CN107987746A - A kind of glass cloth rubber belt and its production technology - Google Patents
A kind of glass cloth rubber belt and its production technology Download PDFInfo
- Publication number
- CN107987746A CN107987746A CN201711377637.2A CN201711377637A CN107987746A CN 107987746 A CN107987746 A CN 107987746A CN 201711377637 A CN201711377637 A CN 201711377637A CN 107987746 A CN107987746 A CN 107987746A
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- Prior art keywords
- glass cloth
- primer
- gasoline
- solution
- glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 48
- 239000011521 glass Substances 0.000 title claims abstract description 48
- 239000004744 fabric Substances 0.000 title claims abstract description 47
- 239000005060 rubber Substances 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 238000005516 engineering process Methods 0.000 title claims abstract description 13
- 239000003292 glue Substances 0.000 claims abstract description 67
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 6
- 238000004804 winding Methods 0.000 claims abstract description 6
- 238000005520 cutting process Methods 0.000 claims abstract description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 111
- 239000000243 solution Substances 0.000 claims description 77
- 239000011347 resin Substances 0.000 claims description 69
- 229920005989 resin Polymers 0.000 claims description 68
- 239000011259 mixed solution Substances 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 33
- 150000003505 terpenes Chemical class 0.000 claims description 32
- 235000007586 terpenes Nutrition 0.000 claims description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 29
- 229920001568 phenolic resin Polymers 0.000 claims description 27
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 claims description 26
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 26
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 20
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 16
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 229920005549 butyl rubber Polymers 0.000 claims description 14
- 239000012895 dilution Substances 0.000 claims description 12
- 238000010790 dilution Methods 0.000 claims description 12
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 12
- 239000011787 zinc oxide Substances 0.000 claims description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 9
- 239000004927 clay Substances 0.000 claims description 8
- 229920002681 hypalon Polymers 0.000 claims description 8
- 229920002367 Polyisobutene Polymers 0.000 claims description 7
- 235000021355 Stearic acid Nutrition 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 7
- 239000008117 stearic acid Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000011592 zinc chloride Substances 0.000 claims description 6
- 235000005074 zinc chloride Nutrition 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 238000001514 detection method Methods 0.000 claims description 2
- 230000000704 physical effect Effects 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 10
- 238000012545 processing Methods 0.000 abstract description 8
- 230000001680 brushing effect Effects 0.000 abstract description 6
- 230000006835 compression Effects 0.000 abstract description 6
- 238000007906 compression Methods 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000012856 packing Methods 0.000 abstract description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 14
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000002390 adhesive tape Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 8
- 235000010215 titanium dioxide Nutrition 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000005011 phenolic resin Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000010074 rubber mixing Methods 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000012945 sealing adhesive Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/168—Zinc halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/14—Glass
- C09J2400/143—Glass in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/006—Presence of polyolefin in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to the production preparation of cellotape, more specifically, it is related to a kind of glass cloth rubber belt and its production technology, need to prepare in face glue and primer before the whole technique processing of this product and complete, the glue configured is applied on glass cloth by coating machine, and wound by the glass cloth that winder finishes brushing, the brushing surface glue on the glass cloth end face of brushing primer again, winding is carried out by winder again and is shaped to glass cloth rubber belt, glass cloth rubber belt is cut, those glass cloth rubber belts after cutting are subjected to resistance to compression again, stretch-proof, the physics such as conductivity and chemical property are checked, qualified products and substandard product at classification, qualified products carry out packing processing, substandard product is recycled.
Description
Technical field
The present invention relates to the production preparation of cellotape, more specifically, it relates to a kind of glass cloth rubber belt and its production
Technique.
Background technology
Early in nineteen twenty-eight, American Richard has just invented adhesive tape in Shandong in Minnesota Sao Paulo.Adhesive tape presses it
Effect classification can be divided into：High temperature gummed tape, two-sided tape, insulating tape, specialty tape, pressure sensitive adhesive tape, cross cutting adhesive tape etc., it is different
The effect of adhesive tape be adapted to different industry requirements.One layer of sticker is scribbled on tape surface, adhesive tape could be made to cling article,
Earliest sticker comes from animal and plant.19th-century, rubber are the main ingredient of sticker, and modern then extensively using each
Kind polymer.Sticker can cling thing, be due to that the intermolecular formation of the molecule of itself and article to be connected is bonded, this
Bond can firmly stick together molecule.
