CN107955691A - A kind of low smell stainless-steel cold-rolling thin plate rolling oil - Google Patents

A kind of low smell stainless-steel cold-rolling thin plate rolling oil Download PDF

Info

Publication number
CN107955691A
CN107955691A CN201711339258.4A CN201711339258A CN107955691A CN 107955691 A CN107955691 A CN 107955691A CN 201711339258 A CN201711339258 A CN 201711339258A CN 107955691 A CN107955691 A CN 107955691A
Authority
CN
China
Prior art keywords
rolling
oil
stainless
thin plate
steel cold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711339258.4A
Other languages
Chinese (zh)
Inventor
肖浩瀛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Kai Kai Lubricating Oil Co Ltd
Original Assignee
Wuxi Kai Kai Lubricating Oil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Kai Kai Lubricating Oil Co Ltd filed Critical Wuxi Kai Kai Lubricating Oil Co Ltd
Priority to CN201711339258.4A priority Critical patent/CN107955691A/en
Publication of CN107955691A publication Critical patent/CN107955691A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/243Cold working
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/244Metal working of specific metals
    • C10N2040/247Stainless steel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of low smell stainless-steel cold-rolling thin plate rolling oil, the preparing raw material of the ROLLING OIL includes following component by mass percentage:Hydrorefined mineral oils 90 95%, polyol-ester type oil agent 3 8%, extreme pressure agent 0.5 3%, antirust agent 0.01 0.5%, antioxidant 0.05 1%.ROLLING OIL provided by the invention eliminates conventional ROLLING OIL and has certain penetrating odor and endanger environment, influence the shortcomings that enterprise employee health while required lubrication, antifriction and plate face detergency in meeting the operation of rolling.

