CN108115138A - Printing material and printing device - Google Patents
Printing material and printing device Download PDFInfo
- Publication number
- CN108115138A CN108115138A CN201710998131.7A CN201710998131A CN108115138A CN 108115138 A CN108115138 A CN 108115138A CN 201710998131 A CN201710998131 A CN 201710998131A CN 108115138 A CN108115138 A CN 108115138A
- Authority
- CN
- China
- Prior art keywords
- metallic
- nozzle
- printing equipment
- printing
- liquid metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007639 printing Methods 0.000 title claims abstract description 48
- 239000000463 material Substances 0.000 title claims abstract description 34
- 229910001338 liquidmetal Inorganic materials 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims description 30
- 238000012545 processing Methods 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 239000004020 conductor Substances 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 7
- 239000010931 gold Substances 0.000 claims description 7
- 229910052737 gold Inorganic materials 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 238000006073 displacement reaction Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 238000010146 3D printing Methods 0.000 abstract description 4
- 239000002923 metal particle Substances 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract 1
- 238000012805 post-processing Methods 0.000 abstract 1
- 239000012815 thermoplastic material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 238000007493 shaping process Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000007769 metal material Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000009183 running Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- ZNKMCMOJCDFGFT-UHFFFAOYSA-N gold titanium Chemical compound [Ti].[Au] ZNKMCMOJCDFGFT-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZSJFLDUTBDIFLJ-UHFFFAOYSA-N nickel zirconium Chemical compound [Ni].[Zr] ZSJFLDUTBDIFLJ-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229910001258 titanium gold Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/115—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by spraying molten metal, i.e. spray sintering, spray casting
-
- B22F1/0003—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
Abstract
The invention provides a printing material and a corresponding printing device. The material is nano liquid metal and is formed by mixing metal particles and liquid components; wherein the metal particles have a particle width on the order of nanometers. The printing material and the printing device effectively overcome the defects that the traditional thermoplastic material has insufficient hardness after 3D printing and molding, is difficult to form a complex configuration, needs post-processing treatment and the like.
Description
Technical field
The present invention relates to rapid shaping fields, and in particular to a kind of printing dress for the material and application of the printing material
It puts.
Background technology
In the manufacturing process of the products such as traditional industry and/or the people's livelihood, either main-body structure or inner body all need
First passing through the mold of mold could be molded, and then can just produce required component via series of processes such as the demouldings again.However,
It is well known that the manufacture of mold body is with high costs, and mold is unfavorable for demoulding and the processes such as last shaping take cumbersome
The cost control of manufacturer.
In recent years it is gradual " rapid shaping technique " prevailing, it is under controlling and manage by computer, using the accurate heap of material
Long-pending mode is deposited into 3D by face, ultimately produces entity by spot deposition into face.The principle of the technology is identical with 3D printing,
For certain thickness material is printed upon on platform repeatedly, move in circles, until generating entire molded part, the nothing in forming process
The auxiliary of mold is needed, and manufacture cost can be greatly reduced for small-scale production.
The material of common rapid shaping technique has plastics, ceramics, resin or metal.However, the material due to these materials
Expect the factor of characteristic, the stereo shaping object obtained after rapid shaping technique plastotype easily shows trapezoidal or corner shape
Non- flat appearance, this problem seem especially prominent on flexure plane.It also, cannot since these materials are more soft
Form complicated shape.In addition, by the object that these materials are formed in intensity well below traditional mold plastotype.
At present, although having been developed that rapid shaping technique is used for metal material.However, traditional metal material is depositing
After mode is molded, there is the problem of not corrosion-resistant and hardness is not strong enough, be easily broken;Furthermore it is to pass through when conventional metals print
Print head molten metal is heated, this can cause print head easily to damage, it is necessary to often replace, undoubtedly cause production and control cost
It is substantially improved.
For above-mentioned technical problem, it would be desirable to a kind of new light printed material for rapid shaping technique and
Corresponding printing device.
The content of the invention
To solve the deficiencies in the prior art, the present invention provides a kind of printing material, and the material is nanometer liquid metal,
It is mixed by metallic and liquid parts;Wherein, the metallic has the particle width of nano-scale.
In an embodiment of the present invention, the clipped wire is formed by the mixing of one or more of zirconium, nickel, aluminium, copper or titanium
Son forms the metallic by the alloy containing several elements in zirconium, nickel, aluminium, copper or titanium.
In an embodiment of the present invention, the liquid parts are metallic stabilizer.The metallic stabilizer refers to containing gold
Belong to the stabilizer of compound, the such as, but not limited to commercial product such as metal soap stabilizer or tin stabilizer.