Such as in joint sealing adhesive tape used in everyday, wire insulation electrical adhesive tape.With the development of polymer chemistry,
The progress of bonding technique and process equipment, adhesive tape is in packaging, printing, automobile, household electrical appliances, electronics, medical treatment, aviation, building, telecommunication
The industries such as equipment are used widely, so the adhesive article used at the position that many commodity and place are invisible to the naked eye is gradual
Increase.
Solvent type pressure-sensitive adhesive of rubber series stick is all by various rubber elastomers and tackifying resin, softening agent, antioxidant, filling
Dissolving is mixed the additives such as agent, colouring agent in organic solvent according to a certain ratio, industrially.Solvent-borne type rubber pressure sensitive glue has
Two kinds of manufacture methods：
1. it is that solid block raw rubber is first cut into fritter and is plasticated on rubber mixing machine.Cut off again after adjustment molecular weight
Cut into pieces on machine, then dissolved in mixing kettle is dissolved with organic solvent, and be mixed into solvent misture and other additives, stir
Adjusted again with organic solvent to required viscosity and solids content after uniformly.
2. being that first solid rubber elastomeric body is cut into small pieces, and tackifying resin is directly mixed in after being plasticated on rubber mixing machine
And other additives are kneaded again, are dissolved and mixed with organic solvent in mixing kettle is dissolved after then glue stuff compounding is shredded
Uniformly.
The pressure sensitive adhesive heat resistance that above two manufacture method produces is poor, every physical index and its undesirable, in tide
It is easily deformed and comes off in wet environment, needs to be unlikely to be peel off when peeling after use, also easily left after peeling off by force
Stick together trace.
The content of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of manufacturing procedure to arrange reasonable, implementation
Simplicity, the adhesive-layer in adhesive tape have good an adhesive property and sealing performance, the lasting glass cloth glue of the service life of adhesive tape
Band and its production technology.
To achieve the above object, the present invention provides following technical solution：
A kind of glass cloth rubber belt, glass cloth rubber belt includes the base material made of glass cloth, coated on the primer on base material and face glue,
The face glue is prepared by the composition that following precentagewise configures：
The primer is prepared by the composition of following parts by weight：
Butyl rubber：Butyl rubber is one kind of synthetic rubber, is synthesized by isobutene and a small amount of isoprene, has good change
Learn stability and heat endurance.
Butadiene-styrene rubber：Have the advantages that ageing-resistant performance is good, water imbibition is low and oil resistant, plasticizer-resistant.Work as styrene-content
Gao Shi, its creep-resistant property is fine, and price is also than relatively low.Therefore, butylbenzene glue elastomer often has preferably resistance to requirement
Plasticizer, ageing-resistant and water resistance pressure-sensitive adhesive agent.The anti-of sub- quick glue can be improved by adding the butadiene-styrene rubber of high-content styrene
Croop property, improves ageing-resistant performance.
Neoprene：Neoprene is wide as adhesive applications scope, has the characteristics that initial adhesion force is big, bond strength is high.Neoprene
The structure of glue is more regular, and the chlorine atom that polarized is larger, therefore crystallinity is high, it is just had preferable cementability at room temperature
It can be particularly suitable for making adhesive with larger cohesive strength.
Clay：Containing irony with tones such as yellowish-brown, canescence, reddish violet, the clay with good plasticity.
Calcium carbonate：Calcium carbonate is a kind of inorganic compound, is commonly called as：Lime stone, lime stone, mountain flour, marble etc..Mainly into
Point：Calcite, chemical formula are CaCO3, it is in neutrality, is substantially insoluble in, is dissolved in hydrochloric acid.It works as in rubber pressure-sensitive adhesive mixing
In its main filling support purpose.
