CN108046291A - 一种醚菌酯生产过程中副产物氯化铵的回收及再利用 - Google Patents
一种醚菌酯生产过程中副产物氯化铵的回收及再利用 Download PDFInfo
- Publication number
- CN108046291A CN108046291A CN201711469603.6A CN201711469603A CN108046291A CN 108046291 A CN108046291 A CN 108046291A CN 201711469603 A CN201711469603 A CN 201711469603A CN 108046291 A CN108046291 A CN 108046291A
- Authority
- CN
- China
- Prior art keywords
- ammonium chloride
- kresoxim
- production process
- recycling
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 title claims abstract description 189
- 235000019270 ammonium chloride Nutrition 0.000 title claims abstract description 86
- 239000006227 byproduct Substances 0.000 title claims abstract description 37
- 239000005800 Kresoxim-methyl Substances 0.000 title claims abstract description 33
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 238000004064 recycling Methods 0.000 title claims abstract description 31
- 238000000855 fermentation Methods 0.000 claims abstract description 26
- 230000004151 fermentation Effects 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000001914 filtration Methods 0.000 claims abstract description 23
- 239000002361 compost Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000001953 recrystallisation Methods 0.000 claims abstract description 19
- 238000001035 drying Methods 0.000 claims abstract description 17
- 238000011084 recovery Methods 0.000 claims abstract description 15
- 238000005516 engineering process Methods 0.000 claims abstract description 13
- 239000000047 product Substances 0.000 claims abstract description 12
- 239000012535 impurity Substances 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 238000007514 turning Methods 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 13
- 241000204031 Mycoplasma Species 0.000 claims description 11
- 241000894006 Bacteria Species 0.000 claims description 9
- 230000003213 activating effect Effects 0.000 claims description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical group [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 8
- 239000000908 ammonium hydroxide Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 230000007423 decrease Effects 0.000 claims description 7
- 239000000706 filtrate Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000001556 precipitation Methods 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 239000012452 mother liquor Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 239000002068 microbial inoculum Substances 0.000 claims description 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 4
- 235000021050 feed intake Nutrition 0.000 abstract description 2
- 238000012271 agricultural production Methods 0.000 abstract 1
- 238000011017 operating method Methods 0.000 abstract 1
- 229960001040 ammonium chloride Drugs 0.000 description 66
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 238000007792 addition Methods 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 150000001408 amides Chemical class 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 241000370738 Chlorion Species 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 150000001263 acyl chlorides Chemical class 0.000 description 6
- 238000004821 distillation Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 235000005822 corn Nutrition 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 239000002085 irritant Substances 0.000 description 4
- 231100000021 irritant Toxicity 0.000 description 4
- 238000007738 vacuum evaporation Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 241000482268 Zea mays subsp. mays Species 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 239000003895 organic fertilizer Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000010977 jade Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- CVTZKFWZDBJAHE-UHFFFAOYSA-N [N].N Chemical group [N].N CVTZKFWZDBJAHE-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000035425 carbon utilization Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/16—Halides of ammonium
