CN108102476A - A kind of paralysis mosquito/fly-killing paint and preparation method thereof - Google Patents
A kind of paralysis mosquito/fly-killing paint and preparation method thereof Download PDFInfo
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- CN108102476A CN108102476A CN201810072361.5A CN201810072361A CN108102476A CN 108102476 A CN108102476 A CN 108102476A CN 201810072361 A CN201810072361 A CN 201810072361A CN 108102476 A CN108102476 A CN 108102476A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
A kind of paralysis mosquito/fly-killing paint and preparation method thereof, the paralysis mosquito/fly-killing paint include coating products and paralysis anophelifuge, and the dosage of the paralysis anophelifuge is equivalent to the 0.1~1.0% of gross mass；The viscosity of the paralysis mosquito/fly-killing paint is 106~116KU, and pH value is 8~9.The method is：Paralysis anophelifuge is added in coating products, stirs evenly, then with screen filtration, obtains paralysis mosquito/fly-killing paint.Coating of the present invention has the function of lasting, efficient mosquito repelling and purification air, and few to human injury, viscosity is 106~116KU, aqueous, nontoxic, tasteless, pollution-free, and the service life of film is long, antibacterial and mouldproof, has excellent scrub performance, antifouling effect is good, and stability is good, easily constructs；The method of the present invention so that simple process and low cost is suitable for industrial production to coating without apparent suspended particulate.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, and in particular to a kind of paralysis mosquito/fly-killing paint and its preparation side
Method.
Background technology
Summer, due to having a humid climate, sultry, summer mosquito was also increased, room in addition to hot weather makes people gloomy
Interior outdoor do not pay attention to that slightly bag will be bitten into, and especially for there is child in family, mosquito-proof summer is even more one big worried.By
The immunity of child Yu itself is low, therefore, once by bite by mosquitos to will be had an impact to its health.Traditional
In mosquito-proof method, most common people are exactly mosquito-repellent incense, anophelifuge, mosquito-repellent water or viscous mosquitos and flies plate etc..Actually these are traditional anti-
Mosquito method is unsuitable to child, and all containing substantial amounts of chemical substance in general anophelifuge, still more some people are to mosquito-repellent incense
The smell of generation is not suitable with, and then is abandoned or used less, and mosquito-proof effect is caused to be not obvious；And usually we used in kitchen it is viscous
Mosquitos and flies plate, not only damages refined, and mosquito-proof effect is also little.Therefore, at present apparently, traditional mosquito-proof method has not applied to
, we go to solve the worry in people's summer, beat there is an urgent need to find a kind of safe and environment-friendly, efficient mosquito repellent material or method
The family trusted is made, user is allowed no longer to worry that child is by mosquito bite in family.
CN101125971A discloses a kind of mosquito repellent, fly, worm functional paint and preparation method thereof, is that one kind is used to expel mosquito
The coating of the invasions such as son, fly, winged insect, ant, screen-like mountain peak dung beetle.But the coating can only be expelled into contact with the mosquito of metope and left
Metope, it is impossible to mosquito be eliminated and dispelled, mosquito is caused still to bite indoor human body.
CN01955696A discloses a kind of Attapulgite window screen paint with function of eradicating mosquitoes, is a kind of coating that can discharge a variety of smells,
Make the mosquito for not liking this smell that can fly away away from window screening, and like the mosquito of this smell, it, can be straight in order to get in
It connects and flutters on Attapulgite window screen paint with function of eradicating mosquitoes, by the adhesion of Attapulgite window screen paint with function of eradicating mosquitoes institute, the insecticide in coating quickly will again
Mosquito is killed.But due to containing fatty acid cane sugar ester and attapulgite in this coating, with viscosity, dust is easily adhered,
Also it is readily adhered on human body, it is both dangerous, it is also unhygienic.
The content of the invention
The technical problems to be solved by the invention are to overcome drawbacks described above existing in the prior art, provide one kind and dispel mosquito
Fly effect is good, few to human injury, scrubbing resistance, and antifouling effect is good, and stability is good, easy working paralysis mosquito/fly-killing paint.