Stearic acid：Sterling is the wax-like small pieces crystalline solid of white slightly gloss, and stearic acid is natural gum, synthetic rubber and glue
Widely applied vulcanizing activator in breast, it is also possible to make plasticizer and softening agent.Stiffened fat is needed during synthetic rubber is produced
Acid makees emulsifying agent, and in rubber pressure-sensitive adhesive, stearic acid can make releasing agent.
Zinc oxide：Zinc oxide is a kind of white filler, but the vulcanization to rubber has facilitation, thus its use can increase
Add the cohesive force and heat resistance of pressure sensitive adhesive.Zinc oxide can also neutralize the acidity of rosin, reduce stimulation of the rosin to skin；Oxygen
Change zinc and also have slight antiseptic property.Due to the above-mentioned multiple functions of zinc oxide, in natural rubber pressure sensitive adhesive, it is a kind of
Indispensable filler.
O-phthalic acid dibutyl ester:Universal plasticizer, is mainly used for the processing of polyvinyl chloride fat, can be additionally used in Hua Dishu
The processing of the high polymers such as fat, acetate resin, ABS resin and rubber.
Polyisobutene：It is through just from polymer made from polymerization as isobutene, its molecular weight can be from hundreds of to millions of.
It is a kind of typical saturation linear polymer.Can improve the resistance to ag(e)ing of rubber under high temperature, weatherability, resist bending breaking property,
The dielectric properties of ozone resistants, rubber, reduce its absorption to water and the infiltration to gas.
Chlorosulfonated polyethylene：Chlorosulfonated polyethylene is by low density polyethylene (LDPE) or high density polyethylene (HDPE) through superchlorination and chlorosulfonation
Reaction is made.For white or yellow elastic body, aromatic hydrocarbon can be dissolved in and chlorohydrocarbon is not dissolved in fat and alcohol, in ketone and ether
Can only be swollen to dissolve, and have excellent ozone resistance, resistance to weathering, chemical resistance etc., preferable physical mechanical
Performance, ageing-resistant performance, heat-resisting and lower temperature resistance, oil resistivity, flame resistance, wearability and resistance to electrical insulating property.Improve pressure sensitive adhesive
Processing performance, the cryogenic property of vulcanizate, and improve its elasticity and reduce hardness.
Titanium dioxide：Titanium dioxide is also known as titanium dioxide, is a kind of most common high-quality white inorganic pigment.Although it is also one
Kind filler, but using its purpose primarily to coloring.
Terpene resin：Terpene-phenolic resin is modified terpene resin, and the incorporation of phenolic resin increases the pole of fourth resin
Property, the cohesive strength for increasing pressure sensitive adhesive is contributed, can also increase the compatibility with butadiene-styrene rubber.Terpene-phenolic resin and terpene
Olefine resin is used with, holding power and the peel strength increase of pressure sensitive adhesive, but initial bonding strength does not reduce.The more terpene of phenolic resin content
Alkene-phenolic resin is more suitable for making the tackifying resin of butadiene-styrene rubber.
Solvent misture is that rubber pressure-sensitive adhesive sticks another most important component in agent in addition to main rubber elastomer, it
Main function assigns pressure sensitive adhesive with necessary stickiness.Just make mixture just because of solvent misture has been mixed into rubber elastomer
System just becomes a real pressure-sensitive adhesive agent to producing necessary original viscosity and cohesive force by viscous material surface.
