CN108101460A - A kind of road pervious concrete and its production technology - Google Patents

A kind of road pervious concrete and its production technology Download PDF

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CN108101460A
CN108101460A CN201711432033.3A CN201711432033A CN108101460A CN 108101460 A CN108101460 A CN 108101460A CN 201711432033 A CN201711432033 A CN 201711432033A CN 108101460 A CN108101460 A CN 108101460A
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pervious concrete
road
road pervious
waterglass
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CN108101460B (en
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肖彬
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Guangxi Wanxin Environmental Protection Building Materials Co.,Ltd.
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Structures (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of road pervious concrete and its production technologies, count in parts by weight, raw material includes:45 60 parts of cement, 140 220 parts of coarse aggregate, 100 165 parts of ultra fine sand, 20 35 parts of water, 16 30 parts of admixture, 24 parts of high efficiency water reducing agent, 6 20 parts of nano silicon dioxide dispersion, 37 parts of waterproofing agent, 25 parts of cracking resistance swelling agent.Road pervious concrete provided by the invention, not easy to crack, compression strength is high, and the intensity of the invention that production technology is used to improve concrete, therefore, present invention gained road pervious concrete has many advantages, such as high water-permeability, high-bearing capacity, long lifespan, easy care.

Description

A kind of road pervious concrete and its production technology
Technical field
The present invention relates to technical field of concrete, and in particular to a kind of road pervious concrete and its production technology.
Background technology
Practice have shown that, it is more and more the main original for causing or accelerating pavement structure to damage into the water in pavement structure Cause.In this regard, relevant expert has carried out many researchs, try hard to by rationally designing Drainage Base material and internal drainage system, To reduce until eliminating the Water Damage on road surface, so as to improve the performance on road surface, extend its service life.Pervious concrete is just It is the new Drainage Base material developed in such a case.
Pervious concrete is also known as celluar concrete, non-fine concrete, permeable terrace.Be by aggregate, cement and water mixing and Into a kind of porous light concrete, it is mainly mutual by coarse aggregate surface cladding a thin layer cement mortar containing only a small amount of fine aggregate It bonds and forms the equally distributed honeycomb structure in hole, therefore have the characteristics that ventilative, permeable and light-weight.Pervious concrete by American-European, Japan and other countries are directed to the defects of road surface of former urban road, and developing use a kind of can allow rainwater to flow into underground, effectively Recharge of groundwater alleviates some Urban Environmental Problems that the level of ground water in city drastically declines etc.;And effectively it can eliminate ground The harm of the environmental pollutions such as the oil compounds on face;Meanwhile pervious concrete be protection underground water, maintaining ecological balance, The excellent pavement material of urban heat land effect can be alleviated;It is conducive to the benign development of environment for human survival and urban rainwater In the work such as reason and water prevention and cure of pollution, there is special significance.
However common pervious concrete is all to reach permeable purpose using the macropore of concrete, porosity characteristic at present, but It is the larger reduction for having resulted in its compression strength of celluar concrete porosity, reduces the service life of concrete.
The content of the invention
Insufficient present in for the above-mentioned prior art, the present invention provides a kind of road pervious concrete and its productions Technique.
A kind of road pervious concrete, including following raw material:45-60 parts of cement, 140-220 parts of coarse aggregate, 100-165 parts of ultra fine sand, 20-35 parts of water, 16-30 parts of admixture, 2-4 parts of high efficiency water reducing agent, nano silicon dioxide dispersion 6- 20 parts, 3-7 parts of waterproofing agent, 2-5 parts of cracking resistance swelling agent.
The coarse aggregate is lime stone rubble.
The ultra fine sand is the one or more in yellow ground, quartz sand or river sand.
The admixture is flyash or/and silicon ash.
The high efficiency water reducing agent is 6- hydroxyl -2- sodium naphthalene sulfonates or/and 2,6- di-t-butyl sodium naphthalene sulfonates.
The waterproofing agent is one in perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Kind is a variety of.
