CN108003801A - A kind of light conversion POE glued membranes and its photovoltaic module of encapsulation - Google Patents
A kind of light conversion POE glued membranes and its photovoltaic module of encapsulation Download PDFInfo
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- CN108003801A CN108003801A CN201711175906.7A CN201711175906A CN108003801A CN 108003801 A CN108003801 A CN 108003801A CN 201711175906 A CN201711175906 A CN 201711175906A CN 108003801 A CN108003801 A CN 108003801A
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- Prior art keywords
- light
- glued membranes
- poe
- poe glued
- converts
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- 239000012528 membrane Substances 0.000 title claims abstract description 62
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 42
- 238000005538 encapsulation Methods 0.000 title abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 21
- 230000000996 additive effect Effects 0.000 claims abstract description 21
- 230000009466 transformation Effects 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 238000004132 cross linking Methods 0.000 claims abstract description 9
- 239000004611 light stabiliser Substances 0.000 claims abstract description 9
- 239000006096 absorbing agent Substances 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- 239000003999 initiator Substances 0.000 claims abstract description 8
- 230000008719 thickening Effects 0.000 claims abstract description 8
- 230000005611 electricity Effects 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 11
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 11
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 11
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 9
- 239000005329 float glass Substances 0.000 claims description 7
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 7
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 6
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims description 6
- 229920005591 polysilicon Polymers 0.000 claims description 6
- ODKXGEBKLRHKGQ-UHFFFAOYSA-N C(C)(C)(C)OO.C(O)(O)=O Chemical compound C(C)(C)(C)OO.C(O)(O)=O ODKXGEBKLRHKGQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- YOEYNURYLFDCEV-UHFFFAOYSA-N tert-butyl hydroxy carbonate Chemical compound CC(C)(C)OC(=O)OO YOEYNURYLFDCEV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- YVAACGXAZGGQSM-UHFFFAOYSA-N 2,2-dimethylpropaneperoxoic acid Chemical compound CC(C)(C)C(=O)OO YVAACGXAZGGQSM-UHFFFAOYSA-N 0.000 claims 2
- SKDYTPBHOGOVME-UHFFFAOYSA-N 1,1,2-triethoxyethene Chemical compound CCOC=C(OCC)OCC SKDYTPBHOGOVME-UHFFFAOYSA-N 0.000 claims 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims 1
- WFEBQEXEKYVLMO-UHFFFAOYSA-N OC1=C(C=C(C=C1)CN)C1=CC=CC=2NN=NC21 Chemical compound OC1=C(C=C(C=C1)CN)C1=CC=CC=2NN=NC21 WFEBQEXEKYVLMO-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- XJUFGFWUKUCNKA-UHFFFAOYSA-N butyl hydroxy carbonate Chemical compound CCCCOC(=O)OO XJUFGFWUKUCNKA-UHFFFAOYSA-N 0.000 claims 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 150000003330 sebacic acids Chemical class 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 238000005829 trimerization reaction Methods 0.000 claims 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 9
- -1 fulminuric acid ester Chemical class 0.000 description 8
- PQMOXTJVIYEOQL-UHFFFAOYSA-N Cumarin Natural products CC(C)=CCC1=C(O)C(C(=O)C(C)CC)=C(O)C2=C1OC(=O)C=C2CCC PQMOXTJVIYEOQL-UHFFFAOYSA-N 0.000 description 6
- FSOGIJPGPZWNGO-UHFFFAOYSA-N Meomammein Natural products CCC(C)C(=O)C1=C(O)C(CC=C(C)C)=C(O)C2=C1OC(=O)C=C2CCC FSOGIJPGPZWNGO-UHFFFAOYSA-N 0.000 description 6
- 238000005266 casting Methods 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 238000004804 winding Methods 0.000 description 5
- 239000002313 adhesive film Substances 0.000 description 4
- 238000007766 curtain coating Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- IXWVXNKDZQRPFW-UHFFFAOYSA-N 2-ethylhexyl 2,2-dimethylpropaneperoxoate Chemical class CCCCC(CC)COOC(=O)C(C)(C)C IXWVXNKDZQRPFW-UHFFFAOYSA-N 0.000 description 2
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- NVBKTGWWQBDICL-UHFFFAOYSA-N 1,2,2-triethoxyethenylsilane Chemical class CCOC([SiH3])=C(OCC)OCC NVBKTGWWQBDICL-UHFFFAOYSA-N 0.000 description 1
- HQWDILUMZXPFNW-UHFFFAOYSA-N 2-cyano-2-nitroacetamide Chemical class NC(=O)C(C#N)[N+]([O-])=O HQWDILUMZXPFNW-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 241000522215 Dipteryx odorata Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- CPBHJGWJMLDUNB-UHFFFAOYSA-N ethenoxysilane Chemical compound [SiH3]OC=C CPBHJGWJMLDUNB-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
