CN108004847A - A kind of new ancient books depickling restorative procedure - Google Patents
A kind of new ancient books depickling restorative procedure Download PDFInfo
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- CN108004847A CN108004847A CN201711219633.1A CN201711219633A CN108004847A CN 108004847 A CN108004847 A CN 108004847A CN 201711219633 A CN201711219633 A CN 201711219633A CN 108004847 A CN108004847 A CN 108004847A
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- depickling
- ancient books
- solution
- books
- dehumidifier
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- 238000000034 method Methods 0.000 title claims abstract description 51
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000000843 powder Substances 0.000 claims abstract description 19
- 238000000889 atomisation Methods 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000005086 pumping Methods 0.000 claims abstract description 5
- 229920000742 Cotton Polymers 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 15
- 238000007789 sealing Methods 0.000 claims description 8
- 230000001186 cumulative effect Effects 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 239000000443 aerosol Substances 0.000 claims description 3
- 238000010422 painting Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- 150000003384 small molecules Chemical class 0.000 claims description 2
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 1
- 238000004321 preservation Methods 0.000 abstract 1
- 238000003672 processing method Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 28
- 239000000243 solution Substances 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000012071 phase Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 7
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000009418 renovation Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 230000008439 repair process Effects 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- JLPGKEQLGPTHHH-UHFFFAOYSA-L CO.[OH-].[Ba+2].[OH-] Chemical compound CO.[OH-].[Ba+2].[OH-] JLPGKEQLGPTHHH-UHFFFAOYSA-L 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/18—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00 of old paper as in books, documents, e.g. restoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of new ancient books depickling restorative procedure.The processing method is：Pending ancient books is put into closed depickling prosthetic device first, dehumidifier operation and vacuum pumping successively are carried out to system after good seal, system is set to maintain drying, and keep under negative pressure after stablizing, open fan group, directly nanoscale alkalescence depickling powder is sent into depickling prosthetic device by gas pipeline, or ultrasonic atomizer is first passed through by alkaline depickling solution atomization, then sent by gas pipeline into depickling prosthetic device, pending ancient books is set sufficiently uniformly to absorb alkaline deacidification agent, ancient books pH is monitored at the same time, realizes the depickling reparation to ancient books.The present invention is not only adapted to the reparation of ancient books, is equally applicable to archives, document, books and Modern Paper, cotton, the depickling reparation of gunny products and preservation and handles.
Description
Technical field
The present invention relates to ancient books depickling to repair field, and in particular to a kind of method of new ancient books depickling reparation.
Background technology
In various libraries of China, museum, archives, be stored in thousands of precious books, painting and calligraphy,
Modern newspaper, archives and other heritage informations, they are the excellent traditional culture elite of the Chinese nation, have important history valency
Value, cultureal value, information value, are the important components in Chinese culture legacy, have not reproducible historic significance.Paper
, as the carrier of these word elite, with the passing of the years, by damage by worms, be acidified, go mouldy, damaged situation it is more and more tighter
Weight, situation are precarious.Paper is manufactured paper with pulp by fibrous raw material and formed, and the stability of cellulose is to maintain ancient books physical property most important
One of condition, cellulose is metastable under neutral and weak basic condition, is generally not easy to be hydrolyzed and aoxidize, but
Under acid condition, due to the catalytic action of acid, the hydrolysis of cellulose significantly increases, after cellulose hydrolysis, due to the degree of polymerization
Reduce, the intensity of ancient books also decreases, and over time, ancient books will dusting.Because acidic chemical during production retains, always
Change degraded produce organic acid, use storage environment caused by acidifying etc. many factors may cause the acidifying of paper to aggravate.
Therefore, it is extremely urgent that thoroughly depickling repairing research is carried out to paper document.Although domestic and international research institution is at present
Carry out the various depickling repairing research to paper document, but skill is repaired in the ripe depickling for obtaining energy practical application yet so far
Art.
Existing depickling renovation technique mainly has liquid phase depickling and gas phase depickling, its principle is all to use alkaline deacidification agent by Gu
Acid in nationality neutralizes and reaches depickling and repair purpose.