The cracking resistance swelling agent is unifor, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide, modification One or more in 4,4'- oxobenzenesulfonyl hydrazide.
Preferably, the waterproofing agent is perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Mixture, wherein the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are (1-3):(1-3):(1-3).
The preparation method of the waterglass compound polyurethane material is:By waterglass, polyether polyol, two fourth of tin dilaurate Ji Xi is mixed, and component A is obtained after stirring evenly, is then uniformly mixed 4,4' methyl diphenylene diisocyanates with plasticizer To B component, then A and B component are mixed, are stirred until homogeneous, stands, obtains waterglass compound polyurethane material, wherein The waterglass, 4,4'- methyl diphenylene diisocyanates, polyether polyol, the matter of dibutyl tin laurate and plasticizer Amount is than being (3-6):(3-6):(0.5-1.5):(0.01-0.05):1.
The plasticizer is epoxidation propylene tamarind grease, diacetyl epoxy soybean olein, hexamethylene -1,2- two It is one or more in carboxylic acid dinonyl.
Preferably, the cracking resistance swelling agent is unifor, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide Mixture, wherein the mass ratio of the unifor, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide be (1- 3):(1-3):(1-3).
It is highly preferred that 4, the 4'- oxobenzenesulfonyl hydrazide of the modification is SiO2The double benzene sulfonyls of modified 4,4'- oxos Hydrazine, the SiO2The preparation method of modified 4,4'- oxobenzenesulfonyl hydrazide is:4,4'- oxobenzenesulfonyl hydrazide is added in into N, It dissolves, is uniformly mixed in dinethylformamide, add in Nano-meter SiO_22Micro mist is ultrasonically treated after stirring evenly, finally by taking out Filter, drying obtain SiO2Modified 4,4'- oxobenzenesulfonyl hydrazide, wherein 4, the 4'- oxobenzenesulfonyl hydrazide, N, N- diformazans Base formamide and Nano-meter SiO_22The mass ratio of micro mist is 1:(1-8):(0.1-0.4).
The production technology of road pervious concrete, which is characterized in that comprise the following steps:
I, weighs each raw material components by weight;
II, is by cement, coarse aggregate, ultra fine sand, water, admixture, high efficiency water reducing agent, nano silicon dioxide dispersion, waterproof Agent, the mixing of cracking resistance swelling agent, obtain road pervious concrete after stirring evenly.
Preferably, the production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
II, stirs evenly coarse aggregate, ultra fine sand, nano silicon dioxide dispersion, obtains mixture;
III, is continuously added into said mixture by cement, water, admixture, high efficiency water reducing agent, waterproofing agent, cracking resistance expansion Agent is uniformly mixed, obtains road pervious concrete.
It is highly preferred that the production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
High efficiency water reducing agent is first added to the water by II, is uniformly mixed, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 30-70wt% into admixture, stirs evenly, and obtains mixture A;
Coarse aggregate, ultra fine sand, nano silicon dioxide dispersion are mixed III, so that the table of coarse aggregate and ultra fine sand Face is in moisture state, obtains mixture B;
IV, adds in mixture B in mixing A, adds in cement, waterproofing agent, cracking resistance swelling agent after mixing, is eventually adding Remaining mixed liquor continues to stir, and obtains road pervious concrete.
By adopting the above-described technical solution, the present invention has the advantages that compared with prior art:
Road pervious concrete provided by the invention, each component reasonable mixture ratio, addition cracking resistance swelling agent make concrete not It is easy to crack, waterproof aqua is added, improves the water penetration ability of concrete, while production technology improves concrete in the present invention Intensity, there is high water-permeability, high-bearing capacity, long lifespan, easy care, and compression strength is not high, easy to crack, and the road is with permeable Concrete disclosure satisfy that the various requirement of engineering for having permeable requirement for concrete, be conducive to maintaining ecological balance and realize to hold Supervention exhibition.
