CN108059994A - It is a kind of to repair secondary composition of friction and its preparation method and application - Google Patents

It is a kind of to repair secondary composition of friction and its preparation method and application Download PDF

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Publication number
CN108059994A
CN108059994A CN201711269884.0A CN201711269884A CN108059994A CN 108059994 A CN108059994 A CN 108059994A CN 201711269884 A CN201711269884 A CN 201711269884A CN 108059994 A CN108059994 A CN 108059994A
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China
Prior art keywords
friction
composition
secondary composition
microns
crushing
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Pending
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CN201711269884.0A
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Chinese (zh)
Inventor
卞睿康
刘越鹏
卞春荣
刘向阳
刘开
尹建华
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Hangzhou Qie Technology Co Ltd
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Hangzhou Qie Technology Co Ltd
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Priority to CN201711269884.0A priority Critical patent/CN108059994A/en
Publication of CN108059994A publication Critical patent/CN108059994A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/26Compounds containing silicon or boron, e.g. silica, sand
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/105Silica
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/055Particles related characteristics
    • C10N2020/06Particles of special shape or size
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/54Fuel economy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/76Reduction of noise, shudder, or vibrations
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines

Abstract

The secondary composition of friction is repaired the invention discloses a kind of, including following weight percentage components:SiO2:25~50%, MgO:20~45%, Fe2O3:5~30%, Fe3O4:5~30%, TiO2:10~20%, Bi2O3:5~20%, Al2O3:5~20%.Its preparation includes:After each component is mixed in proportion, wet ball grinding crushing is carried out, the powder after crushing is put into microwave drier is dried to get the secondary composition of the reparation friction.The composition is added to as additive in lubricating oil, obtain liquid ceramics repair materials, it is filled into engine, the secondary component of friction is surface-treated and is repaired during engine use, is reached and is extended engine life, improve operational safety stability, raising output power, reduce fuel and lubricant consumption, reduce the effect of exhaust emissions.

