CN107997871A - A kind of eye-care fever tablet and preparation method - Google Patents
A kind of eye-care fever tablet and preparation method Download PDFInfo
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- CN107997871A CN107997871A CN201711209933.1A CN201711209933A CN107997871A CN 107997871 A CN107997871 A CN 107997871A CN 201711209933 A CN201711209933 A CN 201711209933A CN 107997871 A CN107997871 A CN 107997871A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F9/00—Methods or devices for treatment of the eyes; Devices for putting-in contact lenses; Devices to correct squinting; Apparatus to guide the blind; Protective devices for the eyes, carried on the body or in the hand
- A61F9/04—Eye-masks ; Devices to be worn on the face, not intended for looking through; Eye-pads for sunbathing
- A61F9/045—Eye-shades or visors; Shields beside, between or below the eyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F7/0241—Apparatus for the preparation of hot packs, hot compresses, cooling pads, e.g. heaters or refrigerators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F7/03—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction
- A61F7/032—Compresses or poultices for effecting heating or cooling thermophore, i.e. self-heating, e.g. using a chemical reaction using oxygen from the air, e.g. pocket-stoves
- A61F7/034—Flameless
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/16—Materials undergoing chemical reactions when used
- C09K5/18—Non-reversible chemical reactions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F2007/0001—Body part
- A61F2007/0002—Head or parts thereof
- A61F2007/0004—Eyes or part of the face surrounding the eyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F2007/0203—Cataplasms, poultices or compresses, characterised by their contents; Bags therefor
- A61F2007/0204—Cataplasms, poultices or compresses, characterised by their contents; Bags therefor containing clay, mud, fango, sand, kaolin clay, volcanic or other inorganic granular solids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F7/00—Heating or cooling appliances for medical or therapeutic treatment of the human body
- A61F7/02—Compresses or poultices for effecting heating or cooling
- A61F2007/0203—Cataplasms, poultices or compresses, characterised by their contents; Bags therefor
- A61F2007/0206—Cataplasms, poultices or compresses, characterised by their contents; Bags therefor containing organic solids or fibres
- A61F2007/0209—Synthetics, e.g. plastics
- A61F2007/0214—Polymers, e.g. water absorbing
Landscapes
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Thermal Sciences (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Biomedical Technology (AREA)
- Physics & Mathematics (AREA)
- Heart & Thoracic Surgery (AREA)
- Ophthalmology & Optometry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a kind of eye-care fever tablet and preparation method, fever content total amount is calculated by 1000g, consisted of the following compositions:Iron powder 180g 400g, fibrous material 30g 90g, activated carbon 50g 200g, water 300g 650g, wet strength agent 4g 12g, anionic coagulation agent 0.5g 2.0g, binder 1.0g 15.0g, electrolyte 5.0g 25.0g;It is coated on after fever content gelatinization by coating method on carrier, eye-care fever tablet is formed after re-dry.It is characteristic of the invention that fever weight is homogeneous, heating temp is stablized, and water vapour amount caused by fever is stablized, and is nursed suitable for eye health protection.Preparation method technique of the present invention is simple, and efficient, cost is low, is worth industrial production to be promoted.
Description
Technical field
The invention belongs to medical heating body technique field, is related to a kind of eye-care fever tablet and preparation method, for eye
Nurse in portion.
Background technology
The basic principle of spontaneous heating body is to utilize primary battery, and carbon makees cathode, and iron makees anode, and electrochemical corrosion occurs, makes iron
Oxidation rate accelerate, chemical energy is changed into thermal energy.
Such as CN201620717679.0, a kind of heating paste insole is disclosed, the heat object in heating paste applied in it
Matter is provided with gas-permeable nets, gas-permeable nets are provided outside to be mixed by iron powder, stone, activated carbon, inorganic salts, water etc. on heating paste
The diaphragm seal of heating paste is sealed, peel is provided with diaphragm seal.Open diaphragm seal as needed when in use, make heating paste and sky
Gas contacts, and generates heat so as to fulfill oxidation of iron powder.
