CN107936752A - A kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint and preparation method thereof - Google Patents
A kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint and preparation method thereof Download PDFInfo
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- CN107936752A CN107936752A CN201711337949.0A CN201711337949A CN107936752A CN 107936752 A CN107936752 A CN 107936752A CN 201711337949 A CN201711337949 A CN 201711337949A CN 107936752 A CN107936752 A CN 107936752A
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- hollow glass
- glass micropearl
- fluorine carbon
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- insulation paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
A kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that hollow glass micropearl cleaning is deoiled first, surface roughening and coupling processing obtain surface coupling processing glass microballoon；Secondly titanium dioxide and lanthana are deposited on to the surface of hollow glass micropearl using hydro-thermal method, obtain modification hollow glass micropearl；Then, fluorine carbon emulsion is prepared by emulsion polymerization；Finally using fluorine carbon emulsion as film forming agent, modification hollow glass micropearl and other auxiliary agents are added, obtain a kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint.The reflective heat-insulation paint of the present invention, has the transmission and absorption compared with low heat conduction coefficient, reduced to infrared emanation energy, and heat insulation is good.
Description
Technical field
The invention belongs to building field, and in particular to a kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint and its preparation
Method.
Background technology
According to statistics, global building energy consumption accounts for the 41% of social total energy consumption, while the indirect discharge that building electricity consumption is brought adds
Building is only second to industry and transport service discharge using directly discharge accounts for 21% or so altogether caused by the initial stage energy.Therefore, build
Energy saving imperative, the emphasis of building energy conservation is exactly to optimize heat insulation system.Insulating mold coating is according to barrier, reflection, spoke
Penetrate mechanism and insulation is carried out to building, heating, air conditioning energy consumption can be reduced, reach energy saving purpose.With building coating industry
Develop rapidly, architectural heat insulation coating forms the compound insulating mold coating of a variety of insulating mechanisms synergistic effect and occurred frequently
Penetrate two kinds of development trends of rate insulating mold coating.Wherein high emissivity insulating mold coating is based on heat radiation principle, can be by coating
Absorb and heat is transmitted in air with certain wavelength, effective adjusting ambient temperature, therefore is subject to the extensive concern of researcher.
The content of the invention
It is an object of the invention to provide a kind of high reflectance hollow glass micropearl base fluorine carbon reflective heat-insulation paint and its
Preparation method.
In order to realize above-mentioned purpose, present invention employs following technical solution：
A kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that hollow glass micropearl cleaning is deoiled first,
Surface is roughened and coupling processing obtains surface coupling processing glass microballoon；Secondly titanium dioxide and lanthana are sunk using hydro-thermal method
Accumulate on the surface of hollow glass micropearl, obtain modification hollow glass micropearl；Then, fluorine carbon emulsion is prepared by emulsion polymerization；Most
Afterwards using fluorine carbon emulsion as film forming agent, modification hollow glass micropearl and other auxiliary agents are added, obtain a kind of hollow glass micropearl base
Fluorine carbon reflective heat-insulation paint.
The hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that it is prepared by following specific steps
Form：
（1）Glass microballoon is placed in magnetic agitation 20-30min cleanings in 80-90 DEG C of water of 10-12 times of parts by weight to deoil, water
Wash 2-3 times, be filtered by vacuum；Glass microballoon after cleaning is placed in magnetic force in the hydrofluoric acid solution of the 4-5% of 8-10 times of parts by weight to stir
Surface roughening 5-8min is mixed, washes 2-3 times, is filtered by vacuum, it is dry, obtain surface roughening glass microballoon；By silane coupling agent kh-
570 are added to the absolute ethyl alcohol of 25-30 times of parts by weight and deionized water with 1：In the mixed liquor of 1 mass ratio configuration, magnetic force stirs
50-60min is mixed, adds surface roughening glass microballoon, 60-65 DEG C of temperature constant magnetic stirring 4-5h, is filtered by vacuum, dry, obtains table
Face coupling processing glass microballoon；
（2）Titanium sulfate and lanthanum nitrate are added in 1/2 deionized water, rise temperature mixes to completely to 60-70 DEG C
Dissolving, adds urea, continues magnetic agitation 50-60min；Addition surface coupling processing glass microballoon, ultrasonic vibration 30-40min,
Remaining deionized water is added, is transferred in reaction kettle, is placed it in after sealing in homogeneous reactor, with 2-3 DEG C/min's
After speed is warming up to 140-150 DEG C, isothermal reaction 3-4h；After question response, filtering, with acetone, absolute ethyl alcohol and deionization
Water washs 2-3 times respectively, and 70-80 DEG C of vacuum drying, obtains modification hollow glass micropearl；
（3）Chlorotrifluoroethylene is added to the deionized water of 10-12 times of parts by weight, is added in reaction kettle, adds sodium carbonate, is adjusted
PH value is to 6-7；Perfluorobutyl ethylene, vinyltriethoxysilane and hydroxyethyl methacrylate are added, with 1000-1200r/
The speed high-speed stirred dispersion and emulsion 40-50min of min, obtains pre-emulsion；Logical nitrogen, rise temperature are added dropwise 1/2 to 60-70 DEG C
Ammonium persulfate solution, control and be added dropwise in 40-60min, 60-70 DEG C of isothermal reaction 3-4, be warming up to 75-85 DEG C continue it is anti-
Answer 1-2h；It is added dropwise remaining ammonium persulfate solution, adds diethylenetriamines, 50-60 DEG C of the reaction was continued 6-8h；Cool to 30
DEG C, sodium carbonate is added, the pH value of lotion is adjusted to 6-7, obtains fluorine carbon emulsion；
（4）Hydroxypropyl methyl cellulose, modification hollow glass micropearl and polyvinyl alcohol are added into fluorine carbon emulsion, with 1800-
The speed high-speed stirred 50-60min of 2000r/min；Sldium lauryl sulfate and diethylene glycol dimethyl ether are added, with 800-1000r/
The speed stirring at low speed 40-50min of min, obtains a kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint.
The preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that step（2）Middle sulphur
Sour titanium, lanthanum nitrate, urea, the mass ratio of surface coupling processing glass microballoon and deionized water are 1：0.2-0.25：0.5-0.6：
8-10：100-120.
The preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that step（3）In three
Fluorine vinyl chloride, perfluorobutyl ethylene, vinyltriethoxysilane, hydroxyethyl methacrylate, ammonium persulfate solution and two are sub-
The mass ratio of ethyl triamine is 1：0.6-0.7：6-8：1.5-2：0.8-1：0.6-0.8.
The preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that step（3）Middle mistake
The concentration of ammonium sulfate is 0.4-0.5mol/L.
The preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that step（4）Middle fluorine
Carbon emulsion, hydroxypropyl methyl cellulose, modification hollow glass micropearl, polyvinyl alcohol, sldium lauryl sulfate and diethylene glycol diformazan
The mass ratio of ether is 1：0.03-0.04：0.15-0.2：0.2-0.25：0.04-0.05：0.02-0.03.
By above-mentioned technical solution, the beneficial effects of the invention are as follows：
The present invention deoils hollow glass micropearl cleaning, surface roughening and coupling processing obtain surface coupling processing glass microballoon；
Then titanium dioxide and lanthana are deposited on to the surface of hollow glass micropearl using hydro-thermal method, it is micro- to obtain modification hollow glass
Pearl；Hollow glass micropearl is modified as the heat insulating function filler of reflective heat-insulation paint using this, one side cenosphere is as one
The big thermal inertia hollow structure material of kind, has the transmission and absorption compared with low heat conduction coefficient, reduced to infrared emanation energy；Separately
On the one hand, deposit the titanium dioxide on hollow glass micropearl surface and lanthana can absorb infra-red radiation in air, and by this spoke
Penetrate energy to reflect away, so that separating thermal energy enters basic unit, obtain good heat insulation；The present invention is with chlorotrifluoroethylene, complete
The fluorocarbon resin that fluorine butylethylene and vinyltriethoxysilane polymerize is film forming agent, then with hydroxyethyl methacrylate
It is cross-linking modified to fluorocarbon resin progress with diethylenetriamines, the toughness and weatherability of coating are enhanced, improves the resistance to of coating
Mill property and adhesion property.The present invention coating good heat-insulation effect and there is excellent mechanical performance, excellent adhesive force；Excellent
Weatherability, water resistance, stain resistance, abrasion resistance etc.；Safety and environmental protection, it is applied widely.
