction under the conditions of 115 DEG C, -0.07MPa
1h is to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 36 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 25 portions of methyl-propyl urocanic acid salt, 23 parts of modified verdelites, 0.2 part of ZX-X1011 antifoaming agent, 0.4 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 72r/min, and 40min is reacted under the conditions of 33 DEG C of maintenance system temperature to get to production
Raw negative oxygen ion environmental protection coating material.
Embodiment 3
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 31 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
25min is answered, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product and 1
Part KH-550 silane coupling agents, 1.6 parts of HL-03 cationic geminis emulsifiers, 1.4 parts of AS-801 novel environment-friendly anionic surfaces
Activating agent, 1 part of BYK-1150 are added in grinder, grinding rate 390r/min, anti-under the conditions of 44 DEG C of maintenance system temperature
10min is answered, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified verdelite；
(2), 53 parts of methylimidazoles, 66 parts of propyl acrylates, 6 parts of acrylamides and 9 parts of ethyl methacrylate are weighed to be added to
In reaction kettle, mixing speed 98r/min reacts 2h under the conditions of 135 DEG C of reduced-pressure backflows of maintenance system temperature, will react kettle temperature
Degree rises to 120 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 83 parts of hydroxy-ethyl acrylates, 15 parts of hydroxypropyl acrylates and 7 parts of acrylic acid are weighed to add
Enter into reaction kettle, mixing speed 93r/min, reacted under the conditions of 110 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos by 2h（Hydroxyl
Ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 96 parts of ethyl acrylates and 9 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 2h is reacted under the conditions of 150 DEG C of maintenance system temperature, product is through continuing vacuum distillation reaction under the conditions of 115 DEG C, -0.07MPa
1h is to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 49 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 33 portions of methyl-propyl urocanic acid salt, 36 parts of modified verdelites, 0.5 part of ZX-X1011 antifoaming agent, 1 part of 819 photoinitiator
It is added in reaction kettle, mixing speed 85r/min, 22min is reacted under the conditions of 40 DEG C of maintenance system temperature to get to generation
Negative oxygen ion environmental protection coating material.
Embodiment 4
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 28 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.7 part of KH-550 silane coupling agent, 1 part of HL-03 cationic geminis emulsifier, 1.2 parts of AS-801 novel environment-friendly anion tables
Face activating agent, 0.8 part of BYK-1150 are added in grinder, grinding rate 370r/min, 36 DEG C of conditions of maintenance system temperature
Lower reaction 18min, product wash 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtain modified electrical
Stone；
(2), 53 parts of methylimidazoles, 59 parts of propyl acrylates, 4 parts of acrylamides and 6 parts of ethyl methacrylate are weighed to be added to
In reaction kettle, mixing speed 87r/min reacts 4h under the conditions of 126 DEG C of reduced-pressure backflows of maintenance system temperature, will react kettle temperature
Degree rises to 120 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 79 parts of hydroxy-ethyl acrylates, 13 parts of hydroxypropyl acrylates and 6 parts of acrylic acid are weighed to add
Enter into reaction kettle, mixing speed 84r/min, reacted under the conditions of 100 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos by 5h（Hydroxyl
Ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 88 parts of ethyl acrylates and 6 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 4h is reacted under the conditions of 139 DEG C of maintenance system temperature, product is through continuing vacuum distillation reaction under the conditions of 115 DEG C, -0.07MPa
1h is to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 45 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 28 portions of methyl-propyl urocanic acid salt, 27 parts of modified verdelites, 0.3 part of ZX-X1011 antifoaming agent, 0.9 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 77r/min, and 26min is reacted under the conditions of 33 DEG C of maintenance system temperature to get to generation
Negative oxygen ion environmental protection coating material.
