CN108047810A - A kind of particle size controling agent for wrapping up red, yellow ink and preparation method thereof and its application process - Google Patents
A kind of particle size controling agent for wrapping up red, yellow ink and preparation method thereof and its application process Download PDFInfo
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- CN108047810A CN108047810A CN201711351742.9A CN201711351742A CN108047810A CN 108047810 A CN108047810 A CN 108047810A CN 201711351742 A CN201711351742 A CN 201711351742A CN 108047810 A CN108047810 A CN 108047810A
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- particle size
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- controling agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a kind of particle size controling agents for wrapping up red, yellow ink and preparation method thereof and its application process, by weight percentage its material component to include：2- acrylamide-2-methyl propane sulfonic 3-6%, methyl methacrylate 61-80%, butyl acrylate 15-31%, azodiisobutyronitrile 2-5%.In the package ink of particle size controling agent zirconium silicate package cadmium sulfoselenide, it is easy to use, storage stability is good, the primary particle size of the package ink precursor synthesized using the particle control agent reaches below 100nm, postmenstruation grinding subsequent processing will not destroy primary particle, package ink disperses average grain diameter 100nm, overcomes and wraps up the shortcomings that too fine color power of reddish yellow abrasive lapping reduces on the market at present.
Description
Technical field
The present invention relates to ink auxiliary agent technical field more particularly to a kind of particle size controling agent for wrapping up red, yellow ink and
Its preparation method and its application process.
Background technology
ZrSiO4 is with high-melting-point (2500 DEG C), high index of refraction (1.93~2.01) and with the spy of high temperature resistance glaze melt
Property, thus it is bright red as wrapping up, yellow preferred package phase is wrapped up, the extensive concern of domestic and foreign scholars is caused, and develops one
Criticize the product of red, the yellow ceramic marking ink of package.
Though the synthesis mode of zirconium silicate package reddish yellow colorant, its package reddish yellow synthesized are related in existing technology
The average grain diameter of material in more than 0.6um, easily reunite in aqueous solution by this level of particle, easily generates precipitation,
It cannot be used for making stable ceramic ink.To meet the requirement of ink jet ink for printing, it is necessary to by the coarse face of particle
Abrasive lapping, and colourity declines after grinding and destroying the crystal structure of pigment in itself causes Yellow Pigment performance bad.Its reason
It is the thinner of colorant grinding, coated good structure will be destroyed, its high-temperature stability is lost, whiten after firing, fades
It can be extremely serious.
Therefore, wrap up reddish yellow colorant synthesis technology be both needed to control in nanoscale, and cannot rearward the phase grinding method, this
And the huge difficult problem that package reddish yellow chromatic ink synthesizes now.
The content of the invention
In view of this, the present invention provides a kind of particle size controling agent for wrapping up red, yellow ink and preparation method thereof and its
Application process.
A kind of particle size controling agent for wrapping up red, yellow ink, by weight percentage its material component include：
Preferably, its material component is by weight percentage：
Preferably, the methyl methacrylate and butyl acrylate mass ratio are 2-5:1.
A kind of preparation method for the particle size controling agent for wrapping up red, yellow ink, method include：
Vacuum distillation pretreatment is carried out to methyl methacrylate, butyl acrylate, under 10.8kPa, recovered (distilled) temperature point
It Wei not be 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics, methyl methacrylate and butyl acrylate are put into N-N dimethyl
It is fully dissolved in formamide, isopropyl alcohol mixed solvent, for use；
Dissolved 2- acrylamide-2-methyl propane sulfonics, methyl methacrylate and butyl acrylate is fully mixed
It closes uniformly, is 180r/min in stir speed (S.S.), temperature is at 40-80 DEG C, and azodiisobutyronitrile, lasting drop is added dropwise with constant flow pump
Add, it is interior when 0.5~6 is small to be added dropwise, obtain thick controlling agent.
Preferably, method further includes：
Obtained controlling agent is added in into acetone, extract and separate purification is carried out, obtains extract liquor；
Extract liquor is placed in drying box, the freeze-day with constant temperature at a temperature of 313k dries extract liquor, obtains wrapping up red
The yellow special particle size controling agent of ceramic ink.
Preferably, the methyl methacrylate and butyl acrylate input amount ratio are 2-5:1.
