CN108046376A - A kind of method of drinking water production - Google Patents

A kind of method of drinking water production Download PDF

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Publication number
CN108046376A
CN108046376A CN201810077791.6A CN201810077791A CN108046376A CN 108046376 A CN108046376 A CN 108046376A CN 201810077791 A CN201810077791 A CN 201810077791A CN 108046376 A CN108046376 A CN 108046376A
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CN
China
Prior art keywords
water
membrane
drinking water
nanofiltration
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810077791.6A
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Chinese (zh)
Inventor
姚维昊
魏永
赵威
马琦琦
江晓东
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Changzhou University
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Changzhou University
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Filing date
Publication date
Application filed by Changzhou University filed Critical Changzhou University
Priority to CN201810077791.6A priority Critical patent/CN108046376A/en
Publication of CN108046376A publication Critical patent/CN108046376A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027Nanofiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/58Multistep processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/005Processes using a programmable logic controller [PLC]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/20Total organic carbon [TOC]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/06Pressure conditions
    • C02F2301/066Overpressure, high pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention relates to a kind of methods of drinking water production, it is an object of the invention to overcome the problems, such as currently using ultrafiltration as core drinking water technology in cannot largely remove part small organic molecule, the further small organic molecule strengthened in removal ultrafiltration production water, increase nanofiltration group technology, form the drinking water of bi-membrane method production high-quality, it ensures water safety, is a technical solution innovated very much.It is characterized in that, specifically comprise the following steps:Raw water is first after Ultra filtration membrane again into nanofiltration membrane component, and two class membrane modules set respective increase to pump respectively, and water yield can manually or automatically be adjusted by valve.