The invention discloses a kind of light conversion POE glued membranes and its photovoltaic module of encapsulation, the light conversion POE glued membranes are prepared by the component of following weight fraction：100 parts of POE resin, 0.5 2.0 parts of organic per-compounds initiator, 0.5 2.5 parts of crosslinking coagent, 0.3 1.5 parts of coupling agent of thickening, 0.1 0.6 parts of light stabilizer, the light transformation additive of 0.1 0.6 parts and 0.05 0.2 parts of UV absorbers.The light transformation additive that light conversion POE glued membranes of the present invention add, there is the blue light that ultraviolet short-wave band is changed into more long-wave band, the photovoltaic module solved under conventional encapsulation materials responds the defects of relatively low to short-wave band, substantially increases the electricity conversion of component, lifts the income of photovoltaic module.
Description
Technical field
The present invention relates to a kind of solar module encapsulating material technology, more particularly to a kind of light conversion POE glued membranes and its
The photovoltaic module of encapsulation.
Background technology
With the continuous development of society, environmental pollution and energy shortage become the ultimate challenge of facing mankind, utilize the sun
It is to solve one of both of these problems most efficient method that clean, reproducible solar energy is converted into electric energy by battery.Light at present
Volt industry development is exceedingly fast, and also progressively develops to the direction of diversification, and high power, high ageing-resistant, inexpensive Components Development are increasingly
As the important directions of each Corporation R ＆ D of industry.
The POE of photovoltaic module has the transparent POE of Plain and the high anti-POE packaging adhesive films of white at present, commonly
The POE of water white transparency not only acts as the effect of encapsulation, while also there is lifting light transmittance to increase the generating efficiency of photovoltaic module；
But the transparent POE of Plain also cannot gradually meet the needs of industry is to high power component, it is used to be layered on battery by releasing
The high anti-POE packaging adhesive films of white of piece lower floor, improve the electricity conversion of component, still with the intensity for improving reflected light
White high anti-POE only increases the absorption of long-wave band.Therefore, this increase converts POE packaging plastics to the light that short-wave band absorbs
Film just has the function that its is special.
Solar radiant energy is converted into electric energy by solar cell by photovoltaic effect, and photovoltaic module one is divided into five layers, from
Top to bottm is once glass, upper strata polymer encapsulation glued membrane, cell piece, lower floor's polymer encapsulation glued membrane, backboard or glass, incident
Light incides cell piece by upper strata glass and upper strata polymer encapsulation glued membrane, and then produces photovoltaic effect, usual cell piece pair
The response of ultraviolet short-wave band is relatively low, therefore prepares a kind of light conversion POE packaging adhesive films, and ultraviolet short-wave band is changed into more long-wave band
Blue light so that increase the generating efficiency of battery, and then additional income.
The content of the invention
For overcome the deficiencies in the prior art, it is an object of the present invention to provide a kind of light conversion POE glued membranes.For
Electricity conversion is low in existing photovoltaic module, it is especially relatively low to short wave response the characteristics of, there is provided one kind manufacture cost it is low,
The high solar cell of power ascension uses up conversion POE packaging adhesive films.
The second object of the present invention is to provide a kind of photovoltaic module by light conversion POE glued membrane encapsulation.
An object of the present invention adopts the following technical scheme that realization：A kind of light conversion POE glued membranes, it is characterised in that institute
Light conversion POE glued membranes are stated to be prepared by the component of following parts by weight：
Further, the melt index 5-100g/10min of the POE resin, fusing point are 50-115 DEG C.Wherein, as compared with
The melt index 40-80g/10min of good POE resin, fusing point are 85-95 DEG C.