Embodiment 5
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 30 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.7 part of KH-550 silane coupling agent, 1.4 parts of HL-03 cationic geminis emulsifiers, 0.8 part of AS-801 novel environment-friendly anion
Surfactant, 0.8 part of BYK-1150 are added in grinder, grinding rate 360r/min, 43 DEG C of items of maintenance system temperature
23min is reacted under part, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified electricity
Gas stone；
(2), 53 parts of methylimidazoles, 62 parts of propyl acrylates, 3.6 parts of acrylamides and 7.5 parts of ethyl methacrylate are weighed to add
Enter into reaction kettle, mixing speed 89r/min, 4.5h is reacted under the conditions of 130 DEG C of reduced-pressure backflows of maintenance system temperature, it will be anti-
Kettle temperature degree is answered to rise to 120 DEG C, continue vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 80 parts of hydroxy-ethyl acrylates, 13 parts of hydroxypropyl acrylates and 4.3 parts of acrylic acid are weighed
It is added in reaction kettle, mixing speed 86r/min, it is anti-under the conditions of 109 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
5.5h is answered, temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzenes
And（Hydroxyl ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 91 parts of ethyl acrylates and 5 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 4h is reacted under the conditions of 147 DEG C of maintenance system temperature, product is through continuing vacuum distillation reaction under the conditions of 115 DEG C, -0.07MPa
1h is to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 46 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 31 portions of methyl-propyl urocanic acid salt, 34 parts of modified verdelites, 0.5 part of ZX-X1011 antifoaming agent, 0.6 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 83r/min, and 35min is reacted under the conditions of 37 DEG C of maintenance system temperature to get to production
Raw negative oxygen ion environmental protection coating material.
Embodiment 6
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 31 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.9 part of KH-550 silane coupling agent, 1.1 parts of HL-03 cationic geminis emulsifiers, 0.8 part of AS-801 novel environment-friendly anion
Surfactant, 0.9 part of BYK-1150 are added in grinder, grinding rate 310r/min, 41 DEG C of items of maintenance system temperature
22min is reacted under part, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified electricity
Gas stone；
(2), 53 parts of methylimidazoles, 62 parts of propyl acrylates, 4.5 parts of acrylamides and 5.5 parts of ethyl methacrylate are weighed to add
Enter into reaction kettle, mixing speed 96r/min, react 4h under the conditions of 132 DEG C of reduced-pressure backflows of maintenance system temperature, will react
Kettle temperature degree rises to 120 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 80 parts of hydroxy-ethyl acrylates, 13 parts of hydroxypropyl acrylates and 5 parts of acrylic acid are weighed to add
Enter into reaction kettle, mixing speed 90r/min, reacted under the conditions of 105 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos by 5.5h
（Hydroxyl ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 92 parts of ethyl acrylates and 7 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 4h is reacted under the conditions of 146 DEG C of maintenance system temperature, product is through continuing vacuum distillation reaction under the conditions of 115 DEG C, -0.07MPa
1h is to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 46 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 30 portions of methyl-propyl urocanic acid salt, 32 parts of modified verdelites, 0.4 part of ZX-X1011 antifoaming agent, 0.7 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 83r/min, and 33min is reacted under the conditions of 38 DEG C of maintenance system temperature to get to production
Raw negative oxygen ion environmental protection coating material.
Embodiment 7
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 26 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.8 part of KH-550 silane coupling agent, 0.7 part of HL-03 cationic geminis emulsifier, 1.3 parts of AS-801 novel environment-friendly anion
Surfactant, 0.8 part of BYK-1150 are added in grinder, grinding rate 340r/min, 43 DEG C of items of maintenance system temperature
23min is reacted under part, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified electricity
Gas stone；
(2), 53 parts of methylimidazoles, 61 parts of propyl acrylates, 5 parts of acrylamides and 6 parts of ethyl methacrylate are weighed to be added to
In reaction kettle, mixing speed 93r/min reacts 2.5h under the conditions of 134 DEG C of reduced-pressure backflows of maintenance system temperature, by reaction kettle
Temperature rises to 120 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 79 parts of hydroxy-ethyl acrylates, 14 parts of hydroxypropyl acrylates and 4.5 parts of acrylic acid are weighed
It is added in reaction kettle, mixing speed 90r/min, it is anti-under the conditions of 108 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
5h is answered, temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos
（Hydroxyl ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 91 parts of ethyl acrylates and 5 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 2.5h is reacted under the conditions of 146 DEG C of maintenance system temperature, product is anti-through continuing vacuum distillation under the conditions of 115 DEG C, -0.07MPa
1h is answered to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 44 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 31 portions of methyl-propyl urocanic acid salt, 33 parts of modified verdelites, 0.4 part of ZX-X1011 antifoaming agent, 0.7 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 75r/min, and 29min is reacted under the conditions of 38 DEG C of maintenance system temperature to get to production
Raw negative oxygen ion environmental protection coating material.