Specific embodiment
The foregoing invention content of the present invention is described in further detail With reference to embodiment, but should not be incited somebody to action This scope for being interpreted as the above-mentioned theme of the present invention is only limitted to following embodiments.
Each raw material introduction in embodiment:
Cement, the P042.5 Portland cements produced using money tide cement plant.
Granite stones, grain size 7mm, purchased from Jin Lian commerce and trade Co., Ltd of Yidu City.
Yellow ground, grain size 0.4-0.8mm, purchased from Zhangpu County Hong Xiang quartz sands Co., Ltd.
Quartz sand, grain size 0.5-1.0mm, purchased from Cheng Xu quartz sands factory of Xinyi City.
Flyash, model kx110-1, purchased from Hebei Ke Xu building materials Co., Ltd.
Silicon ash, grain size is at 0.1~0.3 μm, purchased from Lingshou County Bai Sheng mineral products processing factory.
6- hydroxyl -2- sodium naphthalene sulfonates, No. CAS:135-76-2, product identification N0035, purchased from uncommon love (Shanghai) chemical conversion of ladder Industrial development Co., Ltd.
Perfluorohexanesulfonic acid potassium, No. CAS:3871-99-6, product identification T820158, purchased from Shanghai Mike's woods biochemistry section Skill Co., Ltd.
Isopropyl myristate, No. CAS:110-27-0, model IPM, purchased from Guangzhou Qi Jie Chemical Industry Science Co., Ltd.
Nano silicon dioxide dispersion, model VK-S01B, dioxide-containing silica 30wt%, particle size 15- 20nm, purchased from Xuancheng Jingrui New Material Co., Ltd..
Unifor, No. CAS:1576-35-8, product identification T824719, purchased from Shanghai Mike's woods biochemical technology Co., Ltd.
Azodicarbonamide, No. CAS:123-77-3, model ADC, purchased from Shijiazhuang hongda Xin Ye Co., Ltds.
4,4'- oxobenzenesulfonyl hydrazide, No. CAS:80-51-3, model OBSH, purchased from the limited public affairs of Foshan City's Ou Xi chemical industry Department.
Nano-meter SiO_22Micro mist, model XT-0806-1-1, average grain diameter 20nm are limited purchased from Shanghai lane field nano material Company.
Waterglass, No. CAS:1344-09-8, model 40B, purchased from Foshan Ke Ning new materials Science and Technology Ltd..
Polytetrahydrofuran diol, No. CAS:25190-06-1, product identification P816810, it is biochemical purchased from Shanghai Mike woods Science and Technology Ltd..
Dibutyl tin laurate, No. CAS:77-58-7, purchased from Shanghai Aladdin biochemical technology limited company.
4,4' methyl diphenylene diisocyanates, No. CAS:101-68-8, model BT/1746-4, purchased from Shouguang City's gold Space chemical industry Co., Ltd.
Epoxidation propylene tamarind grease, No. CAS:8103-07-8, model PVC, purchased from the limited public affairs of Guangzhou the Liao Dynastyization chemical industry Department.
Diacetyl epoxy soybean olein, model HM-828, No. CAS:1487263-87-5, purchased from Guangzhou sea Er Ma vegetable fat Co., Ltd.
Hexamethylene -1,2- dicarboxylic acids dinonyl, No. CAS:166412-78-8, model Dinch, purchased from German Bath Husband company.
The mixing plant that raw material uses in preparing is JB-90D type powerful motor mixers, purchased from the intelligent bright instrument of Shanghai Nanhui Factory;Concrete batch plant is JS500 type concrete mixers, purchased from hundred moral Machinery Manufacturing Co., Ltd. of Zhengzhou.
Ultrasonic device is JP-040S type supersonic wave cleaning machines, purchased from Jie Meng cleaning equipments Co., Ltd of Shenzhen.
The model HTDS of microporous membrane filters, the precision of filter core is 10 μm, purchased from the limited public affairs of Guangdong perseverance field filter plant Department.
Drying equipment is DHG-9023A type air dry ovens, purchased from Shanghai Du Te scientific instrument Co., Ltd.