Further, the organic per-compounds initiator is tert-butyl hydroperoxide carbonic acid -2- ethylhexyls, the tert-butyl group
Peroxidating 2- ethylhexyls carbonic ester, t-butylperoxy formic acid 2- ethylhexyl esters, t-butylperoxy formic acid 2- ethyl hexyls
Base ester, carbon peroxy acid-O, O- (1,1- dimethyl ethyls)-O- (2- ethylhexyls) ester, tert-butyl hydroperoxide carbonic acid -2- ethyl hexyls
Mixture more than one or both of ester, tert-butyl peroxy carbonic acid -2- ethylhexyls.Wherein, as preferable additive amount
For 0.6-1.6 parts.
Further, the crosslinking coagent is triisopropyl fulminuric acid ester, Triallyl isocyanurate, three allyls
Base fulminuric acid ester, -2,4,6 (1H, 3H, 5H)-triketone of tri- -2- acrylic -1,3,5- triazines of 1,3,5-, triallyl isocyanide
Mixture more than one or both of acid esters, triallyl isocyanurate, triallyl isocyanurate.Wherein, as compared with
Good additive amount is 0.5-1.6 parts.
Further, the thickening coupling agent is three ethoxy silane of vinyl, (triethoxysilyl) ethene, ethene
Ethyl triethoxy silicane alkane, vinyl triethoxysilane, triethoxy vinyl silane, one kind in Triethoxyvinylsilane or
Two or more mixtures.Wherein, it is 0.5-1.2 parts as preferable additive amount.
Further, the light stabilizer is hindered amine light stabilizer, selected from double (2,2,6,6- tetramethyl -4- piperidines
Alcohol) sebacic acid ester, the double -2,2,6,6- tetramethyl piperidines alcohol ester of sebacic acid, three nitrogen of 2- (2 '-hydroxyl -5 '-aminomethyl phenyl)-benzo
Mixture more than one or both of azoles.Wherein, it is 0.2-0.5 parts as preferable additive amount.
Further, the UV absorbers for [2- hydroxyls -4- (octyloxy) phenyl] phenyl ketone, 2- hydroxyls -4- just
Octyloxybenzophenone, 2- hydroxyl -4- n-octyloxies Benzophenone, 3,5 di-tert-butyl-4-hydroxybenzoic acid -2,4- di-t-butyls
Mixture more than one or both of phenyl ester.Wherein, it is 0.2-0.5 parts as preferable additive amount.
Further, the smooth transformation additive is 4,8- dimethyl -7- carboxyl cumarins.The light transformation additive is by big
The chromophoric groups of conjugated system and some electron characteristics formed with auxochrome group, have and ultraviolet band changed into more long wave
The function of the blue light of section.It absorbs ultraviolet light by itself chromophoric group, causes the energy level transition of intramolecular pi-electron, launches
Longer light wave achievees the purpose that light is changed, while turns stimulative substance intramolecule by way of delivering in relays, and absorbs ultraviolet light
So as to inspire the wavelength of more long-wave band, so as to effectively improve the generating efficiency of battery, additional income.Preferably, 4,8- diformazans
Base -7- carboxyls cumarin is purchased from Japanese day east electrician group.Wherein, it is 0.08-0.15 parts as preferable additive amount.
The second object of the present invention adopts the following technical scheme that realization：A kind of photovoltaic module, including the conversion of ultra-clear glasses, light
POE glued membranes, monocrystalline or polysilicon solar battery slice, light conversion POE glued membranes, float glass or photovoltaic back；The ultrawhite glass
Glass, light conversion POE glued membranes, monocrystalline or polysilicon solar battery slice, light conversion POE glued membranes, float glass or photovoltaic back from
Top to bottm is bonded successively；The light conversion POE glued membranes convert POE glued membranes for light as described above.
Compared with prior art, the beneficial effects of the present invention are：
(1) the light transformation additive that light conversion POE glued membranes of the present invention add, has ultraviolet short-wave band changing into more long wave
The function of the blue light of section, the photovoltaic module solved under conventional encapsulation materials respond the defects of relatively low to short-wave band, substantially increase
The electricity conversion of component.