Embodiment 8
A kind of generation negative oxygen ion environmental protection coating material, its preparation method comprise the following steps：
(1), 80 parts of tourmaline are weighed and 28 parts of acrylic acid are added in hydrothermal reaction kettle, maintain hydrothermal temperature anti-for 45 DEG C
Answer 25min, product is filtered, 500mL water washings 2 times, 500mL ethyl alcohol wash 3 times, through 120 DEG C of dry 15min, by product with
0.7 part of KH-550 silane coupling agent, 0.9 part of HL-03 cationic geminis emulsifier, 0.8 part of AS-801 novel environment-friendly anion
Surfactant, 0.5 part of BYK-1150 are added in grinder, grinding rate 320r/min, 41 DEG C of items of maintenance system temperature
19min is reacted under part, product washs 4 times through 1L EtOH Sonicates, in 75 DEG C, -0.07MPa vacuum drying 6min, obtains modified electricity
Gas stone；
(2), 53 parts of methylimidazoles, 66 parts of propyl acrylates, 5.5 parts of acrylamides and 4.5 parts of ethyl methacrylate are weighed to add
Enter into reaction kettle, mixing speed 92r/min, 3.5h is reacted under the conditions of 128 DEG C of reduced-pressure backflows of maintenance system temperature, it will be anti-
Kettle temperature degree is answered to rise to 120 DEG C, continue vacuum distillation reaction 1h under the conditions of -0.07MPa, obtains methyl-propyl urocanic acid salt；
(3), 70 parts of 2- hydroxybenzimidazoles, 80 parts of hydroxy-ethyl acrylates, 11 parts of hydroxypropyl acrylates and 6 parts of acrylic acid are weighed to add
Enter into reaction kettle, mixing speed 87r/min, reacted under the conditions of 106 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows
Temperature of reaction kettle is risen to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos by 3h（Hydroxyl
Ethyl ester）Urocanic acid salt；
(4), 60 parts of 2-mercaptobenzimidazoles, 91 parts of ethyl acrylates and 6 parts of maleic acids are weighed and are added to hydrothermal reaction kettle
In, 3h is reacted under the conditions of 144 DEG C of maintenance system temperature, product is through continuing vacuum distillation reaction under the conditions of 115 DEG C, -0.07MPa
1h is to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；
(5), 45 parts of 2- sulfydryl benzos are weighed（Ethyl ester）Urocanic acid salt, 44 parts of 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid
Salt, 32 portions of methyl-propyl urocanic acid salt, 35 parts of modified verdelites, 0.2 part of ZX-X1011 antifoaming agent, 0.4 part 819 it is light-initiated
Agent is added in reaction kettle, mixing speed 80r/min, and 30min is reacted under the conditions of 38 DEG C of maintenance system temperature to get to generation
Negative oxygen ion environmental protection coating material.
Reference examples 1
In this reference examples, modified verdelite is not added, other components and preparation method are same as Example 1.
Reference examples 2
In this reference examples, methyl-propyl urocanic acid salt is not added, and other components and preparation method are same as Example 1.
Reference examples 3
In this reference examples, 2- hydroxy benzos are not added（Hydroxyl ethyl ester）Urocanic acid salt, other components are with preparation method with implementing
Example 1 is identical.
Reference examples 4
In this reference examples, 2- sulfydryl benzos are not added（Ethyl ester）Urocanic acid salt, other components and preparation method and embodiment 1
It is identical.