The present invention also provides a kind of printing equipment, the printing equipment includes:One print module, the print module include
An at least nozzle, one end of the print module are connected with an at least raw material supply tube, are filled with and beat in the raw material supply tube
Print material;And a heating platform, the heating platform are located at the lower section of the nozzle, are sprayed to accept by the nozzle
The printed material;Wherein, the printed material is nanometer liquid metal described in claim 1, the nanometer liquid gold
Category is mixed by metallic and liquid parts;Also, the heating platform is before the nanometer liquid metal is accepted, first
Row is heated to an assigned temperature and keeps the temperature to the liquid parts of liquid metal to evaporate, so that the metallic is in the heating
It is molded on platform.
In an embodiment of the present invention, the heating platform fits in the circuit of the metallic plate including a metallic plate and one
Plate is laid with several plain conductors on the circuit board, and the plain conductor is heated by current lead-through, reaches the metallic plate
To the assigned temperature.
In an embodiment of the present invention, the printing equipment is arranged in a processing chamber housing, the processing chamber indoor location
There is a heat sink, the heat sink is used to pump out the high warm generated inside the processing chamber housing by the heating platform
Gas, and extraneous air is sent into the processing chamber housing.
In an embodiment of the present invention, an at least nozzle have a nozzle, the radial width of the nozzle be less than or
Equal to 30 microns.
In an embodiment of the present invention, the heating platform carries out longitudinal direction in forming process in the nanometer liquid metal
Displacement, the unit distance with displacement are 0.1 millimeter.
In an embodiment of the present invention, an at least nozzle is piezoelectric type nozzle.
In an embodiment of the present invention, the assigned temperature is 200 DEG C~300 DEG C.
The nanometer liquid metal that printing equipment of the present invention is formed using special component coordinates the heating flat as raw material
Platform maintains an assigned temperature in forming process, goes out a solid object with piezoelectric type nozzle printing plastotype.The solid object tool
There are the characteristics such as the high rigidity, corrosion resistance and abrasion performance of nanometer liquid metal.
Printed material and printing equipment of the present invention efficiently solve conventional thermoplastic's material in 3D printing plastotype
Afterwards hardness deficiency, be not easy to be formed complex configuration, need after working process processed the shortcomings of.Simultaneously as the heating platform is high
Temperature cooperation so that piezoelectric type nozzle printing may be employed in ground of the present invention printing equipment, and need not heat nozzle molten metal,
It solves the problems, such as that nozzle is easily damaged ground simultaneously, and then reduces production cost.
Description of the drawings
Fig. 1 is the comprehensive architecture schematic diagram of printing equipment of the present invention;
Fig. 2 is the schematic diagram of a heating platform of printing equipment of the present invention;
Fig. 3 is the schematic diagram that printing equipment of the present invention is arranged on a processing chamber housing;
Fig. 4 is a use state diagram of printing equipment of the present invention.
Specific embodiment
The present invention is described in detail with reference to embodiments, embodiment is intended to explain technology rather than limiting the invention
Scheme.
General inkjet printing technology printing can be used in the printing equipment of the present invention, and former by printing of nanometer liquid metal
Material by the process deposited after ejection and coordinates printing equipment in the axial movement of solid three, and then plastotype is into a three-dimensional gold
Belong to object, and the metal object after shaping has splendid precision and hardness, without the working process processed after, you can directly
It uses.
Hereinafter, Fig. 1 to Fig. 3 is referred to, Fig. 1 to Fig. 3 shows a preferred embodiment of printing equipment 1 of the present invention.
As shown in Figure 3, the printing equipment 1 is disposed on running in a processing chamber housing 4, to avoid extraneous ring is subject to
Border factor influences print procedure.The one side of the processing chamber housing 4 is equipped with a control unit 41 and an observation unit 42.The control is single
Member 41 is electrically connected at the printing equipment 1, to control the various runnings of the printing equipment 1 and parameter setting.The sight
Survey portion 42 can make user measure the function situation of the internal printing equipment 1 by 4 appearance of processing chamber housing.
As shown in Figure 1, the printing equipment 1 includes a print module 2, and the print module 2 includes an at least nozzle
21, the nozzle 21 is arranged on a nozzle support plate 20, and with a nozzle 22.One end of the print module 2 is connected at least
One raw material supply tube 23, the raw material supply tube 23 are interior filled with nanometer liquid metal 6 (as shown in Figure 4), the nanometer liquid
Metal 6 is circulated to the nozzle 21.