Embodiment 1
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 6 parts of waterproofing agent, 1 part of unifor, 1 part of azodicarbonamide, SiO2The double benzene of modified 4,4'- oxos 1 part of sulfohydrazide.
The waterproofing agent is the mixing of perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Object, the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
The SiO2The preparation method of modified 4,4'- oxobenzenesulfonyl hydrazide is:4,4'- oxobenzenesulfonyl hydrazide is added Enter in n,N-Dimethylformamide and dissolve, 1h is stirred under the conditions of 30 DEG C, 500r/min, keep temperature and rotating speed constant, add in Nano-meter SiO_22Micro mist continues to stir 30min, 20min is then ultrasonically treated at 40 DEG C, the ultrasonic power of the supersound process is 240W, supersonic frequency 30kHz, then be placed in millipore filter, it filters under the conditions of 25 DEG C, 0.6MPa, finally puts product The oven drying for entering 60 DEG C for 24 hours, obtains SiO2Modified 4,4'- oxobenzenesulfonyl hydrazide, wherein the double benzene sulphurs of 4, the 4'- oxos Hydrazides, N,N-dimethylformamide and Nano-meter SiO_22The mass ratio of micro mist is 1:6:0.2.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor is first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, waterproofing agent, unifor, azodicarbonamide, SiO2The double benzene sulfonyls of modified 4,4'- oxos Hydrazine continues to stir 5min under 30 DEG C, 35r/min, obtains road pervious concrete.
Embodiment 2
It is substantially the same manner as Example 1, it differs only in:The waterproofing agent is perfluorohexanesulfonic acid potassium, myristic acid is different The mixture of propyl ester, the perfluorohexanesulfonic acid potassium, the mass ratio of isopropyl myristate are 1:1.
Embodiment 3
It is substantially the same manner as Example 1, it differs only in:The waterproofing agent is isopropyl myristate, the poly- ammonia of waterglass The mixture of ester composite material, the isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polyether polyol, dibutyl tin laurate, epoxidation propylene acid Soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and di lauric dibutyl Tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then it is 4,4' diphenyl methanes two is different Cyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl stir under the conditions of 40 DEG C, 200r/min 25min obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, standing obtains water afterwards for 24 hours Glass compound polyurethane material.
Embodiment 4
It is substantially the same manner as Example 1, it differs only in:The waterproofing agent is perfluorohexanesulfonic acid potassium, the poly- ammonia of waterglass The mixture of ester composite material, the perfluorohexanesulfonic acid potassium, the mass ratio of waterglass compound polyurethane material are 1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
Comparative example 1
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 1 part of unifor, 1 part of azodicarbonamide, SiO21 part of modified 4,4'- oxobenzenesulfonyl hydrazide.
The SiO2The preparation method of modified 4,4'- oxobenzenesulfonyl hydrazide is:4,4'- oxobenzenesulfonyl hydrazide is added Enter in n,N-Dimethylformamide and dissolve, 1h is stirred under the conditions of 30 DEG C, 500r/min, keep temperature and rotating speed constant, add in Nano-meter SiO_22Micro mist continues to stir 30min, 20min is then ultrasonically treated at 40 DEG C, the ultrasonic power of the supersound process is 240W, supersonic frequency 30kHz, then be placed in millipore filter, it filters under the conditions of 25 DEG C, 0.6MPa, finally puts product The oven drying for entering 60 DEG C for 24 hours, obtains SiO2Modified 4,4'- oxobenzenesulfonyl hydrazide, wherein the double benzene sulphurs of 4, the 4'- oxos Hydrazides, N,N-dimethylformamide and Nano-meter SiO_22The mass ratio of micro mist is 1:6:0.2.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor is first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, unifor, azodicarbonamide, SiO2Modified 4,4'- oxobenzenesulfonyl hydrazide, 30 DEG C, continue under 35r/min to stir 5min, obtain road pervious concrete.