Reference examples 5
The modified verdelite in common electrical stone alternate embodiment 1, other components and preparation side are selected in this reference examples, in formula
Method is same as Example 1.
Reference examples 6
In this reference examples, the methyl-propyl urocanic acid salt in formula in selection conventional acrylic alternate embodiment 1, other groups
Divide same as Example 1 with preparation method.
Reference examples 7
The 2- hydroxy benzos in conventional acrylic hydroxyl ethyl ester alternate embodiment 1 are selected in this reference examples, in formula（Hydroxyl ethyl ester）Miaow
Azoles acrylates, other components and preparation method are same as Example 1.
Reference examples 8
The 2- sulfydryl benzos in conventional propylene acetoacetic ester alternate embodiment 1 are selected in this reference examples, in formula（Ethyl ester）Imidazoles third
Olefin(e) acid salt, other components and preparation method are same as Example 1.
1 embodiment 1 of table and the performance parameter obtained for generating negative oxygen ion environmental protection coating material of reference examples 1~8
| Embodiment 1 | Reference examples 1 | Reference examples 2 | Reference examples 3 | Reference examples 4 | Reference examples 5 | Reference examples 6 | Reference examples 7 | Reference examples 8 | |
| Adhesive force（ASTM grades） | 4B | 4B | 3B | 2B | 3B | 3B | 4B | 3B | 3B |
| Negative oxygen ion maximum burst size/(a/cm3) | 8259 | 0 | 5652 | 4921 | 3815 | 4350 | 5348 | 3967 | 3376 |
The above is the preferred embodiment of the invention, it is noted that for those skilled in the art,
On the premise of the inventive principle is not departed from, several improvements and modifications can also be made, these improvements and modifications are also considered as the hair
Bright protection domain.
Claims (3)
1. a kind of preparation method for generating negative oxygen ion environmental protection coating material, it is characterised in that：Including following raw material components：2- sulfydryl benzene
And（Ethyl ester）Urocanic acid salt, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, methyl-propyl urocanic acid salt, modification
Tourmaline, ZX-X1011 antifoaming agent, 819 photoinitiators, the 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt, 2- hydroxy benzenes
And（Hydroxyl ethyl ester）Urocanic acid salt, methyl-propyl urocanic acid salt, modified verdelite, ZX-X1011 antifoaming agent, 819 light draw
The quality parts ratio for sending out agent is 45：36~49：25~33：23~36：0.2~0.5：0.4~1, wherein, the 2- sulfydryl benzene
And（Ethyl ester）Urocanic acid salt is reacted by 2-mercaptobenzimidazole, ethyl acrylate and maleic acid to be made, the 2-
The quality parts ratio of mercaptobenzimidazole, ethyl acrylate and maleic acid is 60：87~96：4~9, the 2- hydroxyls
Benzo（Hydroxyl ethyl ester）Urocanic acid salt is anti-by 2- hydroxybenzimidazoles, hydroxy-ethyl acrylate, hydroxypropyl acrylate and acrylic acid
It should be made, the 2- hydroxybenzimidazoles, hydroxy-ethyl acrylate, the quality parts ratio of hydroxypropyl acrylate and acrylic acid are
70：75~83：7~15：3~7, the methyl-propyl urocanic acid salt is by methylimidazole, propyl acrylate, acrylamide
It is made with ethyl methacrylate reaction, the methylimidazole, propyl acrylate, acrylamide and ethyl methacrylate
Quality parts ratio is 53：58~66：2~6：4~9, the modified verdelite is even by tourmaline, acrylic acid, KH-550 silane
Join agent, HL-03 cationic geminis emulsifier, AS-801 novel environment-friendlies anion surfactant and BYK-1150 reaction systems
, the tourmaline, acrylic acid, KH-550 silane coupling agents, HL-03 cationic geminis emulsifier, AS-801 novel environment friendlies
The quality parts ratio of type anion surfactant and BYK-1150 are 80：25~31：0.5~1：0.7~1.6：0.6~1.4：
0.4~1.