Description

A kind of method of drinking water production
Technical field
The present invention relates to a kind of methods of water-treatment technology field, specifically utilize the technology of bi-membrane method production drinking water.
Background technology
Drinking Water in China pollution of waterhead problem getting worse, water source are subject to a large amount of industrialness organic pollutions and artificial synthesized The pollution of organic matter, pipe network pollution etc. in addition, traditional tap water production technology can not meet requirement of the people to water quality.
Ultrafiltration is gradually recognized as third generation urban drinking water purification technique, right since ultrafiltration is mainly sieving actoion There is good removal in turbidity, but suspended material, colloid and macromolecular substances can only be removed, and small organic molecule still can be saturating It crosses.It is compared with common process, ultrafiltration producing water water quality has no clear superiority, and with the improvement of living standards, more and more rows Industry and crowd propose the drinking water needs for higher quality.
In order to produce the drinking water of higher quality, it is a kind of that nanofiltration group technology is set to strengthen drinking water treatment after ultrafiltration Good technical measures.Compared with ultrafiltration, nanofiltration possesses higher rejection, it is possible to remove the small molecule in ultrafiltration production water Organic matter improves the security of drinking water.
The content of the invention
It is an object of the invention to overcome currently using ultrafiltration as core drinking water technology in cannot largely remove small point of part The problem of sub- organic matter, the further small organic molecule strengthened in removal ultrafiltration production water increase nanofiltration group technology, form Bi-membrane method produces the drinking water of high-quality, ensures water safety, is a technical solution innovated very much.The present invention be by with What lower technical solution was realized, specifically comprise the following steps:
1. drinking water production device mainly by raw water box (2), booster pump (3), hyperfiltration membrane assembly (4), intermediate water tank (5), Booster pump (6), nanofiltration membrane component (7) composition.Agitating device wherein in raw water box (2), intermediate water tank (5) is set, ensures water quality Isotropic stable;
2. hyperfiltration membrane assembly (4), nanofiltration membrane component (7) are during water is produced using cross-flow filtration, each type of film Component visual water quality situation is run using plural serial stage, is setting value using PLC Frequency Converter Controls each membrane module production water flow, Concentrated water flow adjusts keep constant daily manually;
It 3. can be in raw water box (2), the interior dosing coagulant of intermediate water tank (5) or Powdered Activated Carbon and film depending on raw water quality situation Component forms on-line filtration, to further improve effluent quality, while reduces fouling membrane.
Description of the drawings
The present invention is further described below in conjunction with the accompanying drawings.
Fig. 1 is the process flow chart that bi-membrane method produces drinking water, wherein:1. raw water;2. raw water box;3. booster pump;4. surpass Filter membrane component;5. intermediate water tank;6. booster pump;7. nanofiltration membrane component;8. inlet valve;9. concentrated water valve;10. produce penstock; 11. inlet valve;12. concentrated water valve;13. produce penstock.
Fig. 2 is raw water in embodiment 1, and water is produced in ultrafiltration, and the TOC and COD of water are produced in nanofiltrationMnFigure.
Fig. 3 is the three-dimensional fluorescence figure of raw water in embodiment 1.
Fig. 4 is three fluorograms that water is produced in ultrafiltration in embodiment 1.
Fig. 5 is three fluorograms that water is produced in nanofiltration in embodiment 1.
Specific embodiment
It elaborates below to the embodiment of the present invention:The present embodiment is carried out lower based on the technical solution of the present invention Implement, give detailed embodiment, but protection scope of the present invention is not limited to following embodiments.
Fig. 2~5 are the bi-membrane method production drinking water examples using certain micro-polluted surface lake water as raw water.Ultrafiltration, nanofiltration membrane component Output water TOC and CODMnAs a result respectively as shown in Fig. 2, the TOC, COD of hyperfiltration membrane assembly production waterMnRemoval rate is only respectively 23%, 31%, it is limited to small organic molecule removal, still there is pollution machine object containing more in water;With respect to nanofiltration membrane component production water TOC, CODMnRemoval rate is apparent, is up to respectively 89%, and 77%, it can be seen that good for the removal effect of organic matter.In addition use Three fluorescence are respectively to raw water, and hyperfiltration membrane assembly production water, nanofiltration membrane component production water is detected, as shown in Fig. 3,4,5, in raw water There are apparent two peaks, be respectively class tyrosine and class tryptophan substance, are produced from the two peaks in water in ultrafiltration apparent decrease, but Apparent peak is not found in nanofiltration production water.It can be seen that nanofiltration can be with the removal of non-selectivity for organic matter.To sum up, nanofiltration is for water Middle organic matter has good removal effect, and can be with the removal of non-selectivity, suitable for the production of high-quality drinking water.
Using above-mentioned desirable embodiment according to the invention as enlightenment, by above-mentioned description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property scope is not limited to the content on specification, it is necessary to determine its technical scope according to right.

Claims (5)

1. it is an object of the invention to overcome currently using ultrafiltration as core drinking water technology in cannot largely remove part small molecule The problem of organic matter, the further small organic molecule strengthened in removal ultrafiltration production water increase nanofiltration group technology, form double Embrane method produces the drinking water of high-quality, ensures water safety, is a technical solution innovated very much.It is it is characterized in that, specific Include the following steps:For raw water first after Ultra filtration membrane again into nanofiltration membrane component, two class membrane modules set respective increase respectively Pump, water yield can manually or automatically be adjusted by valve.
2. a kind of method of drinking water production according to claim 1, it is characterised in that:Drinking water production device mainly by Raw water box (2), booster pump (3), hyperfiltration membrane assembly (4), intermediate water tank (5), booster pump (6), nanofiltration membrane component (7) composition.Its Agitating device in middle raw water box (2), intermediate water tank (5) is set, ensures water quality isotropic stable.
3. a kind of method of drinking water production according to claim 1, it is characterised in that:Hyperfiltration membrane assembly (4), NF membrane Component (7) using cross-flow filtration during water is produced, using plural serial stage transported by each type of visual water quality situation of membrane module Row is setting value using PLC Frequency Converter Controls each membrane module production water flow, and concentrated water flow adjusts keep constant daily.
4. a kind of method of drinking water production according to claim 1, it is characterised in that:It can be in original depending on raw water quality situation Water tank (2), the interior dosing coagulant of intermediate water tank (5) or Powdered Activated Carbon and membrane module form on-line filtration, further to carry High effluent quality, while reduce fouling membrane.
5. a kind of method of drinking water production according to claim 1, it is characterised in that:Hyperfiltration membrane assembly, NF membrane group Macromolecule organic film or such as ceramics inoranic membrane can be used in part;Plate membrane or hollow fiber film assembly are combined.
CN201810077791.6A 2018-01-26 2018-01-26 A kind of method of drinking water production Pending CN108046376A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810077791.6A CN108046376A (en) 2018-01-26 2018-01-26 A kind of method of drinking water production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810077791.6A CN108046376A (en) 2018-01-26 2018-01-26 A kind of method of drinking water production