Description

It is a kind of to repair secondary composition of friction and its preparation method and application
Technical field
Secondary composition of friction and its preparation method and application is repaired the present invention relates to a kind of.
Background technology
Liquid ceramics are a kind of new materials, it can substitute used in current lube product have larger dirt to environment Dye, anti-wear and wear-resistant performance be general, with sulphur, phosphorus, chlorine element it is compound based on organic matter lubricating oil antiwear and friction-reducing additive, be tradition The core technology product of the cross-centennial upgrading of lube product.
The performance of mechanical equipment and the precision of constitution equipment component are closely related.By taking automobile as an example, the performance and hair of automobile The precision of the components such as motivation, gearbox, differential mechanism, transmission mechanism, hydraulic system and traveling mechanism is closely related.Since machinery is transported Dynamic component there are intermetallic friction and wear, causes incomplete combustion, fuel consumption increase, vibration and noise to increase, automobile It is short of power, exhaust emissions is exceeded, safety coefficient declines.
The friction and wear of machinery is the main reason for causing the excessively high mechanical energy consumption of all operatings and damage.According to relevant information Statistics:The expenses such as maintenance, repair, stop work and production of the modern industry because rubbing, wearing generation account for gross national product 15%~30%.
Calculate according to related authoritative institution:In friction loss, machinery is set for 30%~50% consumption of the disposable energy in the world Standby to damage and failure about 80% is as caused by friction abrasion, and the serious accident of more than 50% mechanical equipment is all due to Excessive wear caused by lubrication failure.
The secondary abrasion of reduction friction is the most frequently used and most simple effective method is lubricated using lubriation material, lubricating oil Or lubricating grease is the lubriation material generally used at present, since most of lubricating oil or lubricating grease are to generate one between friction is secondary The thin lubricating oil film of layer, reduces coefficient of friction and abrasion, but this layer of oil film is more easily damaged in use, and easily becomes Matter and fail, easily generate deposit, therefore lubricant effect is difficult to the requirement for meeting many application scenarios.
The defects of in order to make up lubricating oil, often adds in various organic matters or inorganic matter to increase in lubricating oil or lubricating grease The greasy property of strong lubricant grease improves the bearing capacity of lubricating film and reduces coefficient of friction.
Since conventional lubrication is theoretical and lubrication product is established in the forties in last century and gradual perfection gets up, when so far Day, antiwear additive on sale is mainly to use using sulphur, phosphorus, chlorine compound as component, lubrication based on chemical membrane mechanism in the market Product.The secondary oil film temperature of friction be more than 130 DEG C, mechanical cold start-up, under stress alternation and overload condition, conventional lubrication product Protection cannot be provided for friction pair.
The content of the invention
Present invention aims at provide a kind of composition for repairing friction pair, said composition be added in base oil, shape Into liquid ceramic material, explosive motor is repaired, is formed slide minute surface in use, engine can be solved and rubbed Wipe secondary reparation task.
The technical solution adopted by the present invention is as follows:
It is a kind of to repair the secondary composition of friction, including following weight percentage components:
SiO2:25~50%, MgO:20~45%, Fe2O3:5~30%, Fe3O4:5~30%, TiO2:10~20%, Bi2O3:5~20%, Al2O3:5~20%.Wherein, SiO2, MgO, Fe2O3, Fe3O4And Al2O3Metal is formed on processing surface Ceramic layer;TiO2And Bi2O3Addition can play catalytic action under the high temperature conditions, the carbon in fuel is allowed to be formed wear-resisting and is had There is the carbon nanomaterial of lubricating action, formed and slide minute surface, greatly improve the anti-friction performance of engine.
The average grain diameter of the composition is 8~17 microns.
The present invention also provides a kind of preparation method for repairing the secondary composition of friction, including:By each component press than After example mixing, wet ball grinding crushing is carried out, the powder after crushing is put into microwave drier and is dried to get the reparation Rub secondary composition.
By controlling the grain size of material, the engine friction pair of the different degrees of wear can be made to be repaired comprehensively, preferably Ground, the powder after crushing have following particle size distribution profiles:
The powder particle of 20wt% has the grain size less than 5 microns;
The powder particle of 50wt% has the grain size less than 10 microns;
The powder particle of 70wt% has the grain size less than 15 microns;
The powder particle of 90wt% has the grain size less than 20 microns.
Preferably, the condition of the drying is:The power of microwave drier is 8~15KW, the frequency of microwave for 800~ 1000MHz, drying time are 5~10 minutes, and drying temperature is 80~120 DEG C.
It is a further object of the present invention to provide a kind of application of the secondary composition of reparation friction, the combinations Object is added to as additive in lubricating oil.
It is added in lubricating oil, is filled into engine using the present composition as additive, normally transported in engine During turning, the industrial sintering process for oozing pottery technique is substituted using friction pressure and frictional heat, it is former that metal occurs in metal surface Sub- substitution reaction, soft dusty material are transformed into the cermet coating that hardness is high, wear-resistant, coefficient of friction is low, rub in metal Wipe the interstitial solid solution of secondary surface generation ceramet.The infiltration of ceramic particle make common metal have ceramic material high temperature resistant, Characteristic corrosion-resistant, with high hardness.The infiltration of ceramic particle makes surfaces of metallic rubbing pairs expand contact area, increase enabling capabilities, It improves the finish of surface of friction pair, reduce coefficient of friction, complete the in-situ immobilization to engine friction pair.
In application process, the additive amount of the composition is adjusted according to the degree of wear of engine, preferably, The addition weight percent of the composition is 5~15 ‰.