Liquid phase depickling repairing method is broadly divided into organic solution depickling and aqueous solution depickling；
Organic solvent depickling repairing method main method has Wei Tuofa, and FMC methods, barium hydroxide-methanol solution depickling reparation, has
Machine solution depickling repairing method has depickling remediation efficiency height, easy to operate, the advantages such as cost is low.Japan, Germany, meaning are big at present
The western countries such as profit, the U.S. use organic solvent method mostly, but organic solvent is inflammable, part organic solvent toxicity is strong, big portion
Divide and be not suitable for oil-soluble ink print, ancient books ink can be caused to dissolve, be stained ancient books, and toxicity is too by force to the peace of operation
Full property requires very high.
Aqueous solution depickling repairing method has the advantages that environmentally safe, easy to operation, economy, depickling repairing effect are good, but
There is also the paper document after processing to there is phenomena such as deformation, shrinkage, has an impact to some writings, thus is unfavorable for scale
Depickling reparation.At present in the world also without technology of the aqua-solution method to whole books progress depickling repair process is solved, if directly
Connect and depickling repair process is carried out to whole ancient books, can be inter-adhesive between paper, serious secondary breakage is caused, to handle and all must
Ancient books first must be dismantled into single page to be handled, be rebound again after the completion of paper document processing, ancient books standing time is long
Natively intensity is very low, dismantles and is very easy to cause breakage, then after document is put into being soaked in solution, and the intensity of paper is just more
It is low, although can depickling reparation, it is too serious to the secondary damage of ancient books, furthermore, books need after liquid soaks
Drying, drying course easily cause the accelerated ageing of fiber, fibrous fracture so that paper turns to be yellow, or even damaged, and this side
Method processing procedure is numerous and diverse, cycle length, and does not apply to.
Gas phase depickling repairing method is broadly divided into diethyl zinc method and morpholine depickling method.
Diethyl zinc depickling method：When acid hydrogen ion in diethyl zinc and ancient books meets, can not only with the hydrogen in paper from
Son reacts, moreover it is possible to which the rapid hydrogen neutralized in water, generates the zinc oxide of solid.This solid oxidation zinc stays in the surface of paper,
There can be certain depickling repairing effect, but diethyl zinc meets air meeting spontaneous combustion, there is very big danger, the document of papery is most
What is be afraid of is exactly fire, and the residual of zinc oxide can also accelerate the photooxidation of paper fibre on partial extent, makes paper jaundice, always
Change, institute is also not so good in this approach.
Morpholine depickling method：Under normal circumstances, morpholine is liquid, and it can mix with water and becomes gas under vacuum
Body, can react with the hydrogen ion in ancient books and reach depickling reparation purpose.This method easily changes paper color, makes news
Paper, periodical etc. turn to be yellow, and processing procedure cannot play reinforcement effect, and very big plus equipment, instrument investment, large-scale promotion by
To limitation.From the point of view of the applicable cases of external depickling recovery technique, the 1970s and 1980s, gas phase depickling reparation with its high-volume at
The advantages of reason, but process conditions required high by the high praise of people, there are security risk, toxicity is big, investment is big, treatment effect not
Uniformly the shortcomings that, limits its extensive use.
The depickling renovation technique of gas phase and liquid phase as domestic and international existing many types at present, but all there are respective
Defect, for example, it is of high cost, operation difficulty is big, and deacidification agent toxicity is big, it is impossible to and large-scale, there are security risk, pollutes environment etc.,
Up to now it has not been found that the ancient book depickling restorative procedure of an energy practical application.
The content of the invention
For the above, in order to overcome the above problem or it is at least part of solve the above problems, the present invention is to provide
A kind of new ancient books depickling restorative procedure.
Gas phase depickling renovation technique and liquid phase depickling renovation technique are combined together by the present invention, using gas phase and liquid phase and
Gas phase/solid phase depickling renovation technique, the secondary damage of paper adhesion, and this technique can be caused by both having avoided liquid phase depickling reparation
Be intended to not destroy the original temperature of ancient books and humidity, it is not necessary to ancient books carry out drying operation, fiber will not aging fracture, ancient books
Will not be turned to be yellow breakage.The worry that gas phase depickling reparation can not find appropriate alkaline gaseous deacidification agent is it also avoid at the same time, it is most of
Organic-inorganic akaline liquid and nanoscale alkalescence depickling powder body material can use this technique to carry out depickling reparation behaviour to ancient books
Make.