A kind of production technology suitable for glass cloth rubber belt includes the following steps：
A. while glass cloth is shaped and examined, primer is configured,
B. primer is coated to glass cloth,
C. after step b, glass cloth is subjected to first time winding,
D. the glass cloth after winding is coated face glue,
E. after step d, glass cloth is carried out second and is wound,
F. the glass cloth after second winds is carried out cutting into specification needed for finished product,
G. finished product is detected into its chemical property and physical property by detection device, and classify qualified products and scrap products,
H. qualified products are packed, substandard product recycling.
The present invention is further：The preparation process following steps of the face glue：
(1) face glue modeling is practiced：Butyl rubber is plasticated 15-20min first, butadiene-styrene rubber is plasticated 5min, and neoprene is plasticated 5min, then will
Three is kneaded 10min, then by clay, polyisobutene in, the powder such as calcium carbonate, stearic acid, zinc oxide, o-phthalic acid dibutyl ester
It is stirred with said mixture and thin after 5min leads into face film；
(2) it is beaten：The gasoline of 40-80kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form face sol solution,
During above-mentioned face sol solution matches, terpene resin, para-tertiary butyl phenol formaldehyde resin and 15-25kg dilution with toluene are mixed simultaneously
1.5 hours composition resin solutions of stirring are spare,
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 10-25kg gasoline is added and is stirred 3-4 days
So that after face film dissolves completely, add 20-40kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
Obtain face glue glue.
The present invention is further：The preparation process following steps of the primer：
(1) primer modeling is practiced：Butyl rubber to be plasticated 15-20min first, butadiene-styrene rubber is plasticated 5min, then both are kneaded 10min,
Chlorosulfonated polyethylene, zinc chloride, calcium carbonate, o-phthalic acid dibutyl ester, titanium dioxide are stirred in said mixture again
It is thin after 5min to lead into primer piece,
(2) it is beaten：The gasoline of 40-80kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form primer solution,
During above-mentioned primer solution ratio, terpene resin, para-tertiary butyl phenol formaldehyde resin and 15-25kg dilution with toluene are mixed simultaneously
1.5 hours composition resin solutions of stirring are spare,
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 10-25kg gasoline is added and is stirred 3-4 days
So that after face film dissolves completely, add 20-40kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
Obtain primer glue.
The present invention is further：The percentage of face glue glue proportioning is：Face film 20%-30%, terpene resin 5%
- 10%, para-tertiary butyl phenol formaldehyde resin 1%-3%, mixed solution 60%-75%, the mixed solution are mixed by toluene and gasoline
Form, the percentage that wherein toluene matches in mixed solution is 15%, and the percentage that gasoline matches in mixed solution is
75%.
A kind of production technology suitable for glass cloth rubber belt according to claim 4, it is characterized in that：The primer glue
Liquid proportioning percentage be：Primer piece 20%-30%, terpene resin 5%-10%, para-tertiary butyl phenol formaldehyde resin5%-10%, mix
Close solution 60%-75%, the mixed solution by toluene and gasoline mixing form, wherein toluene matched in mixed solution hundred
Divide than being 15%, the percentage that gasoline matches in mixed solution is 75%
The present invention is further：The face glue is prepared by the composition that following precentagewise configures：
The present invention is further：Primer is prepared by the composition of following parts by weight：
The deficiencies in the prior art are contrasted, beneficial effects of the present invention are：
The glass cloth rubber belt of the present invention is extremely strong with extremely strong adhesion strength, tensile strength in use.Also have good
Proof voltage ability, temperature resistant capability.
Brief description of the drawings
Fig. 1 is adhesive process flow diagram in face of the present invention.
Fig. 2 is primer process flow diagram of the present invention.
Embodiment
Embodiment 1：Glass cloth rubber belt includes the base material made of glass cloth, coated on the primer on base material and face glue,
Need to prepare in face glue and primer before the whole technique processing of this product and complete,
The preparation process following steps of face glue：
1st, face glue modeling is practiced：30% butyl rubber is plasticated 15min first, the neoprene that 15% butadiene-styrene rubber is plasticated with 0.5%
5min is practiced in modeling, then three is kneaded 10min, by 6% clay, 6% polyisobutene, 6% calcium carbonate, 0.3% tristearin
Acid, 1.6% zinc oxide, the powder such as 3% o-phthalic acid dibutyl ester and said mixture are stirred thin after 5min lead into
Face film,
2nd, it is beaten：The gasoline of 40kg is added in mixer, face film is chipped in mixer and dissolving is mixed in gasoline
2h forms face sol solution.While in face, sol solution matches, in another small mixer, by terpene resin, para-tertiary butyl phenol formaldehyde
It is spare that resin and 15kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution send to mixer knead dough sol solution and carries out mixing 2h, adds 10kg gasoline and is stirred 3 angels
After face film dissolves completely, add 20kg gasoline and carry out thin stirring, solution is obtained by filtration twice after stirring 1.5h
Face glue glue.