A kind of application process for the particle size controling agent for wrapping up red, yellow ink, method include：
In the forerunner's production procedure for wrapping up red, yellow ceramic ink, particle size controling agent is directly added into, additive amount is conjunction
Into the 2~20% of the weight percent of presoma.
Preferably, the particle size controling agent additive amount is the 5~10% of the weight percent of synthesis presoma.
It is provided by the invention the present invention provides a kind of particle size controling agent for wrapping up red, yellow ink and preparation method thereof and
Its application process, particle size controling agent zirconium silicate are wrapped up in the package ink of cadmium sulfoselenide, and easy to use, storage stability is good, makes
Up to below 100nm, postmenstruation grinding is follow-up to be located the primary particle size of the package ink precursor synthesized with the particle control agent
Reason will not destroy primary particle, and package ink disperses average grain diameter 100nm, overcome the current reddish yellow colorant of package on the market and grind
The shortcomings that too fine color power of mill reduces.It inherently solves the disadvantages that package reddish yellow particles of ink is big, and bad dispersibility has
Great market prospects.Wherein, the addition of particle control agent can reduce the activation energy of cadmium sulfoselenide lyosol generation, reduce sulphur
The granular size of cadmium selenide colloidal sol, primary grain size is less than 50nm, and the compound anchoring group that it is generated can oriented attachment titanium dioxide
The Si-OH keys of silicon and Zr-OH keys make the cadmium sulfoselenide micelle of itself and generation combine closely, and form firm zirconium silicate package sulphur
Cadmium selenide structural unit, the structural unit of formation are less than 100nm, far smaller than wrap up the grain diameter of reddish yellow ink on the market.
Description of the drawings
Technical solution in order to illustrate the embodiments of the present invention more clearly, below will be to needed in embodiment description
Attached drawing is briefly described, it should be apparent that, the accompanying drawings in the following description is some embodiments of the present invention.
Fig. 1 is that the TEM of cadmium sulfoselenide colloidal sol primary particle schemes；
Fig. 2 is the TEM figures of the package reddish yellow ceramics marking ink of particle size controling agent synthesis.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is part of the embodiment of the present invention, instead of all the embodiments.Based on the implementation in the present invention
Example, those of ordinary skill in the art's all other embodiments obtained without making creative work, belongs to
The scope of protection of the invention.
It should be appreciated that ought use in this specification and in the appended claims, term " comprising " and "comprising" instruction
Described feature, entirety, step, operation, the presence of element and/or component, but it is not precluded from one or more of the other feature, whole
Body, step, operation, element, component and/or its presence or addition gathered.
It will be further appreciated that the term "and/or" used in description of the invention and the appended claims is
Refer to any combinations and all possible combinations of one or more of the associated item listed, and including these combinations.
Embodiment 1
The particle size controling agent of red, yellow ink is wrapped up, its material component by weight percentage includes：
Its preparation method is：
The accurate 2- acrylamide-2-methyl propane sulfonics for weighing component amount, methyl methacrylate, butyl acrylate and
Azodiisobutyronitrile；
To methyl methacrylate (MMA), butyl acrylate (BA) vacuum distillation pretreatment, under 10.8kPa, temperature is distillated
Degree is respectively 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics (AMPS), MMA and the BA of group component, add in N-N dimethylformamides
(DMF) and the in the mixed solvent of isopropanol, dissolving are for use；
Reactant is sufficiently mixed uniformly, and at stir speed (S.S.) 180r/min, 40~80 DEG C of temperature, azo is added dropwise with constant flow pump
Bis-isobutyronitrile (AIBN), when persistently dropwise addition 0.5~6 is small；
After reaction, by reaction mixture acetone extract separating-purifying, solution thermostatic drying chamber under 313K is obtained
Middle drying obtains the package special particle size controling agent of reddish yellow ceramic ink.
Its application process is：
In the package ink of zirconium silicate package cadmium sulfoselenide, in the forerunner's production procedure for wrapping up bright red ceramic ink,
Above-mentioned particle size controling agent is directly added into, additive amount obtains ceramic ink to synthesize the 6wt% of presoma.
