CN108102794A - A kind of Washine-machine chute detergent, preparation method and applications - Google Patents
A kind of Washine-machine chute detergent, preparation method and applications Download PDFInfo
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- CN108102794A CN108102794A CN201810023877.0A CN201810023877A CN108102794A CN 108102794 A CN108102794 A CN 108102794A CN 201810023877 A CN201810023877 A CN 201810023877A CN 108102794 A CN108102794 A CN 108102794A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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Abstract
The present invention is suitable for cleaning supplies technical field, provides a kind of Washine-machine chute detergent, preparation method and applications, wherein, Washine-machine chute detergent, by weight, including following component：Anion surfactant：2~5 parts；Basic mineral cleaning agent：24~29.5 parts；Builder：10~17 parts；Enzyme preparation：1.5~2.5 parts；And enzyme stabilizers：0.5~1 part；Wherein, enzyme preparation is protease, lipase, pectase, cellulase, hemicellulase, mannonase staphylococcal nuclease, the catalase either one of which of lysozyme or at least two mixture.Enzyme preparation in the Washine-machine chute detergent of the present invention has synergistic effect with anion surfactant, simultaneously under the action of enzyme stabilizers, the enzyme activity stability of enzyme preparation is high, the various spots in removal washing machine tank can effectively be decomposed, cleaning effect is good, and clean noresidue after cleaning, secondary pollution will not be caused, ensure that the sanitation and hygiene of washing machine internal.
Description
Technical field
The invention belongs to cleaning product technical field more particularly to a kind of Washine-machine chute detergent, preparation method and applications.
Background technology
With the policy that country's development household electrical appliances go to the countryside, expand domestic demand, washing machine is popularized in large quantities, becomes people day
The often main tool of cleaning clothing.According to the correlative study of professional health organ the results show that washing machine is after long-term make,
Washings flow between washing machine tank and content, long-term accumulated, and incrustation scale, washing powder educt, clothes fiber and human body are organic
The impurity such as substance will be adhered on internal groove side wall, and are constantly fermented in room temperature, form the spot of various stubbornnesses, while are grown big
Bacterium, germ of amount etc., these spots can pollute next clothing in washing process next time, cause secondary pollution, hand over
Fork pollution etc. is easy to induce various skin diseases, endangers people's health.
Most of existing Washine-machine chute detergent is all declared to have and inhibits bacteria, goes the spots such as scale removal, but in reality
During the use on border, these Washine-machine chute detergents are for being insoluble in the cleaning effect but people not to the utmost of the scale of water
Meaning, and it be easy to cause secondary pollution.
As it can be seen that existing washing machine detergent is unsatisfactory there are cleaning effect, and easily lead to the problem of secondary pollution.
The content of the invention
The embodiment of the present invention provides a kind of Washine-machine chute detergent, it is intended to solve existing washing machine detergent and there is cleaning
Effect is unsatisfactory, and easily leads to the problem of secondary pollution.
The embodiment of the present invention is achieved in that a kind of Washine-machine chute detergent, by weight, including following component：It is cloudy
Ionic surface active agent：2~5 parts；Basic mineral cleaning agent：24~29.5 parts；Builder：10~17 parts；Enzyme preparation：1.5~
2.5 part；And enzyme stabilizers：0.5~1 part；Wherein, enzyme preparation is protease, lipase, pectase, cellulase, hemicellulose
Plain enzyme, mannonase staphylococcal nuclease, catalase either the one of which of lysozyme or at least two it is mixed
Close object.
Preferably, the enzyme preparation is staphylococcal nuclease, catalase, lysozyme, lipase and cellulose
The mixture of enzyme.
Preferably, by weight, the Washine-machine chute detergent includes following component：Anion surfactant：3 parts；
Basic mineral cleaning agent：27.4 parts；Builder：10 parts；Enzyme preparation：2.5 part；And enzyme stabilizers：0.8 part.
Preferably, by weight, the Washine-machine chute detergent includes following component：Anion surfactant：2~5
Part；Basic mineral cleaning agent：24~29.5 parts；Builder：10~17 parts；Enzyme preparation：1.5~2.5 parts；Enzyme stabilizers：0.5~
1 part；Anti-dirt redeposition agent：0.2~0.5 part；Oxidative bleaching agent：40~50 parts；And corrosion inhibition for metal protective agent：6~8 parts.
Preferably, by weight, the Washine-machine chute detergent includes following component：Anion surfactant：3 parts；
Basic mineral cleaning agent：27.4 parts；Builder：10 parts；Enzyme preparation：2.5 part；Enzyme stabilizers：0.8 part；Anti-dirt redeposition agent：
0.3 part；Oxidative bleaching agent：50 parts；And corrosion inhibition for metal protective agent：6 parts.
Preferably, the anion surfactant is dodecyl benzene sulfonic acid, lauryl sodium sulfate, ethoxylation fat
Fat acid the sulfonate either one of which of sodium secondary alkyl sulfonate or at least two mixture；
The basic mineral cleaning agent is sodium carbonate and/or potassium carbonate；
The builder is sodium acid carbonate, sodium tripolyphosphate either the one of which of sodium metasilicate or at least two it is mixed
Close object；
The enzyme stabilizers are wherein the one of borax, potassium sorbate, sodium chloride, inositol, succinic acid or sodium thiosulfate
Kind or at least two mixture.
Preferably, the anti-dirt redeposition agent for sodium carboxymethylcellulose, polyvinylpyrrolidone, polyvinyl alcohol or
The one of which of sodium acrylate homopolymer or at least two mixture；
The oxidative bleaching agent be SODIUM PERCARBONATE, potassium percarbonate, sodium peroxydisulfate, sodium perborate or potassium perborate in extremely
Mixture three kinds few；
The corrosion inhibition for metal protective agent is metasilicate pentahydrate sodium and/or anhydrous sodium metasilicate.