Pending ancient books, is put into closed depickling prosthetic device by a kind of new ancient books depickling restorative procedure first,
Dehumidifier operation and vacuum pumping successively are carried out to system after good seal, system is maintained drying, and is kept under negative pressure steady
After fixed, fan group is opened, is directly sent deacidification agent into depickling prosthetic device by gas pipeline, or first pass through ultrasonic atomizer
By alkaline depickling solution atomization, then the alkaline depickling solution after atomization is sent to depickling prosthetic device by gas pipeline again
In, pending ancient books is sufficiently uniformly absorbed alkaline deacidification agent, while ancient books pH is monitored, realize that the depickling to ancient books is repaiied
It is multiple；
The ancient books include processing ancient times acidity books, archives, documents and materials, books, newpapers and periodicals, paper, calligraphy and painting, cotton and
Fiber crops.
In the above method, the obturator good airproof performance, system keeps room temperature, can reach higher in system and do
Degree and higher vacuum, sealing device volume are adapted to；Meet between described device volume and pending ancient books cumulative volume, fill
Put volume：Pending ancient books cumulative volume=1.1:1~50:1.
In the above method, the dehumidifier operation, is that the humidity in system is extracted into 10%~90% by dehumidifier, and tie up
Hold 2~24 it is small when, close dehumidifier after reaching the object time.The dehumidifier operating time depends on the original humidity of ancient books and sealing fills
Put volume, when the original humidity of ancient books is 8%~9%, device volume for 1.5~2 times of pending ancient books cumulative volume when, dehumidifier 2
~24h；When original humidity often reduces 10%, the dehumidifier time reduces by 2~6h；It is twice when device volume often increases, the dehumidifier time increases
Add 3~8h.
In the above method, the vacuum pumping, carries out, by vacuum pump by system again after the completion of dehumidifier operation
Interior pressure is extracted into 0 to -0.08mpa, closes vacuum pump after reaching goal pressure, enclosed system maintains to stablize negative pressure state until de-
Acid operation is completed.
In the above method, the ultrasonic atomizer is ultrasonic transducer, and ultrasonic transducer is put into equipped with deacidification agent
In container, power on, by piezoelectric ceramic high-frequency resonance, deacidification agent structure disperses are atomized into the aerosol of small molecule.
In the above method, the deacidification agent is nanoscale alkalescence depickling powder body material, alkaline organic solution or alkaline nothing
Machine thing solution；PH value can maintain to stablize in the long period, and non-toxic, pH value is 7~13；The deacidification agent includes but are not limited to
NaOH solution, Ca (OH)2Solution, Cu (OH)2Solution, Fe (OH)3Solution, KOH solution, Na2CO3Solution, NaHCO3Solution,
NH3·H2All basic matterials such as O solution, ethylenediamine solution, phosphate solution, borate solution；Solution passes through pressurization or ultrasound
Atomizer is dispersed as micron to nano grade drop, and average grain diameter is taken off between 1nm~2 μm by gas pipeline with closed
Sour device is connected.
In the above method, the deacidification agent includes but are not limited to a nanometer NaOH powders, Ca (OH)2Powder, Cu (OH)2Powder
Body, Fe (OH)3Powder, KOH powders, Na2CO3Powder or NaHCO3All alkaline powder body materials such as powder, ethylenediamine powder.
In the above method, the blower system, be by gas pipeline by nanoscale alkalescence depickling powder body material or
The deacidification agent of ultrasonic transducer atomization is slowly incorporated into closed depickling prosthetic device, and the deacidification agent allowed in system circulates,
It is evenly distributed.
In the above method, air humidity is maintained at 10%~90% in control system.
In the above method, there are ancient books pH monitorings in the depickling prosthetic device, when monitored ancient books pH reaches 7~8.5
After when left and right and small maintenance 1~48, system is closed.The length of time depends on the acidizing degree and sealing device volume of ancient books,
When the original pH of ancient books is 6~6.5, device volume for 1.5~2 times of pending ancient books cumulative volume when, depickling maintain 2~5 it is small when；It is former
Beginning pH often increases by 0.2, and depickling is held time 1~6h of reduction；Device volume, which often increases, to be twice, and depickling is held time 3~8h of increase.
Compared with prior art, advantage of the invention is that：
Can large batch of processing acidifying ancient books without very big equipment investment；The original temperature of ancient books and wet is not destroyed
Degree, does not destroy paper structure, will not cause secondary damage to ancient books, can be very good to neutralize ancient books middle acid substance, deacidification effect
Fruit is obvious.There is certain alkaline matter to remain in ancient books at the same time, preferably further extend the service life of ancient books.
