CN107987404A - A kind of tensile strength is high, the rubber of good corrosion resistance - Google Patents

A kind of tensile strength is high, the rubber of good corrosion resistance Download PDF

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Publication number
CN107987404A
CN107987404A CN201711311141.5A CN201711311141A CN107987404A CN 107987404 A CN107987404 A CN 107987404A CN 201711311141 A CN201711311141 A CN 201711311141A CN 107987404 A CN107987404 A CN 107987404A
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CN
China
Prior art keywords
parts
rubber
tensile strength
corrosion resistance
good corrosion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711311141.5A
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Chinese (zh)
Inventor
武守全
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Five Wolf God Rubber Products Co Ltd
Original Assignee
Anhui Five Wolf God Rubber Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Five Wolf God Rubber Products Co Ltd filed Critical Anhui Five Wolf God Rubber Products Co Ltd
Priority to CN201711311141.5A priority Critical patent/CN107987404A/en
Publication of CN107987404A publication Critical patent/CN107987404A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/085Copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/327Aluminium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of tensile strength height, the rubber of good corrosion resistance, it is formed according to the parts by weight of following raw material:50 100 parts of chlorohydrin rubber, 60 120 parts of ethylene propylene diene rubber, 4 20 parts of stearic acid, 5 15 parts of zinc oxide, 10 20 parts of aluminium hydroxide, 2 10 parts of sulphur, 23 parts of vulcanizing agent, 12 parts of vulcanization accelerator, 6 15 parts of magnesium silicate, 38 parts of rosin, 13 parts of plasticizer, 15 25 parts of linseed oil, 69 parts of aluminum phosphate, 10 15 parts of phenolic resin, 5 10 parts of copper powder, 4 15 parts of palm wax, 69 parts of carbon nano-fiber.The composition of rubber of the present invention substantially increases anti-mold effect, while the rubber also has that tensile strength is high, high temperature resistant, it is corrosion-resistant the advantages that.