Embodiment 2
The particle size controling agent of red, yellow ink is wrapped up, its material component by weight percentage includes：
Its preparation method is：
The accurate 2- acrylamide-2-methyl propane sulfonics for weighing component amount, methyl methacrylate, butyl acrylate and
Azodiisobutyronitrile；
To methyl methacrylate (MMA), butyl acrylate (BA) vacuum distillation pretreatment, under 10.8kPa, temperature is distillated
Degree is respectively 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics (AMPS), MMA and the BA of group component, add in N-N dimethylformamides
(DMF) and the in the mixed solvent of isopropanol, dissolving are for use；
Reactant is sufficiently mixed uniformly, and at stir speed (S.S.) 180r/min, 40~80 DEG C of temperature, azo is added dropwise with constant flow pump
Bis-isobutyronitrile (AIBN), when persistently dropwise addition 0.5~6 is small；
After reaction, by reaction mixture acetone extract separating-purifying, solution thermostatic drying chamber under 313K is obtained
Middle drying obtains the package special particle size controling agent of reddish yellow ceramic ink.
Its application process is：
In forerunner's production procedure of the yellow ceramic ink of package, above-mentioned particle size controling agent is directly added into, additive amount is
The 8wt% of presoma is synthesized, and obtains ceramic ink.
Embodiment 3
The particle size controling agent of red, yellow ink is wrapped up, its material component by weight percentage includes：
Its preparation method is：
The accurate 2- acrylamide-2-methyl propane sulfonics for weighing component amount, methyl methacrylate, butyl acrylate and
Azodiisobutyronitrile；
To methyl methacrylate (MMA), butyl acrylate (BA) vacuum distillation pretreatment, under 10.8kPa, temperature is distillated
Degree is respectively 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics (AMPS), MMA and the BA of group component, add in N-N dimethylformamides
(DMF) and the in the mixed solvent of isopropanol, dissolving are for use；
Reactant is sufficiently mixed uniformly, and at stir speed (S.S.) 180r/min, 40~80 DEG C of temperature, azo is added dropwise with constant flow pump
Bis-isobutyronitrile (AIBN), when persistently dropwise addition 0.5~6 is small；
After reaction, by reaction mixture acetone extract separating-purifying, solution thermostatic drying chamber under 313K is obtained
Middle drying obtains the package special particle size controling agent of reddish yellow ceramic ink.
Its application process is：
In the forerunner's production procedure for wrapping up bright red ceramic ink, above-mentioned particle size controling agent is directly added into, additive amount
To synthesize the 2wt% of presoma, and obtain ceramic ink.
Embodiment 4
The particle size controling agent of red, yellow ink is wrapped up, its material component by weight percentage includes：
Its preparation method is：
The accurate 2- acrylamide-2-methyl propane sulfonics for weighing component amount, methyl methacrylate, butyl acrylate and
Azodiisobutyronitrile；
To methyl methacrylate (MMA), butyl acrylate (BA) vacuum distillation pretreatment, under 10.8kPa, temperature is distillated
Degree is respectively 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics (AMPS), MMA and the BA of group component, add in N-N dimethylformamides
(DMF) and the in the mixed solvent of isopropanol, dissolving are for use；
Reactant is sufficiently mixed uniformly, and at stir speed (S.S.) 180r/min, 40~80 DEG C of temperature, azo is added dropwise with constant flow pump
Bis-isobutyronitrile (AIBN), when persistently dropwise addition 0.5~6 is small；
After reaction, by reaction mixture acetone extract separating-purifying, solution thermostatic drying chamber under 313K is obtained
Middle drying obtains the package special particle size controling agent of reddish yellow ceramic ink.
Its application process is：
In forerunner's production procedure of the yellow ceramic ink of package, above-mentioned particle size controling agent is directly added into, additive amount is
The 20wt% of presoma is synthesized, and obtains ceramic ink.
Embodiment 5
The particle size controling agent of red, yellow ink is wrapped up, its material component by weight percentage includes：
Its preparation method is：
The accurate 2- acrylamide-2-methyl propane sulfonics for weighing component amount, methyl methacrylate, butyl acrylate and
Azodiisobutyronitrile；
To methyl methacrylate (MMA), butyl acrylate (BA) vacuum distillation pretreatment, under 10.8kPa, temperature is distillated
Degree is respectively 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics (AMPS), MMA and the BA of group component, add in N-N dimethylformamides
(DMF) and the in the mixed solvent of isopropanol, dissolving are for use；
Reactant is sufficiently mixed uniformly, and at stir speed (S.S.) 180r/min, 40~80 DEG C of temperature, azo is added dropwise with constant flow pump
Bis-isobutyronitrile (AIBN), when persistently dropwise addition 0.5~6 is small；
After reaction, by reaction mixture acetone extract separating-purifying, solution thermostatic drying chamber under 313K is obtained
Middle drying obtains the package special particle size controling agent of reddish yellow ceramic ink.