Brief description of the drawings
Fig. 1 is the structure diagram of invention depickling prosthetic device；
Fig. 2 is the structure diagram of intermediate bulkhead；
Fig. 3 is the structure diagram of bookshelf；
Fig. 4 is the gas flow figure of the present invention.
All parts are as follows in figure：
It is double open front door 1, visual windows 2, water storage tank 3, fan group 4, hygrometer 5, dehumidifier 6, vacuum pump 7, pressure gage 8,
PH meter 9, lamp 10, intermediate bulkhead 11, gas pipeline aperture 12, backboard 13, ultrasonic atomizer 14, gas pipeline 15, PLC controls system
System 16, drain valve 17, pulley track 18, bookshelf 19, air outlet 20.
Embodiment
Make further specific detailed description, but embodiments of the present invention are not to the present invention with reference to specific embodiment
It is limited to this, for especially not dated technological parameter, can refer to routine techniques progress.
Depickling prosthetic device structure of the present invention is as follows, as shown in Figure 1 to 4, depickling prosthetic device, including it is double open front door 1,
Fan group 4, dehumidifier 6, vacuum pump 7, lamp 10, intermediate bulkhead 11, gas pipeline aperture 12, backboard 13, ultrasonic atomizer 14, gas
Body pipeline 15 and pulley track 18；The one side of described device, which offers, double opens front door 1；Device is divided into by the intermediate bulkhead 11
The bottom surface of the upper and lower, the upper strata and lower floor is both provided with fan group 4, the backboard 13 opposite with device gate in described device
Dehumidifier 6, vacuum pump 7 and ultrasonic atomizer 14 are provided with outer surface；Intermediate bulkhead lower part surrounding is fixed with lamp 10；Institute
State gas pipeline 15 to be located at and through 11 upper strata of intermediate bulkhead, and gas pipeline aperture 12 be provided with this section of gas pipeline 15,
The gas pipeline 15 is connected with ultrasonic atomizer 14；Pulley track 18 is provided with described device bottom surface.Further include visual window
Mouth 2, double open at left and right sides of 1 both sides of front door and device have visual windows 2.Further include hygrometer 5, pressure gage 8 and pH meter 9；
The hygrometer 5, pressure gage 8 and pH meter 9 may be contained within inside device.Double open is fixed with PLC control system 16 on front door 1, institute
PLC control system is stated, fan group 4, dehumidifier 6, vacuum pump 7,19 integrated control of ultrasonic atomizer 14, lamp 10 and bookshelf are led to
Monitoring humidity meter 5, pressure gage 8, pH meter 9 are crossed, controls lamp switch, fan start and stop, wind speed size, dehumidifying start and stop, dehumidifying wind in real time
Amount, vacuum pump start and stop, vacuumize wind speed, and ultrasonic atomizer start and stop, atomization quantity size, bookshelf rotates start and stop, bookshelf is rotated and stopped
Time.Described device is made of cladding material and inner layer material, and cladding material is carbon steel, and interior layer material is stainless steel；Device is total
Width is 1m~2.5m, is highly 1m~2.5m, and length is 3m~12m.Further include water storage tank 3 and drain valve 17；The lower floor
Water storage tank 3 is provided with bottom surface；The water storage tank 3 is located at device both sides and backboard ground, and 3 height of water storage tank is less than ground
1~10cm of face, width are 1~10cm；The water storage tank 3 and drain valve 17 connect；The pulley track 13 has twice, and twice are slided
Width and 19 equivalent width of bookshelf between wheel track 13.Air outlet 20 is provided with the intermediate bulkhead 11, due near from wind turbine
Portion flow rate it is very fast, direction of the outlet air open area from fan group from the close-by examples to those far off is sequentially increased.The bookshelf 19 is stainless steel
Roller is arranged at matter, bottom；Stainless steel chain is housed, book basket is fixed on chain, and chain is driven by motor, after motor is opened on bookshelf
Book basket is moved up and down, so that absorption of the books to aerosol is more uniform；Book basket for it is upper it is micro- it is wide under micro- narrow design, ancient books side
Face can open side and place upward, and the wind of fan group 4 from top to bottom makes ancient books slightly open, and make deacidification agent infiltration evenly.