Publications (1)

Publication Number Publication Date
CN108046376A true CN108046376A (en) 2018-05-18

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CN201810077791.6A Pending CN108046376A (en) 2018-01-26 2018-01-26 A kind of method of drinking water production

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003154362A (en) * 2001-11-22 2003-05-27 Toray Ind Inc Method and apparatus for treating water
CN2900512Y (en) * 2006-06-02 2007-05-16 浦华控股有限公司 Drinking water treating device
CN102674591A (en) * 2012-05-21 2012-09-19 杭州美亚水处理科技有限公司 Method and device for making drinking water by coal mine water
CN103204598A (en) * 2013-02-22 2013-07-17 浙江开创环保科技有限公司 Whole-house quality-divided purification method
CN203112631U (en) * 2013-03-26 2013-08-07 浙江开创环保科技有限公司 Integrate portable drinking water emergency equipment with self-contained power supply
CN203429000U (en) * 2013-09-16 2014-02-12 沃德思源集团有限公司 Centralized drinking water treatment device employing ultra-filtration and partial nanofiltration in parallel connection
CN104030402A (en) * 2014-05-30 2014-09-10 济南万邦环保科技有限公司 Combined direct drinking water purification device
CN104556481A (en) * 2014-12-24 2015-04-29 北京桑德环境工程有限公司 Treatment system and method for preparing high-hardness underground water into domestic drinking water
CN106186388A (en) * 2015-04-29 2016-12-07 杭州超纳净水设备有限公司 A kind of membrane type household water filter
CN107162111A (en) * 2017-06-12 2017-09-15 哈尔滨工业大学 A kind of ultrafiltration nanofiltration integrated emergency processing unit for drinking water burst pollution and processing polluted drinking water method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003154362A (en) * 2001-11-22 2003-05-27 Toray Ind Inc Method and apparatus for treating water
CN2900512Y (en) * 2006-06-02 2007-05-16 浦华控股有限公司 Drinking water treating device
CN102674591A (en) * 2012-05-21 2012-09-19 杭州美亚水处理科技有限公司 Method and device for making drinking water by coal mine water
CN103204598A (en) * 2013-02-22 2013-07-17 浙江开创环保科技有限公司 Whole-house quality-divided purification method
CN203112631U (en) * 2013-03-26 2013-08-07 浙江开创环保科技有限公司 Integrate portable drinking water emergency equipment with self-contained power supply
CN203429000U (en) * 2013-09-16 2014-02-12 沃德思源集团有限公司 Centralized drinking water treatment device employing ultra-filtration and partial nanofiltration in parallel connection
CN104030402A (en) * 2014-05-30 2014-09-10 济南万邦环保科技有限公司 Combined direct drinking water purification device
CN104556481A (en) * 2014-12-24 2015-04-29 北京桑德环境工程有限公司 Treatment system and method for preparing high-hardness underground water into domestic drinking water
CN106186388A (en) * 2015-04-29 2016-12-07 杭州超纳净水设备有限公司 A kind of membrane type household water filter
CN107162111A (en) * 2017-06-12 2017-09-15 哈尔滨工业大学 A kind of ultrafiltration nanofiltration integrated emergency processing unit for drinking water burst pollution and processing polluted drinking water method

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* Cited by examiner, † Cited by third party
Title
鲁文青: "《水污染与健康》", 31 December 2015, 武汉:湖北科学技术出版社 *

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Application publication date: 20180518