Preferably, other additives are further included in the lubricating oil, such as detersive, dispersant, viscosity modifier, anti-corrosion Agent, antioxidant etc..
Fluid present invention ceramics repair materials use oiliness activator, and liquid ceramics ion surface atomicity ratio is big, table Face can be high, has excellent adsorptivity, adhesiveness and chemical reactivity under frictional heat electrophoretic action, can be in related lubricating oil Other additives are adsorbed onto in friction pair and form thickness up to the elastic oil film of 20 microns or more of activation together, and oil film thickness is 10~20 times of common oil film thickness add the elasticity and leakproofness of lubricating oil oil film, and various additives effect is made to be able to most It gives full play to.
Compared with prior art, the invention has the advantages that:
(1) present invention changes the theory that conventional lubrication oil is protected with high viscosity, film lubrication, realizes surface of friction pair Self-lubricating, selfreparing, from strengthen.Solve equipment cold start-up, stress alternation, impact load, the profit of full speed full load formation Lubricating oil viscosity is lower, and oil film is excessively thin, oil film failure and the technical bottlenecks such as metal fatigue, corrosive wear, Surface Welding at High Temperature, realizes Equipment dynamically maintains in the process of running.The effect of bringing the prolonged mechanical service life.
(2) using fluid present invention ceramics repair materials, abrasion can be eliminated, extends the service life of engine, save oil plant, In, fuel 10~35% is saved, machine oil saving 50~80% protects damage of the engine from low product oil;It balances in cylinder Compression parameters, reduce vibration, reduce the noise of engine, retarder;Reduce the quality requirements to machine oil and fuel.
(3) fluid present invention ceramics repair materials can be applied to automobile, agricultural machinery, naval vessel, wind-driven generator, high-power internal combustion In the mechanical equipments such as machine, the maintenance and repair of engine are applicable not only to, apply also for retarder, bearing, compressor and hydraulic pressure The maintenance and repair of system.
Specific embodiment
Embodiment 1
1st, the preparation of the present composition
The composition by forming following weight percentage components:SiO2:25%, MgO:40%, Fe2O3:5%, Fe3O4:10%, TiO2:10%, Bi2O3:5%, Al2O3:5%.
After above-mentioned each component is mixed in proportion, wet ball grinding crushing is carried out, the powder after crushing is with following grain size point Cloth characteristic:The powder particle of 20wt% has the grain size less than 5 microns;The powder particle of 50wt% has the grain less than 10 microns Footpath;The powder particle of 70wt% has the grain size less than 15 microns;The powder particle of 90wt% has the grain size less than 20 microns. Powder after crushing is put into microwave drier to be dried, the power of microwave drier is 10KW, used microwave frequency For 915MHz, drying time is 6 minutes, and the temperature of micro-wave oven is 105 DEG C, up to the composition after drying.
2nd, the preparation of liquid ceramics repair materials
8.5g above-mentioned compositions are weighed, are added in 1700mL lubricating oil, is uniformly mixed and repairs material to get liquid ceramics Material.
3rd, experimental result
Liquid ceramics repair materials are filled into automobile engine, after 500 kilometers of normally travels, to engine The secondary in-situ immobilization of friction has been carried out, engine, which shows cylinder compression growth and power, at this time increases, and on friction surface Occur " the slip minute surface " that possesses high rigidity and low-friction coefficient.
Processing to new engine, fuel consumption reduce by 5~10%, and exhaust temperature averagely declines 20 DEG C, under oil temperature About 5 DEG C of drop, rotating speed improve 5~10%;Processing to old engine, fuel consumption reduce by 20% or so, exhaust temperature averagely under 20 DEG C or more of drop, oil temperature decline about 5 DEG C, and power significantly increases.It ensure that engine possesses higher durability, improve Efficiency, reduces operating cost, and service life dramatically increases.
The rotating speed of 11 kilowatts of new diesel engines is fixed, tests the engine output under different torques, fuel consumption rate, Hour oil consumption, delivery temperature and oil temperature.Engine first is being not added with surveying under conditions of liquid ceramics repair materials Examination, then in same engine, filling liquid ceramics repair materials, then carry out the test under the same terms.The survey of gained Test result is shown in Table 1.
Table 1
It can be seen that from 1 test data of table using the present embodiment liquid ceramics repair materials to from the carrying out of new engine Reason can reach and oil consumption is descended to reduce by 8% or so at full capacity, and exhaust emissions temperature-averaging declines 20 DEG C, and oil temperature declines 5 DEG C, says Respectively the coefficient of friction of the secondary component of friction is low in bright engine, and effective utility of laser power improves, and friction idle work reduces, work( Rate is discharged, and emission is improved.
Embodiment 2
1st, the preparation of the present composition
The composition by forming following weight percentage components:SiO2:45%, MgO:20%, Fe2O3:10%, Fe3O4:5%, TiO2:10%, Bi2O3:5%, Al2O3:5%.
After above-mentioned each component is mixed in proportion, wet ball grinding crushing is carried out, the powder after crushing is with following grain size point Cloth characteristic:The powder particle of 20wt% has the grain size less than 5 microns;The powder particle of 50wt% has the grain less than 10 microns Footpath;The powder particle of 70wt% has the grain size less than 15 microns;The powder particle of 90wt% has the grain size less than 20 microns. Powder after crushing is put into microwave drier to be dried, the power of microwave drier is 8KW, and used microwave frequency is 1000MHz, drying time are 8 minutes, and the temperature of micro-wave oven is 85 DEG C, up to the composition after drying.
2nd, the preparation of liquid ceramics repair materials
300g above-mentioned compositions are weighed, are added in 30L lubricating oil, are uniformly mixed to get liquid ceramics repair materials.
3rd, experimental result
Liquid ceramics repair materials are filled into the marine engine of " sea fishery ", fishing boat keeps normally travel, warp After spending 14 days, compression pressure without combustion is increased to 3.4 megapascal from 2.4 megapascal, and oil pressure increases to 0.30 megapascal from 0.22 megapascal, section 24% fuel oil is saved, engine scuffing degree drops to 18% from 37%, illustrates that the engine friction pair of fishing boat obtains In-situ immobilization.