Embodiment 1
Take《Cure ancient book》- People's Health Publisher nineteen thirty-seven 5 about 0.004m of version3, it is original that sampling measures paper in books
Humidity is about 8.6%, and it is 0.00625m that book is put into 0.25m*0.25m*0.1m volumes3Deacidifying device in, first to system
Dehumidifier is carried out, the dehumidifier time is 4h, and dehumidifier is closed after arrival time.Then vacuum pump is opened, pressure in system is extracted into-
Vacuum pump is closed after 0.05mpa.Then ultrasonic atomizer is opened, deacidification agent selection NaOH solids and water are according to mass ratio 20:80
Ratio be uniformly mixed, be put into container, using ultrasonic transducer by the NaOH solution prepared be atomized, imported by gas pipeline
Depickling reparation operation is carried out in sealing container, by controlling gas pipeline valve, by air humidity control in system 50%
Left and right, whens acidic materials in and in paper, monitor the pH value of ancient books；When monitored ancient books pH reaches 7.2, continue to
Stable system 2h, is then shut off system.Paper performance average value such as following table before and after sampling contrast depickling is repaired：
Embodiment 2
Take《Cure ancient book》- People's Health Publisher nineteen thirty-seven 5 about 0.004m of version3, it is original that sampling measures paper in books
Humidity is about 9.2%, and it is 0.00625m that book is put into 0.25m*0.25m*0.1m volumes3Deacidifying device in, first to system
Dehumidifier is carried out, the dehumidifier time is 3h, and dehumidifier is closed after arrival time.Then vacuum pump is opened, pressure in system is extracted into-
Vacuum pump is closed after 0.07mpa.Then ultrasonic atomizer is opened, deacidification agent selection NaOH solids and water are according to mass ratio 20:80
Ratio be uniformly mixed, be put into container, using ultrasonic transducer by the NaOH solution prepared be atomized, imported by gas pipeline
Depickling reparation operation is carried out in sealing container, by controlling gas pipeline valve, by air humidity control in system 50%
Left and right, whens acidic materials in and in paper, monitor the pH value of ancient books；When monitored ancient books pH reaches 7.2, continue to
Stable system 2h, is then shut off system.Paper performance average value such as following table before and after sampling contrast depickling is repaired：
Embodiment 3
Take《Cure ancient book》- People's Health Publisher nineteen thirty-seven 5 about 0.004m of version3, it is original that sampling measures paper in books
Humidity is about 7.3%, and it is 0.00625m that book is put into 0.25m*0.25m*0.1m volumes3Deacidifying device in, first to system
Dehumidifier is carried out, the dehumidifier time is 4h, and dehumidifier is closed after arrival time.Then vacuum pump is opened, pressure in system is extracted into-
Vacuum pump is closed after 0.05mpa.Then ultrasonic atomizer is opened, deacidification agent selection NaOH solids and water are according to mass ratio 30:70
Ratio be uniformly mixed, be put into container, using ultrasonic transducer by the NaOH solution prepared be atomized, imported by gas pipeline
Depickling reparation operation is carried out in sealing container, by controlling gas pipeline valve, by air humidity control in system 50%
Left and right, whens acidic materials in and in paper, monitor the pH value of ancient books；When monitored ancient books pH reaches 7.2, continue to
Stable system 2h, is then shut off system.Paper performance average value such as following table before and after sampling contrast depickling is repaired：
The above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not to the present invention
Embodiment restriction.For those of ordinary skill in the field, can also make on the basis of the above description
Other various forms of changes or variation.There is no necessity and possibility to exhaust all the enbodiments.It is all the present invention
All any modification, equivalent and improvement made within spirit and principle etc., should be included in the protection of the claims in the present invention
Within the scope of.
Claims (10)
1. a kind of new ancient books depickling restorative procedure, it is characterised in that pending ancient books is put into closed depickling first and is repaiied
In apparatus for coating, dehumidifier operation and vacuum pumping successively are carried out to system after good seal, system is maintained drying, and in negative pressure
It is lower to keep after stablizing, fan group is opened, is directly sent deacidification agent into depickling prosthetic device by gas pipeline, or first pass through super
Then alkaline depickling solution after atomization is sent to depickling and repaiied by sound atomizer by alkaline depickling solution atomization by gas pipeline again
In apparatus for coating, pending ancient books is sufficiently uniformly absorbed alkaline deacidification agent, while ancient books pH is monitored, realize to ancient books
Depickling reparation；
The ancient books includes processing ancient times acidity books, archives, documents and materials, books, newpapers and periodicals, paper, calligraphy and painting, cotton and fiber crops.