Preferably, the anion surfactant includes the substance of following parts by weight：3 parts of lauryl sodium sulfate；
The basic mineral cleaning agent includes the substance of following parts by weight：27.4 parts of sodium carbonate；
The builder includes the substance of following parts by weight：10 parts of sodium acid carbonate；
The enzyme preparation includes the substance of following parts by weight：0.5 part of staphylococcal nuclease, 0.5 part of lysozyme, peroxide
Change 0.5 part of 0.5 part of hydrogen enzyme, 0.5 part of lipase and cellulase；
The enzyme stabilizers include the substance of following parts by weight：0.3 part of borax, 0.2 part of succinic acid and thiosulfuric acid
0.3 part of sodium；
The anti-dirt redeposition agent includes the substance of following parts by weight：0.3 part of sodium carboxymethylcellulose；
The oxidative bleaching agent includes the substance of following parts by weight：50 parts of SODIUM PERCARBONATE；
The corrosion inhibition for metal protective agent includes the substance of following parts by weight：6 parts of metasilicate pentahydrate sodium.
The embodiment of the present invention also provides the preparation method of Washine-machine chute detergent, includes the following steps：
Step 1：Formula according to above-mentioned Washine-machine chute detergent weighs each component, spare；
Step 2：The enzyme preparation and enzyme stabilizers low temperature are freezed to be put into blender after being dehydrated and stirred evenly, and will
The anion surfactant is added in the blender, is mixed evenly, is obtained A powder；
Step 3：The basic mineral cleaning agent and builder are added in blender, is uniformly mixed, obtains B powder；
Step 4：The A powder and B powder are uniformly mixed, obtain the Washine-machine chute detergent.
The embodiment of the present invention also provides the application of Washine-machine chute detergent, and when cleaning washing machine tank, washing machine tank is noted
At water to high water level, the Washine-machine chute detergent is added in into the washing machine tank, starts washing machine so that the washing machine
Slot detergent closes power supply after fully dissolving, start washing machine herein after impregnating 1~3h, according to Normal Wash standard cleaning one
Time, it is rinsed well after discharging sewage with clear water.
It is described in detail below with cleaning pulsator washing machine：
Pulsator washing machine is filled into water to high water level, then Washine-machine chute detergent provided in an embodiment of the present invention is direct
Pour into washing machine drum, usage and dosage is 25g/L water, open power initiation washing machine operating 5min (can be put into one piece it is clean
Towel is in order to avoid washing machine dallies) so that Washine-machine chute detergent is completely dissolved in water, power supply is closed, impregnates 1~3h so as to wash
The spot of clothing machine detergent and washing machine internal is fully reacted, and immersion finishes, and opens power supply, is started washing machine, is washed according to daily
It washs after standard (washing-rinsing-dehydration) is cleaned one time and discharges sewage, then rinsed well with clear water.
It should be noted that the dosage of Washine-machine chute detergent can be according to the pollution level inside washing machine tank and capacity
Size increases and decreases the dosage of Washine-machine chute detergent as one sees fit.For example, the pollution level of washing machine tank is relatively low, washing machine can be reduced
The dosage of slot detergent.
Below to each raw material in above-mentioned Washine-machine chute detergent the effect of and ingredient do specific description：
Protease：Protease can be used as skin conditioning agent.The ingredient is that decomposing protein is Amino acid, and hydrolysate is in skin
Surface layer forms one layer of amino acid and spreads out object film, make skin keep wetting with it is smooth.
Lipase：It can accelerate lipolysis, also with Oily conditioning is made, temperature and pH be required more.Pectase：Fruit
Glue enzyme is fermented refined by aspergillus niger and obtains.Appearance is in light yellow powder.Pectase is mainly used for fruit-vegetable juice beverage and fruit wine
Squeeze the juice and clarify, to decompose pectin have good effect.
Cellulase and hemicellulase can remove fabric surface because of the microtriche and bobbles that occur after repeatedly washing.When washing
During the villus microballoon that attachment left behind by washing clothing in clothing trough, cellulase can effectively go it with hemicellulase
It removes.
Mannase:Mannosan decomposes the manna oligosacchride generated, improves flora composition, reduces Escherichia coli, sramana
The infection of Salmonella.
Staphylococcal nuclease：Bacterial biofilm is that a large amount of cells are attached to the surface of solids and organism surface living
The formation of micropopulation biofilms can increase the ability that bacterium resists antibiotic and escapes host immunity attack, so as to
The prolonged and repeated infection of many bacteriosises is caused to occur.Staphylococcal nuclease is one of staphylococcus aureus important
There is direct contact between the formation of virulence factor, staphylococcal nuclease and biofilm, play and inhibit what biofilm was formed
Important function.
Catalase：The hydrogen peroxide that can be degraded in detergent Liquid Residue.
Lysozyme：It is a kind of to hydrolyze the alkaline enzyme that polysaccharide is sticked in pathogenic bacteria.Mainly by destroying the N- acetyl in cell membrane
β-Isosorbide-5-Nitrae glycosidic bond between muramic acid and n-acetylglucosamine makes the insoluble glutinous polysaccharide of cell membrane resolve into soluble glycopeptide,
Cell wall rupture content is caused to escape and make bacterolysis.Lysozyme can also with negatively charged virus protein directly in conjunction with,
Double salt is formed with DNA, RNA, apoprotein, is made virally inactivated.Therefore, which has the effects that antibacterial, anti-inflammatory, antiviral,
It is and safe.
Dodecyl benzene sulfonic acid：For in all kinds of detergent, cosmetic formulations, there is good decontamination, moistening, foaming, breast
The performances such as change, scattered.
Lauryl sodium sulfate：White or faint yellow powdery is dissolved in water, insensitive to alkali and hard water, has decontamination, emulsification
With excellent foaming power, toothpaste and paste, powdery, the foaming agent of shampoo are also served as.
Ethoxylated fatty acid sulfonate：It is a kind of comprehensive anion surfactant of performance, low foam, alkaline-resisting, tool
There is good emulsion dispersion ability, having splendid prevents from instead staiing performance.In anion surfactant, ethoxylation fat
Fat acid sulfonate is the current highest product of washing ability, and washing ability is far above other anionic products.