Description

A kind of tensile strength is high, the rubber of good corrosion resistance
Technical field
The present invention relates to a kind of tensile strength height, the rubber of good corrosion resistance.
Background technology
Rubber industry is the important component of chemical industry, tire, sebific duct, adhesive tape, rubber roller, rubber seal, adhesive plaster The rubbers such as product are widely used in the national warp such as automobile production, aircraft manufacturing, Crude Oil Transportation, telecommunications, hospital The industry-by-industry of Ji, it has also become one of important basic industry.It is well known that the basic raw material of rubber industry is exactly natural rubber Glue and synthetic rubber, the natural rubber whether obtained from nature, or the synthesis rubber that the mankind are obtained by industrialization means Glue, although they have the high resiliency of preciousness and other a series of excellent performances, itself still there is lacking for many in performance Point, in order to produce the rubber for meeting actual use performance requirement, improves process industrial art performance and reduces rubber Cost, it is necessary to add various chemical substances, these chemical substances are collectively referred to as compounding agent or processing aid.Compounding agent is according to effect It is broken generally into vulcanizing agent, accelerating agent, activating agent, antioxidant, antiscorching agent, reinforcing agent, tackifier, plasticizer and other compounding agents.
The content of the invention
The purpose of the present invention is that to solve the above-mentioned problems and provides a kind of tensile strength height, the rubber of good corrosion resistance Glue.
To achieve these goals, the present invention is achieved by the following technical solutions:A kind of tensile strength is high, corrosion-resistant Property good rubber, it is formed according to the parts by weight of following raw material:50-100 parts of chlorohydrin rubber, ethylene propylene diene rubber 60-120 Part, 4-20 parts of stearic acid, 5-15 parts of zinc oxide, 10-20 parts of aluminium hydroxide, 2-10 parts of sulphur, 2-3 parts of vulcanizing agent, vulcanization promote 1-2 parts of agent, 6-15 parts of magnesium silicate, 3-8 parts of rosin, 1-3 parts of plasticizer, 15-25 parts of linseed oil, 6-9 parts of aluminum phosphate, phenolic aldehyde tree 10-15 parts of fat, 5-10 parts of copper powder, 4-15 parts of palm wax, 6-9 parts of carbon nano-fiber.
Further, a kind of tensile strength is high, the rubber of good corrosion resistance, its according to following raw material parts by weight array Into:50-80 parts of chlorohydrin rubber, 60-100 parts of ethylene propylene diene rubber, 4-18 parts of stearic acid, 5-13 parts of zinc oxide, aluminium hydroxide 10- 18 parts, 2-8 parts of sulphur, 2-3 parts of vulcanizing agent, 1-2 parts of vulcanization accelerator, 6-12 parts of magnesium silicate, 3-7 parts of rosin, plasticizer 1-3 Part, 15-20 parts of linseed oil, 6-8 parts of aluminum phosphate, 10-13 parts of phenolic resin, 5-8 parts of copper powder, 4-13 parts of palm wax, nano-sized carbon 6-8 parts of fiber.
Further, a kind of tensile strength is high, the rubber of good corrosion resistance, its according to following raw material parts by weight array Into:70 parts of chlorohydrin rubber, 80 parts of ethylene propylene diene rubber, 12 parts of stearic acid, 9 parts of zinc oxide, 14 parts of aluminium hydroxide, 5 parts of sulphur, sulphur 2 parts of agent, 1 part of vulcanization accelerator, 10 parts of magnesium silicate, 5 parts of rosin, 2 parts of plasticizer, 18 parts of linseed oil, 7 parts of aluminum phosphate, phenol 12 parts of urea formaldehyde, 6 parts of copper powder, 8 parts of palm wax, 7 parts of carbon nano-fiber.
In summary the invention has the advantages that:The composition of rubber of the present invention substantially increases anti-mold effect, The rubber also has that tensile strength is high at the same time, high temperature resistant, it is corrosion-resistant the advantages that.
Embodiment
Specific embodiment 1:A kind of tensile strength is high, the rubber of good corrosion resistance, its according to following raw material parts by weight Composition:50 parts of chlorohydrin rubber, 60 parts of ethylene propylene diene rubber, 4 parts of stearic acid, 5 parts of zinc oxide, 10 parts of aluminium hydroxide, 2 parts of sulphur, 2 parts of vulcanizing agent, 1 part of vulcanization accelerator, 6 parts of magnesium silicate, 3 parts of rosin, 1 part of plasticizer, 15 parts of linseed oil, 6 parts of aluminum phosphate, phenol 10 parts of urea formaldehyde, 5 parts of copper powder, 4 parts of palm wax, 6 parts of carbon nano-fiber.
Specific embodiment 2:A kind of tensile strength is high, the rubber of good corrosion resistance, its according to following raw material parts by weight Composition:70 parts of chlorohydrin rubber, 80 parts of ethylene propylene diene rubber, 12 parts of stearic acid, 9 parts of zinc oxide, 14 parts of aluminium hydroxide, 5 parts of sulphur, 2 parts of vulcanizing agent, 1 part of vulcanization accelerator, 10 parts of magnesium silicate, 5 parts of rosin, 2 parts of plasticizer, 18 parts of linseed oil, 7 parts of aluminum phosphate, 12 parts of phenolic resin, 6 parts of copper powder, 8 parts of palm wax, 7 parts of carbon nano-fiber.
Specific embodiment 3:A kind of tensile strength is high, the rubber of good corrosion resistance, its according to following raw material parts by weight Composition:100 parts of chlorohydrin rubber, 120 parts of ethylene propylene diene rubber, 20 parts of stearic acid, 15 parts of zinc oxide, 20 parts of aluminium hydroxide, sulphur 10 parts, 3 parts of vulcanizing agent, 2 parts of vulcanization accelerator, 15 parts of magnesium silicate, 8 parts of rosin, 3 parts of plasticizer, 25 parts of linseed oil, aluminum phosphate 9 parts, 15 parts of phenolic resin, 10 parts of copper powder, 15 parts of palm wax, 9 parts of carbon nano-fiber.
Embodiment provided above is the better embodiment of the present invention, is only used for the convenient explanation present invention, not to this hair The limitation of bright work in any form, any those of ordinary skill in the art, if putting forward skill not departing from the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from the technical feature content of the present invention, in the range of still falling within the technology of the present invention feature.

