CN108102555A - A kind of inorganic high-temperature resistant cementing compositions and preparation method and application - Google Patents
A kind of inorganic high-temperature resistant cementing compositions and preparation method and application Download PDFInfo
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- CN108102555A CN108102555A CN201711450969.9A CN201711450969A CN108102555A CN 108102555 A CN108102555 A CN 108102555A CN 201711450969 A CN201711450969 A CN 201711450969A CN 108102555 A CN108102555 A CN 108102555A
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- temperature resistant
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- cementing compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
- C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Sealing Material Composition (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of inorganic high-temperature resistant cementing compositions and fluid sealant and preparation methods and application, are made of following component:40 55 parts by weight of liquid sodium silicate;30 45 parts by weight of aluminium silicate powder;8 12 parts by weight of magnesia;15 20 parts by weight of silicon nitride;20 30 parts by weight of quartz sand.Preparation method includes the following steps:It is prepared by S1 raw materials:It is prepared by S11 liquid sodium silicates;It is prepared by S12 aluminium silicate powders;It is prepared by S13 magnesia;It is prepared by S14 silicon nitrides;It is prepared by S15 quartz sands;S2 is prepared.A kind of application of inorganic high-temperature resistant cementing compositions on plastic protective coating is prepared.The present invention has the advantages that high temperature resistant, not easily to fall off, at low cost and use scope are wide.
Description
Technical field
The present invention relates to protective coating technique fields, and in particular to a kind of inorganic high-temperature resistant cementing compositions and fluid sealant with
Preparation method and application.
Background technology
Inorganic coating is to use ceramics or glass state material and part metals, adds and is coated in metal or ceramic surface to reach increasing
It imitates and a kind of film layer for purpose of lengthening the life.Such as heat-resisting, the antioxidant coating applied in terms of aerospace, the temperature control applied on satellite
Coating, the wear-resistant coating applied in mechanical industry are applied in the biological coating and chemical industry applied on artificial body resistance to
Soda acid coating etc..According to different purposes and use environment, the technique of inorganic coating is also different.Cladding process is by inorganic compound
Coating is tuned into slurry, with brush, spraying, wire mark the methods of coated in ceramics or metal substrate surface, then in low temperature or room
Temperature is lower to be cured or burns till at high temperature.Spraying process be directly with the inorganic compound powder centainly matched, by high temperature spray gun,
The surface for spraying to metal substrate forms.Vapour deposition method is a kind of technology that material evaporation is made to be deposited on by painting device surface,
Thickness is only millimicron to micron order, applied to extremely fine and more special occasion.Inorganic coating is widely used at present
Various fields.The artificial satellite cover of various models successfully applies thermal control coating.Plasma spraying multi-layer composite coatings,
Heat-insulated thermal protective coating as large rocket engine jet pipe and the sealing ring and axis for being widely used in chemical industry, machinery field
It holds and waits wear parts.Sunlight absorption rate very high do not burn coating and black enamel are used as photothermal conversion on solar water heater
Coating is applied.Oxide-coated artificial bone and cermet tooth is sprayed on metallic matrix to answer what clinic succeeded
With.
The fast development of plastics industry also brings a series of social concerns caused by waste plastic and rubbish waste plastics.
Deep people is to the every nook and cranny of society for the application of plastic products, and from industrial production to clothing, food, lodging and transportion -- basic necessities of life, plastic products are ubiquitous.People
Start to find, plastic garbage stealthily to we gushed come, drastically influence our health and living environment, such as
Some agricultural lands start the underproduction due to influence of discarded mulch, and " white pollution " that waste plastics triggers starts that people is allowed to have a headache,
The Undec cutlery box of without putrefaction can not be recycled effectively, and life is had no way of doing it processing with plastic garbage.Plastic refuse increase severely and by
Society caused by this and environmental problem pendulum put the place for existence of living in whole world people in face of people.