Sodium secondary alkyl sulfonate：It is a kind of excellent anion surfactant, penetration is strong.In highly basic, high temperature, oxidant
In the presence of, still with superior infiltration, emulsification, degreasing, washing ability.
Sodium carbonate：White powder, soluble easily in water and glycerine widely use in the multiple fields such as food, washing, pharmacy.
Potassium carbonate, sodium acid carbonate, sodium tripolyphosphate：Three is alkalescent substance, is washed in industry is washed frequently as helping
Agent.
Sodium metasilicate：A kind of nontoxic, tasteless, non-harmful white powder or crystallization, it is soluble easily in water, insoluble in alcohol and
Acid has certain protective effect to metal.
Borax：For semi-transparent clear crystal or white monoclinic system crystal powder, odorless is salty, and pH tune is used as in makeup
Save agent.The vigor size and vigor stability of enzyme are affected by system pH, therefore borax is also common enzyme stabilizers,
It plays an important role in the present invention to the vigor stability of complex enzyme.
Potassium sorbate：Sorb potassium has excellent anti-corrosion, antibacterial, sterilization, oxidation resistance.Potassium sorbate antifungal activity
Higher, antiyeast activity is general, and antibacterial activity is relatively low, and optimal use pH value range is less than 4.5, free divided sorbic acid
Son can just work.
Succinic acid：With special acid esters taste, have been widely used in washing industry tool, the two has one for acidicenzym
Fixed stabilization.
Sodium chloride：Sodium chloride has thickening, stablizes, restrains, firming effect, adjusts grease surface tension, bactericidal antiphlogistic.
Sodium thiosulfate：It is usually used in washing industry.The two can influence the active group of enzyme, have one for enzyme stability
Fixed influence.
Inositol：Under the conditions of existing for inositol, the increase of solvent water surface tension causes preferential hydration to act on.Protein point
The loss of sub- intermolecular forces and suitable foldable structure can increase the interface between protein and solution, so as to increase additive and egg
The intermolecular conjugation of white matter, makes the stability of protein molecule increase.
Sodium carboxymethylcellulose：With good dispersibility, there is stronger emulsifying capacity to grease and wax；Have simultaneously
There are stronger water suction and water holding capacity, binding agent is used as in daily chemical industry, resists dignified dose again.
Polyvinylpyrrolidone：Property is stablized under normal temperature and pressure, has the powder that hydrophily easily flows white or substantial white
End.Have micro- smelly, colourless, nontoxic, non-stimulated, be soluble in a variety of organic solvents of hydration.It forms a film, disperse, emulsifying power with excellent
Power.Polyvinylpyrrolidone is added in detergent good anti-annesl effect, and can enhance washing ability.
Polyvinyl alcohol：It is non-toxic and tasteless pollution-free, there is good film forming, there is very strong parent for porous, water-wetted surface
And power, there is good adhesive effect to pigment and other fine solid particles.
Sodium acrylate homopolymer：It is a kind of new functional macromolecule material and important chemical products, thickener, tool can be used as
There are fixing metal ions, the negative consequence of energy tissue metal ion pair product, while have and thicken well, foam,
The performances such as anti-dirt redeposition, emulsification, film forming and water conservation, are a kind of surfactants with a variety of specific functions.
SODIUM PERCARBONATE, potassium percarbonate, sodium peroxydisulfate：The advantages that nontoxic, odorless, pollution-free is respectively provided with, while also there is drift
In vain, the features such as sterilization, washing, good water solubility.
Sodium perborate, potassium perborate：Washing, decontamination, bleaching, sterilize, eliminate the unusual smell with fabric protect color increase it is gorgeous and other effects, extensively
For washing, in cosmetics.
Anhydrous sodium metasilicate：With the difference of metasilicate pentahydrate sodium, it is without the crystallization water, effect and metasilicate pentahydrate sodium phase
Seemingly, there is de-sludging, emulsification, scattered, moistening, permeability and have buffer capacity to pH value, be widely used in all kinds of washing industries.
Metasilicate pentahydrate sodium：It is a kind of nontoxic, tasteless, non-harmful white powder or crystalline particle, it is soluble easily in water, it is insoluble
In alcohol and acid, aqueous solution has de-sludging, emulsification, scattered, moistening, permeability and has buffer capacity to pH value, widely in alkalescence
Applied to all kinds of washing industries.
Enzyme preparation in Washine-machine chute detergent provided in an embodiment of the present invention has with anion surfactant to be cooperateed with
Effect, while under the action of enzyme stabilizers, the enzyme activity stability of enzyme preparation is high, can effectively decompose in removal washing machine tank
Various spots, cleaning effect is good, and clean noresidue after cleaning, will not cause secondary pollution, ensure that the clear of washing machine internal
Clean health.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Enzyme preparation in Washine-machine chute detergent provided in an embodiment of the present invention has with anion surfactant to be cooperateed with
Effect, while under the action of enzyme stabilizers, the enzyme activity stability of enzyme preparation is high, can effectively decompose in removal washing machine tank
Various spots, cleaning effect is good, and clean noresidue after cleaning, will not cause secondary pollution, ensure that the clear of washing machine internal
Clean health.
Technical scheme and technique effect are described further below by way of specific embodiment.
Embodiment 1：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(3 parts of lauryl sodium sulfate)；Basic mineral cleaning agent (26.8 parts of sodium carbonate)；Builder (11 parts of sodium acid carbonate)；Enzyme preparation
(0.3 part of lipase, 0.3 part of cellulase, 0.3 part of staphylococcal nuclease, 0.3 part of catalase, 0.3 part of lysozyme),
Totally 1.5 parts；Enzyme stabilizers (0.2 part of borax, 0.2 part of succinic acid, 0.1 part of sodium thiosulfate), totally 0.5 part；Anti-dirt is redeposited
Agent (0.2 part of sodium carboxymethylcellulose)；Oxidative bleaching agent (50 parts of SODIUM PERCARBONATE)；Corrosion inhibition for metal protective agent (metasilicate pentahydrate sodium 7
Part).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent, includes the following steps：
Step 1：Formula according to above-mentioned Washine-machine chute detergent weighs each component, spare.