Embodiment
The hollow glass micropearl base fluorine carbon reflective heat-insulation paint of the present embodiment, it is prepared by following specific steps：
（1）Glass microballoon is placed in magnetic agitation 30min cleanings in 85 DEG C of water of 12 times of parts by weight to deoil, is washed 3 times, vacuum
Filter；Glass microballoon after cleaning is placed in magnetic agitation surface in 5% hydrofluoric acid solution of 10 times of parts by weight and is roughened 8min,
Washing 3 times, is filtered by vacuum, dry, obtains surface roughening glass microballoon；Silane coupling agent kh-570 is added to 30 times of parts by weight
Absolute ethyl alcohol and deionized water with 1：In the mixed liquor of 1 mass ratio configuration, magnetic agitation 60min, adds surface roughening glass
Glass microballon, 65 DEG C of temperature constant magnetic stirring 5h, are filtered by vacuum, dry, obtain surface coupling processing glass microballoon；
（2）Titanium sulfate and lanthanum nitrate are added in 1/2 deionized water, rise temperature mixes to completely molten to 70 DEG C
Solution, adds urea, continues magnetic agitation 60min；Surface coupling processing glass microballoon is added, ultrasonic vibration 40min, adds remaining
Deionized water, be transferred in reaction kettle, placed it in after sealing in homogeneous reactor, is warming up to the speed of 3 DEG C/min
After 150 DEG C, isothermal reaction 4h；After question response, filtering, 3 times are washed with acetone, absolute ethyl alcohol and deionized water respectively, and 80
DEG C vacuum drying, obtain modification hollow glass micropearl；
（3）Chlorotrifluoroethylene is added to the deionized water of 12 times of parts by weight, is added in reaction kettle, adds sodium carbonate, adjusts pH
It is worth to 6-7；Perfluorobutyl ethylene, vinyltriethoxysilane and hydroxyethyl methacrylate are added, with the speed of 1200r/min
Rate high-speed stirred dispersion and emulsion 50min, obtains pre-emulsion；Logical nitrogen, rise temperature to 70 DEG C, be added dropwise 1/2 ammonium persulfate it is molten
Liquid, controls and is added dropwise in 60min, 70 DEG C of isothermal reactions 4, is warming up to 85 DEG C the reaction was continued 2h；Remaining ammonium persulfate is added dropwise
Solution, adds diethylenetriamines, 60 DEG C of the reaction was continued 6h；Cool to 30 DEG C, add sodium carbonate, adjust the pH value of lotion to 6-
7, obtain fluorine carbon emulsion；
（4）Hydroxypropyl methyl cellulose, modification hollow glass micropearl and polyvinyl alcohol are added into fluorine carbon emulsion, with 1800r/
The speed high-speed stirred 60min of min；Sldium lauryl sulfate and diethylene glycol dimethyl ether are added, with the speed low speed of 1000r/min
50min is stirred, obtains a kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint.
The step of the present embodiment（2）Middle titanium sulfate, lanthanum nitrate, urea, surface coupling processing glass microballoon and deionized water
Mass ratio be 1：0.25：0.5：10：120.
The step of the present embodiment（3）Middle chlorotrifluoroethylene, perfluorobutyl ethylene, vinyltriethoxysilane, methyl-prop
The mass ratio of olefin(e) acid hydroxyl ethyl ester, ammonium persulfate solution and diethylenetriamines is 1：0.7：8：2：0.8：0.6.
The step of the present embodiment（3）The concentration of middle ammonium persulfate solution is 0.5mol/L.
The step of the present embodiment（4）Middle fluorine carbon emulsion, hydroxypropyl methyl cellulose, modification hollow glass micropearl, polyethylene
The mass ratio of alcohol, sldium lauryl sulfate and diethylene glycol dimethyl ether is 1：0.04：0.2：0.25：0.05：0.03.