(2) in addition, light conversion POE glued membranes and its photovoltaic module preparation process of encapsulation are simple, light transformation additive
Adding influences the basic performance of POE glued membranes without obvious, while the effective electricity conversion for improving component.
(3) at the same time, light conversion POE glued membranes and its photovoltaic module of encapsulation also have excellent uvioresistant performance, with
Conventional POE encapsulating materials are compared, and light conversion POE glued membranes absorb ultraviolet so as to excite blue light, greatly reduce photovoltaic module
The xanthochromia occurred during use by ultraviolet ageing and cracking.
Brief description of the drawings
Fig. 1 is the structure diagram for the photovoltaic module that the present invention converts POE glued membranes containing light；
In figure：1st, ultra-clear glasses；2nd, light conversion POE glued membranes；3rd, monocrystalline or polysilicon solar battery slice；4th, float glass
Or photovoltaic back.
Embodiment
In the following, with reference to attached drawing and embodiment, the present invention is described further, it is necessary to which explanation is, not
Under the premise of afoul, new implementation can be formed between various embodiments described below or between each technical characteristic in any combination
Example.
In the present invention, if not refering in particular to, all parts, percentage are unit of weight, used equipment and raw material etc.
It is commercially available or commonly used in the art.Method in following embodiments, is the normal of this area unless otherwise instructed
Rule method.
It is specific embodiment of the present invention below, used raw material, equipment etc. remove special limit in the following embodiments
It can be obtained outside fixed by buying pattern.
Embodiment 1
The present invention provides a kind of light to convert POE glued membranes, the component composition of following parts by weight：100 parts of melt index are
10g/10min, the POE resin that fusing point is 105 DEG C, 2.0 parts of carbon peroxy acid-O, O- (1,1- dimethyl ethyls)-O- (2- ethyl hexyls
Base) ester (organic per-compounds initiator), 0.5 part of Triallyl isocyanurate (crosslinking coagent), 0.3 part of three second of vinyl
Oxysilane (thickening coupling agent), 0.1 part of double (2,2,6,6- tetramethyl -4- piperidine alcohols) sebacic acid ester (light stabilizer), 0.6 part
[2- hydroxyls -4- (octyloxy) phenyl] phenyl ketone (UV absorbers), (light turns 0.2 part of 4,8- dimethyl -7- carboxyls cumarin
Change additive), said components are uniformly mixed by mixing kettle, casting machine is put into and process conditions routinely sets ginseng
Number, light conversion POE glued membranes are made by plasticizing extrusion, curtain coating, traction, winding.
Embodiment 2
The present invention provides a kind of light to convert POE glued membranes, the component composition of following parts by weight：100 parts of melt index are
30g/10min, the POE resin that fusing point is 100 DEG C, 1.6 parts of tert-butyl hydroperoxide carbonic acid -2- ethylhexyl (organic peroxy chemical combination
Thing initiator), 0.8 part of iso-cyanuric acid triallyl ester (crosslinking coagent), (the thickening coupling of 0.5 part of vinyl triethoxysilane
Agent), 0.2 part of double (2,2,6,6- tetramethyl -4- piperidine alcohols) sebacic acid ester (light stabilizer), 0.5 part of 2- hydroxyl -4- n-octyloxy
Benzophenone (UV absorbers), 0.15 part of 4,8- dimethyl -7- carboxyls cumarin (light transformation additive), by said components
Be uniformly mixed by mixing kettle, input casting machine and process conditions routinely set parameter, by plasticizing extrusion, be cast,
Light conversion POE glued membranes are made in traction, winding.
Embodiment 3
The present invention provides a kind of light to convert POE glued membranes, the component composition of following parts by weight：100 parts of melt index are
40g/10min, the POE resin that fusing point is 90 DEG C, 1.4 parts of tert-butyl hydroperoxide 2- ethylhexyls carbonic ester (organic peroxy chemical combination
Thing initiator), 1.0 parts of -2,4,6 (1H, 3H, 5H)-triketones (crosslinking coagent) of tri- -2- acrylic -1,3,5- triazines of 1,3,5-,
0.8 part of triethoxy vinyl silane (thickening coupling agent), the double -2,2,6,6- tetramethyl piperidines alcohol esters of 0.3 part of sebacic acid (stablize by light
Agent), 0.4 part of 2- hydroxyl -4- n-octyl phenyls ketone (UV absorbers), 0.12 part of 4,8- dimethyl -7- carboxyl cumarin
(light transformation additive), said components are uniformly mixed by mixing kettle, input casting machine and process conditions routinely are set
Good parameter, light conversion POE glued membranes are made by plasticizing extrusion, curtain coating, traction, winding.