Illustrate, the nanometer liquid metal 6 of the invention mainly by several 61 and one liquid of metallic into
62 mixing (as shown in Figure 4) is divided to be formed.The liquid parts 62 are metallic stabilizer.The metallic stabilizer refers to containing gold
Belong to the stabilizer of compound, the such as, but not limited to commercial product such as metal soap stabilizer or tin stabilizer.Also, the liquid
State ingredient 62 can be with colorant, and the metallic 61 is mixed in the liquid parts 62.Each metallic 61
Particle width with nano-scale.In the present embodiment, the particle width of the metallic 61 is 1 nanometer.The metal
Particle 61 can be prepared by any of method.
In other words, the nanometer liquid metal 6 of the invention is nanometer liquid metal, the molding nanometer liquid metal of institute
Alloy contains the atom of size significant difference, thus can form fine and closely woven mixing, and free volume is low.In addition, the nano fluid
State metal material is also without apparent fusing point, therefore in fusing point, viscosity can drastically reduce unlike crystalline form metal, and viscosity can be with
The rise of temperature and be slowly decreased.Therefore, at high temperature, the nanometer liquid metal material is similar with plastics, in shaping period
Room machine property can be controlled extremely easily.Also because viscosity can prevent atom from moving to form orderly lattice, institute
Even if state nanometer liquid metal material is still maintained its amorphous nature after thermoforming.The nanometer liquid gold of the present invention
Belong to 6 be applicant after research experiment for many years, develop comprising being mainly made of several mixing in zirconium, nickel, aluminium, copper or titanium
The metallic 61 forms the metallic by the alloy containing several elements in zirconium, nickel, aluminium, copper or titanium, such as
But it is not limited to Zirconium-nickel alloy, zirtan or other any of alloys containing mentioned component.
The radial width of the nozzle 22 is less than or equal to 30 microns, is enough the nanometer liquid metal for spraying nano-scale
6.Further, since the present invention is using nanometer liquid metal as raw material, the piezoelectric type spray of general inkjet printing technology can be applicable in
Head, is not required to heat ink gun, is so easier to the shapes and sizes of control ink dot, and more robust without easy damaged spray
Head, and coordinate the liquid parts 62 of different colorants, can spray printing go out the nanometer liquid metals 6 of different colours.
Continuing with referring to Fig. 1, the heating platform 3 is located at the underface of nozzle 21, to accept what is sprayed by nozzle 21
Nanometer liquid metal 6.In a preferred embodiment, as shown in Figure 2, the heating platform 3 includes a metallic plate 31 and a patch
Together in the circuit board 32 of 31 bottom side of metallic plate, wherein being laid with several plain conductors 321 on the circuit board 32, the metal is led
Line 321 can be copper lines, be heated by current lead-through heating.It illustrates, the metallic plate 31 is aluminium material
Material, with good thermal conductivity, and the plain conductor 321 is posted by the metallic plate 31, inhales the metallic plate 31
It receives the heat of plain conductor 321 and increases temperature.The temperature of required heating it is different according to the ingredient of the nanometer liquid metal 6 and
There is change.
Refer to Fig. 3, the processing chamber housing 4 is equipped with a heat sink 5, to pump out 4 inside of processing chamber housing because
The high temperature hot gas for heating platform 3 and generating, and extraneous air is sent into processing chamber housing 4, utilize natural inflow cycle down lower
The temperature in chamber 4 is managed, nanometer liquid metal 6 is avoided to generate phenomenon of expanding with heat and contract with cold;The heat sink 5 can be in processing chamber housing 4
Opposite two sides open up air outlet and air inlet, and scavenger fan and supply fan can be further configured to promote chamber interior
Air circulation.
Printing equipment 1 of the present invention when in use, by 41 setup parameter of control unit of the processing chamber housing 4 and behaviour
Make, nanometer liquid metal 6 is sprayed (such as the 4th figure by figure of the print module 2 according to CAD by nozzle 22
It is shown), and be undertaken on the metallic plate 31 of heating platform 3.At this point, the print module 2 and heating platform 3 according to it is required into
The figure of type can carry out x-axis, y-axis and z-axis movement respectively, wherein the heating platform 3 can be using unit as 0.1 millimeter (mm)
Minimum range carry out length travel.In other words, while 22 material spray of nozzle, the heating platform 3 is progressively to moving down
It is dynamic, nanometer liquid metal 6 is made to be deposited on the metallic plate 31.Specifically, heat platform 3 and accept nanometer liquid metal 6
Before, an assigned temperature is heated in advance, starts to accept nanometer liquid metal 6 afterwards again.The assigned temperature continues to nano fluid
The liquid parts 62 of state metal 6 evaporate, so that the metallic 61 completes forming process on the heating platform 3.It is described
The temperature setting of heating platform 3 is the material settling out degree ensured when nanometer liquid metal 6 is molded, in a preferred embodiment
In, the assigned temperature is to be preferred between 200 to 300 DEG C.For example, if the nanometer liquid metal 6 is nano titanium gold
Belong to alloy, then the temperature of the metallic plate 31 must maintain 280 DEG C, positive and negative to allow for 3 DEG C, until the liquid gold on metallic plate 31
Belong to shaping completely.