Further technical problems to be solved of the invention are to overcome drawbacks described above existing in the prior art, provide a kind of painting
Material is suitable for the industrial preparation method for benumbing mosquito/fly-killing paint without apparent suspended particulate, simple process and low cost.
The technical solution adopted by the present invention to solve the technical problems is as follows：A kind of paralysis mosquito/fly-killing paint, including coating
Product and paralysis anophelifuge, the dosage of the paralysis anophelifuge are equivalent to the 0.1~1.0% of gross mass；It is described to benumb the painting that wipes out the flies and mosquitoes
The viscosity of material is 106~116KU, and pH value is 8~9.The paralysis anophelifuge is after a kind of leg by mosquitos and flies contacts so that god
Through paralysis, mosquitos and flies broken leg is ultimately resulted in and dead preparation.Paralysis anophelifuge is the functional components in coating, by upsetting insect
The normal physiological of nerve is allowed to by excited, spasm to benumbing and broken leg is dead, to achieve the purpose that dispel mosquito.If paralysis is anti-
The dosage of mosquito agent is excessive, then cost raises, if dosage is too low, mosquito-proof effect reduces.Under the viscosity and pH value, the fiber crops
The service life of numbness mosquito/fly-killing paint film is long, antibacterial and mouldproof, has excellent scrub performance, antifouling effect is good, stability
It is good, easily construct；If pH value is relatively low, viscosity is unstable, if viscosity is too high, workability is bad, and film levelability is bad, leads
Paralysis anophelifuge is caused to be unevenly distributed, so as to reduce the effect of anti-mosquito.Coating products in the paralysis mosquito/fly-killing paint can
Think commercially available, can also be prepared by the prior art.
Preferably, the paralysis anophelifuge is after a kind of leg by mosquitos and flies contacts so that neural paralysis ultimately results in mosquito
Fly broken leg and dead preparation.The paralysis anophelifuge is repelled mosquitoes and flies by smell, but a kind of when the leg of mosquitos and flies contacts painting
After material, by benumbing its nerve, cause the auxiliary agent of mosquitos and flies broken leg and death, repelled mosquitoes and flies by paralysis than being driven by taste
It removes, it is not only more environmentally friendly, and eradicative rate higher, it will not be influenced beautiful because the body of mosquito is adhered on coating.More
Preferably, the paralysis anophelifuge is purchased from Japanese Daiwa Chemical Ind Co., Ltd., model 20SS.
Preferably, the coating products mainly include following raw material：It is water, hydroxyethyl cellulose, wetting agent, dispersant, anti-
Mould dose, fungicide, antifoaming agent, pigment, filler, coalescents, antifreezing agent, aqueous, environmental protective styrene-acrylic emulsion, thickener, levelling agent and
Neutralizer.A kind of non-ionic surfactant of hydroxyethyl cellulose, uniformly disperses the additives such as pigment, filler, stablizes
And provide thickening power.Wetting agent, dispersant have remarkable wetting and dispersibility to pigment, can make solid material be more easy to by
Water-soaked, system is uniform, suspendability increase, do not precipitate, make whole system physico-chemical property the same, at the same improve colouring intensity and
Pigment storage stability.Mould inhibitor, fungicide have broad-spectrum antibacterial effect, to Gram-positive, negative bacteria, saccharomycete and mould
Bacterium has a very strong inhibitory action, and concentration is low and safety economy, long using the term of validity, ensures that coating is stale-proof within the shelf-life
It loses rotten, ensures that film is corroded from mould, maintain protection and the decoration functions of coating.In coating material production, air can be involved in
And bubble is formed, bubble can be also generated in the work progress of coating, antifoaming agent can be in the non-formation stages of foam or formation
It penetrates into foamed elastic film later and is distributed in vacuolar membrane, reducing surface tension causes thin layer to rupture.Pigment assigns coating
With the numerous colors of film, the decoration and protectiveness of film are improved.Filler improves the mechanical performance of coating and film, and assigns coating
Preferable mobility, can opening effect and workability increase coating thickness.Coalescents can improve the filming performance of coating,
The minimum film formation temperature of coating is reduced, improves the scrub resistance of coating.Antifreezing agent is to prevent from freezing during coating low temperature, to ensure to apply
Expect the storage stability during low temperature.Aqueous, environmental protective styrene-acrylic emulsion is film forming matter, and main function is securely to adhere to ground, together
When scattered color stuffing particle bonded become a whole film.