Embodiment 5
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 6 parts of waterproofing agent, 1.5 parts of unifor, 1.5 parts of azodicarbonamide.
The waterproofing agent is the mixing of perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Object, the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor, waterproofing agent are first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains Mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, unifor, azodicarbonamide continue to stir 5min under 30 DEG C, 35r/min, obtain Road pervious concrete.
Embodiment 6
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 6 parts of waterproofing agent, 1.5 parts of azodicarbonamide, 1.5 parts of 4,4'- oxobenzenesulfonyl hydrazide.
The waterproofing agent is the mixing of perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Object, the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor is first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, waterproofing agent, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide, continue under 30 DEG C, 35r/min 5min is stirred, obtains road pervious concrete.
Embodiment 7
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 6 parts of waterproofing agent, 1.5 parts of unifor, 1.5 parts of 4,4'- oxobenzenesulfonyl hydrazide.
The waterproofing agent is the mixing of perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Object, the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor is first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, waterproofing agent, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide, continue under 30 DEG C, 35r/min 5min is stirred, obtains road pervious concrete.
Embodiment 8
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 6 parts of waterproofing agent, 1 part of unifor, 1 part of azodicarbonamide, 1 part of 4,4'- oxobenzenesulfonyl hydrazide.
The waterproofing agent is the mixing of perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Object, the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor is first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, waterproofing agent, unifor, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide, 30 DEG C, Continue to stir 5min under 35r/min, obtain road pervious concrete.
Comparative example 2
A kind of road pervious concrete, including following raw material:55 parts of cement, 200 parts of lime stone rubble, yellow ground 80 parts, 80 parts of quartz sand, 30 parts of water, 14 parts of flyash, 14 parts of silicon ash, 3 parts of 6- hydroxyl -2- sodium naphthalene sulfonates, nano silicon dioxide 15 parts of dispersion liquid, 6 parts of waterproofing agent.
The waterproofing agent is the mixing of perfluorohexanesulfonic acid potassium, isopropyl myristate, waterglass compound polyurethane material Object, the perfluorohexanesulfonic acid potassium, isopropyl myristate, the mass ratio of waterglass compound polyurethane material are 1:1:1.
The preparation method of the waterglass compound polyurethane material is:4 are pressed first:4:1:0.03:0.5:0.5 mass ratio Weigh waterglass, 4,4'- methyl diphenylene diisocyanates, polytetrahydrofuran diol, dibutyl tin laurate, epoxidation third Olefin(e) acid soya-bean oil ester and hexamethylene -1,2- dicarboxylic acids dinonyl, then by waterglass, polytetrahydrofuran diol and tin dilaurate two Butyl tin stirs 30min under the conditions of 40 DEG C, 200r/min, obtains component A after mixing;Then by 4,4' diphenyl methanes Diisocyanate, epoxidation propylene tamarind grease, hexamethylene -1,2- dicarboxylic acids dinonyl are under the conditions of 40 DEG C, 200r/min 25min is stirred, obtains B component;It keeps temperature and rotating speed constant, A and B component is mixed, continue to stir 1h, stand and obtain afterwards for 24 hours To waterglass compound polyurethane material.
The production technology of road pervious concrete, comprises the following steps:
I, weighs each raw material components by weight;
Unifor is first added to the water by II, and 5min is mixed under 30 DEG C, 35r/min, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 50wt% into flyash, silicon ash, continues to stir under 30 DEG C, 35r/min 3min obtains mixture A;
Lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion are mixed III, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture B;
IV, adds in mixture B in mixing A, continues to stir 3min under 30 DEG C, 35r/min, adds in after mixing surplus Remaining mixed liquor, cement, waterproofing agent continue to stir 5min under 30 DEG C, 35r/min, obtain road pervious concrete.