Step 2：Be put into blender and stir evenly after enzyme preparation and enzyme stabilizers low temperature are freezed dehydration, and by the moon from
Sub- surfactant is added in blender, is mixed evenly, is obtained A powder, wherein, low temperature, which freezes dehydration, can keep enzyme preparation
Vigor stability.
Step 3：By in basic mineral cleaning agent and builder input blender, it is uniformly mixed, obtains B powder；
Step 4：A powder obtained above and B powder are uniformly mixed, obtain Washine-machine chute detergent product.
Embodiment 2：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(2 parts of lauryl sodium sulfate)；Basic mineral cleaning agent (25.2 parts of sodium carbonate)；Builder (12 parts of sodium acid carbonate)；Enzyme preparation
(0.5 part of lipase, 0.8 part of cellulase, 0.3 part of staphylococcal nuclease, 0.5 part of catalase, 0.4 part of lysozyme),
Totally 2.5 parts；Enzyme stabilizers (0.4 part of borax, 0.4 part of succinic acid, 0.2 part of sodium thiosulfate), totally 1 part；Anti-dirt redeposition agent
(0.3 part of sodium carboxymethylcellulose)；Oxidative bleaching agent (50 parts of SODIUM PERCARBONATE)；Corrosion inhibition for metal protective agent (metasilicate pentahydrate sodium 7
Part).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 1.
Embodiment 3：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(3 parts of lauryl sodium sulfate)；Basic mineral cleaning agent (27.4 parts of sodium carbonate)；Builder (10 parts of sodium acid carbonate)；Enzyme preparation
(0.5 part of lipase, 0.5 part of cellulase, 0.5 part of staphylococcal nuclease, 0.5 part of catalase, 0.5 part of lysozyme),
Totally 2.5 parts；Enzyme stabilizers (0.3 part of borax, 0.2 part of succinic acid, 0.3 part of sodium thiosulfate), totally 0.8 part；Anti-dirt is redeposited
Agent (0.3 part of sodium carboxymethylcellulose)；Oxidative bleaching agent (50 parts of SODIUM PERCARBONATE)；Corrosion inhibition for metal protective agent (metasilicate pentahydrate sodium 6
Part).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 1.
Embodiment 4：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(5 parts of lauryl sodium sulfate)；Basic mineral cleaning agent (24 parts of sodium carbonate)；Builder (10 parts of sodium acid carbonate)；Enzyme preparation (fat
0.5 part of fat enzyme, 0.5 part of cellulase, 0.5 part of staphylococcal nuclease, 0.2 part of catalase, 0.3 part of lysozyme), totally 2
Part；Enzyme stabilizers (0.2 part of borax, 0.2 part of succinic acid, 0.1 part of sodium thiosulfate), totally 0.5 part；Anti-dirt redeposition agent (carboxylic
0.5 part of sodium carboxymethylcellulose pyce)；Oxidative bleaching agent (50 parts of SODIUM PERCARBONATE)；Corrosion inhibition for metal protective agent (8 parts of metasilicate pentahydrate sodium).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 1.
Embodiment 5：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(2 parts of lauryl sodium sulfate)；Basic mineral cleaning agent (29.5 parts of sodium carbonate)；Builder (17 parts of sodium acid carbonate)；Enzyme preparation
(0.7 part of lipase, 0.8 part of cellulase, 0.3 part of staphylococcal nuclease, 0.5 part of catalase, 0.2 part of lysozyme),
Totally 2.5 parts；Enzyme stabilizers (0.3 part of borax, 0.2 part of succinic acid, 0.3 part of sodium thiosulfate), totally 0.8 part；Anti-dirt is redeposited
Agent (0.2 part of sodium carboxymethylcellulose)；Oxidative bleaching agent (40 parts of SODIUM PERCARBONATE)；Corrosion inhibition for metal protective agent (metasilicate pentahydrate sodium 8
Part).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 1.
Embodiment 6：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(2 parts of dodecyl benzene sulfonic acid, 3 parts of lauryl sodium sulfate), totally 5 parts；Basic mineral cleaning agent (23 parts of sodium carbonate, potassium carbonate 6
Part), totally 29 parts；Builder (9 parts of sodium acid carbonate, 4 parts of sodium tripolyphosphate), totally 13 parts；Enzyme preparation (1.5 parts of lysozyme)；Enzyme is steady
Determine agent (0.6 part of borax)；Anti-dirt redeposition agent (0.2 part of sodium carboxymethylcellulose, 0.2 part of polyvinylpyrrolidone), totally 0.4
Part；Oxidative bleaching agent (35 parts of SODIUM PERCARBONATE, 5 parts of potassium percarbonate), totally 40 parts；Corrosion inhibition for metal protective agent (metasilicate pentahydrate sodium 4
Part, 3 parts of anhydrous sodium metasilicate).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 1.
Embodiment 7：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(1 part of lauryl sodium sulfate, 1 part of ethoxylated fatty acid sulfonate, 1 part of sodium secondary alkyl sulfonate), totally 3 parts；Basic mineral is clear
Lotion (27.4 parts of sodium carbonate)；Builder (5 parts of sodium acid carbonate, 5 parts of sodium metasilicate), totally 10 parts；Enzyme preparation (.2 parts of proteinase-10,
0.4 part of lipase, 0.3 part of mannase, 0.6 part of staphylococcal nuclease, 0.2 part of catalase, 0.8 part of lysozyme),
Totally 2.5 parts；Enzyme stabilizers (0.3 part of borax, 0.2 part of potassium sorbate, 0.3 part of succinic acid), totally 0.8 part；Anti-dirt redeposition agent
(0.2 part of sodium carboxymethylcellulose, 0.1 part of sodium acrylate homopolymer), totally 0.3 part；Oxidative bleaching agent (28 parts of SODIUM PERCARBONATE, mistake
10 parts of potassium carbonate, 4 parts of sodium peroxydisulfate, 3 parts of sodium perborate, 5 parts of potassium perborate), totally 50 parts；(five water are inclined for corrosion inhibition for metal protective agent
5 parts of sodium metasilicate, 1 part of anhydrous sodium metasilicate), totally 6 parts.