Preferably, in the coating products, the parts by weight of each raw material are：20~30 parts of water, hydroxyethyl cellulose 0.2~
0.5 part, 0.1~0.6 part of wetting agent, 0.1~0.4 part of dispersant, 0.05~0.50 part of mould inhibitor, fungicide 0.05~0.50
Part, 0.3~0.8 part of antifoaming agent, 10~15 parts of pigment, 15~40 parts of filler, 0.4~0.8 part of coalescents, antifreezing agent 1~3
Part, 10~20 parts of aqueous, environmental protective styrene-acrylic emulsion, 0.3~1.0 part of thickener, 0.2~0.6 part of levelling agent, neutralizer 0.1~0.2
Part.The dosage of each raw material must be appropriate, if the dosage of hydroxyethyl cellulose is excessive, product viscosity is excessively high, can not construct, if dosage
Very few, then viscosity is relatively low, and color stuffing generates precipitation, it is difficult to stir evenly；If wetting agent, dispersant dosage are excessive, influence to apply
The water resistance of film if dosage is very few, can cause color stuffing to disperse bad, reduce coating covering power, can also produce color stuffing
It gives birth to deposit clumps and can not construct；If the dosage of mould inhibitor, fungicide is excessive, cost rise, if dosage is too low, coating
Antiseptic property reduces, and easy putrid and deteriorated or film easily goes mouldy during storage；If the dosage of antifoaming agent is excessive, cost liter
Shrinkage cavity is easily generated during high and construction, if dosage is too low, defoaming effect is bad, and film is defective；If color stuffing dosage is excessive,
Then cost raises, if dosage is too low, covering power is bad；If the dosage of coalescents is excessive, cost rise, if dosage mistake
Low, then film-formation result is bad, influences the service life of film；If the dosage of antifreezing agent is excessive, cost rise, if dosage mistake
It is low, then low-temperature storage below 0 degree of product will be caused to freeze, can not be used；If the dosage of aqueous, environmental protective styrene-acrylic emulsion is excessive, into
This rise if dosage is too low, can cause the scrub performance of film to reduce, can also influence the service life of film.
Preferably, the hydroxyethyl cellulose B30K that the hydroxyethyl cellulose produces for South Korea's Samsung.
Preferably, the wetting agent is without alkylphenol polyoxyethylene ether class compound, and the alcohols table of easily biological-degradable
Face activating agent.It is highly preferred that the wetting agent is purchased from Clariant, model LCN407.
Preferably, the dispersant is commercially available ammonium acrylate dipersant, carboxylic acid sodium salt dispersant or phosphonate dispersants
One or more of Deng.It is highly preferred that the dispersant is purchased from the modest and amiable chemical industry in Nantong, model 5040.
Preferably, the mould inhibitor is diuron, carbendazim, 2- octyl groups -3 (2H)-isothiazolone or 2- methyl -3 (2H)
One or more of isothiazolone etc..It is highly preferred that the mould inhibitor is purchased from Dongguan City Chuan Lian specializations trade Co., Ltd, type
Number be BDH355.
Preferably, the fungicide is that dinitric acid magnesium, (2H) isothiazolone of 5- chloro-2-methyls -3 or 2- methyl -3 (2H) are different
One or more of thiazolone copper nitrate (II) etc..It is highly preferred that be purchased from Guangdong enlightening U.S. biotechnology limited for the fungicide
Company, model KSG201.
Preferably, the antifoaming agent is dimethyl silicone polymer solution and mineral oil.It is highly preferred that the antifoaming agent is moral
NXZ, the 334 type antifoaming agent of Kening Co., Ltd of state production.
Preferably, the pigment is anatase thpe white powder.
Preferably, the filler is kaolin and powdered whiting.
Preferably, the coalescents are ethylene glycol monobutyl ether, alcohol ester 12, dipropylene, ethylene glycol, propylene glycol
One or more of ether or propandiol butyl ether etc..
Preferably, the antifreezing agent is ethylene glycol or propylene glycol.