Description

A kind of low smell stainless-steel cold-rolling thin plate rolling oil
Technical field
The invention belongs to metallurgy rolling mill oil product field, is related to a kind of stainless-steel cold-rolling thin plate rolling oil, more particularly to one The low smell stainless-steel cold-rolling thin plate rolling oil of kind.
Background technology
Stainless steel has good corrosion resistance, heat resistance, low temperature intensity and mechanical property, and feature is intensity height, cold Drastically hardened during deformation, but plasticity is good.Stainless-steel cold-rolling rolling is that rotary roller gives band pressure under certain condition, makes band Material produces a kind of processing method of plastic deformation, and the rolling mill practice condition of stainless steel thin plate is very harsh, it is desirable to matched to make ROLLING OIL will reduce the friction between roll and plate, reduce roll wear, there is provided stable frictional interface, improves plate Surface quality.
ROLLING OIL generally selects refined mineral oil, while adds the multiple functions additive such as oiliness improver, extreme pressure agent, antirust agent Blending forms.At present, in order to ensure that ROLLING OIL has good greasy property, ROLLING OIL supplier can select to add larger ratio The sulfur-bearing or/and phosphor-included additive of example, in addition, in order to make rolled surface that there is good plate face detergency and improve ROLLING OIL Antifriction performance, all choosing addition containing alcohol, the oiliness improver of acids.And sulphur and phosphorus in extreme pressure agent, and it is commonly used for the long-chain of oiliness improver Fatty alcohol and aliphatic acid mostly have heavier penetrating odor, can be produced during long-term high temperature circulation use stronger Strong penetrating odor, not only pollution rolling work on the spot environment, can also cause human body certain harm.
Disclosed in CN106281592A using containing inactive alkyl polysulfide, light sulfide aliphatic acid, ashless Sulphur and phosphorus antiwear extreme pressure agent component, sulfur-bearing, phosphorous extreme pressure additive still can produce penetrating odor, pollute environment. CN106566598A, which is proposed, to be used containing lauryl alcohol and lauric oiliness improver and uses dialkyl dithiophosphate as pole Agent is pressed, still without pollution problem of the solution penetrating odor to environment.ROLLING OIL mentioned by above patent has certain Using effect, but it with the addition of sulphur system, phosphorus system extreme pressure agent in preparation process, or fatty alcohol, aliphatic acid oiliness improver are with the addition of, or Using the additive or base oil component of particular components requirement, consequently, it is possible to which more or less there are spinosity for prepared ROLLING OIL Swash property smell, pollute live processing environment, influence related personnel's health, materials procurement is difficult, and ROLLING OIL cost increase etc. is asked Topic.Therefore, penetrating odor, the higher stainless-steel cold-rolling thin plate rolling oil of sexual valence is not present in invention one kind in process It is particularly important.
The content of the invention
In order to solve the above technical problem, the present invention provides a kind of stainless-steel cold-rolling thin plate rolling oil, especially it is to provide A kind of low smell stainless-steel cold-rolling thin plate rolling oil.
For this purpose, the present invention uses following technical scheme:
The present invention provides a kind of low smell stainless-steel cold-rolling thin plate rolling oil, the preparing raw material of the ROLLING OIL presses quality Percentage composition includes following component:
The long-chain fatty alcohol and aliphatic acid that the present invention replaces choosing in conventional ROLLING OIL using polyol-ester type oil agent, this Sample can produce penetrating odor to avoid ROLLING OIL during high temperature circulation, so as to avoid influencing health.Also, choose Extreme pressure agent is used cooperatively with polyol-ester type oil agent, can make ROLLING OIL provided by the invention needed in the operation of rolling is met The penetrating odor that conventional ROLLING OIL produces is eliminated while the lubrication wanted, plate face spatter property, and then avoids causing dirt to environment Dye, influence the problems such as health of employee, and ROLLING OIL provided by the invention is a kind of low smell stainless-steel cold-rolling thin plate rolling oil.And And the preparing raw material as described above that the present invention uses derives from a wealth of sources, the purchasing of raw materials is simple, and cost is relatively low.
In the present invention, the mass percentage of the hydrorefined mineral oils is 90-95%, for example, 90%, 91%, 92%th, 93%, 94%, 95% etc..
Preferably, oil 60N and/or base oil 70N based on the hydrorefined mineral oils.
In the present invention, the mass percentage of the oiliness improver is 3-8%, for example, 3%, 4%, 5%, 6%, 7%, 8% etc..
Preferably, the polyol-ester type oil agent is tricarboxymethyl propane oleate, the trimethylolpropane oleic acid pungent last of the ten Heavenly stems In acid esters, pentaerythritol oleate or neopentyl glycol dioleate any one or at least two combination.
In the present invention, the mass percentage of the extreme pressure agent is 0.5-3%, for example, 0.5%, 1%, 1.5%, 2%, 2.5%th, 3% etc..
Preferably, the extreme pressure agent is polyester extreme pressure agent.
Preferably, the polyester extreme pressure agent is oil-soluble polyester.
Preferably, the molecular weight of the polyester extreme pressure agent is 12000-25000, for example, 12000,15000,20000, 25000 etc..
Traditional sulfur-bearing and/or phosphorous extreme pressure agent are different from, the present invention can select oil-soluble polymerization ester as extreme pressure Agent, can so be discharged in the long-term use to avoid sulfur-bearing and/or phosphorous extreme pressure agent penetrating odor to environment and Harm caused by human body;And oil-soluble polymerization ester can farthest avoid using together with polyol-ester type oil agent During discharge penetrating odor.