Embodiment 9
It is substantially the same manner as Example 1, it differs only in:The production technology of the road pervious concrete, feature It is, comprises the following steps:
The production technology of road pervious concrete, which is characterized in that comprise the following steps:
I, weighs each raw material components by weight;
II, by cement, lime stone rubble, yellow ground, quartz sand, water, flyash, silicon ash, 6- hydroxyl -2- sodium naphthalene sulfonates, receive Rice silica dispersions, waterproofing agent, unifor, azodicarbonamide, SiO2The double benzene sulfonyls of modified 4,4'- oxos 5min is mixed under 30 DEG C, 35r/min in hydrazine, obtains road pervious concrete.
Embodiment 10
It is substantially the same manner as Example 1, it differs only in:The production technology of the road pervious concrete, feature It is, comprises the following steps:
I, weighs each raw material components by weight;
II, stirs evenly lime stone rubble, yellow ground, quartz sand, nano silicon dioxide dispersion, in 30 DEG C, 35r/min Under continue stir 3min so that the surface of aggregate be in moisture state, obtain mixture;
III, is continuously added into said mixture by cement, water, flyash, silicon ash, 6- hydroxyl -2- sodium naphthalene sulfonates, waterproof Agent, unifor, azodicarbonamide, SiO2Modified 4,4'- oxobenzenesulfonyl hydrazide, is stirred under 30 DEG C, 35r/min 5min is mixed, is uniformly mixed, obtains road pervious concrete.
Test case 1
Water permeability is tested:According to the journal of writings of Zheng Mulian《The infiltration coefficient and test method of celluar concrete》In The test method of 5 sections, road in embodiment 1-10 and comparative example 1 is measured with the infiltration coefficient of pervious concrete, It the results are shown in Table 1.
Table 1:Water permeability is tested
Sample Infiltration coefficient/cms-1
Embodiment 1 1.16
Embodiment 2 0.97
Embodiment 3 0.95
Embodiment 4 0.98
Embodiment 5 1.05
Embodiment 6 1.03
Embodiment 7 1.07
Embodiment 8 1.06
Embodiment 9 1.11
Embodiment 10 1.13
Comparative example 1 0.76
Embodiment 1-4 and 1 data of comparative example can be seen that using perfluorohexanesulfonic acid potassium, myristic acid in comparison sheet Isopropyl ester, the waterproofing agent of waterglass compound polyurethane material combination, water permeability are better than in embodiment 2-4 by perflexane sulphur The poly- ammonia of waterglass prepared by the plasticizer of the arbitrary two kinds of compoundings of sour potassium, isopropyl myristate, waterglass compound polyurethane material The comparative example 2 of ester composite material and unused waterproofing agent, therefore waterproofing agent is added in concrete in embodiment 1, improves The water permeability of road pervious concrete.
Test case 2
Tensile splitting strength performance test:According to《Standard for test methods of mechanical properties of ordinary concrete》Regulation, will be real Road is tested it after conserving 3 days, 10 days and 30 days respectively with pervious concrete and is split obtained by applying in a 1-10 and comparative example 2 Split tensile strength.Testing result is shown in Table 2.
Table 2:Tensile splitting strength performance
It observes table 2 to understand, the present invention improves concrete inner structure, enhance concrete by adding cracking resistance swelling agent Tensile splitting strength performance.Comparing embodiment 5-8 understands that embodiment 8 is used by toluene sulfonyl hydrazide, azodicarbonamide, 4, The cracking resistance swelling agent of 4'- oxobenzenesulfonyl hydrazide combination is applied in concrete, obtained road pervious concrete, splitting Tensile strength properties are better than road pervious concrete in embodiment 5-7, and (cracking resistance swelling agent is by toluene sulfonyl hydrazide, azo diformazan Arbitrary two kinds of amide, 4,4'- oxobenzenesulfonyl hydrazide, which combines, to be prepared) and unused cracking resistance swelling agent comparative example 1; In embodiment 1 in cracking resistance swelling agent used in road pervious concrete, by SiO2The double benzene sulfonyls of modified 4,4'- oxos Hydrazine substitutes 4,4'- oxobenzenesulfonyl hydrazide, compared with road pervious concrete in embodiment 8, further improves road use The tensile splitting strength performance of pervious concrete.