Preferably, the solid content of the aqueous, environmental protective styrene-acrylic emulsion is 46~48%.The aqueous, environmental protective styrene-acrylic emulsion is low
The aqueous polymer emulsion of taste anti-pollution high-quality interior wall coating is synthesized using room-temperature self crosslinking technology, and minimum film formation temperature is only
For 4 DEG C, without alkylphenol polyoxyethylene ether class compound, formaldehyde and formaldehyde releaser are not added, is dropped using unique technology
Low VOC, makes coating products meet stringent VOC limitation standards, and coating smell is lower.
Preferably, the thickener is hydrophobically modified Sodium Polyacrylate, hydrophobically modified poly amic acid or the poly- ammonia of nonionic
One or more of ester compounds etc..It is highly preferred that the thickener is purchased from Nantong break Thailand chemical industry, model TT935.
Preferably, the levelling agent is the compound of commercial polyurethane association type.It is highly preferred that the levelling agent is purchased from
Sea consolidates Industrial Co., Ltd., model DSX3220.
Preferably, the neutralizer is in dimethylethanolamine, ethanolamine, ammonium hydroxide or 2-amino-2-methyl-1-propanol etc.
One or more.It is highly preferred that the neutralizer consolidates the C-950 neutralizers of Industrial Co., Ltd.'s production for Shanghai.
Preferably, the preparation method of the coating products, comprises the following steps：
（1）It adds water in mixer, adds in hydroxyethyl cellulose while stirring, be evenly stirred until that hydroxyethyl cellulose is transparent
The liquid of grainless；
（2）In step（1）In the liquid of the transparent grainless of gained, wetting agent, dispersant, mould inhibitor, fungicide and one are added in
Part antifoaming agent after stirring evenly, adds pigment, filler, after stirring evenly, then grinding distribution, obtain abrasive；
（3）By step（2）Gained abrasive is placed in paint pot, adds in coalescents, antifreezing agent and aqueous, environmental protective while stirring
Styrene-acrylic emulsion stirs evenly, then adjusts pH value to 8~9 with neutralizer, adds thickener, remainder antifoaming agent and levelling
Agent stirs evenly, and obtains coating products.
Preferably, step（1）In, the mixing speed for adding in hydroxyethyl cellulose is 600~800 revs/min.If rotating speed mistake
Low, then hydroxyethyl cellulose easily lumps, and disperses not open, if rotating speed is excessively high, easily generates bubble.
Preferably, step（2）In, the dosage of the antifoaming agent is the 1/3~2/3 of antifoaming agent total amount.Antifoaming agent is divided into two
The purpose that part adds in is to be, dispersion stage adds part antifoaming agent to be to eliminate the bubble generated in production process, sizes mixing the stage
It is for eliminating the bubble generated in work progress to add in remaining antifoaming agent.
Preferably, step（2）In, the mixing speed added in after pigment, filler is 1000~1600 revs/min.This step carries
High rotating speed is to preferably disperse pigment, filler.
Preferably, step（2）In, grinding distribution to fineness is 40~60 μm.
Preferably, step（3）In, the mixing speed for adding in coalescents, antifreezing agent and aqueous, environmental protective styrene-acrylic emulsion is 300
~500 revs/min.It is emulsion breaking in order to prevent that this step, which reduces rotating speed,.
Technical solution is as follows used by the present invention further solves its technical problem：A kind of system for benumbing mosquito/fly-killing paint
Preparation Method adds in paralysis anophelifuge in coating products, stirs evenly, then with screen filtration, obtain paralysis mosquito/fly-killing paint.
Preferably, the mesh number of the sieve is 50~150 mesh.
Beneficial effects of the present invention are as follows：
（1）Present invention paralysis mosquito/fly-killing paint is using nontoxic, safety and environmental protection mosquito-proof assistant agent, by benumbing it after the contact of mosquitos and flies foot
Nerve, cause mosquito broken leg dead, mosquitos and flies will not be adhered on coating, and due to being contact mosquito eradication rather than passing through
Therefore smell, has the function of lasting, efficient mosquito repelling and purification air, few to human injury；
（2）The viscosity of present invention paralysis mosquito/fly-killing paint is 106~116KU, aqueous, nontoxic, tasteless, pollution-free, meets green
Environment-friendly products standard, and the service life of film is long, antibacterial and mouldproof, has excellent scrub performance, antifouling effect is good, stablizes
Property it is good, easily construct, the technical standard of the high-class product " resin latex dope " of GB/T9756~2009 be fully achieved；
（3）The method of the present invention to benumb mosquito/fly-killing paint without apparent suspended particulate, and simple process and low cost is suitable for industry
Production.