In the present invention, the mass percentage of the antirust agent is 0.01-0.5%, for example, 0.01%, 0.1%, 0.2%th, 0.3%, 0.4%, 0.5% etc..
Preferably, the antirust agent is that sulfonate, alkenyl succinate, fatty acid amide, benzotriazole or benzotriazole derive In thing any one or at least two combination.
In the present invention, the mass percentage of the antioxidant is 0.05-1%, for example, 0.05%, 0.1%, 0.3%, 0.5%th, 0.7%, 1% etc..
Preferably, the antioxidant is dialkyl diphenylamine and/or the derivative of 2,6- di-tert-butylphenol.
Relative to the prior art, the invention has the advantages that:
In the present invention, choose extreme pressure agent to be used cooperatively with polyol-ester type oil agent, provided by the invention roll can be made Liquefaction eliminates the irritation gas that conventional ROLLING OIL produces while required lubrication, plate face spatter property in meeting the operation of rolling Taste, and then the problems such as avoid polluting environment, influencing the health of employee;The present invention uses oil based on hydrogenation mineral oil, Used polyol ester oiliness improver component is commercial product, and other raw material are common is easy to get, and cost is relatively low.
Embodiment
Technical scheme is further illustrated below by embodiment.Those skilled in the art should be bright , the embodiment be only to aid in understand the present invention, be not construed as to the present invention concrete restriction.
Embodiment 1
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils 60N;Oiliness improver is tricarboxymethyl propane oleate;The molecular weight of extreme pressure agent is 12000;Antirust agent is alkenyl succinic acid and the composition of benzotriazole derivative, and the mass ratio of the two is 2:3;Antioxidant is dioxane Base diphenylamines.
Embodiment 2
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils 70N;Oiliness improver is pentaerythritol oleate;The molecular weight of extreme pressure agent is 25000;Antirust agent is alkenyl succinic acid and the composition of benzotriazole derivative, and the mass ratio of the two is 2:3;Antioxidant is dioxane Base diphenylamines and 2,6- DI-tert-butylphenol compounds, the two mass ratio are 1:1.
Embodiment 3
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils are the composition of 60N and 70N, the two mass ratio is 1:1;Oiliness improver is three hydroxyl first Base propane oleate;The molecular weight of extreme pressure agent is 20000;Antirust agent is the composition of fatty acid amide and benzotriazole derivative, The mass ratio of the two is 2:1;Antioxidant is dialkyl diphenylamine.
Embodiment 4
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils are the composition of 60N and 70N, the two mass ratio is 46:47;Oiliness improver is season penta Tetrol oleate;The molecular weight of extreme pressure agent is 15000;Antirust agent for alkenyl succinic acid and benzotriazole derivative composition, two The mass ratio of person is 1:1;Antioxidant is dialkyl diphenylamine.
Embodiment 5
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils 60N;Oiliness improver is the pungent decylate of trimethylolpropane oleic acid and neopentyl glycol two The composition of oleate, the mass ratio of the two are 2:2.3;The molecular weight of extreme pressure agent is 18000;Antirust agent is alkenyl succinic acid; Antioxidant is dialkyl diphenylamine.
Embodiment 6
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils 70N;Oiliness improver is tricarboxymethyl propane oleate, trimethylolpropane oleic acid The composition of pungent decylate and neopentyl glycol dioleate, the mass ratio of three is 2:2:4;The molecular weight of extreme pressure agent is 22000; Antirust agent is benzotriazole derivative;Antioxidant is dialkyl diphenylamine.
Embodiment 7
The preparing raw material of ROLLING OIL provided in this embodiment includes following component by mass percentage:
Wherein, hydrorefined mineral oils 60N;Oiliness improver is tricarboxymethyl propane oleate;The molecular weight of extreme pressure agent is 17000;Antirust agent is fatty acid amide;Antioxidant is dialkyl diphenylamine.
Comparative example 1
Difference lies in the oiliness improver in this comparative example is the combination of lauryl alcohol, tetradecyl alchohol and epoxy ethyl ester with embodiment 1 Thing, the mass ratio of three is 1:1:4.
Comparative example 2
Difference lies in the extreme pressure agent in this comparative example is tricresyl phosphate with embodiment 1.
The performance for the ROLLING OIL that comparing embodiment 1-7 and comparative example 1-2 is provided, the results are shown in Table 1:
Table 1
The test data provided from table 1 can be seen that ROLLING OIL kinematic viscosity, flash-point and maximum provided by the invention without card Sting load and comparative example difference is smaller, illustrate that ROLLING OIL provided by the invention can substitute traditional ROLLING OIL and use completely, and The saponification number of ROLLING OIL provided by the invention has different degrees of raising, illustrates that ROLLING OIL provided by the invention has and is rolled than tradition The more preferable greasy property of oil.In addition, from the point of view of smell test result after the oxidation of 60 DEG C of baking ovens, the ROLLING OIL that embodiment provides produces Smell it is slight, but comparative example has obvious penetrating odor, and from this point of view, ROLLING OIL provided by the invention is a kind of low gas Taste stainless sheet steel rolls oil product.
Applicant states that the present invention illustrates the low smell stainless-steel cold-rolling thin plate rolling of the present invention by above-described embodiment Oil, but the invention is not limited in above-described embodiment, that is, do not mean that the present invention has to rely on above-described embodiment and could implement.Institute Belong to those skilled in the art it will be clearly understood that any improvement in the present invention, to the equivalence replacement of each raw material of product of the present invention And the addition of auxiliary element, selection of concrete mode etc., all fall within protection scope of the present invention and the open scope.