Its application process is：
In the forerunner's production procedure for wrapping up bright red ceramic ink, above-mentioned particle size controling agent is directly added into, additive amount
To synthesize the 5wt% of presoma, and obtain ceramic ink.
Embodiment 6
The particle size controling agent of red, yellow ink is wrapped up, its material component by weight percentage includes：
Its preparation method is：
The accurate 2- acrylamide-2-methyl propane sulfonics for weighing component amount, methyl methacrylate, butyl acrylate and
Azodiisobutyronitrile；
To methyl methacrylate (MMA), butyl acrylate (BA) vacuum distillation pretreatment, under 10.8kPa, temperature is distillated
Degree is respectively 40 DEG C, 60 DEG C；
2- acrylamide-2-methyl propane sulfonics (AMPS), MMA and the BA of group component, add in N-N dimethylformamides
(DMF) and the in the mixed solvent of isopropanol, dissolving are for use；
Reactant is sufficiently mixed uniformly, and at stir speed (S.S.) 180r/min, 40~80 DEG C of temperature, azo is added dropwise with constant flow pump
Bis-isobutyronitrile (AIBN), when persistently dropwise addition 0.5~6 is small；
After reaction, by reaction mixture acetone extract separating-purifying, solution thermostatic drying chamber under 313K is obtained
Middle drying obtains the package special particle size controling agent of reddish yellow ceramic ink.
Its application process is：
In forerunner's production procedure of the yellow ceramic ink of package, above-mentioned particle size controling agent is directly added into, additive amount is
The 10wt% of presoma is synthesized, and obtains ceramic ink.
Comparative example 1
In the forerunner's production procedure for wrapping up bright red ceramic ink, above-mentioned particle size controling agent is not added with, obtains ceramic ink.
Comparative example 2
In forerunner's production procedure of the yellow ceramic ink of package, above-mentioned particle size controling agent is not added with, obtains ceramic ink.
The package reddish yellow ceramics marking ink of embodiment 1-6 and comparative example 1-2 are subjected to Physickemical Properties,
As a result it is as follows：
According to the data in several tables, scheme in combination with the TEM of Fig. 1 and Fig. 2, it can be seen that：The Grain size controlling of this synthesis
In package ink of the agent for zirconium silicate package cadmium sulfoselenide, easy to use, storage stability is good, is closed using the particle control agent
Into package ink precursor primary particle size up to 100nm or so, it is more excellent at below 100nm, the follow-up place of postmenstruation grinding
Reason will not destroy primary particle, and package ink disperses average grain diameter 100nm, overcome the current reddish yellow colorant of package on the market and grind
The shortcomings that too fine color power of mill reduces, has great market prospects.It is big inherently to solve package reddish yellow particles of ink, point
The shortcomings that property is poor is dissipated, there are great market prospects.Wherein, the addition of particle control agent can reduce the life of cadmium sulfoselenide lyosol
Into activation energy, reduce cadmium sulfoselenide colloidal sol granular size, primary grain size be less than 50nm, and its generate compound anchoring group
The energy Si-OH keys of oriented attachment silica and Zr-OH keys, make the cadmium sulfoselenide micelle of itself and generation combine closely, and form jail
Solid zirconium silicate package cadmium sulfoselenide structural unit, the structural unit of formation is less than 100nm, far smaller than wraps up reddish yellow on the market
The grain diameter of ink.
The steps in the embodiment of the present invention can be sequentially adjusted, merged and deleted according to actual needs.
It is described in detail herein, applies specific case and the principle of the present invention and embodiment are explained
It states, above example is only intended to help the method and its core concept for understanding the present invention；Meanwhile for the general skill of this field
Art personnel, thought according to the invention, there will be changes in specific embodiments and applications, in conclusion this
Description should not be construed as limiting the invention.