Specific embodiment
With reference to embodiment, the invention will be further described.
Paralysis anophelifuge is purchased from Japanese Daiwa Chemical Ind Co., Ltd., model used in the embodiment of the present invention
20SS；Used hydroxyethyl cellulose is purchased from South Korea's Samsung, model B30K；Used wetting agent is purchased from Clariant, type
Number be LCN407；Used dispersant is purchased from the modest and amiable chemical industry in Nantong, model 5040；Used mould inhibitor is purchased from Dongguan City
Chuan Lian specializations trade Co., Ltd, model BDH355；Used fungicide is purchased from Guangdong Dimei Biological Technology Co., Ltd.,
Model KSG201；Used antifoaming agent is purchased from German Kening Co., Ltd, model NXZ, 334；Used thickener is purchased from
Nantong break Thailand chemical industry, model TT935；Used levelling agent is purchased from Shanghai and consolidates Industrial Co., Ltd., model
DSX3220；Used neutralizer is purchased from Shanghai and consolidates Industrial Co., Ltd., model C-950；The embodiment of the present invention is used
Raw material or chemical reagent, unless otherwise specified, obtained by routine business approach.
Coating products reference example 1~3
The parts by weight of each raw material are as shown in table 1 in coating products：
The parts by weight table of 1 coating products reference example of table, 1~3 each raw material
Note：Wherein, antifoaming agent NXZ is in step（2）It adds in, antifoaming agent 334 is in step（3）It adds in.
The preparation method reference example 1 of coating products
（1）According to each parts by weight of raw materials described in reference example 1 in table 1, add water in mixer, under 700 revs/min of rotating speeds, side
It stirs side and adds in hydroxyethyl cellulose, be evenly stirred until the liquid of the transparent grainless of hydroxyethyl cellulose；
（2）According to each parts by weight of raw materials described in reference example 1 in table 1, in step（1）In the liquid of the transparent grainless of gained, add
Enter wetting agent, dispersant, mould inhibitor, fungicide and 0.2 parts by weight antifoaming agent, under 1200 revs/min of rotating speeds, after stirring evenly,
Pigment, filler are added, after stirring evenly, then grinding distribution obtains abrasive to 50 μm；
（3）According to each parts by weight of raw materials described in reference example 1 in table 1, by step（2）Gained abrasive is placed in paint pot, 400
Under rev/min rotating speed, coalescents, antifreezing agent and aqueous, environmental protective styrene-acrylic emulsion are added in while stirring, stirs evenly, then uses neutralizer
PH value is adjusted to 8.5, thickener, 0.4 parts by weight antifoaming agent and levelling agent is added, stirs evenly, obtain coating products.
The preparation method reference example 2 of coating products
（1）According to each parts by weight of raw materials described in reference example 2 in table 1, add water in mixer, under 600 revs/min of rotating speeds, side
It stirs side and adds in hydroxyethyl cellulose, be evenly stirred until the liquid of the transparent grainless of hydroxyethyl cellulose；
（2）According to each parts by weight of raw materials described in reference example 2 in table 1, in step（1）In the liquid of the transparent grainless of gained, add
Enter wetting agent, dispersant, mould inhibitor, fungicide and 0.15 parts by weight antifoaming agent, under 1000 revs/min of rotating speeds, after stirring evenly,
Pigment, filler are added, after stirring evenly, then grinding distribution obtains abrasive to 60 μm；
（3）According to each parts by weight of raw materials described in reference example 2 in table 1, by step（2）Gained abrasive is placed in paint pot, 300
Under rev/min rotating speed, coalescents, antifreezing agent and aqueous, environmental protective styrene-acrylic emulsion are added in while stirring, stirs evenly, then uses neutralizer
PH value is adjusted to 9, thickener, 0.25 parts by weight antifoaming agent and levelling agent is added, stirs evenly, obtain coating products.