2. a kind of preparation method for generating negative oxygen ion environmental protection coating material according to claim 1, it is characterised in that：The production
Raw negative oxygen ion environmental protection coating material is as made from following preparation method：(1), it is according to quality parts ratio by tourmaline and acrylic acid
80：25~31 are added in hydrothermal reaction kettle, and maintaining hydrothermal temperature, product is filtered, 500mL for 45 DEG C of reaction 25min
Water washing 2 times, 500mL ethyl alcohol wash 3 times, are 0.5~1 by product and quality parts ratio through 120 DEG C of dry 15min：0.7~
1.6：0.6~1.4：0.4~1 KH-550 silane coupling agents, HL-03 cationic geminis emulsifier, AS-801 novel environment-friendlies
Anion surfactant and BYK-1150 are added in grinder, grinding rate be 300~390r/min, maintenance system temperature
10~25min is reacted under the conditions of 35~44 DEG C, product washs 4 times through 1L EtOH Sonicates, is dried in vacuo in 75 DEG C, -0.07MPa
6min obtains modified verdelite；(2), by methylimidazole, propyl acrylate, acrylamide and ethyl methacrylate according to matter
It is 53 to measure portion rate：58~66：2~6：4~9 are added in reaction kettle, mixing speed be 85~98r/min, maintenance system temperature
It spends under the conditions of 123~135 DEG C of reduced-pressure backflows and reacts 2~6h, temperature of reaction kettle is risen to 120 DEG C, is continued under the conditions of -0.07MPa
Vacuum distillation reaction 1h, obtains methyl-propyl urocanic acid salt；(3), by 2- hydroxybenzimidazoles, hydroxy-ethyl acrylate, third
Olefin(e) acid hydroxypropyl acrylate and acrylic acid are according to quality parts ratio 70：75~83：7~15：3~7 are added in reaction kettle, and mixing speed is
80~93r/min reacts 2~6h under the conditions of 99~110 DEG C of maintenance system temperature, -0.06MPa reduced-pressure backflows, will react kettle temperature
Degree rises to 115 DEG C, continues vacuum distillation reaction 1h under the conditions of -0.07MPa to get to 2- hydroxy benzos（Hydroxyl ethyl ester）Imidazoles propylene
Hydrochlorate；(4), by 2-mercaptobenzimidazole, ethyl acrylate and maleic acid according to quality parts ratio 60：87~96：4~9
Be added in hydrothermal reaction kettle, under the conditions of 135~150 DEG C of maintenance system temperature react 2~5h, product through 115 DEG C ,-
Continue vacuum distillation reaction 1h under the conditions of 0.07MPa to get to 2- sulfydryl benzos（Ethyl ester）Urocanic acid salt；(5), by 2- mercaptos
Base benzo（Ethyl ester）Urocanic acid salt, 2- hydroxy benzos（Hydroxyl ethyl ester）Urocanic acid salt, methyl-propyl urocanic acid salt,
Modified verdelite, ZX-X1011 antifoaming agent, 819 photoinitiators are according to quality parts ratio 45：36~49：25~33：23~36：
0.2~0.5：0.4~1 is added in reaction kettle, mixing speed be 72~85r/min, 33~40 DEG C of conditions of maintenance system temperature
It is lower reaction 22~40min to get to generate negative oxygen ion environmental protection coating material.