In the prior art, the coating of plastics is focusing more on plastic coating.In inorganic adhesive, when heating temperature is more than
The softening point or decomposition temperature of high molecular material, also lose the effect of coating.For heat safe resin, coating is used as
For adhesive effect it is poor.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of inorganic high-temperature resistant cementing compositions and sealings
Glue and preparation method and application, solve the problems, such as coating non-refractory.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of inorganic high-temperature resistant cementing compositions, are made of following component:
Adding liquid sodium metasilicate, aluminium silicate powder, magnesia, silicon nitride and quartz sand in inorganic high-temperature resistant cementing compositions,
It is inorganic raw material, at low cost, melting temperature is high, and superficial attractive forces are strong;Good seal, it is easy to use, it is water-fast corrosion-resistant;In temperature
It spends in the environment for being 0.1-50MPa for 20-700 DEG C and pressure, adhesive strength is big, favorable sealing property.
Liquid sodium silicate is liquid, has colourless clear viscous shape and the light color translucent.Main component is silica
(SiO2) and sodium oxide molybdena (Na2O), the raw material of two kinds of mode of appearance production and processings of viscous liquid is soda ash and quartz sand.
For aluminium silicate powder as functional aid, it can be widely used for environment-friendly water-based building coating, ink, plastics, rubber, skin
The fields such as leather, printing and dyeing, papermaking.Add in indoor and outdoor building coating, printing coating slurry, outside leather casein finiss, alkyd paint, acrylic acid
In the products such as wall paint, powdery paints, white base coat, road marking paint, titanium white synergistic effect is generated, saves titanium dioxide dosage
About 15~25%, therefore product cost can be greatly lowered, and properties of product are may significantly improve, such as whiteness, dry film covering power, storage
Stability, weatherability, wear resistance, scrub resistance etc.;Also the workability of product can be improved, such as reduce the thermoplasticity of film,
Improve the tackiness, dust absorption etc. of surface.The thickening that priming paint can be made somewhat slight so as to improve its brushability, is prevented vertical
The sagging phenomenon of application.
Magnesia goes out a system with the demand and development in industrialization upgrading and new and high technology functional material market, development & production
High-new fine magnesium oxide product is arranged, is mainly used for senior lubricant, advanced tanning carries basicity grade, food-grade, medicine, silicon steel grade, height
Nearly ten kind compositions such as grade electromagnetism grade, high-purity magnesium oxide.
Silicon nitride is a kind of important structural ceramic material.It is a kind of superhard substance, itself has lubricity, and resistance to
Abrasion is atomic crystal;It is anti-oxidant during high temperature.And it can also resist thermal shock, be heated to 1000 DEG C or more in air,
Quick refrigeration drastically heats again, will not fragmentation.There is so excellent characteristic just because of silicon nitride ceramics, people are usually sharp
The mechanical components such as bearing, blade of gas turbine, mechanical seal ring, permanent mold are manufactured with it.
Further, the density of the liquid sodium silicate is 1.30-1.35g/cm3。
Further, the aluminium silicate powder, magnesia are SILVER REAGENT, the mesh of granularity >=500.
Further, the silicon nitride is nano-silicon nitride.
Further, the quartz sand is super-fine silicon micro-powder.
The density domination of liquid sodium silicate within the above range, it is good to glue glutinous effect;The size controlling of other inorganic material exists
In smaller scope, the surface area bigger of contact, superficial attractive forces increase, and the coating of formation is even closer careful.
A kind of preparation method of inorganic high-temperature resistant cementing compositions, includes the following steps:
It is prepared by S1 raw materials:
It is prepared by S11 liquid sodium silicates:Density 1.30-1.35g/cm is diluted to distilled water or deionized water3;
It is prepared by S12 aluminium silicate powders:Closed appearance is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In device;
It is prepared by S13 magnesia:Closed container is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In;
It is prepared by S14 silicon nitrides:Closed container is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In;
It is prepared by S15 quartz sands:Distilled water or deionized water are cleaned 2-3 times, 150-160 DEG C of drying, ball milling or finely ground by hand,
The mesh of granularity >=500 is stored in after calcining 15-20min in 800-900 DEG C of high temperature resistant stove in closed container;
S2 is prepared:Liquid sodium silicate, aluminium silicate powder and magnesia, silicon nitride and quartz sand puddled in the ratio until
There is no slag particle and agglomerate to get the inorganic high-temperature resistant fluid sealant.
