CN107964129B - 一种码垛机械手用耐磨胶套 - Google Patents
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Abstract
本发明涉及自动化设备技术领域,尤其涉及一种码垛机械手用耐磨胶套,所述码垛机械手用耐磨胶套由复合胶套和纳米荧光涂层构成,所述纳米荧光涂层涂覆于复合胶套的外表面,所述复合胶套由以下重量份的原料制成:天然橡胶85~105份,顺丁橡胶50~80份,高耐磨炭黑50~80份,硫磺0.5~1.5份,促进剂TMTD 5~15份和弹性纤维15~20份。本发明的码垛机械手用耐磨胶套耐磨损和耐腐蚀性好,高弹性,使用周期长,成本低;具有自清洁和荧光特性,利于高效管理,节能减排;降低码垛机械手的维修频率及成本,促进企业高效运转,增加企业效益。
Description
技术领域
本发明涉及自动化设备技术领域,尤其涉及一种耐腐蚀、高弹性的码垛机械手用耐磨胶套。
背景技术
码垛机械手能将不同外形尺寸的包装货物,整齐、自动地码在托盘或生产线上等。为充分利用托盘的面积和码堆物料的稳定性,机器人具有物料码垛顺序、排列设定器。可满足从低速到高速,从包装袋到纸箱,从码垛一种产品到码垛多种不同产品。应用于产品搬运、码垛等,广泛应用于汽车、物流、家电、医药、食品饮料等不同领域。目前国内已经有了多家的码垛机械手生产企业,这些企业的出现使得进口产品的价格下降很多,促进了码垛机械手的广泛应用,但是这些企业的产品在性能上与进口产品还有一定的差距,同时很多企业的产品的控制***都是购买国外的,这就受制于国外。由于生产线繁重的工作需求,企业会引进昂贵的码垛机械手来减省工人、提高效率,提高产品品质、安全性好、提升企业形象。但是,在实际使用过程中,码垛机械手在高效、频繁的使用过程中,不堪高负荷运转,导致码垛机械手的卡爪等部位磨损厉害,若遇到具有腐蚀性的货品,则更是大大减少了码垛机械手的使用寿命,使用周期短,造成企业维修、更换成本高。此外,维修过程也会导致工程延误,造成巨大的企业损失。因此,探索一种低成本、耐磨损的码垛机械手护套是本领域技术人员亟待解决的技术问题。
发明内容
本发明为了克服传统码垛机械手使用寿命短,维修成本高的问题,提供了一种耐腐蚀、高弹性的码垛机械手用耐磨胶套。
为了实现上述目的,本发明采用以下技术方案:
一种码垛机械手用耐磨胶套,所述码垛机械手用耐磨胶套由复合胶套和纳米荧光涂层构成,所述纳米荧光涂层涂覆于复合胶套的外表面,所述复合胶套由以下重量份的原料制成:天然橡胶85~105份,顺丁橡胶50~80份,高耐磨炭黑50~80份,硫磺0.5~1.5份,促进剂TMTD5~15份和弹性纤维15~20份。
本发明采用天然橡胶改性的顺丁橡胶产品作为码垛机械手用耐磨胶套中复合胶套的主要原料,其中天然橡胶的弹性大,定伸强度高,抗撕裂性和电绝缘性优良,耐磨性和耐旱性良好,加工性佳,易于其它材料粘合,与顺丁橡胶协同增效,提高复合胶套的弹性。体系中加入弹性纤维和高耐磨炭黑则进一步增强了复合胶套的韧性、弹性,表面涂覆纳米荧光涂层,一方面可以增加耐腐蚀性,另一方面荧光特性有利于管理者在码垛机械手的夜间操作环境中进行***管理,减少照明灯的使用,节能减排。
作为优选,所述弹性纤维选自高弹性聚乙稀纤维,蜘蛛丝和蚕丝中的一种或几种。
高弹性聚乙稀纤维,简称为高弹性或者高模量聚乙烯纤维,是分子量在100~500万的聚乙烯所纺出的纤维,为目前世界上比强度和比模量最高的纤维。蜘蛛丝是自然界最强韧的纤维,其断裂强度1.3GPa,伸长率40%,被誉为“生物钢”,本发明采用由生物质材料蜘蛛丝和蚕丝作为弹性纤维,大大减少了化学试剂的使用,合成过程更为绿色环保。本发明在复合胶套的橡胶体系中加入高弹性聚乙稀纤维、蜘蛛丝或蚕丝,大大提高了码垛机械手用耐磨胶套的机械强度和弹性。