Claims (7)

1. a kind of repair the secondary composition of friction, which is characterized in that including following weight percentage components:
SiO2:25~50%, MgO:20~45%, Fe2O3:5~30%, Fe3O4:5~30%, TiO2:10~20%, Bi2O3:5 ~20%, Al2O3:5~20%.
2. according to claim 1 repair the secondary composition of friction, which is characterized in that the average grain diameter of the composition is 8~17 microns.
3. a kind of preparation method according to claim 1 or 2 for repairing the secondary composition of friction, which is characterized in that including: After each component is mixed in proportion, wet ball grinding crushing is carried out, the powder after crushing is put into microwave drier and is dried, i.e., Obtain the secondary composition of the reparation friction.
4. the preparation method according to claim 3 for repairing the secondary composition of friction, which is characterized in that the powder after crushing With following particle size distribution profiles:
The powder particle of 20wt% has the grain size less than 5 microns;
The powder particle of 50wt% has the grain size less than 10 microns;
The powder particle of 70wt% has the grain size less than 15 microns;
The powder particle of 90wt% has the grain size less than 20 microns.
5. the preparation method according to claim 3 for repairing the secondary composition of friction, which is characterized in that the item of the drying Part is:The power of microwave drier is 8~15KW, and the frequency of microwave is 800~1000MHz, and drying time is 5~10 minutes, Drying temperature is 80~120 DEG C.
A kind of 6. application according to claim 1 or 2 for repairing the secondary composition of friction, which is characterized in that the group It closes object to be added in lubricating oil as additive, obtains liquid ceramics repair materials.
7. the application according to claim 6 for repairing the secondary composition of friction, which is characterized in that the composition adds Add weight percentage is 5~15 ‰.
CN201711269884.0A 2017-12-05 2017-12-05 It is a kind of to repair secondary composition of friction and its preparation method and application Pending CN108059994A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724576A (en) * 2019-10-24 2020-01-24 大连乾承科技开发有限公司 Preparation for repairing abrasion of wind power generation gearbox and preparation method and application method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1727456A (en) * 2005-07-28 2006-02-01 谢传林 Agent for repairing abrasion resistance of metal
CN1850953A (en) * 2005-12-30 2006-10-25 邢延涛 Inorganic composite nano intelligent repair agent, and its preparing method
CN101715479A (en) * 2007-04-11 2010-05-26 瓦卢莱克曼内斯曼油气法国公司 Frictional coefficient is suitable for the lubricating composition of the screwing element in the assembly of tubular threaded joint
CN102465049A (en) * 2011-07-15 2012-05-23 刘永斌 Metal wear self-repair protecting agent
CN107384512A (en) * 2017-07-20 2017-11-24 瑙gぜ Micro-nano intelligent Base Metal abrasion self-repair material and its preparation and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1727456A (en) * 2005-07-28 2006-02-01 谢传林 Agent for repairing abrasion resistance of metal
CN1850953A (en) * 2005-12-30 2006-10-25 邢延涛 Inorganic composite nano intelligent repair agent, and its preparing method
CN101715479A (en) * 2007-04-11 2010-05-26 瓦卢莱克曼内斯曼油气法国公司 Frictional coefficient is suitable for the lubricating composition of the screwing element in the assembly of tubular threaded joint
CN102465049A (en) * 2011-07-15 2012-05-23 刘永斌 Metal wear self-repair protecting agent
CN107384512A (en) * 2017-07-20 2017-11-24 瑙gぜ Micro-nano intelligent Base Metal abrasion self-repair material and its preparation and application

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110724576A (en) * 2019-10-24 2020-01-24 大连乾承科技开发有限公司 Preparation for repairing abrasion of wind power generation gearbox and preparation method and application method thereof
CN110724576B (en) * 2019-10-24 2022-05-20 大连乾承科技开发有限公司 Preparation for repairing abrasion of wind power generation gearbox and preparation method and application method thereof

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