2. ancient books depickling restorative procedure according to claim 1, it is characterised in that described device volume and pending Gu
Meet between nationality cumulative volume, device volume：Pending ancient books cumulative volume=1.1:1~50:1.
3. ancient books depickling restorative procedure according to claim 1, it is characterised in that the dehumidifier operation, is to pass through dehumidifier
Air humidity in system is extracted into 10% ~ 90% by machine, and maintain 2 ~ 24 it is small when；The dehumidifier operating time depends on the original of ancient books
Humidity and sealing device volume, when the original humidity of ancient books is 8% ~ 9%, device volume is pending 1.5 ~ 2 times of ancient books cumulative volume
When, the dehumidifier time is 2 ~ 24h；When original humidity often reduces 10%, the dehumidifier time reduces by 2 ~ 6h；It is twice when device volume often increases,
The dehumidifier time increases by 3 ~ 8h.
4. ancient books depickling restorative procedure according to claim 1, it is characterised in that the vacuum pumping, is in dehumidifier
Carried out again after the completion of operation, pressure in system is extracted into 0 to -0.08mpa by vacuum pump；Enclosed system maintains to stablize negative pressure
State is until depickling operation is completed.
5. ancient books depickling restorative procedure according to claim 1, it is characterised in that the ultrasonic atomizer changes for ultrasound
Energy device, ultrasonic transducer is put into the container equipped with deacidification agent, is powered on, by piezoelectric ceramic high-frequency resonance, by depickling
Agent structure disperses and be atomized into the aerosol of small molecule.
6. nanoscale deacidification agent according to claim 1, it is characterised in that the deacidification agent is nanoscale alkalescence depickling powder
Body material, alkaline organic solution or alkali inorganic substance solution；PH value is 7 ~ 13；It is molten that the alkalescence depickling solution includes NaOH
Liquid, Ca (OH)2Solution, Cu (OH)2Solution, Fe (OH)3Solution, KOH solution, Na2CO3Solution, NaHCO3Solution, NH3·H2O is molten
Liquid, ethylenediamine solution, phosphate solution or borate solution；The alkalescence depickling solution is broken up by pressurization or ultrasonic atomizer
Into micron to nano grade drop, average grain diameter is between 1nm ~ 2 μm.
7. nanoscale deacidification agent according to claim 1, it is characterised in that the deacidification agent powder includes nanometer NaOH powder
Body, Ca (OH)2Powder, Cu (OH)2Powder, Fe (OH)3Powder, KOH powders, Na2CO3Powder or NaHCO3Powder or ethylenediamine powder
Body.
8. ancient books depickling restorative procedure according to claim 1, it is characterised in that the fan group, is to pass through gas
The deacidification agent that nanoscale alkalescence depickling powder body material or ultrasonic transducer are atomized slowly is incorporated into closed depickling reparation by pipeline
In device, and the deacidification agent allowed in system circulates, and is evenly distributed.
9. ancient books depickling restorative procedure according to claim 1, it is characterised in that air humidity is maintained in control system
10%~90%。
10. ancient books depickling restorative procedure according to claim 1, it is characterised in that have in the depickling prosthetic device
Ancient books pH monitor, when monitored ancient books pH reach 7 ~ 8.5 or so and maintain 1 ~ 48 it is small when after, closing system；The length of time takes
Certainly in the acidizing degree and sealing device volume of ancient books, when the original pH of ancient books is 6 ~ 6.5, device volume is total for pending ancient books
During 1.5 ~ 2 times of volume, depickling maintain 2 ~ 5 it is small when；Original pH often increases by 0.2, and depickling is held time 1 ~ 6h of reduction；Device volume is every
Increasing is twice, and depickling is held time 3 ~ 8h of increase.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711219633.1A CN108004847B (en) | 2017-11-28 | 2017-11-28 | Ancient book deacidification and restoration method |
| EP18883588.8A EP3643834A4 (en) | 2017-11-28 | 2018-10-31 | Novel method for repairing ancient book by deacidification |
| PCT/CN2018/113229 WO2019105168A1 (en) | 2017-11-28 | 2018-10-31 | Novel method for repairing ancient book by deacidification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711219633.1A CN108004847B (en) | 2017-11-28 | 2017-11-28 | Ancient book deacidification and restoration method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108004847A true CN108004847A (en) | 2018-05-08 |