The preparation method of inorganic high-temperature resistant cementing compositions is simple, and the temperature and time of calcination process is consistent, saves process,
It can calcine together;The composition high temperature resistant being prepared, adhesive effect is good, not easily to fall off, adapts to different working environments, should
It is wide with scope.
A kind of application of inorganic high-temperature resistant cementing compositions on plastic protective coating is prepared.Plastic protective coating uses nothing
Organic coating, high temperature resistance is good, adapts to different working environments, not easily to fall off, not aging, usage time is long, at low cost.
The beneficial effects of the invention are as follows:
1. adding liquid sodium metasilicate, aluminium silicate powder, magnesia, silicon nitride and quartz in inorganic high-temperature resistant cementing compositions
Sand is inorganic raw material, at low cost, and melting temperature is high, and superficial attractive forces are strong;Good seal, it is easy to use, it is water-fast corrosion-resistant;
In the environment that temperature is 20-700 DEG C and pressure is 0.1-50MPa, adhesive strength is big, favorable sealing property;
2. the density domination of liquid sodium silicate is within the above range, it is good to glue glutinous effect;The size controlling of other inorganic material
In smaller scope, the surface area bigger of contact, superficial attractive forces increase, and the coating of formation is even closer careful;
3. the preparation method of inorganic high-temperature resistant cementing compositions is simple, the temperature and time of calcination process is consistent, saves work
Sequence can calcine together;The composition high temperature resistant being prepared, adhesive effect is good, not easily to fall off, adapts to different building rings
Border has a wide range of application;
4. plastic protective coating uses inorganic coating, high temperature resistance is good, adapts to different working environments, is not easy to take off
Fall, not aging, usage time is long, at low cost.
Specific embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention is not
It is confined to as described below.
A kind of inorganic high-temperature resistant cementing compositions, are made of following component:
Specifically, the density of the liquid sodium silicate is 1.30-1.35g/cm3。
Specifically, the aluminium silicate powder, magnesia are SILVER REAGENT, the mesh of granularity >=500.
Specifically, the silicon nitride is nano-silicon nitride.
Specifically, the quartz sand is super-fine silicon micro-powder.
The design parameter of embodiment 1- embodiments 6 is as shown in table 1, the technology that embodiment 1- embodiments 4 limit for the present invention
Parameter.
Table 1
Above-mentioned inorganic high-temperature resistant cementing compositions are applied on plastic protective coating is prepared, and its preparation method includes following step
Suddenly:
It is prepared by S1 raw materials:
It is prepared by S11 liquid sodium silicates:Density 1.30-1.35g/cm is diluted to distilled water or deionized water3;
It is prepared by S12 aluminium silicate powders:Closed appearance is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In device;
It is prepared by S13 magnesia:Closed container is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In;
It is prepared by S14 silicon nitrides:Closed container is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In;
It is prepared by S15 quartz sands:Distilled water or deionized water are cleaned 2-3 times, 150-160 DEG C of drying, ball milling or finely ground by hand,
The mesh of granularity >=500 is stored in after calcining 15-20min in 800-900 DEG C of high temperature resistant stove in closed container;
S2 is prepared:Liquid sodium silicate, aluminium silicate powder and magnesia, silicon nitride and quartz sand puddled in the ratio until
There is no slag particle and agglomerate to get the inorganic high-temperature resistant fluid sealant.
The specific performance parameter of the protective coating on plastics of embodiment 1- embodiments 4 is as shown in table 2:
Embodiment | 1 | 2 | 3 | 4 |
Temperature tolerance/DEG C | 650 | 680 | 670 | 690 |
Viscosity g/cm3 | 1.39 | 1.40 | 1.41 | 1.42 |
Alkali resistance | It is excellent | It is excellent | It is excellent | It is excellent |
Fuel resistance | It is excellent | It is excellent | It is excellent | It is excellent |
Resistance to combustion gas | It is excellent | It is excellent | It is excellent | It is excellent |
Surface roughness | Ra<0.4μm | Ra<0.4μm | Ra<0.4μm | Ra<0.4μm |
Table 2
The above is only the preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein
Form is not to be taken as the exclusion to other embodiment, and available for various other combinations, modification and environment, and can be at this
In the text contemplated scope, it is modified by the technology or knowledge of above-mentioned introduction or association area.And those skilled in the art institute into
Capable modifications and changes do not depart from the spirit and scope of the present invention, then all should be in the protection domain of appended claims of the present invention
It is interior.