In conclusion the nanometer liquid metal 6 that printing equipment 1 of the present invention is formed with special component is raw material, cooperation heats
Platform 3 maintains an assigned temperature in forming process, and printing plastotype with piezoelectric type nozzle 21 goes out a solid object.The solid of acquisition
Object has the characteristics such as high rigidity, corrosion resistance and the abrasion performance of nanometer liquid metal 6, effectively solves conventional thermoplastic's material
After 3D printing plastotype, hardness deficiency, be not easy to be formed complex configuration, need after working process processed the shortcomings of.Simultaneously as heating is flat
Platform 3 high temperature cooperation, the present invention may be employed piezoelectric type nozzle 21 and prints, and need not heating nozzle molten metal, solve spray
The problem of head is easily damaged, and then reduce production and management cost.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, without departing from the inventive concept of the premise, can also make several changes, improvements and modifications, these change, improve and moisten
Decorations also should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of printing material, which is characterized in that the material is nanometer liquid metal, is mixed by metallic and liquid parts
It closes;Wherein, the metallic has the particle width of nano-scale.
2. material as described in claim 1, which is characterized in that by one or more of zirconium, nickel, aluminium, copper or titanium mixing group
The metallic is formed into the metallic or by the alloy containing several elements in zirconium, nickel, aluminium, copper or titanium.
3. material as described in claim 1, which is characterized in that the liquid parts are metallic stabilizer.
4. a kind of printing equipment, the printing equipment includes:
One print module, the print module include an at least nozzle, and one end of the print module is connected with an at least raw material
Supply pipe, the raw material supply tube is interior to be filled with printed material;And
One heating platform, the heating platform are located at the lower section of the nozzle, are beaten to accept as described in spraying the nozzle
Print material;
Wherein, the printed material is nanometer liquid metal described in claim 1, and the nanometer liquid metal is by metallic
It is mixed with liquid parts;Also,
The heating platform is heated to an assigned temperature and keeps the temperature to liquid gold in advance before the nanometer liquid metal is accepted
The liquid parts evaporation of category, so that the metallic is molded on the heating platform.
5. printing equipment as claimed in claim 4, which is characterized in that the heating platform is fitted in including a metallic plate and one
The circuit board of the metallic plate is laid with several plain conductors on the circuit board, and the plain conductor adds by current lead-through
Heat makes the metallic plate reach the assigned temperature.
6. printing equipment as claimed in claim 4, which is characterized in that the printing equipment is arranged in a processing chamber housing, institute
It states and a heat sink is installed in processing chamber housing, the heat sink is used to pump out inside the processing chamber housing because of the heating
The high temperature hot gas that platform generates, and extraneous air is sent into the processing chamber housing.
7. printing equipment as claimed in claim 4, which is characterized in that an at least nozzle has a nozzle, the nozzle
Radial width be less than or equal to 30 microns.
8. printing equipment as claimed in claim 4, which is characterized in that it is described heating platform in the nanometer liquid metal into
Length travel is carried out during type, the unit distance with displacement is 0.1 millimeter.
9. printing equipment as claimed in claim 4, which is characterized in that an at least nozzle is piezoelectric type nozzle.
10. printing equipment as claimed in claim 4, which is characterized in that the assigned temperature is 200 DEG C~300 DEG C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW105134704 | 2016-10-27 | ||
TW105134704A TWI611851B (en) | 2016-10-27 | 2016-10-27 | Printing device for molding liquid metal |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108115138A true CN108115138A (en) | 2018-06-05 |
CN108115138B CN108115138B (en) | 2021-02-26 |
Family
ID=61728500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710998131.7A Active CN108115138B (en) | 2016-10-27 | 2017-10-24 | Printing material and printing device |
Country Status (2)
Country | Link |
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CN (1) | CN108115138B (en) |
TW (1) | TWI611851B (en) |
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WO2020132162A1 (en) * | 2018-12-20 | 2020-06-25 | Jabil Inc. | Apparatus, system and method of additive manufacturing using ultra-fine jetted material |
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WO2020132162A1 (en) * | 2018-12-20 | 2020-06-25 | Jabil Inc. | Apparatus, system and method of additive manufacturing using ultra-fine jetted material |
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CN108115138B (en) | 2021-02-26 |
TWI611851B (en) | 2018-01-21 |
TW201815495A (en) | 2018-05-01 |
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