3. a kind of preparation method for generating negative oxygen ion environmental protection coating material according to claim 2, it is characterised in that：The electricity
Gas stone grain diameter is 10~20 μm.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010053245.6A CN111100491A (en) | 2017-12-21 | 2017-12-21 | Preparation method of negative oxygen ion environment-friendly coating |
| CN201711392769.2A CN108117779B (en) | 2017-12-21 | 2017-12-21 | Environment-friendly coating capable of generating negative oxygen ions and preparation method thereof |
| CN202010052400.2A CN111100490A (en) | 2017-12-21 | 2017-12-21 | Preparation method of environment-friendly coating capable of generating negative oxygen ions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711392769.2A CN108117779B (en) | 2017-12-21 | 2017-12-21 | Environment-friendly coating capable of generating negative oxygen ions and preparation method thereof |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010053245.6A Division CN111100491A (en) | 2017-12-21 | 2017-12-21 | Preparation method of negative oxygen ion environment-friendly coating |
| CN202010052400.2A Division CN111100490A (en) | 2017-12-21 | 2017-12-21 | Preparation method of environment-friendly coating capable of generating negative oxygen ions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108117779A true CN108117779A (en) | 2018-06-05 |
| CN108117779B CN108117779B (en) | 2020-02-21 |
Family
ID=62230776
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010053245.6A Withdrawn CN111100491A (en) | 2017-12-21 | 2017-12-21 | Preparation method of negative oxygen ion environment-friendly coating |
| CN201711392769.2A Active CN108117779B (en) | 2017-12-21 | 2017-12-21 | Environment-friendly coating capable of generating negative oxygen ions and preparation method thereof |
| CN202010052400.2A Withdrawn CN111100490A (en) | 2017-12-21 | 2017-12-21 | Preparation method of environment-friendly coating capable of generating negative oxygen ions |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010053245.6A Withdrawn CN111100491A (en) | 2017-12-21 | 2017-12-21 | Preparation method of negative oxygen ion environment-friendly coating |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010052400.2A Withdrawn CN111100490A (en) | 2017-12-21 | 2017-12-21 | Preparation method of environment-friendly coating capable of generating negative oxygen ions |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN111100491A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370348A (en) * | 2018-09-28 | 2019-02-22 | 浙江安益新材料有限公司 | A kind of aqueous ecological, environmental protective paint of pencil rod and preparation method thereof |
| CN111410857A (en) * | 2020-04-24 | 2020-07-14 | 浙江纳壹环境科技有限公司 | Preparation system and preparation process of water-based negative oxygen ion coating and coating composition |
| CN111790233A (en) * | 2019-04-08 | 2020-10-20 | 廊坊鹏帮木业有限公司 | Anion liquid capable of purifying air and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011031442A2 (en) * | 2009-08-28 | 2011-03-17 | 3M Innovative Properties Company | Polymerizable ionic liquid comprising multifunctional cation and antistatic coatings |
| CN102491354A (en) * | 2011-12-05 | 2012-06-13 | 河北工业大学 | Preparation method of nano-scale tourmaline powder |
| CN104419305A (en) * | 2013-08-28 | 2015-03-18 | 青岛蓝农谷农产品研究开发有限公司 | Synthetic leather coating having strong adsorption capacity and preparation method thereof |
| CN106632775A (en) * | 2016-09-13 | 2017-05-10 | 西安交通大学 | Preparation method of high-transmittance self-healing ionic liquid gel with good mechanical properties |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100913938B1 (en) * | 2006-09-25 | 2009-09-10 | (주) 맵코리아 | Anti-fouling Paint Composition |
| KR20090085773A (en) * | 2008-02-05 | 2009-08-10 | 삼원중공업 주식회사 | Antifouling addictive, method of the same and composition including the same |
| CN103450761B (en) * | 2013-09-16 | 2015-10-28 | 深圳市宜丽环保科技有限公司 | A kind of heat-insulation thermal-insulation water-based paint with air purification function |
| CN105315727B (en) * | 2015-11-23 | 2018-04-06 | 大美泰康（天津）生态科技有限公司 | The environmental multifunctional inorganic dry powder paint of releasable negative oxygen ion |
-
2017
- 2017-12-21 CN CN202010053245.6A patent/CN111100491A/en not_active Withdrawn
- 2017-12-21 CN CN201711392769.2A patent/CN108117779B/en active Active