- C01C1/164—Ammonium chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711469603.6A CN108046291B (zh) | 2017-12-29 | 2017-12-29 | 一种醚菌酯生产过程中副产物氯化铵的回收及再利用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711469603.6A CN108046291B (zh) | 2017-12-29 | 2017-12-29 | 一种醚菌酯生产过程中副产物氯化铵的回收及再利用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108046291A true CN108046291A (zh) | 2018-05-18 |
CN108046291B CN108046291B (zh) | 2021-07-09 |
Family
ID=62129242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201711469603.6A Active CN108046291B (zh) | 2017-12-29 | 2017-12-29 | 一种醚菌酯生产过程中副产物氯化铵的回收及再利用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108046291B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111547741A (zh) * | 2020-05-25 | 2020-08-18 | 京博农化科技有限公司 | 一种醚菌酯生产过程中副产物氯化铵的回收方法 |
CN113135582A (zh) * | 2021-04-01 | 2021-07-20 | 常州大学 | 一种氯化钠联合制备碳酸钠与氯化铵的生产方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101244878A (zh) * | 2008-02-25 | 2008-08-20 | 南京大学 | 一种对硝基苯胺生产废水的治理与资源回收利用的方法 |
CN104591465A (zh) * | 2015-01-30 | 2015-05-06 | 深圳市危险废物处理站有限公司 | 一种线路板蚀刻废液回收行业含氨氮废水资源化利用和处理的方法 |
CN104726510A (zh) * | 2013-12-24 | 2015-06-24 | 中粮生物化学(安徽)股份有限公司 | 一种发酵制备赖氨酸的方法 |
-
2017
- 2017-12-29 CN CN201711469603.6A patent/CN108046291B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101244878A (zh) * | 2008-02-25 | 2008-08-20 | 南京大学 | 一种对硝基苯胺生产废水的治理与资源回收利用的方法 |
CN104726510A (zh) * | 2013-12-24 | 2015-06-24 | 中粮生物化学(安徽)股份有限公司 | 一种发酵制备赖氨酸的方法 |
CN104591465A (zh) * | 2015-01-30 | 2015-05-06 | 深圳市危险废物处理站有限公司 | 一种线路板蚀刻废液回收行业含氨氮废水资源化利用和处理的方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111547741A (zh) * | 2020-05-25 | 2020-08-18 | 京博农化科技有限公司 | 一种醚菌酯生产过程中副产物氯化铵的回收方法 |
CN113135582A (zh) * | 2021-04-01 | 2021-07-20 | 常州大学 | 一种氯化钠联合制备碳酸钠与氯化铵的生产方法 |
Also Published As
Publication number | Publication date |
---|---|
CN108046291B (zh) | 2021-07-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104261947B (zh) | 一种利用苏氨酸发酵废弃物制备的肥料 | |
EP0284339B1 (en) | Chelated plant nutrients | |
US5876479A (en) | Composition and method of manufacturing a liquid humic acid based soil enhancer | |
Muhmood et al. | Biochar seeding promotes struvite formation, but accelerates heavy metal accumulation | |
CN106336253A (zh) | 利用多级膜分离技术浓缩沼液制造有机肥料的生产工艺 | |
CN104447108B (zh) | 一种腐植酸滴灌专用肥及其制备方法 | |
CN103159531A (zh) | 一种含多种植物醇和中微量元素螯合的液体肥料及其制备方法 | |
US20120255334A1 (en) | Soluble organic fertilizer | |
CN1124784C (zh) | 香菇菌糠及柄蒂提取物制备生物农药及其工艺 | |
CN104609950B (zh) | 有机螯合黄腐酸钾硅肥及其生产工艺 | |
CN108046291A (zh) | 一种醚菌酯生产过程中副产物氯化铵的回收及再利用 | |
US3374081A (en) | Precipitation of minerals from brines | |
CN105061082B (zh) | 基于化感自毒作用的花生连作障碍调理剂及其施用方法 | |
CN107032855A (zh) | 利用畜禽粪便发酵沼渣制备有机肥的方法 | |
CN115557813B (zh) | 一种有机液体肥及其制备方法 | |
CN110759783A (zh) | 一种复合微生物有机水溶肥料及其制备方法 | |
CN112624845A (zh) | 一种利用黄姜废水生产水溶肥的工艺方法 | |
CN113845386A (zh) | 一种高塔腐植酸型复合肥及其制备方法 | |
CN106892709A (zh) | 一种生防型蔬菜专用速溶肥料及其制备方法 | |
US10189749B2 (en) | Humic acid lignite coal based liquid fertilizer | |
RU2107054C1 (ru) | Способ получения комплексного удобрения | |
JPH0248486A (ja) | 有機発酵肥料の製造方法 | |
CN110128214A (zh) | 一种利用酵母浓浆废液生产含腐植酸水溶肥料的方法 | |
US11999663B2 (en) | Liquid organic nutrient for agricultural use and production method thereof | |
US11512029B1 (en) | Multipurpose fertilizer composition and method of manufacturing the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Recovery and reuse of ammonium chloride, a by-product in the production of ether bacterial ester Effective date of registration: 20211123 Granted publication date: 20210709 Pledgee: SHANDONG CHAMBROAD PETROCHEMICALS Co.,Ltd. Pledgor: CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE Co.,Ltd. Registration number: Y2021980013118 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220905 Granted publication date: 20210709 Pledgee: SHANDONG CHAMBROAD PETROCHEMICALS Co.,Ltd. Pledgor: CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE Co.,Ltd. Registration number: Y2021980013118 |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240530 Address after: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee after: Shandong Jingbo Agrochemical Technology Co.,Ltd. Country or region after: China Address before: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee before: CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE Co.,Ltd. Country or region before: China |