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 1.
Embodiment 8：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(2 parts of sodium secondary alkyl sulfonate)；Basic mineral cleaning agent (25 parts of sodium carbonate)；Builder (13 parts of sodium acid carbonate, sodium metasilicate 4
Part), totally 17 parts；Enzyme preparation (.1 parts of proteinase-10,0.3 part of lipase, 0.1 part of hemicellulase, staphylococcal nuclease 0.3
Part, 0.2 part of catalase, 0.5 part of lysozyme), totally 1.5 parts；Enzyme stabilizers (0.5 part of borax).
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is substantially the same manner as Example 1, difference
It is：Step 3：By basic mineral cleaning agent, anti-dirt redeposition agent, oxidative bleaching agent, builder, corrosion inhibition for metal protective agent
It puts into blender, is uniformly mixed, obtains C powder；And step 4：A powder is obtained by above-mentioned and C powder is uniformly mixed, and is obtained
Washine-machine chute detergent product.
Embodiment 9：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(2 parts of dodecyl benzene sulfonic acid, 1 part of lauryl sodium sulfate, 1 part of ethoxylated fatty acid sulfonate), totally 4 parts；Basic mineral
Cleaning agent (25 parts of sodium carbonate, 4.5 parts of potassium carbonate), totally 29.5 parts；Builder (10 parts of sodium acid carbonate, 2 parts of sodium tripolyphosphate, partially
2 parts of sodium metasilicate), totally 14 parts；Enzyme preparation (1 part of lipase, 1.5 parts of lysozyme), totally 2.5 parts；Enzyme stabilizers (potassium sorbate 0.2
Part, 0.4 part of inositol), totally 0.6 part.
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is identical with embodiment 8.
Embodiment 10：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(1 part of dodecyl benzene sulfonic acid, 2 parts of lauryl sodium sulfate, 1 part of ethoxylated fatty acid sulfonate, sodium secondary alkyl sulfonate 1
Part), totally 5 parts；Basic mineral cleaning agent (20 parts of sodium carbonate, 4 parts of potassium carbonate), totally 24 parts；Builder (10 parts of sodium acid carbonate)；Enzyme
Preparation (0.3 part of pectase, 0.4 part of catalase, 1 part of lysozyme), totally 1.7 parts；Enzyme stabilizers (0.2 part of borax, sorbic acid
0.1 part of potassium, 0.1 part of sodium chloride, 0.1 part of inositol, 0.3 part of succinic acid, 0.2 part of sodium thiosulfate), totally 1 part.
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 8.
Embodiment 11：
A kind of formula of Washine-machine chute detergent is as follows：By weight, including following component：Anion surfactant
(3 parts of lauryl sodium sulfate)；Basic mineral cleaning agent (25 parts of sodium carbonate, 2.4 parts of potassium carbonate), totally 27.4 parts；Builder (carbon
Sour 8 parts of hydrogen sodium, 2 parts of sodium tripolyphosphate), totally 10 parts；Enzyme preparation (.3 parts of proteinase-10,0.4 part of lipase, 0.4 part of pectase, fibre
Plain 0.2 part of the enzyme of dimension, 0.2 part of mannase, 0.5 part of staphylococcal nuclease, 0.2 part of catalase, 0.3 part of lysozyme),
Totally 2.5 parts；Enzyme stabilizers (0.4 part of borax, 0.1 part of sodium chloride, 0.1 part of succinic acid, 0.2 part of sodium thiosulfate), totally 0.8 part.
In an embodiment of the present invention, the preparation method of Washine-machine chute detergent is same as Example 8.
It should be noted that in embodiments of the present invention, enzyme preparation is protease, lipase, pectase, cellulase,
Hemicellulase, mannonase staphylococcal nuclease, the catalase either one of which of lysozyme or at least two
The mixture of kind.For convenience of description, above embodiments only show several preferred compositions modes therein, in actual application
In, it can arbitrarily choose a kind of or at least two substances therein and be compounded, build detergent formula system, it is only necessary to keep
Shared parts by weight are 1.5~2.5 parts to the substance in formula, just do not enumerate one of the various combination sides herein
Formula.
Based on it is above-mentioned identical the reasons why, the present embodiments relate to anion surfactant be detergent alkylate sulphur
Acid, lauryl sodium sulfate, ethoxylated fatty acid the sulfonate either one of which of sodium secondary alkyl sulfonate or at least two
Mixture；Basic mineral cleaning agent is sodium carbonate and/or potassium carbonate；Builder is sodium acid carbonate, sodium tripolyphosphate or inclined
The one of which of sodium metasilicate or at least two mixture；Enzyme stabilizers are borax, potassium sorbate, sodium chloride, inositol, amber
The sour either one of which of sodium thiosulfate or at least two mixture；Anti-dirt redeposition agent is carboxymethyl cellulose
Sodium, polyvinylpyrrolidone, the polyvinyl alcohol either one of which of sodium acrylate homopolymer or at least two mixture；Oxygen
Change bleaching agent is at least three kinds of mixing in SODIUM PERCARBONATE, potassium percarbonate, sodium peroxydisulfate, sodium perborate or potassium perborate
Object；Corrosion inhibition for metal protective agent is metasilicate pentahydrate sodium and/or anhydrous sodium metasilicate.The various combinations of these above-mentioned components
It does not enumerate herein one by one.
In order to further illustrate the performance of Washine-machine chute detergent provided in an embodiment of the present invention, below by way of test example into
One step illustrates the advantageous effect of Washine-machine chute detergent provided in an embodiment of the present invention：
Experiment one：Enzyme activity stability test
1st, test specimen：Washine-machine chute detergent product provided in an embodiment of the present invention.