Test case 3
Compression strength performance test:According to GB/T 50080-2001《Standard for test methods of properties of ordinary concrete mixture mark It is accurate》, gained road in embodiment 1-10 is cut into pervious concrete to the test block of 100mm × 100mm × 100mm, respectively into The row maintenance of 3 days, 10 days and 30 days, pressurizes to it using hydraulic universal forcing press after a period of time is conserved, simultaneously For the uniform force during test block is pressed, two sheet metals have been padded successively in the top and bottom of test block, it is anti-for re-test Compressive Strength.The results are shown in Table 3.
Table 3:Compression strength performance test
As shown in Table 3, road is stirred with the concrete in pervious concrete preparation process, employing optimization in embodiment 1 Technique:Admixture is allowed first to form admixture dispersion liquid with water, and aggregate is then mixed to form with nano silicon dioxide dispersion, then will Admixture dispersion liquid, aggregate nano silicon dioxide dispersion are mixed with other raw materials, and admixture dispersion liquid can be by aggregate surface Hole fully absorb, enhance aggregate, improve the intensity of concrete, the compression strength of gained road pervious concrete It can be better than the road pervious concrete prepared using production technology in embodiment 9-10.
The above described is only a preferred embodiment of the present invention, limitation in any form is not done to the present invention, therefore The equivalent or simple change that all principles according to described in inventional idea of the present invention are done is included in the protection domain of patent of the present invention It is interior;Those skilled in the art can do various modifications or additions to described specific embodiment Or substitute in a similar way, without departing from structure of the invention or surmount scope defined in the claims, It is within the scope of protection of the invention.

Claims (10)

1. a kind of road pervious concrete, which is characterized in that including following raw material:45-60 parts of cement, coarse aggregate 140-200 parts, 100-165 parts of ultra fine sand, 20-35 parts of water, 16-30 parts of admixture, 2-4 parts of high efficiency water reducing agent, nanometer titanium dioxide 6-20 parts of silicon dispersion liquid, 3-7 parts of waterproofing agent, 2-5 parts of cracking resistance swelling agent.
2. road pervious concrete as described in claim 1, which is characterized in that the waterproofing agent is perfluorohexanesulfonic acid One or more in potassium, isopropyl myristate, waterglass compound polyurethane material.
3. road pervious concrete as described in claim 1, which is characterized in that the cracking resistance swelling agent is tolysulfonyl One or more in hydrazine, azodicarbonamide, 4,4'- oxobenzenesulfonyl hydrazide, the 4,4'- oxobenzenesulfonyl hydrazide of modification.
4. road pervious concrete as described in claim 1, it is characterised in that:
The coarse aggregate is lime stone rubble;
The ultra fine sand is the one or more in yellow ground, quartz sand or river sand;
The admixture is flyash or/and silicon ash;
The high efficiency water reducing agent is 6- hydroxyl -2- sodium naphthalene sulfonates or/and 2,6- di-t-butyl sodium naphthalene sulfonates.
5. road pervious concrete as claimed in claim 2, which is characterized in that the waterglass compound polyurethane material Preparation method is:Waterglass, polyether polyol, dibutyl tin laurate are mixed, component A is obtained after stirring evenly, then 4,4' methyl diphenylene diisocyanates are uniformly mixed with plasticizer to obtain B component, then A and B component are mixed, stirred It mixes to uniform, stands, obtain waterglass compound polyurethane material;
The waterglass, 4,4'- methyl diphenylene diisocyanates, polyether polyol, dibutyl tin laurate and plasticizer Mass ratio be (3-6):(3-6):(0.5-1.5):(0.01-0.05):1.
