CN108064888A - A kind of slow-release Pesticidal combination - Google Patents
A kind of slow-release Pesticidal combination Download PDFInfo
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- CN108064888A CN108064888A CN201711406915.2A CN201711406915A CN108064888A CN 108064888 A CN108064888 A CN 108064888A CN 201711406915 A CN201711406915 A CN 201711406915A CN 108064888 A CN108064888 A CN 108064888A
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- pesticidal combination
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/20—Fabaceae or Leguminosae [Pea or Legume family], e.g. pea, lentil, soybean, clover, acacia, honey locust, derris or millettia
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
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Abstract
The present invention provides a kind of slow-release Pesticidal combination, which is characterized in that including the following key component matched in parts by weight:15 25 parts of 25 35 part, nanometer SAPO of pyrethroid, 31 molecular sieves, 10 16 parts of alfalfa antibacterial peptide, 37 parts of gluconic acid polyhexamethylene guanide, 6 13 parts of carboxybetaine, 40 65 parts of edible alcohol.Achievable steady release of the pyrethroid under normal temperature condition of the present invention, with reference to plant component, security further improves, and pest is killed for space, particularly the prevention of flying pest, there is good insecticidal effect.
Description
Technical field
The present invention relates to a kind of slow-release Pesticidal combination, it can be achieved that pyrethroid steadily releasing under normal temperature condition
It puts, pest is killed for space, particularly the prevention of flying pest.
Background technology
Household insecticide has a long history, and China has with various natural plants, mineral before thousands of years
Smoke fire burns the record of mosquito.By thousands of years of differentiation, it is now widely used for mainly having mosquito in terms of mosquito control
Fragrant, electric culicifuge incense, vaporizer mosquito liquid, aerosol, spray etc..The Medication structure of these insecticides also several times changes, as plan is removed
Worm chrysanthemum esters medicine succeed in developing and extensive use, this kind of efficiently, low toxicity, safety hygienic medication gradually instead of to people and animals with
Environment has the medicines such as the Ba Sha of serious harm.However, the insecticide used at present there are toxicity it is big, have peculiar smell, have to environment pollution,
It is anti-to kill the shortcomings of area is small, timeliness is short, toxic residue amount is big.As people are to the growing interest of environmental protection and own health,
The production of global insecticide is positive to be started to change from scalar type to quality and safety type, and Devoting Major Efforts To Developing is efficiently, low toxicity, the new of safety kill
Worm agent has become world insecticide industrial expansion direction.
The content of the invention
In view of this, the present invention provides a kind of slow-release Pesticidal combination, and the achievable pyrethroid of the present invention is in room temperature
Under the conditions of steady release, with reference to plant component, security further improves, and pest is killed for space, particularly flight
The prevention of pest has good insecticidal effect.
Technical solution provided by the invention is:A kind of slow-release Pesticidal combination, which is characterized in that including it is following by weight
The key component of number proportioning:25-35 parts of pyrethroid, 15-25 parts of nano SAPO-31 molecular sieve, alfalfa antibacterial peptide
10-16 parts, 3-7 parts of gluconic acid polyhexamethylene guanide, 6-13 parts of carboxybetaine, 40-65 parts of edible alcohol.
Further, parts by weight shared by the pyrethroid are 28-33 parts.
Further, parts by weight shared by the nano SAPO-31 molecular sieve are 18-23 parts.
Further, parts by weight shared by the alfalfa antibacterial peptide are 12-14 parts.
Further, parts by weight shared by the gluconic acid polyhexamethylene guanide are 5-6 parts.
Further, parts by weight shared by the carboxybetaine are 8-11 parts.
A kind of preparation method of slow-release Pesticidal combination, including step in detail below:
S1. the proportioning of each component of the present invention is by pyrethroid, nano SAPO-31 molecular sieve, alfalfa antibacterial peptide, grape
Saccharic acid polyhexamethylene guanide is mixed into carboxybetaine and edible alcohol, is mixed evenly to obtain mixed liquor at 0-40 DEG C;
S2. the mixed liquor is placed in autoclave, the nitrogen after boosting by high-pressure diaphragm pump, heating is added in into autoclave
And it stirs and forms suspension;
S3. the suspension by coaxial at least a pair of nozzles staggered relatively is sprayed and hit, the cladding microcapsule particle of precipitation
It is separated with nitrogen by gas-solid separator up to slow-release Pesticidal combination.
In the present invention, using pyrethroid extract, gluconic acid polyhexamethylene guanide, alfalfa antibacterial peptide as deinsectization group
The main component of object is closed, it is safe and non-toxic, any discomfort of human body will not be caused, do not interfere with health more.In the present invention
Pyrethroid extract and alfalfa antibacterial peptide interaction, can act on pest skin surface, it is direct and rapid
The selective permeability to substance that energetic supersession and cell and organelle of the destruction dependent on membrane structure integrality are depended on for existence, makes
Nutriment and metabolite can not make it lose nutrition and its growth is caused to become feeble and die normally through cell membrane.Nanometer SAPO-31
It interacts between molecular sieve and gluconic acid polyhexamethylene guanide so that gluconic acid polyhexamethylene guanide reaches the effect of sustained release
Fruit, and pass through and destroy its cell membrane, the ingredient of small molecule is made to enter in cell membrane and is combined with intracellular polar substances, makes egg
White matter can not synthesize, and inhibit the activity of enzyme or functional protein in pest body, kill pest.