The per distribution ratio of each element is during the glue glue proportioning of face：Face film 20%, terpene resin 5%, para-tertiary butyl phenol
Formaldehyde resin 1%, mixed solution 74%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is matched somebody with somebody in mixed solution
The percentage of ratio is 15%, and the percentage that gasoline matches in mixed solution is 75%.Since toluene and gasoline are in mixing match
During have part volatilization, as long as so both total amounts for reaching of proportioning of control.
The preparation process following steps of primer：
1st, primer modeling is practiced：40 parts of butyl rubbers are plasticated 15min first, 10 parts of butadiene-styrene rubbers are plasticated 5min, then both are kneaded
10min, then by 1 part of terpene resin, 1 part of para-tertiary butyl phenol formaldehyde resin, 3 parts of chlorosulfonated polyethylenes and its be stirred, finally by 5
Part zinc chloride, 5 parts of calcium carbonate, 1 part of o-phthalic acid dibutyl ester, 5 parts of titanium dioxides and said mixture are stirred thin after 5min
Lead into primer piece.
2nd, it is beaten：The gasoline of 40kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form primer solution.While primer solution ratio, in another small mixer, by terpene resin, para-tertiary butyl phenol
It is spare that formaldehyde resin and 15kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 10kg gasoline is added and is stirred 3 days
So that after face film dissolves completely, add 20kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
To primer glue.
The per distribution ratio of each element is during primer glue proportioning：Primer piece 20%, terpene resin 5%, para-tertiary butyl phenol
Formaldehyde resin 2%, mixed solution 73%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is matched somebody with somebody in mixed solution
The percentage of ratio is 15%, and the percentage that gasoline matches in mixed solution is 75%.
The primer liquid configured is applied on glass cloth by coating machine, and the glass finished by winder to brushing
Cloth is wound, then the brushing surface glue on the glass cloth end face of brushing primer, then is carried out winding by winder and be shaped to glass
Glass cloth rubber belt, cuts glass cloth rubber belt, then those glass cloth rubber belts after cutting are carried out resistance to compression, stretch-proof, conduction
The physics such as rate and chemical property are checked that qualified products and substandard product at classification, qualified products carry out packing processing, no
Qualified products are recycled.
The substandard product occupation rate occurred among this embodiment is 5%.The compression strength of finished product is 200N/10mm,
Rate 7% is stretched in fracture, and heatproof is 150 °, proof voltage 1KV, adhesion rate 5N/25mm.
Embodiment two：
1st, face glue modeling is practiced：45% butyl rubber is plasticated 20min first, the neoprene modeling that 30% butadiene-styrene rubber is plasticated with 4%
Practice 5min, then three is kneaded 10min, by 15% clay, 15% polyisobutene, 20% calcium carbonate, 0.7% tristearin
Acid, 2.3% zinc oxide, the powder such as 7% o-phthalic acid dibutyl ester and said mixture are stirred thin after 5min lead into
Face film,
2nd, it is beaten：The gasoline of 80kg is added in mixer, face film is chipped in mixer and dissolving is mixed in gasoline
2h forms face sol solution.While in face, sol solution matches, in another small mixer, by terpene resin, para-tertiary butyl phenol formaldehyde
It is spare that resin and 25kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution send to mixer knead dough sol solution and carries out mixing 2h, adds 25kg gasoline and is stirred 4 angels
After face film dissolves completely, add 40kg gasoline and carry out thin stirring, solution is obtained by filtration twice after stirring 1.5h
Face glue glue.