Claims (6)
1. a kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint, it is characterised in that first go hollow glass micropearl cleaning
Oil, surface roughening and coupling processing obtain surface coupling processing glass microballoon；Secondly hydro-thermal method is used by titanium dioxide and oxidation
Lanthanum is deposited on the surface of hollow glass micropearl, obtains modification hollow glass micropearl；Then, fluorine carbon breast is prepared by emulsion polymerization
Liquid；Finally using fluorine carbon emulsion as film forming agent, modification hollow glass micropearl and other auxiliary agents are added, it is micro- to obtain a kind of hollow glass
Pearl base fluorine carbon reflective heat-insulation paint.
2. the hollow glass micropearl base fluorine carbon reflective heat-insulation paint according to claims 1, it is characterised in that it is by as follows
Specific steps are prepared：
（1）Glass microballoon is placed in magnetic agitation 20-30min cleanings in 80-90 DEG C of water of 10-12 times of parts by weight to deoil, water
Wash 2-3 times, be filtered by vacuum；Glass microballoon after cleaning is placed in magnetic force in the hydrofluoric acid solution of the 4-5% of 8-10 times of parts by weight to stir
Surface roughening 5-8min is mixed, washes 2-3 times, is filtered by vacuum, it is dry, obtain surface roughening glass microballoon；By silane coupling agent kh-
570 are added to the absolute ethyl alcohol of 25-30 times of parts by weight and deionized water with 1：In the mixed liquor of 1 mass ratio configuration, magnetic force stirs
50-60min is mixed, adds surface roughening glass microballoon, 60-65 DEG C of temperature constant magnetic stirring 4-5h, is filtered by vacuum, dry, obtains table
Face coupling processing glass microballoon；
（2）Titanium sulfate and lanthanum nitrate are added in 1/2 deionized water, rise temperature mixes to completely to 60-70 DEG C
Dissolving, adds urea, continues magnetic agitation 50-60min；Addition surface coupling processing glass microballoon, ultrasonic vibration 30-40min,
Remaining deionized water is added, is transferred in reaction kettle, is placed it in after sealing in homogeneous reactor, with 2-3 DEG C/min's
After speed is warming up to 140-150 DEG C, isothermal reaction 3-4h；After question response, filtering, with acetone, absolute ethyl alcohol and deionization
Water washs 2-3 times respectively, and 70-80 DEG C of vacuum drying, obtains modification hollow glass micropearl；
（3）Chlorotrifluoroethylene is added to the deionized water of 10-12 times of parts by weight, is added in reaction kettle, adds sodium carbonate, is adjusted
PH value is to 6-7；Perfluorobutyl ethylene, vinyltriethoxysilane and hydroxyethyl methacrylate are added, with 1000-1200r/
The speed high-speed stirred dispersion and emulsion 40-50min of min, obtains pre-emulsion；Logical nitrogen, rise temperature are added dropwise 1/2 to 60-70 DEG C
Ammonium persulfate solution, control and be added dropwise in 40-60min, 60-70 DEG C of isothermal reaction 3-4, be warming up to 75-85 DEG C continue it is anti-
Answer 1-2h；It is added dropwise remaining ammonium persulfate solution, adds diethylenetriamines, 50-60 DEG C of the reaction was continued 6-8h；Cool to 30
DEG C, sodium carbonate is added, the pH value of lotion is adjusted to 6-7, obtains fluorine carbon emulsion；
（4）Hydroxypropyl methyl cellulose, modification hollow glass micropearl and polyvinyl alcohol are added into fluorine carbon emulsion, with 1800-
The speed high-speed stirred 50-60min of 2000r/min；Sldium lauryl sulfate and diethylene glycol dimethyl ether are added, with 800-1000r/
The speed stirring at low speed 40-50min of min, obtains a kind of hollow glass micropearl base fluorine carbon reflective heat-insulation paint.
3. the preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint according to claims 2, its feature exist
In step（2）Middle titanium sulfate, lanthanum nitrate, urea, the mass ratio of surface coupling processing glass microballoon and deionized water are 1：0.2-
0.25：0.5-0.6：8-10：100-120.