Carboxybetaine and edible alcohol in the present invention, using the strong bonding of carboxybetaine, help dissolubility to ease up
Effect is released, the active ingredient of desinsection and carboxybetaine is made to form highly miscible slow-releasing system, high molecular slow-release system is suitable
In foring volatilization retarding agent, its volatilization effect is reduced, achievees the purpose that sustained release, and above-mentioned substance biological compatibility is good, toxicity
It is relatively low, it is safe.
Preferably, deinsectization composition of the invention is housefly, lucilia sericata, Culex pipiens pallens for circling in the air property pest, three bands
Beak culex, Culex quinquefasciatus, aedes albopictus, Aedes aegypti or the killing effect of Anopheles sinensis are more excellent.
Compared with prior art, the present invention has the following advantages and beneficial effects:
Slow-release Pesticidal combination provided by the invention is prepared simply, and by using the composition proportion of special ratios, synthesis obtains
Slow-release Pesticidal combination good fluidity, easy to use available for the combination liquid of Sprayable, deinsectization effect is good, and discharge
Persistently, stability is preferable, also, main component is vegetable-derived components in slow-release Pesticidal combination provided by the invention, to people
Body is non-stimulated, high safety.
Specific embodiment
For those skilled in the art is made to understand the production technology and technique effect of the present invention in detail, below specifically to produce
Example come be further described the present invention application and technique effect.
Embodiment 1-5 operating procedures:It is matched according to each component parts by weight, prepares slow-release desinsection group according to the following steps
Close object:S1. the proportioning of each component of the present invention is by pyrethroid, nano SAPO-31 molecular sieve, alfalfa antibacterial peptide, grape
Saccharic acid polyhexamethylene guanide is mixed into carboxybetaine and edible alcohol, is mixed evenly to obtain mixed liquor at 0-40 DEG C;
S2. the mixed liquor is placed in autoclave, the nitrogen after boosting by high-pressure diaphragm pump, heating is added in into autoclave
And it stirs and forms suspension;
S3. the suspension by coaxial at least a pair of nozzles staggered relatively is sprayed and hit, the cladding microcapsule particle of precipitation
It is separated with nitrogen by gas-solid separator up to slow-release Pesticidal combination.
Each raw material components proportionings of embodiment 1-5 and comparative example 1-2 are as shown in table 1.
Each raw material components proportioning tables of table 1 embodiment 1-5 and comparative example 1-2
Properties of product are tested
The Pesticidal combination as made from embodiment 1-5 and comparative example 1-2 component proportions is sprayed, by 30 houseflies living, 20
Anopheles living is respectively put into each closed chamber, is sprayed into respectively on tank wall with spray method using sprayer, spray value is
6ml.Start timing and periodically observe and record 24 it is small when after knock down number of elements, the mosquitos and flies in removing case, chamber placement 72
Be respectively put into equal number of mosquitos and flies again after hour, start timing and periodically observe and record 24 it is small when after knock down number of elements.Knot
Fruit is as shown in table 2.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
Moreover, it will be appreciated that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
Using specification as an entirety, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art
It is appreciated that other embodiment.For the technical detail of all not detailed descriptions in the present invention, can be appointed by this field
One prior art is realized.
Claims (6)
1. a kind of slow-release Pesticidal combination, which is characterized in that including the following key component matched in parts by weight:Intend deinsectization
25-35 parts of chrysanthemum ester, 15-25 parts of nano SAPO-31 molecular sieve, 10-16 parts of alfalfa antibacterial peptide, gluconic acid polyhexamethylene
3-7 parts of guanidine, 6-13 parts of carboxybetaine, 40-65 parts of edible alcohol.
2. the slow-release Pesticidal combination according to claim 1, which is characterized in that weight shared by the pyrethroid
It is 28-33 parts to measure number.
3. the slow-release Pesticidal combination according to claim 1, which is characterized in that the nano SAPO-31 molecular sieve
Shared parts by weight are 18-23 parts.
4. the slow-release Pesticidal combination according to claim 1, which is characterized in that the alfalfa antibacterial peptide institute
Parts by weight are accounted for as 12-14 parts.
5. the slow-release Pesticidal combination according to claim 1, which is characterized in that poly- six methylene of gluconic acid
Parts by weight shared by base guanidine are 5-6 parts.
6. the slow-release Pesticidal combination according to claim 1, which is characterized in that weight shared by the carboxybetaine
It is 8-11 parts to measure number.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711406915.2A CN108064888A (en) | 2017-12-22 | 2017-12-22 | A kind of slow-release Pesticidal combination |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711406915.2A CN108064888A (en) | 2017-12-22 | 2017-12-22 | A kind of slow-release Pesticidal combination |
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Publication Number | Publication Date |
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CN108064888A true CN108064888A (en) | 2018-05-25 |
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CN201711406915.2A Pending CN108064888A (en) | 2017-12-22 | 2017-12-22 | A kind of slow-release Pesticidal combination |
Country Status (1)
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CN (1) | CN108064888A (en) |
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2017
- 2017-12-22 CN CN201711406915.2A patent/CN108064888A/en active Pending
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Application publication date: 20180525 |
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