Claims (8)
1. a kind of particle size controling agent for wrapping up red, yellow ink, which is characterized in that its material component includes by weight percentage：
2. particle size controling agent as described in claim 1, which is characterized in that its material component is by weight percentage：
3. particle size controling agent as described in claim 1, it is characterised in that：The methyl methacrylate and butyl acrylate matter
Amount is than being 2-5:1.
4. a kind of preparation method for the particle size controling agent for wrapping up red, yellow ink, which is characterized in that method includes：
Vacuum distillation pretreatment is carried out to methyl methacrylate, butyl acrylate, under 10.8kPa, recovered (distilled) temperature is respectively
40℃、60℃；
2- acrylamide-2-methyl propane sulfonics, methyl methacrylate and butyl acrylate are put into N-N dimethyl formyls
It is fully dissolved in amine, isopropyl alcohol mixed solvent, for use；
Dissolved 2- acrylamide-2-methyl propane sulfonics, methyl methacrylate and butyl acrylate are sufficiently mixed
It is even, it is 180r/min in stir speed (S.S.), temperature is at 40-80 DEG C, and azodiisobutyronitrile is added dropwise with constant flow pump, lasting to be added dropwise,
0.5~6 it is interior when small be added dropwise, obtain thick controlling agent.
5. preparation method as claimed in claim 4, which is characterized in that method further includes：
Obtained controlling agent is added in into acetone, extract and separate purification is carried out, obtains extract liquor；
Extract liquor is placed in drying box, the freeze-day with constant temperature at a temperature of 313k dries extract liquor, obtains package reddish yellow pottery
The special particle size controling agent of ceramic ink water.
6. preparation method as claimed in claim 4, it is characterised in that：The methyl methacrylate is put into butyl acrylate
Amount is than being 2-5:1.
7. a kind of application process for the particle size controling agent for wrapping up red, yellow ink, which is characterized in that method includes：
In the forerunner's production procedure for wrapping up red, yellow ceramic ink, particle size controling agent is directly added into, before additive amount is synthesis
Drive the 2~20% of the weight percent of body.
8. method the use as claimed in claim 7, it is characterised in that：The particle size controling agent additive amount is synthesis presoma
The 5~10% of weight percent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711351742.9A CN108047810B (en) | 2017-12-15 | 2017-12-15 | Grain size control agent for wrapping red ink and yellow ink, and preparation method and application method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711351742.9A CN108047810B (en) | 2017-12-15 | 2017-12-15 | Grain size control agent for wrapping red ink and yellow ink, and preparation method and application method thereof |
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| CN108047810A true CN108047810A (en) | 2018-05-18 |
| CN108047810B CN108047810B (en) | 2020-12-29 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| WO2016011277A1 (en) * | 2014-07-16 | 2016-01-21 | Electronics For Imaging, Inc. | Ceramic inkjet ink for red decoration |
| CN106590031A (en) * | 2016-12-02 | 2017-04-26 | 佛山市华意陶瓷颜料有限公司 | Cadmium sulfoselenide occlusion pigment, ceramic ink and preparation method of cadmium sulfoselenide occlusion pigment |
| CN106752108A (en) * | 2016-12-02 | 2017-05-31 | 佛山市华意陶瓷颜料有限公司 | A kind of yellow cadmium system occlusion pigment, ceramic ink and preparation method thereof |
-
2017
- 2017-12-15 CN CN201711351742.9A patent/CN108047810B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224727A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Eco-friendly glaze ink for ceramic jet printing and preparation method thereof |
| WO2016011277A1 (en) * | 2014-07-16 | 2016-01-21 | Electronics For Imaging, Inc. | Ceramic inkjet ink for red decoration |
| CN106590031A (en) * | 2016-12-02 | 2017-04-26 | 佛山市华意陶瓷颜料有限公司 | Cadmium sulfoselenide occlusion pigment, ceramic ink and preparation method of cadmium sulfoselenide occlusion pigment |
| CN106752108A (en) * | 2016-12-02 | 2017-05-31 | 佛山市华意陶瓷颜料有限公司 | A kind of yellow cadmium system occlusion pigment, ceramic ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 马晓芳: "《聚丙烯酸酯型超分散剂的合成与应用》", 《中国优秀硕士学位论文全文数据库（电子期刊），工程科技Ⅰ辑》 * |
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| CN108047810B (en) | 2020-12-29 |
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