The per distribution ratio of each element is during the glue glue proportioning of face：Face film 20%, terpene resin 5%, para-tertiary butyl phenol
Formaldehyde resin 1%, mixed solution 74%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is matched somebody with somebody in mixed solution
The percentage of ratio is 15%, and the percentage that gasoline matches in mixed solution is 75%.
The preparation process following steps of primer：
1st, primer modeling is practiced：50 parts of butyl rubbers are plasticated 20min first, 20 parts of butadiene-styrene rubbers are plasticated 5min, then both are kneaded
10min, then by 8 parts of terpene resins, 6 parts of para-tertiary butyl phenol formaldehyde resins, 5 parts of chlorosulfonated polyethylenes and its be stirred, finally by 7
Part zinc chloride, 15 parts of calcium carbonate, 9 parts of o-phthalic acid dibutyl esters, 8 parts of titanium dioxides and said mixture are stirred thin after 5min
Lead into primer piece.
2nd, it is beaten：The gasoline of 80kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form primer solution.While primer solution ratio, in another small mixer, by terpene resin, para-tertiary butyl phenol
It is spare that formaldehyde resin and 15kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 25kg gasoline is added and is stirred 4 days
So that after face film dissolves completely, add 40kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
To primer glue.
The per distribution ratio of each element is during primer glue proportioning：Primer piece 30%, terpene resin 9%, para-tertiary butyl phenol
Formaldehyde resin 1%, mixed solution 60%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is matched somebody with somebody in mixed solution
The percentage of ratio is 15%, and the percentage that gasoline matches in mixed solution is 75%.
In process of production, primer knead dough glue is during thin lead to, it is necessary to spend the 2 of opposite embodiment 1 for the present embodiment two
Times time.Production efficiency is not high.The compression strength of finished product is 250N/10mm, and rate 3% is stretched in fracture, and heatproof is 180 °, proof voltage
2KV, adhesion rate 7N/25mm.
Embodiment three：
1st, face glue modeling is practiced：35% butyl rubber is plasticated 17min first, the neoprene that 20% butadiene-styrene rubber is plasticated with 0.7%
5min is practiced in modeling, then three is kneaded 10min, by 10% clay, 10% polyisobutene, 10% calcium carbonate, 0.4%
The powders such as stearic acid, 2% zinc oxide, 4% o-phthalic acid dibutyl ester and said mixture are stirred thin logical after 5min
Into face film,
2nd, it is beaten：The gasoline of 60kg is added in mixer, face film is chipped in mixer and dissolving is mixed in gasoline
2h forms face sol solution.While in face, sol solution matches, in another small mixer, by terpene resin, para-tertiary butyl phenol formaldehyde
It is spare that resin and 20kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 25kg gasoline is added and is stirred 4 days
So that after face film dissolves completely, add 30kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
To face glue glue.
The per distribution ratio of each element is during the glue glue proportioning of face：Face film 25%, terpene resin 7%, para-tertiary butyl phenol
Formaldehyde resin 3%, mixed solution 65%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is matched somebody with somebody in mixed solution
The percentage of ratio is 15%, and the percentage that gasoline matches in mixed solution is 75%.
The preparation process following steps of primer：
1st, primer modeling is practiced：50 parts of butyl rubbers are plasticated 17min first, 20 parts of butadiene-styrene rubbers are plasticated 5min, then both are kneaded
10min, then by 8 parts of terpene resins, 6 parts of para-tertiary butyl phenol formaldehyde resins, 5 parts of chlorosulfonated polyethylenes and its be stirred, finally by 7
Part zinc chloride, 15 parts of calcium carbonate, 9 parts of o-phthalic acid dibutyl esters, 8 parts of titanium dioxides and said mixture are stirred thin after 5min
Lead into primer piece.
2nd, it is beaten：The gasoline of 60kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form primer solution.While primer solution ratio, in another small mixer, by terpene resin, para-tertiary butyl phenol
It is spare that formaldehyde resin and 20kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 20kg gasoline is added and is stirred 4 days
So that after face film dissolves completely, add 35kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
To primer glue.