Such as CN201410169753.5, disclose a kind of spontaneous heating patch, the spontaneous heating patch by iron powder, active powdered carbon,
Inorganic salts, vermiculite, konjaku flour, water composition, the weight percentage of each component are:Iron powder, 30%-50%;Active powdered carbon,
10%-20%;Inorganic salts, 13%-18%;Vermiculite, 5%-10%;Konjaku flour, 3%-10%;Water, 10%-15%.Konjaku flour
Water suction and water retention characteristic with super 80-100 times of own vol, can control spontaneous heating material in storage life and exothermic oxidation phase
Ambient humidity.
The various heating pastes being made using the principle or other heaters of spontaneous heating body or fever tablet etc., application range
Extensively, it can be not only used for body heating, it may also be used for body local is nursed.
Such as apply and carry out nursing cover glass in people's eye, CN201620215008.4, discloses a kind of with physical therapy work
Cover glass, is equipped with the graphene euthermic chip with physiotherapy function in eyeshade body, on the graphene euthermic chip
End is equipped with Ai Xiang layers of Chinese medicine therapy covering, liposuction gas phase alundum (Al2O3) layer and lavender successively;For human body eye-care.
The applicant is devoted for years to, in the research of eyeshield medication, obtain by technological innovation of the invention.
The content of the invention
The object of the present invention is to provide the eye-care fever tablet and preparation method of a kind of stable quality.
The present invention is achieved in that a kind of eye-care fever tablet, fever content total amount by 1000g calculating, by with
Lower component composition:
It is coated on after fever content gelatinization by coating method on carrier, eye-care fever tablet is formed after re-dry.
Further, fibrous material is natural plant fibre, and wet strength agent is polyamine epichlorohydrin resin, and electrolyte is
Sodium chloride, anionic coagulation agent are sodium carboxymethylcellulose.
Further, binder selects water dissolvable adhesive or hot melt binder;Water dissolvable adhesive includes starch, paste
Essence, polyvinyl alcohol, polyethylene glycol, povidone, xanthans, animal glue and hydroxypropyl methylcellulose;Hot melt binder includes poly- ammonia
Ester, polystyrene, polyacrylate and ethene-acetate ethylene copolymer.
Further, iron particle size is 1~300 μm;Carbon dust Powder Particle Size is 1~850 μm.
Further, iron particle size is 50~200 μm;Carbon dust Powder Particle Size is 50~350 μm.
Further preferably, content total amount of generating heat is calculated by 1000g, and component is as follows:
Further preferably, content total amount of generating heat is calculated by 1000g, and component is as follows:
A kind of preparation method of eye-care fever tablet,
(1) water, polyamine epichlorohydrin resin, fibrous material, activated carbon are mixed at normal temperatures, stirred evenly;
Binder, sodium carboxymethylcellulose and iron powder are added, is sufficiently stirred into pastel;
(2) pastel is uniformly coated on carrier, thickness control in 0.8mm-1.8mm scopes, coated carrier into
Enter after baking oven is segmented is dried at different temperature, water content control cuts into suitable size tablet below 5%;
(3) by adding sodium chloride solution and being wrapped up with ventilated membrane on each tablet, sent out up to eye-care
Backing;
(4) start to generate heat after running into air when eye-care fever uses, temperature continues between rising to 40~50 DEG C
Suitable vapor is produced for a period of time and during fever, there is promotion ocular circulation, moisten eye skin effect.
Carrier used is a kind of in paper, non-woven fabrics, breathable films when pastel is coated with preparation method.
Further preferably, the condition of different temperatures stage drying is:
First with 80~90 DEG C baking 3~7min, then with 90~100 DEG C baking 3~7min, finally with 105~115 DEG C dry 3~
7min, drying time are controlled in 9~21min.