Claims (7)
1. a kind of inorganic high-temperature resistant cementing compositions, which is characterized in that be made of following component:
2. a kind of inorganic high-temperature resistant cementing compositions according to claim 1, which is characterized in that the liquid sodium silicate
Density is 1.30-1.35g/cm3。
3. a kind of inorganic high-temperature resistant cementing compositions according to claim 1, which is characterized in that the aluminium silicate powder, oxygen
It is SILVER REAGENT to change magnesium, the mesh of granularity >=500.
4. a kind of inorganic high-temperature resistant cementing compositions according to claim 1, which is characterized in that the silicon nitride is nanometer
Silicon nitride.
5. a kind of inorganic high-temperature resistant cementing compositions according to claim 1, which is characterized in that the quartz sand is ultra-fine
Silicon powder.
6. the preparation method of a kind of inorganic high-temperature resistant cementing compositions described in claim 5, which is characterized in that including walking as follows
Suddenly:
It is prepared by S1 raw materials:
It is prepared by S11 liquid sodium silicates:Density 1.30-1.35g/cm is diluted to distilled water or deionized water3;
It is prepared by S12 aluminium silicate powders:Closed container is stored in respectively after calcining 15-20min in 800-900 DEG C of high temperature resistant stove
In;
It is prepared by S13 magnesia:It is stored in respectively in closed container after calcining 15-20min in 800-900 DEG C of high temperature resistant stove;
It is prepared by S14 silicon nitrides:It is stored in respectively in closed container after calcining 15-20min in 800-900 DEG C of high temperature resistant stove;
It is prepared by S15 quartz sands:Distilled water or deionized water are cleaned 2-3 times, 150-160 DEG C of drying, ball milling or by hand finely ground, granularity
>=500 mesh are stored in after calcining 15-20min in 800-900 DEG C of high temperature resistant stove in closed container;
S2 is prepared:Liquid sodium silicate, aluminium silicate powder and magnesia, silicon nitride and quartz sand are puddled until not having in the ratio
Slag particle and agglomerate are to get the inorganic high-temperature resistant fluid sealant.
7. a kind of inorganic high-temperature resistant cementing compositions of claim 1-5 any one of them answering on plastic protective coating is prepared
With.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109825117A (en) * | 2019-01-25 | 2019-05-31 | 上海溟澄环保科技有限公司 | The negative ion paint and preparation method thereof of formaldehyde and organic compound gas can be removed |
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CN105440957A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Potassium silicate binder |
CN107000322A (en) * | 2014-12-12 | 2017-08-01 | Ask化学品股份有限公司 | Build the method and the adhesive of hydrated glass of mould and core layer by layer using the adhesive of hydrated glass |
CN107236464A (en) * | 2017-06-16 | 2017-10-10 | 中国人民解放军第五七九工厂 | A kind of high-temperature resistant gas fluid sealant and its preparation method and application |
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2017
- 2017-12-27 CN CN201711450969.9A patent/CN108102555A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107000322A (en) * | 2014-12-12 | 2017-08-01 | Ask化学品股份有限公司 | Build the method and the adhesive of hydrated glass of mould and core layer by layer using the adhesive of hydrated glass |
CN105440957A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Potassium silicate binder |
CN107236464A (en) * | 2017-06-16 | 2017-10-10 | 中国人民解放军第五七九工厂 | A kind of high-temperature resistant gas fluid sealant and its preparation method and application |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109825117A (en) * | 2019-01-25 | 2019-05-31 | 上海溟澄环保科技有限公司 | The negative ion paint and preparation method thereof of formaldehyde and organic compound gas can be removed |
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Application publication date: 20180601 |