Claims (8)

1. a kind of stainless-steel cold-rolling thin plate rolling oil, it is characterised in that the preparing raw material of the ROLLING OIL presses mass percentage Including following component:
2. stainless-steel cold-rolling thin plate rolling according to claim 1 oil, it is characterised in that the hydrorefined mineral oils are Base oil 60N and/or base oil 70N.
3. stainless-steel cold-rolling thin plate rolling oil according to claim 1 or 2, it is characterised in that the polyol-ester type oil Property agent is tricarboxymethyl propane oleate, the pungent decylate of trimethylolpropane oleic acid, pentaerythritol oleate or neopentyl glycol two In oleate any one or at least two combination.
4. the stainless-steel cold-rolling thin plate rolling oil according to any one of claim 1-3, it is characterised in that the extreme pressure Agent is polyester extreme pressure agent.
5. stainless-steel cold-rolling thin plate rolling oil according to claim 4, it is characterised in that the polyester extreme pressure agent is oil The polyester of dissolubility.
6. stainless-steel cold-rolling thin plate rolling oil according to claim 4 or 5, it is characterised in that the polyester extreme pressure agent Molecular weight be 12000-25000.
7. the stainless-steel cold-rolling thin plate rolling oil according to any one of claim 1-6, it is characterised in that the antirust Agent is any one or at least two in sulfonate, alkenyl succinate, fatty acid amide, benzotriazole or benzotriazole derivative Combination.
8. the stainless-steel cold-rolling thin plate rolling oil according to any one of claim 1-7, it is characterised in that the antioxygen Agent is dialkyl diphenylamine and/or the derivative of 2,6- di-tert-butylphenols.
CN201711339258.4A 2017-12-14 2017-12-14 A kind of low smell stainless-steel cold-rolling thin plate rolling oil Pending CN107955691A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711339258.4A CN107955691A (en) 2017-12-14 2017-12-14 A kind of low smell stainless-steel cold-rolling thin plate rolling oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711339258.4A CN107955691A (en) 2017-12-14 2017-12-14 A kind of low smell stainless-steel cold-rolling thin plate rolling oil

Publications (1)

Publication Number Publication Date
CN107955691A true CN107955691A (en) 2018-04-24

Family

ID=61958849

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711339258.4A Pending CN107955691A (en) 2017-12-14 2017-12-14 A kind of low smell stainless-steel cold-rolling thin plate rolling oil

Country Status (1)

Country Link
CN (1) CN107955691A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401275A (en) * 2018-09-11 2019-03-01 苏州市雄林新材料科技有限公司 A kind of high fire-retardance softness TPU film and preparation method thereof
CN110408456A (en) * 2018-04-28 2019-11-05 宝山钢铁股份有限公司 A kind of suitable single chassis reversable mill produces the cold rolling oil of high-strength steel product
CN110951529A (en) * 2019-12-24 2020-04-03 欧陆宝(天津)新材料科技有限公司 High-iron motor vehicle width viscosity temperature shock absorber oil and preparation method thereof
CN111040849A (en) * 2019-12-17 2020-04-21 上海帕卡兴产化工有限公司 Lubrication protective agent and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4181619A (en) * 1978-10-30 1980-01-01 Mobil Oil Corporation Antiwear composition
US20040204326A1 (en) * 2003-04-08 2004-10-14 Crompton Corporation Anti-oxidants in soluble oil base for metal working fluids
CN102399616A (en) * 2011-10-12 2012-04-04 彭美东 Synthetic circulating emulsified oil for rolling
CN105296117A (en) * 2015-11-26 2016-02-03 上海帕卡兴产化工有限公司 Environment-friendly low-odor rolling oil and preparation method thereof
CN106281592A (en) * 2016-07-14 2017-01-04 天津市澳路浦润滑科技股份有限公司 Stainless-steel cold-rolling thin plate rolling oil
CN106590843A (en) * 2016-11-30 2017-04-26 广州科卢斯流体科技有限公司 Precision stainless steel band cold-rolling rolling oil
JP2017110090A (en) * 2015-12-16 2017-06-22 大同化学工業株式会社 Cold rolled oil composition and cold rolling method