Further preferably, the condition of different temperatures stage drying is:First with 80~90 DEG C of 4~6min of baking, then with 90~100
DEG C dry 4~6min, finally with 105~115 DEG C baking 4~6min, drying time control in 12~18min.
The present invention gropes to Suitable ingredients and suitable dosage by repetition test, the suitable eye of stable quality is made
The heater that portion uses, technique is simple, efficient, and cost is low, is worth industrial production to be promoted.
The invention is analyzed:
Just be conceived at the beginning of present invention design, when use run into air after start to generate heat, temperature rises to 40~50 DEG C
Between continue for some time and certain vapor produced during fever, have promotion ocular circulation, moisten eye
Skin acts on.
Therefore, if the water content of heater and the control of moisturizer dosage are improper, in view of hermetic bag cannot 100% prevent it is saturating
Gas, fever tablet will cause hardness larger in storage process because moisture loss is more, and such fever tablet is not easy with eye
Shape is bent, be worn over it is long on eyes have uncomfortable sensation, can also influence heat insulation effect, the easy side leakage of vapor.
This requires that heater is neither too hard, nor too soft, and can be appropriately curved according to eye shape, so that manufactured eyeshade energy
Enough it is close to eye circumference, steam parcel eyes surrounding, can moisten eye circumference skin, deep layer sub-percolation maintenance, alleviates asthenopia;Steamed with tradition
Vapour phase ratio, is not in the phenomenon that overheat, hot etc. cause burn of the eye, and effect is releived, and protects the tender and lovely skin of eye.In order to up to
To above technique effect, by the effort of inventor, after the content gelatinization that will generate heat, it is coated on carrier, passes through
Eye-care fever tablet is formed after drying.
Spreading formation process of the present invention and existing compressing technique and copy in fever in moulding process processed
Tolerant all moisture content containing larger proportion, it is sheet to be both needed to by drying and moulding.Inventor has found to start just to use the prior art
In 105~115 DEG C of temperature drying, fever tablet in the state of High water cut directly contact high temperature, understand because of heater uneven heating
And wrinkle, and it is difficult to control the water content of fever tablet after drying.By grope experimental study find, drying condition by low temperature to compared with
The stage drying technique of high-temperature, solves the problems, such as that fever tablet hardness is excessive and wrinkles well, meanwhile, facilitate water content control
System is below 5%.
In short, advantages of the present invention:
1. coating process speed is fast, production efficiency is high, it is adapted to flow line production;Coating process to reach large area equal
Even property and can large scale production;
2. eye-care fever tablet thickness is uniform made from coating process, heating temp is stablized;
3. the material of coating process consumption is few, production cost is low;
4. the sodium chloride of a catalytic action adds after eye-care fever tablet is dried and cuts shaping, prevent and other things
One piece of material adds and causes the situation that partial oxidation reaction is occurred as soon as in drying course, avoids influencing the heating effect of finished product;
5. by the way of different temperatures segmentation drying, eye-care fever tablet can be avoided to wrinkle, and from being relatively easy to control dry
The water content of eye-care fever tablet after dry.
Brief description of the drawings
Fig. 1 is fever tablet cross section structure figure of the present invention;
Fig. 2 is fever tablet side block diagram of the present invention;
Fig. 3 is fever tablet structure diagram of the present invention;
Fig. 4 is the embodiment of the present invention 1,2 fever tablet heating temp time history plots;
Fig. 5 is 3,4,5 fever tablet heating temp time history plot of the embodiment of the present invention.
Embodiment
By specific examples below, the invention will be further described, but the embodiment be merely to illustrate the present invention and
It is not the limitation present invention.
Embodiment 1
【Formula】
【Preparation method】
(1) water, polyamine epichlorohydrin resin, fibrous material, activated carbon are mixed at normal temperatures, stirred evenly;
Binder, sodium carboxymethylcellulose and iron powder are added, is sufficiently stirred into pastel;
(2) pastel is uniformly coated in appropriate carrier, thickness control is in 0.8mm-1.8mm scopes, coated load
Body is segmented (water content control is below 5%) after progress is sufficiently dried at different temperature into baking oven, and it is suitable to cut into
Size tablet;
(3) appropriate sodium chloride solution is added and with breathing freely by the method that sprays, spray or be added dropwise on each tablet
Film is wrapped up, up to eye-care fever tablet.