The preparation method reference example 3 of coating products
（1）According to each parts by weight of raw materials described in reference example 3 in table 1, add water in mixer, under 800 revs/min of rotating speeds, side
It stirs side and adds in hydroxyethyl cellulose, be evenly stirred until the liquid of the transparent grainless of hydroxyethyl cellulose；
（2）According to each parts by weight of raw materials described in reference example 3 in table 1, in step（1）In the liquid of the transparent grainless of gained, add
Enter wetting agent, dispersant, mould inhibitor, fungicide and 0.3 parts by weight antifoaming agent, under 1400 revs/min of rotating speeds, after stirring evenly,
Pigment, filler are added, after stirring evenly, then grinding distribution obtains abrasive to 40 μm；
（3）According to each parts by weight of raw materials described in reference example 3 in table 1, by step（2）Gained abrasive is placed in paint pot, 500
Under rev/min rotating speed, coalescents, antifreezing agent and aqueous, environmental protective styrene-acrylic emulsion are added in while stirring, stirs evenly, then uses neutralizer
PH value is adjusted to 8.5, thickener, 0.5 parts by weight antifoaming agent and levelling agent is added, stirs evenly, obtain coating products.
A kind of paralysis mosquito/fly-killing paint embodiment 1
Including 1 coating products of reference example and 1.0 parts by weight paralysis anophelifuge, the dosage of the paralysis anophelifuge is equivalent to gross mass
1%；The viscosity of the paralysis mosquito/fly-killing paint is 110KU, pH value 8.5.
A kind of paralysis mosquito/fly-killing paint embodiment 2
Including 2 coating products of reference example and 0.5 parts by weight paralysis anophelifuge, the dosage of the paralysis anophelifuge is equivalent to gross mass
0.5%；The viscosity of the paralysis mosquito/fly-killing paint is 112KU, pH value 9.
A kind of paralysis mosquito/fly-killing paint embodiment 3
Including 3 coating products of reference example and 0.2 parts by weight paralysis anophelifuge, the dosage of the paralysis anophelifuge is equivalent to gross mass
0.2%；The viscosity of the paralysis mosquito/fly-killing paint is 111KU, pH value 8.5.
A kind of preparation method embodiment 1 for benumbing mosquito/fly-killing paint
The paralysis anophelifuge of 1.0 parts by weight is added in 1 coating products of reference example, is stirred evenly, then with the sieve mistake of 100 mesh
Filter, obtains paralysis mosquito/fly-killing paint.
After testing, the viscosity of gained paralysis mosquito/fly-killing paint is 110KU, without apparent suspended particulate.
A kind of preparation method embodiment 2 for benumbing mosquito/fly-killing paint
The paralysis anophelifuge of 0.5 parts by weight is added in 2 coating products of reference example, is stirred evenly, then with the sieve mistake of 120 mesh
Filter, obtains paralysis mosquito/fly-killing paint.
After testing, the viscosity of gained paralysis mosquito/fly-killing paint is 112KU, without apparent suspended particulate.
A kind of preparation method embodiment 3 for benumbing mosquito/fly-killing paint
The paralysis anophelifuge of 0.2 parts by weight is added in 3 coating products of reference example, is stirred evenly, then with the sieve mistake of 80 mesh
Filter, obtains paralysis mosquito/fly-killing paint.
After testing, the viscosity of gained paralysis mosquito/fly-killing paint is 111KU, without apparent suspended particulate.
The performance of Examples 1 to 3 paralysis mosquito/fly-killing paint is tested, and is compared with relevant criterion, as a result such as
Shown in table 2.
2 Examples 1 to 3 of table benumbs mosquito/fly-killing paint the performance test results and relevant criterion contrast table
As shown in Table 2, Examples 1 to 3 paralysis mosquito/fly-killing paint is aqueous, nontoxic, tasteless, pollution-free, meets green product
Standard, and the service life of film is long, antibacterial and mouldproof, has excellent scrub performance, antifouling effect is good, and stability is good, easily
The technical standard of the high-class product " resin latex dope " of GB/T9756~2009 is fully achieved in construction, main performance.