4. the preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint according to claims 2, its feature exist
In step（3）Middle chlorotrifluoroethylene, perfluorobutyl ethylene, vinyltriethoxysilane, hydroxyethyl methacrylate, over cure
The mass ratio of acid ammonium solution and diethylenetriamines is 1：0.6-0.7：6-8：1.5-2：0.8-1：0.6-0.8.
5. the preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint according to claims 2, its feature exist
In step（3）The concentration of middle ammonium persulfate solution is 0.4-0.5mol/L.
6. the preparation method of the hollow glass micropearl base fluorine carbon reflective heat-insulation paint according to claims 2, its feature exist
In step（4）Middle fluorine carbon emulsion, hydroxypropyl methyl cellulose, modification hollow glass micropearl, polyvinyl alcohol, sldium lauryl sulfate
Mass ratio with diethylene glycol dimethyl ether is 1：0.03-0.04：0.15-0.2：0.2-0.25：0.04-0.05：0.02-0.03.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795256A (en) * | 2018-07-11 | 2018-11-13 | 佛山市陵谐环保科技有限公司 | A kind of heat insulation coating and preparation method thereof |
| CN109486305A (en) * | 2018-11-12 | 2019-03-19 | 山西大学 | A kind of dedicated Eyeshield energy-saving blast coating in classroom and its preparation method and application |
| CN111620625A (en) * | 2020-05-28 | 2020-09-04 | 广东复特新型材料科技有限公司 | Compression-resistant heat-insulation mortar without hollowing |
| CN111995883A (en) * | 2019-05-27 | 2020-11-27 | 中国石油化工股份有限公司 | Preparation method of metal oxide/hollow microsphere composite filler |
| CN113201258A (en) * | 2021-04-30 | 2021-08-03 | 东莞大宝化工制品有限公司 | Water-based high-reflection transparent finish paint and preparation method thereof |
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| CN102226042A (en) * | 2011-04-20 | 2011-10-26 | 天津恒实通工程技术发展有限公司 | Method for coating hollow microbeads with titanium-lanthanum oxides |
| CN103483944A (en) * | 2013-09-30 | 2014-01-01 | 海南大学 | Light-reflection, heat-insulation and anticorrosion paint and preparation method thereof |
| CN106497257A (en) * | 2016-09-27 | 2017-03-15 | 安徽吉思特智能装备有限公司 | Heat-insulated radial pattern coating of the enhanced fluorine carbon of a kind of Titanium Dioxide and preparation method thereof |
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2017
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| CN102226042A (en) * | 2011-04-20 | 2011-10-26 | 天津恒实通工程技术发展有限公司 | Method for coating hollow microbeads with titanium-lanthanum oxides |
| CN103483944A (en) * | 2013-09-30 | 2014-01-01 | 海南大学 | Light-reflection, heat-insulation and anticorrosion paint and preparation method thereof |
| CN106497257A (en) * | 2016-09-27 | 2017-03-15 | 安徽吉思特智能装备有限公司 | Heat-insulated radial pattern coating of the enhanced fluorine carbon of a kind of Titanium Dioxide and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795256A (en) * | 2018-07-11 | 2018-11-13 | 佛山市陵谐环保科技有限公司 | A kind of heat insulation coating and preparation method thereof |
| CN109486305A (en) * | 2018-11-12 | 2019-03-19 | 山西大学 | A kind of dedicated Eyeshield energy-saving blast coating in classroom and its preparation method and application |
| CN111995883A (en) * | 2019-05-27 | 2020-11-27 | 中国石油化工股份有限公司 | Preparation method of metal oxide/hollow microsphere composite filler |
| CN111995883B (en) * | 2019-05-27 | 2021-11-09 | 中国石油化工股份有限公司 | Preparation method of metal oxide/hollow microsphere composite filler |
| CN111620625A (en) * | 2020-05-28 | 2020-09-04 | 广东复特新型材料科技有限公司 | Compression-resistant heat-insulation mortar without hollowing |
| CN113201258A (en) * | 2021-04-30 | 2021-08-03 | 东莞大宝化工制品有限公司 | Water-based high-reflection transparent finish paint and preparation method thereof |
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Application publication date: 20180420 |