2nd, test method：The Washine-machine chute detergent product that the embodiment of the present invention 1~11 is provided number 1~11 respectively
Number, the test products for then having numbered these are stored under the conditions of being placed in room temperature (20 DEG C~30 DEG C), and test one at quarterly intervals
The enzyme activity of secondary each test products calculates and records corresponding enzyme activity, completes experiment within 12 months.
It is the enzyme activity testing principle and method of various enzyme preparations below：
(1) the enzyme activity test of staphylococcal nuclease：Staphylococcal nuclease is a weight for staphylococcus aureus
Virulence factor is wanted, by cultivating staphylococcus aureus, after adding in staphylococcal nuclease, tests S. aureus colonies
Kind number, so as to react staphylococcal nuclease vigor size, the reference of specific experiment method《Cosmetics safety technical specification 2015
Version》Chapter 5, Micro biological Tests method --- the staphylococcus aureus method of inspection.
(2) the enzyme activity test of lysozyme：Light is divided with reference to the measure of lysozyme in GB/T 25879-2010 egg whites
Photometry
(3) the enzyme activity test of catalase：Hydrogen peroxide can be catalytically decomposed in catalase.In pH 7.0,25
At DEG C, 1 μm of ol H of degradation per minute2O2For an enzyme activity unit.
(4) lipase activity power is tested：With reference to the detection method of GB/T 23535-2009 lipase preparations.
(5) the enzyme activity test of cellulase：With reference to QB 2583-2003 cellulase preparation detection methods.
(6) the enzyme activity test of pectase：Pectase hydrolysis of pectin, generates galacturonic acid, and the latter has reproducibility aldehyde
Base can be quantitative determined with secondary idous acid system, and the amount for generating galacturonic acid can be used for the vigor for representing pectase.
(7) the enzyme activity test of hemicellulase：Hemicellulase hydrolyzed xylan, the reduced sugar released is (with xylose
Meter) it is reacted with 3,5- dinitrosalicylic acids (DNS), generation color change, the reduced sugar of this color change and release is (with xylose
Meter) amount it is proportional, i.e., it is directly proportional to the enzyme activity in enzyme sample.By checking standard song in the absorbance value of 550nm
Line can determine the amount that reduced sugar generates (using xylose as reference substance), so that it is determined that going out the unit of activity of enzyme.
(8) the enzyme activity detection (referring to international standard) of mannase：Under conditions of 37 DEG C, pH value is 5.5, every point
Clock 1 μm of required enzyme amount of ol reduced sugars of degradation release from mannosan (Sigma G0753) solution that concentration is 3mg/mL
For an enzyme activity unit U.
Mannosan can be degraded into oligosaccharides and monose by mannase.Oligosaccharides with reducing end under neutral and there is also former base
Under the conditions of boiling water bath with DNS reagents chromogenic reaction can occur for the monose of group.The intensity of reaction solution color is generated with enzymolysis
It is directly proportional to reduce sugar amount, and the growing amount of reduced sugar is directly proportional to the vigor of mannase in reaction solution.
3rd, result of the test：The following table 1 is referred to, wherein, enzyme activity=(enzyme activity × 100%)/initial enzyme activity.
Table 1
It can be drawn from the test result of upper table 1, Washine-machine chute detergent provided in an embodiment of the present invention is in room temperature (20
DEG C~30 DEG C) under the conditions of store 12 months after, the enzyme activity of the various enzymes in formula is positively retained at more than 99%, so this hair
The formula system for the Washine-machine chute detergent that bright embodiment provides can maintain the stability of various enzymes well, it is ensured that it makes
Use effect.
Experiment two：Bacteria quantified Killing test
1st, test specimen：Washine-machine chute detergent product provided in an embodiment of the present invention.
2nd, test method：With reference to the Ministry of Public Health《Disinfection technology standard》2008 editions.Test strain：It is staphylococcus aureus, big
Enterobacteria, Pseudomonas aeruginosa, Candida albicans.
During experiment, the Washine-machine chute detergent sample that the embodiment of the present invention 1~11 provides is configured to respectively dense
The sample for 1% is spent, and is positioned in the volumetric flask or conical flask of number 1~11, it is spare.And preparation experiment bacteria suspension, it puts down
It is dispensed into the conical flask of number 1a~11a, then, each test liquid of equivalent is taken to be added to the conical flask of 1a~11a respectively
In, it will be sufficiently mixed after test liquid and experiment with the test strain in bacteria suspension uniformly and after the 20min that interacts, start to test
And record the killing rate of the test strain in each conical flask.
Washine-machine chute detergent provided in an embodiment of the present invention is placed under the conditions of room temperature (20 DEG C~30 DEG C) and is stored, and point
The Washine-machine chute detergent pair that each embodiment provides is not tested and recorded according to above-mentioned test method with after 12 months after six months
The killing rate of test strain.
3rd, result of the test：Result of the test refers to the following table 2, wherein, killing rate=(the strain quantity survived after experiment/initial
The quantity of strain) × 100%.
Table 2
As can be seen that Washine-machine chute detergent provided in an embodiment of the present invention is for golden yellow from the result of the test of upper table 2
Color staphylococcus, Escherichia coli, Pseudomonas aeruginosa, the initial killing rate of Candida albicans more than 98%, and with storage when
Between increase, Washine-machine chute detergent provided in an embodiment of the present invention is positively retained at the killing rate of above-mentioned four kinds of test strains
More than 95%, it can be seen that, the vigor stability of enzyme in the formula system of Washine-machine chute detergent provided in an embodiment of the present invention
Good, bactericidal effect is good, and the Washine-machine chute detergent that wherein embodiment of the present invention 3 provides is to the killing rate of above-mentioned four kinds of test strains
Preferably, so the stability of the complex enzyme in embodiment 3 is best.
Experiment three：Metal corrosion-resistant is tested
1st, test specimen：Washine-machine chute detergent product provided in an embodiment of the present invention.
2nd, test method：With reference to the Ministry of Public Health《Disinfection technology standard》2008 editions.