6. road pervious concrete as claimed in claim 3, which is characterized in that the double benzene sulphurs of 4,4'- oxos of the modification Hydrazides is SiO2Modified 4,4'- oxobenzenesulfonyl hydrazide, the SiO2The preparation side of modified 4,4'- oxobenzenesulfonyl hydrazide Method is:4,4'- oxobenzenesulfonyl hydrazide is added in n,N-Dimethylformamide and is dissolved, is uniformly mixed, adds in Nano-meter SiO_22It is micro- Powder is ultrasonically treated after stirring evenly, and finally obtains SiO by filtering, drying2Modified 4,4'- oxobenzenesulfonyl hydrazide;
The 4,4'- oxobenzenesulfonyl hydrazide, N,N-dimethylformamide and Nano-meter SiO_22The mass ratio of micro mist is 1:(1-8): (0.1-0.4)。
7. road pervious concrete as claimed in claim 5, which is characterized in that the plasticizer is epoxidation propylene tamarind It is one or more in grease, diacetyl epoxy soybean olein, hexamethylene -1,2- dicarboxylic acids dinonyls.
8. a kind of production technology of road pervious concrete as described in claim 1, which is characterized in that including following steps Suddenly:
I, weighs each raw material components by weight;
II, is by cement, coarse aggregate, ultra fine sand, water, admixture, high efficiency water reducing agent, nano silicon dioxide dispersion, waterproofing agent, anti- Swelling agent mixing is split, road pervious concrete is obtained after stirring evenly.
9. the production technology of road pervious concrete as claimed in claim 8, which is characterized in that comprise the following steps:
I, weighs each raw material components by weight;
II, mixes coarse aggregate, ultra fine sand, nano silicon dioxide dispersion, and mixture is obtained after stirring evenly;
III, is continuously added into said mixture by cement, water, admixture, high efficiency water reducing agent, waterproofing agent, cracking resistance swelling agent, is mixed It closes uniformly, obtains road pervious concrete.
10. the production technology of road pervious concrete as claimed in claim 9, which is characterized in that comprise the following steps:
I, weighs each raw material components by weight;
High efficiency water reducing agent is first added to the water by II, is uniformly mixed, obtains mixed liquor;
III, adds in the above-mentioned mixed liquor of 30-70wt% into admixture, stirs evenly, and obtains mixture A;
Coarse aggregate, ultra fine sand, nano silicon dioxide dispersion are mixed III, so that the surface of coarse aggregate and ultra fine sand is in Moisture state obtains mixture B;
IV, adds in mixture B in mixing A, adds in cement, waterproofing agent, cracking resistance swelling agent after mixing, is eventually adding residue Mixed liquor continue to stir, obtain road pervious concrete.
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CN110183186A (en) * 2019-04-24 2019-08-30 东南大学 A kind of preparation method of high-strength high pervious concrete
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108708244A (en) * 2018-06-22 2018-10-26 杜宇 A kind of highway road surface and preparation method thereof not cracked
US20200102248A1 (en) * 2018-09-28 2020-04-02 King Fahd University Of Petroleum And Minerals High performance concretes and methods of making thereof
US10882791B2 (en) * 2018-09-28 2021-01-05 King Fahd University Of Petroleum And Minerals High performance concretes and methods of making thereof
CN109400019A (en) * 2018-10-23 2019-03-01 青铜峡市晶砂实业有限公司 A kind of quartz sand water-permeable brick and preparation method
CN110183186A (en) * 2019-04-24 2019-08-30 东南大学 A kind of preparation method of high-strength high pervious concrete
CN110183186B (en) * 2019-04-24 2021-09-21 东南大学 Preparation method of high-strength and high-permeability concrete
CN111592295A (en) * 2020-04-22 2020-08-28 嵊州市路通水泥制品有限公司 Production process of pre-slurry in-situ mixing pervious concrete
CN117342807A (en) * 2023-12-05 2024-01-05 山东崇正特种水泥有限公司 Low-heat cement and production process thereof
CN117342807B (en) * 2023-12-05 2024-01-30 山东崇正特种水泥有限公司 Low-heat cement and production process thereof
CN117418488A (en) * 2023-12-18 2024-01-19 中国石油大学(华东) Combined stone blocking wall construction method with energy consumption, shock absorption and drainage functions

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