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4181619A (en) * 1978-10-30 1980-01-01 Mobil Oil Corporation Antiwear composition
US20040204326A1 (en) * 2003-04-08 2004-10-14 Crompton Corporation Anti-oxidants in soluble oil base for metal working fluids
CN102399616A (en) * 2011-10-12 2012-04-04 彭美东 Synthetic circulating emulsified oil for rolling
CN105296117A (en) * 2015-11-26 2016-02-03 上海帕卡兴产化工有限公司 Environment-friendly low-odor rolling oil and preparation method thereof
JP2017110090A (en) * 2015-12-16 2017-06-22 大同化学工業株式会社 Cold rolled oil composition and cold rolling method
CN106281592A (en) * 2016-07-14 2017-01-04 天津市澳路浦润滑科技股份有限公司 Stainless-steel cold-rolling thin plate rolling oil
CN106590843A (en) * 2016-11-30 2017-04-26 广州科卢斯流体科技有限公司 Precision stainless steel band cold-rolling rolling oil

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张旭等: "GP-600型高润滑性硅钢轧制油的研制及工业应用 ", 《炼油技术与工程》 *
张旭等: "GP-600型高润滑性硅钢轧制油的研制及工业应用", 《炼油技术与工程》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408456A (en) * 2018-04-28 2019-11-05 宝山钢铁股份有限公司 A kind of suitable single chassis reversable mill produces the cold rolling oil of high-strength steel product
CN109401275A (en) * 2018-09-11 2019-03-01 苏州市雄林新材料科技有限公司 A kind of high fire-retardance softness TPU film and preparation method thereof
CN111040849A (en) * 2019-12-17 2020-04-21 上海帕卡兴产化工有限公司 Lubrication protective agent and preparation method thereof
CN110951529A (en) * 2019-12-24 2020-04-03 欧陆宝(天津)新材料科技有限公司 High-iron motor vehicle width viscosity temperature shock absorber oil and preparation method thereof
CN110951529B (en) * 2019-12-24 2022-09-09 欧陆宝(天津)新材料科技有限公司 High-iron motor vehicle width viscosity temperature shock absorber oil and preparation method thereof

Similar Documents

Publication Publication Date Title
CN107955691A (en) A kind of low smell stainless-steel cold-rolling thin plate rolling oil
CN101016498A (en) Composition of cold rolling sheet rolling oil
CN108570341A (en) A kind of belt steel rolling oil and its production method
CN102994202A (en) Cold-strip steel rolling oil compound and preparation method thereof
CN102002416A (en) Cold rolling oil composition and use thereof
CN105154180A (en) Preparation method of rolling oil for cold rolling of sheets
CN106281592B (en) Stainless-steel cold-rolling thin plate rolling oil
CN105602674B (en) Biodegradable Process of Emulsifying Oil For Rolling composition and purposes
CN106590843A (en) Precision stainless steel band cold-rolling rolling oil
CN1126809C (en) Oil composition for cold rolling of stainless steel sheel
CN108865365A (en) Stable emulsifying type straight carbon steel cold rolling oil and application thereof
JP4020341B2 (en) Metalworking oil composition
CN112239695A (en) Plain carbon steel cold rolling oil composition and application thereof
JPH01139694A (en) Lubrication oil
CN105087122A (en) Rolling oil composition for cold-rolled stainless steel sheet and preparation method thereof
CN105623811A (en) Stainless steel calendaring plate dripping oil
JP2010195912A (en) Lubricant for press-working stainless alloy plate or steel plate, and method for press-working stainless alloy plate or steel plate therewith
CN106281600A (en) Anticorrosion type rolling oil composition and application thereof
JPH01301793A (en) Lubricating oil
CN105087121A (en) Rolling oil composition for cold rolling of middle-width strip steel plate and preparation method thereof
JP2010065134A (en) Lubricant for press-working stainless alloy plate or steel plate, and method for press-working stainless alloy plate or steel plate therewith
KR20000037610A (en) Hot rolling oil composition for rough rolling
CN105062627B (en) A kind of rolling oil composition and preparation method for broad strip mill
JPH0241392A (en) Lubricating oil
CN102925249A (en) Metal rolling oil macromolecule polybasic acid additives and preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
AD01 Patent right deemed abandoned

Effective date of abandoning: 20210924

AD01 Patent right deemed abandoned