Preprocessing process：Prepare sheet metal (stainless steel/copper piece) 12 fritters of similary material first, and number/be labeled as 1
~No. 12, then, sheet metal is placed in the detergent of Action of Surfactant and impregnated 10 minutes, fully deoiled, clear water
It cleans；Or with being cleaned after the smearing oil removing of magnesia paste, sheet metal two sides and periphery surface are ground off with No. 120 granularity waterproof abrasive papers
Oxide layer, then rinsed with tap water.It is measured after drying and records the diameter, thickness, aperture (being accurate to 0.1mm) of each sheet metal
Anhydrous propanone or absolute ethyl alcohol degreasing again are used afterwards.Be placed in 50 DEG C of constant incubators dry 1 it is small when, treat that its temperature is down to room
It weighs and records after temperature.
Prepare sample solution：The Washine-machine chute detergent provided with the embodiment of the present invention 1~11 distinguishes compound concentration and is
10% test liquid, it is spare.The beaker of 12 500mL is taken, respectively number 1~12, wherein No. 1 is blank control group, burnt
One piece of pretreated sheet metal is put into cup, and adds in 200mL distilled water and sheet metal is immersed in beaker, is dipped into regulation
After time when small (such as 1), sheet metal from soak is taken out, 50 DEG C of constant temperature incubation is put into after being rinsed well with tap water
In case it is dry 1 it is small when, with scales/electronic balance weighing (being accurate to 2 decimals) and remember after then sheet metal taking-up is cooled to room temperature
Record, while the color change situation for the sheet metal that detects by an unaided eye and record.2~No. 12 are respectively test group, and No. 2 real for the present invention
The Washine-machine chute detergent test group of the offer of example 1 is provided, No. 3 Washine-machine chute detergent test groups provided for the embodiment of the present invention 2,
No. 4 Washine-machine chute detergent test groups ... provided for the embodiment of the present invention 3 and so on, No. 12 are the embodiment of the present invention 11
The Washine-machine chute detergent test group of offer.The processing method of test group and above-mentioned blank control group are essentially the same, different
It is that distilled water is substituted for the Washine-machine chute detergent test liquid of corresponding each embodiment.
3rd, result of the test：During entire experiment, color essentially unchangedization of 1~No. 12 sheet metal, and sheet metal
The equal ＜ 0.0100mm/a of corrosion rate, i.e. no corrosion phenomenon, so washing machine tank provided in an embodiment of the present invention cleans
Agent to metal no corrosion, for cleaning washing machine washing machine internal metal parts will not be caused to cause corrosion damage.
Wherein, table 3 is corrosivity graded index detail list.
Table 3
| Corrosion rate R (mm/a) | Rank |
| ＜ 0.0100 | No corrosion |
| 0.0100~＜ 0.100 | Mild corrosion |
| 0.100~＜ 1.00 | Moderate corrosion |
| ≥1.00 | Severe is corroded |
Experiment four：Clean clean effect experiment
(1) greasy dirt clean effect is tested：
1st, test specimen：The Washine-machine chute detergent product that the embodiment of the present invention 1~11 provides.
2nd, test principle and method：With reference in QB/T4348-2012 5.6 relevant regulations.
3rd, result of the test：Refer to the following table 4.
Table 4
| Test specimen group | Detergency (%) |
| Embodiment 1 | 99.12 |
| Embodiment 2 | 98.15 |
| Embodiment 3 | 99.39 |
| Embodiment 4 | 97.61 |
| Embodiment 5 | 99.02 |
| Embodiment 6 | 99.11 |
| Embodiment 7 | 98.64 |
| Embodiment 8 | 98.29 |
| Embodiment 9 | 98.99 |
| Embodiment 10 | 97.82 |
| Embodiment 11 | 98.96 |
Washing machine tank easily adheres to greasy spot during storage on washing machine cell wall, which is marked using country
Quasi- QB/T4348-2012 provides the detergency test method of kitchen heavy oil product, tests removal effect of the present invention for greasy dirt,
Provide that kitchen heavy oil product is greater than or equal to 80% in standard.As shown in Table 4, washing machine tank cleaning provided in an embodiment of the present invention
The soil removal efficiency of agent reaches more than 97%, reaches as high as 99.39%, hence it is evident that higher than the 80% of national Specification, therefore, this hair
The clean effect for the Washine-machine chute detergent that bright embodiment provides is good, is conducive to keep the sanitation and hygiene of washing machine internal.
(2) clothes stains clean effect is tested：
1st, test specimen：The Washine-machine chute detergent product that the embodiment of the present invention 1~11 provides.
2nd, test principle and method：With reference to GB/T 13174-2008 dress materials detergent detergency and Xun Huan scourability
Measure and QB/T 1224-2012 dress materials wash agent by liquid.
3rd, result of the test：Refer to the following table 5.Wherein, detergency experimental concentration is 0.1%, standard liquid detergent experimental concentration is
0.2%；JB-01 --- carbon black greasy dirt cloth；JB-02 --- albumen soiled cotton；JB-03 --- sebum soiled cotton.Collar detergency country
Standard parameter index request is as follows：Tri- kinds of experiment soiled cottons of JB-01, JB-02, JB-03 are all higher than or equal to standard liquid detergent.
Table 5
Easily adhere to the spots such as human body sweat stain, clothing lint residue, the experiment on washing machine cell wall by long-term use
Using standard GB/T/T 13174-2008 dress materials detergent detergency and the Xun Huan measure of scourability and QB/T 1224-
2012 dress materials wash the detergency test method of agent by liquid, and the test present invention is for JB-01 carbon black greasy dirts cloth, JB-02 albumen
The removal effect of soiled cotton, JB-03 sebum soiled cottons.As shown in Table 5, the decontamination of Washine-machine chute detergent provided in an embodiment of the present invention
Force value is significantly greater than standard liquid detergent, i.e., the strong detergency of Washine-machine chute detergent provided in an embodiment of the present invention, cleaning effect
Fruit is good, is conducive to.