Embodiment 4
The present invention provides a kind of light to convert POE glued membranes, the component composition of following parts by weight：100 parts of melt index are
60g/10min, the POE resin that fusing point is 85 DEG C, (organic per-compounds draw 1.2 parts of tert-butyl peroxy carbonic acid -2- ethylhexyls
Send out agent), 1.2 parts of triallyl isocyanates (crosslinking coagent), 1.0 parts of three ethoxy silane of vinyl (thickening coupling agent), 0.4 part
Sebacic acid double -2,2,6,6- tetramethyl piperidines alcohol ester (light stabilizer), 0.3 part of 2- hydroxyl -4- n-octyloxy Benzophenone (ultraviolet light
Absorbent), 0.1 part of 4,8- dimethyl -7- carboxyls cumarin (light transformation additive), said components are mixed by mixing kettle equal
Even, light turn is made by plasticizing extrusion, curtain coating, traction, winding in input casting machine and process conditions routinely set parameter
Change POE glued membranes.
Embodiment 5
The present invention provides a kind of light to convert POE glued membranes, the component composition of following parts by weight：100 parts of melt index are
70g/10min, the POE resin that fusing point is 80 DEG C, 0.8 part of t-butylperoxy formic acid 2- ethylhexyl ester (organic peroxy chemical combination
Thing initiator), 1.4 parts of triisopropyl fulminuric acid esters (crosslinking coagent), 1.2 parts of (triethoxysilyl) ethene (increase
Viscous coupling agent), 0.5 part of 2- (2 '-hydroxyl -5 '-aminomethyl phenyl)-benzotriazole (light stabilizer), 0.2 part of bis- tertiary fourth of 3,5-
Base -4- hydroxymethyl-benzoic acids -2,4- 6- di-tert-butyl phenyl ester (UV absorbers), 0.08 part of 4,8- dimethyl -7- carboxyl tonka-bean
Plain (light transformation additive), said components are uniformly mixed by mixing kettle, put into casting machine and process conditions routinely are set
Parameter is set, light conversion POE glued membranes are made by plasticizing extrusion, curtain coating, traction, winding.
Embodiment 6
The present invention provides a kind of light to convert POE glued membranes, the component composition of following parts by weight：100 parts of melt index are
80g/10min, the POE resin that fusing point is 75 DEG C, 0.6 part of tert-butyl hydroperoxide carbonic acid -2- ethylhexyl (organic per-compounds
Initiator), 1.6 parts of triallyl isocyanurates (crosslinking coagent), 1.4 parts of Triethoxyvinylsilanes (thickening coupling agent),
0.6 part of 2- (2 '-hydroxyl -5 '-aminomethyl phenyl)-benzotriazole (light stabilizer), 0.1 part of [2- hydroxyls -4- (octyloxy) benzene
Base] phenyl ketone (UV absorbers), 0.05 part of 4,8- dimethyl -7- carboxyls cumarin (light transformation additive), by above-mentioned group
Lease making is crossed mixing kettle and is uniformly mixed, input casting machine and process conditions routinely set parameter, by plasticizing extrusion, flows
Prolong, draw, wind be made light conversion POE glued membranes.
Effect assessment and performance detection
Do not add by formula identical example 1-6 but light transformation additive and match comparative example 1-6 respectively, according to《GBT
29848-2013 photovoltaic component encapsulatings ethylene-vinyl acetate copolymer (POE) glued membrane》Light made from example 1-6 is converted
POE glued membranes performance of photovoltaic module made from POE glued membranes made from comparative example 1-6 and respectively carries out contrast test.Contrast
Test result such as table 1 below：
Wherein, as shown in Figure 1, photovoltaic module includes ultra-clear glasses 1, light conversion POE glued membranes 2, monocrystalline or the polysilicon sun
Can cell piece 3, light conversion POE glued membranes 2, float glass or photovoltaic back 4；The ultra-clear glasses, light conversion POE glued membranes, monocrystalline
Or polysilicon solar battery slice, light conversion POE glued membranes, float glass or photovoltaic back are bonded successively from top to bottom；The light
Convert POE glued membranes and convert POE glued membranes for light prepared by embodiment 1-6.