Examples 1 to 3 is benumbed into mosquito/fly-killing paint and commercially available common coating carries out mosquito-proof measure of merit, test method is such as
Under：
Examples 1 to 3 is benumbed into mosquito/fly-killing paint and commercially available common coating respectively according to 120g/m2Coating weight brushing in sample
On plate, after dried coating film, test sample plate is placed on plastic culture dish（90mm diameters × 20mm H）Bottom, film is upward,
10 mosquitoes are put into culture dish, makes mosquito engaged test sample, and seals culture dish；At 25 DEG C, the ring of relative humidity 65%
It is tested under border；Mosquito eradication quantity counts after preset time, and experimental result is as shown in table 3.
3 Examples 1 to 3 of table benumbs mosquito/fly-killing paint and the mosquito-proof measure of merit contrast table of commercially available common coating
As shown in Table 3, the embodiment of the present invention 1~3 benumbs mosquito/fly-killing paint has apparent mosquito-proof effect compared with common coating,
Particularly suitable for there is the indoor wall in the family for the demand of wiping out the flies and mosquitoes, school, hospital and hotel decoration.
Claims (10)
1. a kind of paralysis mosquito/fly-killing paint, it is characterised in that：Including coating products and paralysis anophelifuge, the paralysis anophelifuge
Dosage is equivalent to the 0.1~1.0% of gross mass；The viscosity of the paralysis mosquito/fly-killing paint is 106~116KU, and pH value is 8~9.
2. mosquito/fly-killing paint is benumbed according to claim 1, which is characterized in that the coating products mainly include following original
Material：It is water, hydroxyethyl cellulose, wetting agent, dispersant, mould inhibitor, fungicide, antifoaming agent, pigment, filler, coalescents, antifreeze
Agent, aqueous, environmental protective styrene-acrylic emulsion, thickener, levelling agent and neutralizer.
3. mosquito/fly-killing paint is benumbed according to claim 2, it is characterised in that：In the coating products, the weight of each raw material
Part it is：It is 20~30 parts of water, 0.2~0.5 part of hydroxyethyl cellulose, 0.1~0.6 part of wetting agent, 0.1~0.4 part of dispersant, mould proof
0.05~0.50 part of agent, 0.05~0.50 part of fungicide, 0.3~0.8 part of antifoaming agent, 10~15 parts of pigment, 15~40 parts of filler,
0.4~0.8 part of coalescents, 1~3 part of antifreezing agent, 10~20 parts of aqueous, environmental protective styrene-acrylic emulsion, 0.3~1.0 part of thickener, stream
Flat 0.2~0.6 part of agent, 0.1~0.2 part of neutralizer.
4. mosquito/fly-killing paint is benumbed according to Claims 2 or 3, it is characterised in that：The wetting agent is to gather without alkyl phenol
Ethylene oxide ether compound, and the alcohol surfactants of easily biological-degradable；The dispersant disperses for commercially available ammonium acrylate salt
One or more of agent, carboxylic acid sodium salt dispersant or phosphonate dispersants；The mould inhibitor is diuron, carbendazim, 2- are pungent
One or more of base -3 (2H)-isothiazolone or 2- methyl -3 (2H) isothiazolone；The fungicide is dinitric acid magnesium, 5-
One or more of (2H) isothiazolone of chloro-2-methyl -3 or (2H) the isothiazolone copper nitrate of 2- methyl -3 (II)；It is described to disappear
Infusion is dimethyl silicone polymer solution and mineral oil；The pigment is anatase thpe white powder；The filler is for kaolin and again
Matter calcium carbonate；The coalescents for ethylene glycol monobutyl ether, alcohol ester 12, dipropylene, ethylene glycol, propylene-glycol ethyl ether or
One or more of propandiol butyl ether；The antifreezing agent is ethylene glycol or propylene glycol；The aqueous, environmental protective styrene-acrylic emulsion is consolidated
Content is 46~48%；The thickener is hydrophobically modified Sodium Polyacrylate, hydrophobically modified poly amic acid or non-ionic polyurethane
One or more of compound；The levelling agent is the compound of commercial polyurethane association type；The neutralizer is dimethyl
One or more of ethanolamine, ethanolamine, ammonium hydroxide or 2-amino-2-methyl-1-propanol.