- 2017-12-21 CN CN202010052400.2A patent/CN111100490A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011031442A2 (en) * | 2009-08-28 | 2011-03-17 | 3M Innovative Properties Company | Polymerizable ionic liquid comprising multifunctional cation and antistatic coatings |
| CN102491354A (en) * | 2011-12-05 | 2012-06-13 | 河北工业大学 | Preparation method of nano-scale tourmaline powder |
| CN104419305A (en) * | 2013-08-28 | 2015-03-18 | 青岛蓝农谷农产品研究开发有限公司 | Synthetic leather coating having strong adsorption capacity and preparation method thereof |
| CN106632775A (en) * | 2016-09-13 | 2017-05-10 | 西安交通大学 | Preparation method of high-transmittance self-healing ionic liquid gel with good mechanical properties |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370348A (en) * | 2018-09-28 | 2019-02-22 | 浙江安益新材料有限公司 | A kind of aqueous ecological, environmental protective paint of pencil rod and preparation method thereof |
| CN111790233A (en) * | 2019-04-08 | 2020-10-20 | 廊坊鹏帮木业有限公司 | Anion liquid capable of purifying air and preparation method and application thereof |
| CN111410857A (en) * | 2020-04-24 | 2020-07-14 | 浙江纳壹环境科技有限公司 | Preparation system and preparation process of water-based negative oxygen ion coating and coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111100491A (en) | 2020-05-05 |
| CN108117779B (en) | 2020-02-21 |
| CN111100490A (en) | 2020-05-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108117779A (en) | A kind of generation negative oxygen ion environmental protection coating material and preparation method thereof | |
| CN103937367B (en) | A kind of white cathode electrophoresis dope and preparation method thereof and using method | |
| CN106221358A (en) | A kind of 3D prints furniture ink and preparation method thereof | |
| CN102516477A (en) | Nano titanium dioxide/ acrylate composite emulsion and preparation method thereof | |
| CN103834260B (en) | A kind of non-ion aqueous epoxy resin latex and preparation method thereof | |
| CN102787529A (en) | Preparation method of starch adhesive for papermaking coating, its product, and application of product | |
| CN103333352A (en) | Preparation method of crosslinked grafted modified polyvinyl alcohol surface reinforcing agent | |
| WO2018041129A1 (en) | Epoxy emulsion and preparation method therefor | |
| CN106118838A (en) | Circulation and stress can be diluted and use photovoltaic silicon wafer wire cutting liquid | |
| CN106752831A (en) | One kind is for electric armour clamp corrosion-resistant composite organic modified polyurethane water paint and preparation method thereof | |
| CN107180916A (en) | A kind of flexible infiltration perovskite photovoltaic material | |
| CN105885696A (en) | Aqueous coating for electrostatic spraying | |
| CN104004434A (en) | Waterborne epoxy varnish applied to damp ground and preparation method thereof | |
| CN101735408B (en) | High-decoration alcohol acid-organosilicon crylic acid composite waterborne resin | |
| CN106497343A (en) | A kind of modified carbon nano-tube anticorrosion and antistatic paint | |
| CN106758236B (en) | A kind of hydrophobic type stiffening agent and preparation method thereof, application method | |
| CN108047849A (en) | A kind of low formaldehyde environment-friendly type coating and preparation method thereof | |
| CN107955504A (en) | A kind of Water-borne Alkyd Coatings for wood product surface | |
| CN108531053A (en) | A kind of preparation method of modified aniline terpolymer/water-base resin composite anticorrosion coating | |
| CN107236384A (en) | A kind of crackle paint | |
| CN101270186B (en) | Polyaniline watersoluble dispersion and preparation method thereof | |
| CN106543917A (en) | The preparation method of maleic anhydride dry method esterification starch adhesive | |
| CN104910761A (en) | Electromagnetic wave absorbing coating and preparation method thereof | |
| CN106542760B (en) | Ceramic nano high temperature adhesives | |
| CN109705687A (en) | A kind of priming paint and preparation method thereof for PVC board |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An environmental protection coating for producing negative oxygen ion and its preparation method Effective date of registration: 20230221 Granted publication date: 20200221 Pledgee: Bank of Jinhua Limited by Share Ltd. science and Technology Branch Pledgor: JINHUA LIANCHUANG PLASTIC POWDER TECHNOLOGY CO.,LTD. Registration number: Y2023980033086 |