The per distribution ratio of each element is during primer glue proportioning：Primer piece 28%, terpene resin 5%, para-tertiary butyl phenol
Formaldehyde resin 2%, mixed solution 65%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is matched somebody with somebody in mixed solution
The percentage of ratio is 15%, and the percentage that gasoline matches in mixed solution is 75%.
The substandard product occupation rate of the present embodiment 3 is 1.8%.The compression strength of finished product is 230N/10mm, and rate is stretched in fracture
8%, heatproof is 180 °, proof voltage 2.5KV, adhesion rate 8N/25mm.
Example IV：
1st, face glue modeling is practiced：40% butyl rubber is plasticated 18min first, the neoprene that 22% butadiene-styrene rubber is plasticated with 0.75%
5min is practiced in modeling, then three is kneaded 10min, by 12% clay, 12% polyisobutene, 12% calcium carbonate, 0.45%
The powders such as stearic acid, 1.95% zinc oxide, 5% o-phthalic acid dibutyl ester and said mixture are stirred thin after 5min
Lead into face film,
2nd, it is beaten：Added in mixer60The gasoline of kg, face film is chipped in mixer and dissolving is mixed in gasoline
2h forms face sol solution.While in face, sol solution matches, in another small mixer, by terpene resin, para-tertiary butyl phenol formaldehyde
It is spare that resin and 23kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 20kg gasoline is added and is stirred 4 days
So that after face film dissolves completely, add 35kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
To face glue glue.
The per distribution ratio of each element is during the glue glue proportioning of face：Face film 26%, terpene resin 8.5%, to tertiary fourth
Fluosite 1.5%, mixed solution 64%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is in mixed solution
The percentage of middle proportioning is 15%, and the percentage that gasoline matches in mixed solution is 75%.
The preparation process following steps of primer：
1st, primer modeling is practiced：70 parts of butyl rubbers are plasticated 18min first, 30 parts of butadiene-styrene rubbers are plasticated 5min, then both are kneaded
10min, then by 5 parts of terpene resins, 5 parts of para-tertiary butyl phenol formaldehyde resins, 8 parts of chlorosulfonated polyethylenes and its be stirred, finally will
10 parts of zinc chloride, 10 parts of calcium carbonate, 5 parts of o-phthalic acid dibutyl esters, 10 parts of titanium dioxides and said mixture are stirred 5min
It is thin afterwards to lead into primer piece.
2nd, it is beaten：The gasoline of 70kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form primer solution.While primer solution ratio, in another small mixer, by terpene resin, para-tertiary butyl phenol
It is spare that formaldehyde resin and 22kg dilution with toluene are mixed and stirred for 1.5 hours composition resin solutions.
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 25kg gasoline is added and is stirred 4 days
So that after face film dissolves completely, add 36kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
To primer glue.
The per distribution ratio of each element is during primer glue proportioning：Primer piece 27%, terpene resin 7.5%, to tertiary fourth
Fluosite7.5%, mixed solution 63%.Mixed solution is made of toluene and gasoline mixing, and wherein toluene is in mixed solution
The percentage of middle proportioning is 15%, and the percentage that gasoline matches in mixed solution is 75%.
Production efficiency of the present embodiment four among production and processing improves 20% with respect to embodiment 1-3, and unqualified
Rate 1%.The compression strength of finished product is 260N/10mm, and rate 2% is stretched in fracture, and heatproof is 200 °, proof voltage 3KV, adhesion rate 10N/
25mm。
Comparative example 1- embodiments 4, embodiment 4 are highly preferred embodiment of the present invention.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, and those skilled in the art exists
Common variations and alternatives are carried out in the range of technical solution of the present invention should all include within the scope of the present invention.