The test result of table 1 embodiment 1-6 and comparative example 1-6
Component output power and the percentage (Cell To Module abbreviation CTM values) of cell piece power summation represent component
The degree of power loss, the degree of the higher expression component package power loss of CTM values are smaller.As can be seen from the above table, light converts
The addition of additive influences the basic performance of POE glued membranes without obvious, and CTM values are effectively improved also above contrast groups
The electricity conversion of component.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (9)
1. a kind of light converts POE glued membranes, it is characterised in that the light conversion POE glued membranes are prepared by the component of following parts by weight
Form：
2. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the melt index 5-100g/ of the POE resin
10min, fusing point are 50-115 DEG C.
3. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the organic per-compounds initiator is uncle
Butyl peroxy carbonic acid -2- ethylhexyls, tert-butyl hydroperoxide 2- ethylhexyls carbonic ester, t-butylperoxy formic acid 2- ethyls
Base ester, t-butylperoxy formic acid 2- ethylhexyls, carbon peroxy acid-O, O- (1,1- dimethyl ethyls)-O- (2- ethyl hexyls
Base) ester, tert-butyl hydroperoxide carbonic acid -2- ethylhexyls, it is more than one or both of tert-butyl peroxy carbonic acid -2- ethylhexyls
Mixture.
4. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the crosslinking coagent is the different trimerization of triisopropyl
Cyanate, Triallyl isocyanurate, iso-cyanuric acid triallyl ester, tri- -2- acrylic -1,3,5- triazines of 1,3,5- -
One in 2,4,6 (1H, 3H, 5H)-triketones, triallyl isocyanate, triallyl isocyanurate, triallyl isocyanurate
Kind or two or more mixtures.
5. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the thickening coupling agent is three ethoxy of vinyl
Silane, (triethoxysilyl) ethene, vinyltriethoxysilane, vinyl triethoxysilane, triethoxy ethene
Mixture more than one or both of silane, Triethoxyvinylsilane.
6. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the light stabilizer is stablized for hindered amines light
Agent, selected from double (2,2,6,6- tetramethyl -4- piperidine alcohols) sebacic acid esters, sebacic acid double -2,2,6,6- tetramethyl piperidine alcohol esters, 2-
Mixture more than one or both of (2 '-hydroxyl -5 '-aminomethyl phenyl)-benzotriazole.
7. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the UV absorbers are [2- hydroxyls -4-
(octyloxy) phenyl] phenyl ketone, 2-hydroxy-4-n-octoxybenzophenone, 2- hydroxyl -4- n-octyloxies Benzophenone, 3,5 2 uncles
Mixture more than one or both of butyl -4-HBA -2,4- 6- di-tert-butyl phenyl esters.
8. light as claimed in claim 1 converts POE glued membranes, it is characterised in that the smooth transformation additive for 4,8- dimethyl-
7- carboxyl cumarins.
9. a kind of photovoltaic module, it is characterised in that including ultra-clear glasses, light conversion POE glued membranes, monocrystalline or polycrystalline silicon solar electricity
Pond piece, light conversion POE glued membranes, float glass or photovoltaic back；The ultra-clear glasses, light conversion POE glued membranes, monocrystalline or polysilicon
Solar battery sheet, light conversion POE glued membranes, float glass or photovoltaic back are bonded successively from top to bottom；The light converts POE glue
Film is that claim 1-8 any one of them light such as converts POE glued membranes.