| CN108004847B CN108004847B (en) | 2021-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711219633.1A Active CN108004847B (en) | 2017-11-28 | 2017-11-28 | Ancient book deacidification and restoration method |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3643834A4 (en) |
| CN (1) | CN108004847B (en) |
| WO (1) | WO2019105168A1 (en) |
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| CN108914701A (en) * | 2018-08-30 | 2018-11-30 | 华南理工大学 | One kind can be used for whole volume ancient books depickling enhancing bracing means in batches |
| CN109342382A (en) * | 2018-11-23 | 2019-02-15 | 复旦大学 | A kind of preparation method of the depickling functional paper with pH response fluorescence probe |
| WO2019105168A1 (en) * | 2017-11-28 | 2019-06-06 | 华南理工大学 | Novel method for repairing ancient book by deacidification |
| CN110284366A (en) * | 2019-06-27 | 2019-09-27 | 中山大学 | A kind of gas phase depickling reinforcement means of paper relics |
| CN110552238A (en) * | 2019-08-26 | 2019-12-10 | 华南理工大学 | Paper reinforcing and strengthening treatment liquid and method for reinforcing and strengthening paper |
| US20200157742A1 (en) * | 2017-11-28 | 2020-05-21 | South China University Of Technology | Novel device for deacidifying, reinforcing and strengthening ancient books |
| CN111851143A (en) * | 2020-08-25 | 2020-10-30 | 南京博物院 | Process and equipment for deacidifying whole paper document |
| CN112056794A (en) * | 2020-09-14 | 2020-12-11 | 高新亮 | Ancient book document management placer |
| CN112921705A (en) * | 2021-01-25 | 2021-06-08 | 杭州众材科技有限公司 | Particle embedded paper deacidification protection method |
| CN113186754A (en) * | 2021-04-09 | 2021-07-30 | 杭州众材科技股份有限公司 | Protection method suitable for paper homogenization deacidification |
| CN115216997A (en) * | 2022-07-27 | 2022-10-21 | 南京博物院 | Method for deacidifying paper |
| CN116590960A (en) * | 2023-06-02 | 2023-08-15 | 南通鑫炜信息技术有限公司 | Paper archives and ancient books repairing process and repairing device based on silk screen |
| CN116752378A (en) * | 2023-05-09 | 2023-09-15 | 华南理工大学 | Method for in-situ formation of calcium carbonate in paper literature and deacidification treatment process |
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| CN115928495B (en) * | 2022-11-25 | 2024-07-23 | 复旦大学 | Mineralized bacterial cellulose multifunctional protection lining paper for preventive protection of paper cultural relics and preparation method and application thereof |
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| US11549218B2 (en) * | 2017-11-28 | 2023-01-10 | South China University Of Technology | Device for deacidifying, reinforcing and strengthening ancient books |
| WO2019105168A1 (en) * | 2017-11-28 | 2019-06-06 | 华南理工大学 | Novel method for repairing ancient book by deacidification |
| US20200157742A1 (en) * | 2017-11-28 | 2020-05-21 | South China University Of Technology | Novel device for deacidifying, reinforcing and strengthening ancient books |
| CN108914701A (en) * | 2018-08-30 | 2018-11-30 | 华南理工大学 | One kind can be used for whole volume ancient books depickling enhancing bracing means in batches |
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| CN110284366A (en) * | 2019-06-27 | 2019-09-27 | 中山大学 | A kind of gas phase depickling reinforcement means of paper relics |
| CN110552238A (en) * | 2019-08-26 | 2019-12-10 | 华南理工大学 | Paper reinforcing and strengthening treatment liquid and method for reinforcing and strengthening paper |
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| CN113186754B (en) * | 2021-04-09 | 2022-05-06 | 杭州众材科技股份有限公司 | Protection method suitable for paper homogenization deacidification |
| CN115216997A (en) * | 2022-07-27 | 2022-10-21 | 南京博物院 | Method for deacidifying paper |
| CN116752378A (en) * | 2023-05-09 | 2023-09-15 | 华南理工大学 | Method for in-situ formation of calcium carbonate in paper literature and deacidification treatment process |
| CN116590960A (en) * | 2023-06-02 | 2023-08-15 | 南通鑫炜信息技术有限公司 | Paper archives and ancient books repairing process and repairing device based on silk screen |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019105168A1 (en) | 2019-06-06 |
| EP3643834A1 (en) | 2020-04-29 |
| CN108004847B (en) | 2021-08-10 |
| EP3643834A4 (en) | 2021-03-10 |
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