Claims (8)
1. a kind of glass cloth rubber belt, the glass cloth rubber belt includes the base material made of glass cloth, coated on the primer on base material
And face glue, it is characterized in that：
The face glue is prepared by the composition that following precentagewise configures：
The primer is prepared by the composition of following parts by weight：
2. a kind of production technology suitable for glass cloth rubber belt according to claim 1, it is characterized in that：The production technology bag
Include following steps：
A. while glass cloth is shaped and examined, primer is configured,
B. primer is coated to glass cloth,
C. after step b, glass cloth is subjected to first time winding,
D. the glass cloth after winding is coated face glue,
E. after step d, glass cloth is carried out second and is wound,
F. the glass cloth after second winds is carried out cutting into specification needed for finished product,
G. finished product is detected into its chemical property and physical property by detection device, and classify qualified products and scrap products,
H. qualified products are packed, substandard product recycling.
3. a kind of production technology suitable for glass cloth rubber belt according to claim 2, it is characterized in that：
The preparation process following steps of the face glue：
(1) face glue modeling is practiced：Butyl rubber is plasticated 15-20min first, butadiene-styrene rubber is plasticated 5min, and neoprene is plasticated 5min, then will
Three is kneaded 10min, then by clay, polyisobutene in, the powder such as calcium carbonate, stearic acid, zinc oxide, o-phthalic acid dibutyl ester
It is stirred with said mixture and thin after 5min leads into face film；
(2) it is beaten：The gasoline of 40-80kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form face sol solution,
During above-mentioned face sol solution matches, terpene resin, para-tertiary butyl phenol formaldehyde resin and 15-25kg dilution with toluene are mixed simultaneously
1.5 hours composition resin solutions of stirring are spare,
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 10-25kg gasoline is added and is stirred 3-4 days
So that after face film dissolves completely, add 20-40kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
Obtain face glue glue.
4. a kind of production technology suitable for glass cloth rubber belt according to claim 2, it is characterized in that：
The preparation process following steps of the primer：
(1) primer modeling is practiced：Butyl rubber to be plasticated 15-20min first, butadiene-styrene rubber is plasticated 5min, then both are kneaded 10min,
Chlorosulfonated polyethylene, zinc chloride, calcium carbonate, o-phthalic acid dibutyl ester, titanium dioxide are stirred in said mixture again
It is thin after 5min to lead into primer piece,
(2) it is beaten：The gasoline of 40-80kg is added in mixer, face film is chipped in mixer and gasoline is mixed
Dissolve 2h and form primer solution,
During above-mentioned primer solution ratio, terpene resin, para-tertiary butyl phenol formaldehyde resin and 15-25kg dilution with toluene are mixed simultaneously
1.5 hours composition resin solutions of stirring are spare,
Resin solution is sent to mixer knead dough sol solution and carries out mixing 2h, 10-25kg gasoline is added and is stirred 3-4 days
So that after face film dissolves completely, add 20-40kg gasoline and carry out thin stirring, solution is filtered twice after stirring 1.5h
Obtain primer glue.
5. a kind of production technology suitable for glass cloth rubber belt according to claim 3, it is characterized in that：The face glue glue
The percentage of proportioning is：Face film 20%-30%, terpene resin 5%-10%, para-tertiary butyl phenol formaldehyde resin 1%-3%, mixing
Solution 60%-75%, the mixed solution are made of toluene and gasoline mixing, the percentage that wherein toluene matches in mixed solution
Than for 15%, the percentage that gasoline matches in mixed solution is 75%.
6. a kind of production technology suitable for glass cloth rubber belt according to claim 4, it is characterized in that：The primer glue
The percentage of proportioning is：Primer piece 20%-30%, terpene resin 5%-10%, para-tertiary butyl phenol formaldehyde resin 5%-10%, mixing
Solution 60%-75%, the mixed solution are made of toluene and gasoline mixing, the percentage that wherein toluene matches in mixed solution
Than for 15%, the percentage that gasoline matches in mixed solution is 75%.
7. a kind of glass cloth rubber belt according to claim 1, it is characterized in that：What the face glue was configured by following precentagewise
Composition is prepared：
8. a kind of glass cloth rubber belt according to claim 1, it is characterized in that：The primer by following parts by weight combination
Thing is prepared：
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113119203A (en) * | 2021-04-21 | 2021-07-16 | 南京夜龙新材料科技有限公司 | Manufacturing and processing method of butyl rubber waterproof sealant adhesive tape |
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