【Application method】Starting to generate heat after running into air during use, 2.8-3.4min temperature rises to 40 DEG C or so,
Between 40~50 DEG C, continue 24.7-25.7min, and the vapor of 0.3g~0.5g or so is produced during fever.
Embodiment 2
【Formula】
【Application method】Starting to generate heat after running into air during use, 2.9-3.5min temperature rises to 40 DEG C or so,
Between 40~50 DEG C, duration 19.3-20.3min, and the water of generation 0.3g~0.5g or so steams during fever
Gas.
Embodiment 3
【Formula】
【Application method】Starting to generate heat after running into air during use, 2.1-2.7min temperature rises to 40 DEG C or so,
Between 40~50 DEG C, duration 15.7-16.7min, and the water of generation 0.2g~0.3g or so steams during fever
Gas.
Embodiment 4
【Formula】
【Application method】Starting to generate heat after running into air during use, 2.5-3.1min temperature rises to 40 DEG C or so,
Between 40~50 DEG C, duration 14.1-15.1min, and the water of generation 0.3g~0.5g or so steams during fever
Gas.
Embodiment 5
【Formula】
【Application method】Starting to generate heat after running into air during use, 2.7-3.3min temperature rises to 40 DEG C or so,
Between 40~50 DEG C, duration 19.9-20.9min, and 0.3g~0.5g or so vapor is produced during fever.
It should be noted that described above is presently preferred embodiments of the present invention, the invention is not limited in above-mentioned
Embodiment, as long as it reaches the technique effect of the present invention with identical means, should all belong to protection scope of the present invention.
Claims (11)
1. a kind of eye-care fever tablet, its characteristic are, fever content total amount is calculated by 1000g, by following component group
Into:
It is coated on after fever content gelatinization by coating method on carrier, eye-care fever tablet is formed after re-dry.
2. a kind of eye-care fever tablet according to claim 1, it is characterised in that fibrous material is fine for natural plants
Dimension, wet strength agent is polyamine epichlorohydrin resin, and electrolyte is sodium chloride, and anionic coagulation agent is sodium carboxymethylcellulose.
3. a kind of eye-care fever tablet according to claim 1, it is characterised in that binder selects water dissolvable adhesive
Or hot melt binder;Water dissolvable adhesive includes starch, dextrin, polyvinyl alcohol, polyethylene glycol, povidone, xanthans, animal
Glue and hydroxypropyl methylcellulose;It is common that hot melt binder includes polyurethane, polystyrene, polyacrylate and ethene-vinyl acetate
Polymers.
4. a kind of eye-care fever tablet according to claim 1, it is characterised in that iron particle size is 1~300 μm;Carbon
Powder Particle Size is 1~850 μm.
5. a kind of eye-care fever tablet according to claim 4, it is characterised in that iron particle size is 50~200 μm;Carbon
Powder Particle Size is 50~350 μm.
6. according to a kind of any eye-care fever tablets of claim 1-5, it is characterised in that fever content total amount is pressed
1000g is calculated, and component is as follows:
7. according to a kind of any eye-care fever tablets of claim 1-5, it is characterised in that fever content total amount is pressed
1000g is calculated, and component is as follows:
8. according to a kind of preparation method of any eye-care fever tablets of claim 1-7, it is characterised in that:
(1) water, polyamine epichlorohydrin resin, fibrous material, activated carbon are mixed at normal temperatures, stirred evenly;Add
Binder, sodium carboxymethylcellulose and iron powder, are sufficiently stirred into pastel;
(2) pastel is uniformly coated on carrier, in 0.8mm-1.8mm scopes, coated carrier enters to be dried thickness control
Case is segmented at different temperature be dried after, water content control cuts into suitable size tablet below 5%;
(3) by adding sodium chloride solution and being wrapped up with ventilated membrane on each tablet, up to eye-care fever tablet;
(4) start to generate heat after running into air when eye-care fever uses, temperature continues one section between rising to 40~50 DEG C
Time and suitable vapor is produced during fever, there is promotion ocular circulation, moisten eye skin effect.