Claims (3)

1. a kind of tensile strength is high, the rubber of good corrosion resistance, it is characterised in that is formed according to the parts by weight of following raw material: 50-100 parts of chlorohydrin rubber, 60-120 parts of ethylene propylene diene rubber, 4-20 parts of stearic acid, 5-15 parts of zinc oxide, aluminium hydroxide 10-20 Part, 2-10 parts of sulphur, 2-3 parts of vulcanizing agent, 1-2 parts of vulcanization accelerator, 6-15 parts of magnesium silicate, 3-8 parts of rosin, 1-3 parts of plasticizer, 15-25 parts of linseed oil, 6-9 parts of aluminum phosphate, 10-15 parts of phenolic resin, 5-10 parts of copper powder, 4-15 parts of palm wax, Nano carbon fibers 6-9 parts of dimension.
2. a kind of tensile strength according to claim 1 is high, the rubber of good corrosion resistance, it is characterised in that according to following The parts by weight composition of raw material:50-80 parts of chlorohydrin rubber, 60-100 parts of ethylene propylene diene rubber, 4-18 parts of stearic acid, zinc oxide 5- 13 parts, 10-18 parts of aluminium hydroxide, 2-8 parts of sulphur, 2-3 parts of vulcanizing agent, 1-2 parts of vulcanization accelerator, 6-12 parts of magnesium silicate, rosin 3-7 parts, 1-3 parts of plasticizer, 15-20 parts of linseed oil, 6-8 parts of aluminum phosphate, 10-13 parts of phenolic resin, 5-8 parts of copper powder, palm 4-13 parts of wax, 6-8 parts of carbon nano-fiber.
3. a kind of tensile strength according to claim 1 is high, the rubber of good corrosion resistance, it is characterised in that according to following The parts by weight composition of raw material:70 parts of chlorohydrin rubber, 80 parts of ethylene propylene diene rubber, 12 parts of stearic acid, 9 parts of zinc oxide, hydroxide 14 parts of aluminium, 5 parts of sulphur, 2 parts of vulcanizing agent, 1 part of vulcanization accelerator, 10 parts of magnesium silicate, 5 parts of rosin, 2 parts of plasticizer, linseed oil 18 parts, 7 parts of aluminum phosphate, 12 parts of phenolic resin, 6 parts of copper powder, 8 parts of palm wax, 7 parts of carbon nano-fiber.
CN201711311141.5A 2017-12-11 2017-12-11 A kind of tensile strength is high, the rubber of good corrosion resistance Withdrawn CN107987404A (en)

Priority Applications (1)

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CN201711311141.5A CN107987404A (en) 2017-12-11 2017-12-11 A kind of tensile strength is high, the rubber of good corrosion resistance

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CN201711311141.5A CN107987404A (en) 2017-12-11 2017-12-11 A kind of tensile strength is high, the rubber of good corrosion resistance

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111349279A (en) * 2020-03-31 2020-06-30 江苏通用科技股份有限公司 Organic copper composite rubber composite material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642189A (en) * 2013-11-15 2014-03-19 蚌埠赛英电子科技发展有限公司 Modified ethylene propylene diene monomer composite gasket material, and preparation method thereof
CN103694577A (en) * 2013-12-04 2014-04-02 铜陵日兴电子有限公司 Rubber sealing ring of antioxidant capacitor and preparation method thereof
CN106832868A (en) * 2015-12-04 2017-06-13 宁波海浪电器有限公司 Rubber compounding

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642189A (en) * 2013-11-15 2014-03-19 蚌埠赛英电子科技发展有限公司 Modified ethylene propylene diene monomer composite gasket material, and preparation method thereof
CN103694577A (en) * 2013-12-04 2014-04-02 铜陵日兴电子有限公司 Rubber sealing ring of antioxidant capacitor and preparation method thereof
CN106832868A (en) * 2015-12-04 2017-06-13 宁波海浪电器有限公司 Rubber compounding

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111349279A (en) * 2020-03-31 2020-06-30 江苏通用科技股份有限公司 Organic copper composite rubber composite material and preparation method thereof

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Application publication date: 20180504