作为优选,所述纳米荧光涂层由以下重量份的原料制成:纳米二氧化钛5~10份,镍基合金10~20份,远红外陶瓷粉体100~120份,钼酚醛树脂20~40份,氨基硅烷5~15份和稀土三基色荧光粉5~15份。
本发明的纳米荧光涂层配方体系中加入适量的镍基合金,镍基合金为耐蚀合金,其在高温下有较高的强度与一定的抗氧化腐蚀,能够增强码垛机械手用耐磨胶套的稳定性和抗腐蚀性。钼酚醛树脂作为结合剂具有耐烧蚀、冲刷、强度好的有点,使用其制备的码垛机械手用耐磨胶套工艺性好,耐腐蚀性强。选用氨基硅烷作为增粘剂,其氨基上带有两个活泼氢可以和各种聚合物发生反应,从而通过化学键将两种性质完全不同的材料紧密的结合起来,使得制备的纳米荧光涂层粘结度高,实用性强。
远红外陶瓷粉体则可以与其他组分协同增效,提高耐腐蚀性,主要原理如下:物体中的电子震动或激发,就会向外放出辐射能,一切物体只要在开氏零度以上都会有红外线向外辐射。随着辐射体材质分子结构和温度等诸多条件的不同,其辐射波长也各不相同。在辐射波段中,当分子中的原子或原子团从高能量的振动状态转变为低能量的振动状态时,会产生2.5~25μm的远红外辐射,当码垛机械手所搬运货物产生的酸性腐蚀液流经纳米荧光涂层后,在其表面自由能的作用下,腐蚀液的表面张力可从72×10-3N·m-1降低到60×10-3N·m-1。同时经过表面自由能的激活震荡,不但能活化酸性的腐蚀液,使其不容易缔合,造成腐蚀,而且还能活化其它具有腐蚀性能的液体。
稀土三基色荧光粉(俗称夜光粉)分别是红粉、绿粉、蓝粉按一定的比例混合而成。它解决了卤磷酸盐荧光粉长期存在的光效和显色性不能同时提高的矛盾,具有发光谱带窄,发光能量更为集中,且在短波紫外线激发下稳定性高,高温特性好的优异性能,使用具有荧光性能的纳米涂层使得配有本发明码垛机械手用耐磨胶套的码垛机械手在夜间操作环境中,有利于管理者进行***高效管理,减少照明灯的使用,节能减排。
加入纳米二氧化钛一方面可以提高码垛机械手用耐磨胶套的耐腐蚀性,另一方面能够使得码垛机械手用耐磨胶套具有自清洁作用,主要原理如下:在紫外光下纳米二氧化钛能够催化空气中的氧气产生超氧自由基,利用纳米二氧化钛的光催化性和超亲水性,可以把吸附在表面的有机物分解成CO2和H2O,同时对空气中的有害气体有高效的分解和消除作用,并能降低分解紫外线的辐射,使本发明码垛机械手用耐磨胶套的抗老化能力增强,同时具有纳米抗菌自清洁效果,起到防霉、除菌、除湿的作用。
作为优选,所述稀土三基色荧光粉选自Y2O3:Eu,MgAl11O19:Ce,Tb和BaMg2Al16O27:Eu中的一种或几种。
稀土三基色荧光粉中,红粉为铕激活的氧化钇(Y2O3:Eu),绿粉为铈、铽激活的铝酸盐(MgAl11O19:Ce,Tb),蓝粉为低价铕激活的铝酸钡镁(BaMg2Al16O27:Eu),三种粉按一定比例混合,可以得到不同的色温。
作为优选,所述远红外陶瓷粉体由以下重量份的组分组成:白炭黑40~60份,氧化铝30~50份和氯化银25~30份。
作为优选,所述镍基合金选自镍钼合金和镍铜合金中的一种或两种。
作为优选,所述氨基硅烷选自3-氨丙基三甲氧基硅烷和三苯基氨基硅烷中的一种或两种。
因此,本发明具有如下有益效果:
(1)耐磨损和耐腐蚀性好,高弹性,使用周期长,成本低;
(2)具有自清洁和荧光特性,利于高效管理,节能减排;
(3)降低码垛机械手的维修频率及成本,促进企业高效运转,增加企业效益。
具体实施方式
下面通过具体实施例,对本发明的技术方案作进一步具体的说明。
在本发明中,若非特指,所有设备和原料均可从市场购得或是本行业常用的,下述实施例中的方法,如无特别说明,均为本领域常规方法。
实施例1
一种码垛机械手用耐磨胶套,由复合胶套和纳米荧光涂层构成,纳米荧光涂层涂覆于复合胶套的外表面,具体的:
复合胶套由以下配比的原料制成:天然橡胶85g,顺丁橡胶50g,高耐磨炭黑50g,硫磺0.5g,促进剂TMTD 5g和高弹性聚乙稀纤维15g;