Load used when 9. pastel is coated with a kind of eye-care fever piece preparation method according to claim 1 and 8
Body is paper, a kind of in non-woven fabrics, breathable films.
10. preparation method according to claim 8, it is characterised in that the condition of different temperatures stage drying is:
3~7min first are dried with 80~90 DEG C, then 3~7min are dried with 90~100 DEG C, finally with 105~115 DEG C of 3~7min of baking, are dried
Dry time control is in 9~21min.
11. preparation method according to claim 8, it is characterised in that the condition of different temperatures stage drying is:First with 80
~90 DEG C of 4~6min of baking, then 4~6min are dried with 90~100 DEG C, finally with 105~115 DEG C of 4~6min of baking, drying time control
In 12~18min.
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CN201711209933.1A CN107997871B (en) | 2017-11-27 | 2017-11-27 | Eye care heating sheet and preparation method thereof |
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CN107997871B CN107997871B (en) | 2020-09-15 |
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Cited By (7)
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---|---|---|---|---|
CN108743027A (en) * | 2018-05-15 | 2018-11-06 | 威莱(广州)日用品有限公司 | A kind of steam eye patch and preparation method thereof |
CN109456739A (en) * | 2018-10-22 | 2019-03-12 | 清华大学 | Spontaneous hotting mask of temperature control based on inorganic-phase variable and preparation method thereof |
CN109589203A (en) * | 2018-10-22 | 2019-04-09 | 清华大学 | The heating paste of temperature control film and the spontaneous hotting mask of constant temperature based on organic phase-change |
CN109620522A (en) * | 2018-10-22 | 2019-04-16 | 清华大学 | A kind of spontaneous hotting mask of paper-like and preparation method thereof |
CN109620537A (en) * | 2019-01-17 | 2019-04-16 | 上饶市护康实业有限公司 | A kind of steam eye patch and preparation method thereof |
CN109620526A (en) * | 2019-01-17 | 2019-04-16 | 上饶市护康实业有限公司 | A kind of preparation method of sheet fever tablet |
CN109646180A (en) * | 2019-02-02 | 2019-04-19 | 广州生美生物科技有限公司 | A kind of graphene steam eye patch and preparation method thereof |
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CN108743027A (en) * | 2018-05-15 | 2018-11-06 | 威莱(广州)日用品有限公司 | A kind of steam eye patch and preparation method thereof |
CN108743027B (en) * | 2018-05-15 | 2019-11-01 | 威莱(广州)日用品有限公司 | A kind of steam eye patch and preparation method thereof |
CN109456739A (en) * | 2018-10-22 | 2019-03-12 | 清华大学 | Spontaneous hotting mask of temperature control based on inorganic-phase variable and preparation method thereof |
CN109589203A (en) * | 2018-10-22 | 2019-04-09 | 清华大学 | The heating paste of temperature control film and the spontaneous hotting mask of constant temperature based on organic phase-change |
CN109620522A (en) * | 2018-10-22 | 2019-04-16 | 清华大学 | A kind of spontaneous hotting mask of paper-like and preparation method thereof |
CN109620537A (en) * | 2019-01-17 | 2019-04-16 | 上饶市护康实业有限公司 | A kind of steam eye patch and preparation method thereof |
CN109620526A (en) * | 2019-01-17 | 2019-04-16 | 上饶市护康实业有限公司 | A kind of preparation method of sheet fever tablet |
CN109646180A (en) * | 2019-02-02 | 2019-04-19 | 广州生美生物科技有限公司 | A kind of graphene steam eye patch and preparation method thereof |
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