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|---|---|---|---|
| CN201711175906.7A CN108003801A (en) | 2017-11-22 | 2017-11-22 | A kind of light conversion POE glued membranes and its photovoltaic module of encapsulation |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109852289A (en) * | 2018-12-22 | 2019-06-07 | 中智(泰兴)电力科技有限公司 | A kind of monocrystalline silicon heterojunction solar cell generating electricity on two sides component package film and packaging technology |
| CN111073531A (en) * | 2019-12-11 | 2020-04-28 | 广州鹿山新材料股份有限公司 | Low-temperature curing POE (polyolefin elastomer) adhesive film and double-glass assembly packaged by same |
| CN112980339A (en) * | 2021-02-04 | 2021-06-18 | 浙江祥隆科技有限公司 | Packaging adhesive film with light diffusion and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863916A (en) * | 2012-09-14 | 2013-01-09 | 宁波威克丽特功能塑料有限公司 | POE (ethylene-octene copolymer) spectrum conversion solar cell packaging rubber film and preparation method thereof |
| CN104530995A (en) * | 2015-01-19 | 2015-04-22 | 苏州度辰新材料有限公司 | Solar cell encapsulation adhesive film and preparation method thereof |
| CN104927686A (en) * | 2015-05-21 | 2015-09-23 | 杭州福斯特光伏材料股份有限公司 | Solar cell packaging adhesive film with high light conversion efficiency |
| CN105400055A (en) * | 2014-09-08 | 2016-03-16 | 日东电工株式会社 | Sealing material composition for solar cells, sealing material layer for solar cells using same, and solar cell module |
| CN105684163A (en) * | 2013-10-30 | 2016-06-15 | 日东电工株式会社 | Wavelength-conversion encapsulant composition, wavelength-converted encapsulant layer, and solar cell module using same |
-
2017
- 2017-11-22 CN CN201711175906.7A patent/CN108003801A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863916A (en) * | 2012-09-14 | 2013-01-09 | 宁波威克丽特功能塑料有限公司 | POE (ethylene-octene copolymer) spectrum conversion solar cell packaging rubber film and preparation method thereof |
| CN105684163A (en) * | 2013-10-30 | 2016-06-15 | 日东电工株式会社 | Wavelength-conversion encapsulant composition, wavelength-converted encapsulant layer, and solar cell module using same |
| CN105400055A (en) * | 2014-09-08 | 2016-03-16 | 日东电工株式会社 | Sealing material composition for solar cells, sealing material layer for solar cells using same, and solar cell module |
| CN104530995A (en) * | 2015-01-19 | 2015-04-22 | 苏州度辰新材料有限公司 | Solar cell encapsulation adhesive film and preparation method thereof |
| CN104927686A (en) * | 2015-05-21 | 2015-09-23 | 杭州福斯特光伏材料股份有限公司 | Solar cell packaging adhesive film with high light conversion efficiency |
Non-Patent Citations (6)
| Title |
|---|
| 《高性能染料敏化太阳能电池的构筑及其光生电子传输特性》: "《高性能染料敏化太阳能电池的构筑及其光生电子传输特性》", 31 December 2014, 黑龙江大学出版社 * |
| 李子东 等: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 * |
| 梁兴泉等: "我国稀土光功能农膜的研究进展", 《广西大学学报（自然科学版）》 * |
| 邢凤兰 等: "《印染助剂》", 31 July 2008, 化学工业出版社 * |
| 陈治良: "《电泳涂装实用技术》", 30 September 2009, 上海科学技术出版社 * |
| 雷燕: "《实用化工材料手册 合成材料及其助剂》", 31 May 1994, 广东科技出版社 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109852289A (en) * | 2018-12-22 | 2019-06-07 | 中智(泰兴)电力科技有限公司 | A kind of monocrystalline silicon heterojunction solar cell generating electricity on two sides component package film and packaging technology |
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| CN116262871A (en) * | 2021-12-13 | 2023-06-16 | 阿特斯阳光电力集团股份有限公司 | Packaging adhesive film and preparation method and application thereof |
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| CN115717005A (en) * | 2022-12-02 | 2023-02-28 | 浙江省白马湖实验室有限公司 | Super-hydrophilic self-cleaning coating composition and preparation method thereof |
| CN117080312A (en) * | 2023-09-27 | 2023-11-17 | 中国科学院微电子研究所 | Photovoltaic device, packaging system and packaging method thereof |
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| CN117720474A (en) * | 2024-02-07 | 2024-03-19 | 江苏鹿山新材料有限公司 | Reactive light conversion material, light conversion packaging adhesive film and photovoltaic module |
| CN117720474B (en) * | 2024-02-07 | 2024-04-12 | 江苏鹿山新材料有限公司 | Reactive light conversion material, light conversion packaging adhesive film and photovoltaic module |
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