纳米荧光涂层由以下配比的原料制成:纳米二氧化钛5g,镍钼合金10g,远红外陶瓷粉体(白炭黑40g,氧化铝30g和氯化银30g)100g,钼酚醛树脂20g,三苯基氨基硅烷5g和BaMg2Al16O27:Eu 5g。
实施例2
一种码垛机械手用耐磨胶套,由复合胶套和纳米荧光涂层构成,纳米荧光涂层涂覆于复合胶套的外表面,具体的:
复合胶套由以下配比的原料制成:天然橡胶105g,顺丁橡胶80g,高耐磨炭黑80g,硫磺1.5g,促进剂TMTD 15g,高弹性聚乙稀纤维10g和蚕丝10g;
纳米荧光涂层由以下配比的原料制成:纳米二氧化钛10g,镍钼合金15g,镍铜合金5g,远红外陶瓷粉体(白炭黑60g,氧化铝35g和氯化银25g)120g,钼酚醛树脂40g,3-氨丙基三甲氧基硅烷5g,三苯基氨基硅烷10g,Y2O3:Eu 7g和MgAl11O19:Ce,Tb 8g。
实施例3
一种码垛机械手用耐磨胶套,由复合胶套和纳米荧光涂层构成,纳米荧光涂层涂覆于复合胶套的外表面,具体的:
复合胶套由以下配比的原料制成:天然橡胶90g,顺丁橡胶65g,高耐磨炭黑65g,硫磺1g,促进剂TMTD 10g,高弹性聚乙稀纤维9g,蜘蛛丝9g;
纳米荧光涂层由以下配比的原料制成:纳米二氧化钛7g,镍铜合金15g,远红外陶瓷粉体(白炭黑42份,氧化铝50份和氯化银26份)118g,钼酚醛树脂30g,3-氨丙基三甲氧基硅烷10g,Y2O3:Eu 10g。
对实施例1-3码垛机械手用耐磨胶套的性能指标做检测,结果如表1所示:
表1.检测结果
性能指标 | 实施例1 | 实施例2 | 实施例3 |
扯断强度(MPa) | 35 | 36 | 33 |
扯断伸长率(%) | 368 | 375 | 345 |
自清洁性 | 有 | 有 | 有 |
缓蚀率(%) | 92.5 | 93 | 94 |
由表1可以看出,本发明的码垛机械手用耐磨胶套具有较高的强度,较好的弹性及耐腐蚀性,还具有一定的自清洁功能。
本发明的码垛机械手用耐磨胶套耐磨损和耐腐蚀性好,高弹性,使用周期长,成本低;具有自清洁和荧光特性,利于高效管理,节能减排;降低码垛机械手的维修频率及成本,促进企业高效运转,增加企业效益。
以上所述仅为本发明的较佳实施例,并非对本发明作任何形式上的限制,在不超出权利要求所记载的技术方案的前提下还有其它的变体及改型。
Claims (6)
1.一种码垛机械手用耐磨胶套,其特征在于,所述码垛机械手用耐磨胶套由复合胶套和纳米荧光涂层构成,所述纳米荧光涂层涂覆于复合胶套的外表面,所述复合胶套由以下重量份的原料制成:天然橡胶85~105份,顺丁橡胶50~80份,高耐磨炭黑50~80份,硫磺0.5~1.5份,促进剂TMTD 5~15份和弹性纤维15~20份;所述纳米荧光涂层由以下重量份的原料制成:纳米二氧化钛5~10份,镍基合金10~20份,远红外陶瓷粉体100~120份,钼酚醛树脂20~40份,氨基硅烷5~15份和稀土三基色荧光粉5~15份。
2.根据权利要求1所述的一种码垛机械手用耐磨胶套,其特征在于,所述弹性纤维选自高弹性聚乙稀纤维,蜘蛛丝和蚕丝中的一种或几种。
3.根据权利要求1所述的一种码垛机械手用耐磨胶套,其特征在于,所述稀土三基色荧光粉选自Y2O3:Eu,MgAl11O19:Ce,Tb和BaMg2Al16O27:Eu中的一种或几种。
4.根据权利要求1所述的一种码垛机械手用耐磨胶套,其特征在于,所述远红外陶瓷粉体由以下重量份的组分组成:白炭黑40~60份,氧化铝30~50份和氯化银25~30份。
5.根据权利要求1所述的一种码垛机械手用耐磨胶套,其特征在于,所述镍基合金选自镍钼合金和镍铜合金中的一种或两种。
6.根据权利要求1所述的一种码垛机械手用耐磨胶套,其特征在于,所述氨基硅烷选自3-氨丙基三甲氧基硅烷和三苯基氨基硅烷中的一种或两种。
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