5. according to one of claim 2~4 paralysis mosquito/fly-killing paint, which is characterized in that the preparation side of the coating products
Method comprises the following steps：
（1）It adds water in mixer, adds in hydroxyethyl cellulose while stirring, be evenly stirred until that hydroxyethyl cellulose is transparent
The liquid of grainless；
（2）In step（1）In the liquid of the transparent grainless of gained, wetting agent, dispersant, mould inhibitor, fungicide and one are added in
Part antifoaming agent after stirring evenly, adds pigment, filler, after stirring evenly, then grinding distribution, obtain abrasive；
（3）By step（2）Gained abrasive is placed in paint pot, adds in coalescents, antifreezing agent and aqueous, environmental protective while stirring
Styrene-acrylic emulsion stirs evenly, then adjusts pH value to 8~9 with neutralizer, adds thickener, remainder antifoaming agent and levelling
Agent stirs evenly, and obtains coating products.
6. mosquito/fly-killing paint is benumbed according to claim 5, it is characterised in that：Step（1）In, add in hydroxyethyl cellulose
Mixing speed is 600~800 revs/min.
7. according to the paralysis mosquito/fly-killing paint of claim 5 or 6, it is characterised in that：Step（2）In, the use of the antifoaming agent
It measures as the 1/3~2/3 of antifoaming agent total amount；The mixing speed added in after pigment, filler is 1000~1600 revs/min；Grinding distribution
It it is 40~60 μm to fineness.
8. according to one of claim 5~7 paralysis mosquito/fly-killing paint, it is characterised in that：Step（3）In, it adds in film forming and helps
The mixing speed of agent, antifreezing agent and aqueous, environmental protective styrene-acrylic emulsion is 300~500 revs/min.
9. according to the preparation method of one of claim 1~8 paralysis mosquito/fly-killing paint, it is characterised in that：In coating products
It is middle to add in paralysis anophelifuge, it stirs evenly, then with screen filtration, obtains paralysis mosquito/fly-killing paint.
10. the preparation method of mosquito/fly-killing paint is benumbed according to claim 9, it is characterised in that：The mesh number of the sieve is
50~150 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810072361.5A CN108102476A (en) | 2018-01-25 | 2018-01-25 | A kind of paralysis mosquito/fly-killing paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810072361.5A CN108102476A (en) | 2018-01-25 | 2018-01-25 | A kind of paralysis mosquito/fly-killing paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108102476A true CN108102476A (en) | 2018-06-01 |
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ID=62221241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810072361.5A Pending CN108102476A (en) | 2018-01-25 | 2018-01-25 | A kind of paralysis mosquito/fly-killing paint and preparation method thereof |
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| CN (1) | CN108102476A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114921965A (en) * | 2022-06-13 | 2022-08-19 | 温多利遮阳材料（德州）股份有限公司 | Anti-mosquito coating, anti-mosquito sun-shading fabric containing same, and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693378A (en) * | 2005-05-13 | 2005-11-09 | 上海玉平化学材料有限公司 | Environmental protection type insecticide coating and its preparation tech. |
| CN101225260A (en) * | 2008-01-31 | 2008-07-23 | 奥顿开林（江苏）化工有限公司 | Inner wall paint having disinsection efficiency |
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2018
- 2018-01-25 CN CN201810072361.5A patent/CN108102476A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693378A (en) * | 2005-05-13 | 2005-11-09 | 上海玉平化学材料有限公司 | Environmental protection type insecticide coating and its preparation tech. |
| CN101225260A (en) * | 2008-01-31 | 2008-07-23 | 奥顿开林（江苏）化工有限公司 | Inner wall paint having disinsection efficiency |
Non-Patent Citations (1)
| Title |
|---|
| 吕少仿等: "《精细化工新编》", 28 February 2003, 湖北科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114921965A (en) * | 2022-06-13 | 2022-08-19 | 温多利遮阳材料（德州）股份有限公司 | Anti-mosquito coating, anti-mosquito sun-shading fabric containing same, and preparation method and application thereof |
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Application publication date: 20180601 |