Enzyme preparation in Washine-machine chute detergent formula provided in an embodiment of the present invention has with anion surfactant
Synergistic effect, while under the action of enzyme stabilizers, the enzyme activity stability of enzyme preparation is high, can effectively decompose removal washing machine tank
In various spots, cleaning effect is good, and clean noresidue after cleaning, and will not cause secondary pollution, ensure that washing machine internal
Sanitation and hygiene, and to stainless steel/copper piece no corrosion.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of Washine-machine chute detergent, which is characterized in that by weight, including following component：
Anion surfactant：2~5 parts；
Basic mineral cleaning agent：24~29.5 parts；
Builder：10~17 parts；
Enzyme preparation：1.5~2.5 parts；And
Enzyme stabilizers：0.5~1 part；
Wherein, enzyme preparation is protease, lipase, pectase, cellulase, hemicellulase, mannonase staphylococcus
Nuclease, the catalase either one of which of lysozyme or at least two mixture.
2. Washine-machine chute detergent as described in claim 1, which is characterized in that the enzyme preparation for staphylococcal nuclease,
Catalase, lysozyme, the mixture of lipase and cellulase.
3. Washine-machine chute detergent as described in claim 1, which is characterized in that by weight, including following component：
Anion surfactant：3 parts；
Basic mineral cleaning agent：27.4 parts；
Builder：10 parts；
Enzyme preparation：2.5 part；And
Enzyme stabilizers：0.8 part.
4. Washine-machine chute detergent as described in claim 1, which is characterized in that by weight, including following component：
Anion surfactant：2~5 parts；
Basic mineral cleaning agent：24~29.5 parts；
Builder：10~17 parts；
Enzyme preparation：1.5~2.5 parts；
Enzyme stabilizers：0.5~1 part；
Anti-dirt redeposition agent：0.2~0.5 part；
Oxidative bleaching agent：40~50 parts；And
Corrosion inhibition for metal protective agent：6~8 parts.
5. Washine-machine chute detergent as claimed in claim 4, which is characterized in that by weight, including following component：
Anion surfactant：3 parts；
Basic mineral cleaning agent：27.4 parts；
Builder：10 parts；
Enzyme preparation：2.5 part；
Enzyme stabilizers：0.8 part；
Anti-dirt redeposition agent：0.3 part；
Oxidative bleaching agent：50 parts；And
Corrosion inhibition for metal protective agent：6 parts.
6. Washine-machine chute detergent as described in claim 1, which is characterized in that
The anion surfactant is dodecyl benzene sulfonic acid, lauryl sodium sulfate, ethoxylated fatty acid sulfonate
The either one of which of sodium secondary alkyl sulfonate or at least two mixture；
The basic mineral cleaning agent is sodium carbonate and/or potassium carbonate；
The builder is sodium acid carbonate, the sodium tripolyphosphate either one of which of sodium metasilicate or at least two mixing
Object；
The enzyme stabilizers are borax, potassium sorbate, sodium chloride, inositol, succinic acid or sodium thiosulfate one of which or
The mixture of person at least two.
7. Washine-machine chute detergent as claimed in claim 4, which is characterized in that
The anti-dirt redeposition agent is sodium carboxymethylcellulose, polyvinylpyrrolidone, polyvinyl alcohol or sodium acrylate are equal
The one of which of polymers or at least two mixture；
The oxidative bleaching agent is at least three in SODIUM PERCARBONATE, potassium percarbonate, sodium peroxydisulfate, sodium perborate or potassium perborate
The mixture of kind；
The corrosion inhibition for metal protective agent is metasilicate pentahydrate sodium and/or anhydrous sodium metasilicate.
8. Washine-machine chute detergent as claimed in claim 4, which is characterized in that
The anion surfactant includes the substance of following parts by weight：3 parts of lauryl sodium sulfate；
The basic mineral cleaning agent includes the substance of following parts by weight：27.4 parts of sodium carbonate；
The builder includes the substance of following parts by weight：10 parts of sodium acid carbonate；
The enzyme preparation includes the substance of following parts by weight：0.5 part of staphylococcal nuclease, 0.5 part of lysozyme, hydrogen peroxide
0.5 part of 0.5 part of enzyme, 0.5 part of lipase and cellulase；
The enzyme stabilizers include the substance of following parts by weight：0.3 part of borax, 0.2 part of succinic acid and sodium thiosulfate 0.3
Part；
The anti-dirt redeposition agent includes the substance of following parts by weight：0.3 part of sodium carboxymethylcellulose；
The oxidative bleaching agent includes the substance of following parts by weight：50 parts of SODIUM PERCARBONATE；
The corrosion inhibition for metal protective agent includes the substance of following parts by weight：6 parts of metasilicate pentahydrate sodium.
9. the preparation method of the Washine-machine chute detergent as described in claim 1~8 any one, which is characterized in that including such as
Lower step：
Formula according to the Washine-machine chute detergent as described in claim 1~8 any one weighs each component, spare；
It is put into blender and stirs evenly after the enzyme preparation and enzyme stabilizers low temperature are freezed dehydration, and by the anion table
Face activating agent is added in the blender, is mixed evenly, is obtained A powder；
The basic mineral cleaning agent and builder are added in blender, is uniformly mixed, obtains B powder；
The A powder and B powder are uniformly mixed, obtain the Washine-machine chute detergent.
10. the application of the Washine-machine chute detergent as described in claim 1~8 any one, which is characterized in that do washing in cleaning
During trough, washing machine tank is filled at high water level, the Washine-machine chute detergent is added in into the washing machine tank, startup is washed
Clothing machine starts washing machine, according to just so that the Washine-machine chute detergent closes power supply after fully dissolving herein after impregnating 1~3h
Often washing standard cleaning one time, is rinsed well after discharging sewage with clear water.
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| CN108913374A (en) * | 2018-07-11 | 2018-11-30 | 林少忠 | A kind of detergent and preparation method thereof containing flat leaf thorn celery extract |
| EP3892707A1 (en) * | 2020-04-06 | 2021-10-13 | Dalli-Werke GmbH & Co. KG | Liquid detergent composition, kit and dosing system |
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