CN107930374A - A kind of efficient oxidation wet desulfurization system - Google Patents

A kind of efficient oxidation wet desulfurization system Download PDF

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Publication number
CN107930374A
CN107930374A CN201711224457.0A CN201711224457A CN107930374A CN 107930374 A CN107930374 A CN 107930374A CN 201711224457 A CN201711224457 A CN 201711224457A CN 107930374 A CN107930374 A CN 107930374A
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China
Prior art keywords
pressure
air
spray ring
spraying layer
pump
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CN201711224457.0A
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Chinese (zh)
Inventor
倪飞
冯翼飞
刘兴亚
高华金
张文彬
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Jiangsu Minsheng Heavy Industry Co Ltd
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Jiangsu Minsheng Heavy Industry Co Ltd
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Priority to CN201711224457.0A priority Critical patent/CN107930374A/en
Publication of CN107930374A publication Critical patent/CN107930374A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/504Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of efficient oxidation wet desulfurization system, including desulfurizing tower, gas inlet and exhanst gas outlet are provided with the desulfurizing tower, catch basin is formed on the bottom of the desulfurizing tower, the gas inlet is connected with exhaust gases passes, hybrid hydrostatic case is provided with the exhaust gases passes, the exhaust gases passes of the hybrid hydrostatic case leading portion are mixing flue, the first pressure-air spray ring perpendicular with airflow direction is provided with the mixing flue, the windward side of the first pressure-air spray ring is evenly arranged with multiple spiral nozzles, the first pressure-air spray ring is connected with high-pressure pump.At least one spiral fan blade is provided with the middle part of the hybrid hydrostatic case, the hybrid hydrostatic case upper wall is provided with multiple cleaning sprayers, and the bottom of the hybrid hydrostatic case is provided with inclined floor, and the lower end of the inclined floor is connected by sewage draining valve with dredge pump.The present invention has the advantages that dependable performance, oxidation efficiency are high, operating cost is low, desulfurization effect is preferable.

Description

A kind of efficient oxidation wet desulfurization system
Technical field
The present invention relates to technical field of waste gas treatment, and in particular to a kind of efficient oxidation wet desulfurization system.
Background technology
With rapid development of economy, the industry such as electric power, metallurgy, chemical industry and building materials produces substantial amounts of cigarette containing sulfur dioxide Gas, is discharged into air and pollutes, and sulfur dioxide becomes one of Air Pollutant Discharge.In order to eliminate sulfur dioxide pollution, people Many methods for reducing SO2 emissions are found through great efforts, wherein with the most use with wet desulphurization.Usual wet desulphurization When directly obtain be sulfur dioxide and be modulated into " slurries " shape absorbent reaction generation sulphite, in many cases for Easy to desulfurization product recycling, it is necessary to sulfite oxidation into sulfate.Although contain in the flue gas containing sulfur dioxide A certain amount of oxygen, can play the role of ite being oxidized to sulfate, but oxygen content is relatively low in flue gas after all, it is impossible to Ite is completely oxidized to sulfate, it is necessary to other supplemental oxygen.The industrial absorption tower bottom that is typically employed in sets catch basin, The sulphite " slurries " stored into catch basin is passed through air, oxidative salt in the form of bubbling.For example, with lime stone Or lime is absorbent, remove flue gas in sulfur dioxide when, absorption tower bottom be provided with storage absorbent lime stone or lime and The circulating slot of desulfurization product calcium sulfite " slurries ", air is blasted to circulating slot, makes calcium sulfite oxidation into easy to recycling Calcium sulfate (gypsum).
There are two defects for this method that air oxidation sulphite is passed through in the form of bubbling:" bubbling " mode mass transfer Efficiency is low, and coefficient of oxygen utilization is low, and required air quantity is big, increases flue gas after desulfurization amount;The air being passed through will pass through " slurries " layer, gram The resistance that clothes " slurries " layer is formed, overcomes resistance to require the expenditure of energy, it is desirable to which oxidation effectiveness is good, and " slurries " layer passed through is got over Thickness, resistance is bigger, and energy consumption is higher.During practical application, in order to reach best oxidation effectiveness, aeration tube is set, is opened up on pipe The air outlet slit of even distribution, enables air to be uniformly distributed on slot cross-section catchmenting;" slurries " that increase air passes through as far as possible at the same time Layer thickness.So necessarily cause the pressure head increase for conveying the air blower of air, increase energy expenditure.A kind of therefore it provides oxidation It is efficient, operating cost is low, the preferable wet desulfurization system of desulfurization effect becomes urgent problem to be solved.
The content of the invention
For the above problem of the prior art, it is an object of the present invention to provide a kind of desulfuration efficiency height, operating cost The significant efficient oxidation wet desulfurization system of oxidation effectiveness low, to sulphite.
To reach above-mentioned purpose, the technical solution adopted by the present invention is:A kind of efficient oxidation wet desulfurization system, including it is de- Sulphur tower, gas inlet and exhanst gas outlet are provided with the desulfurizing tower, and catch basin is formed on the bottom of the desulfurizing tower;It is described to catchment Agitating device, aeration tube are provided with groove, the aeration tube is connected with Aeration fan;The catch basin is also supplied with slurries respectively Pump is drawn to pump, gypsum to be connected;
The desulfurizing tower top is disposed with the first spraying layer, the second spraying layer, the 3rd spraying layer from up to down, each spray The nozzle misalignment of drenching layer is set, and the first spraying layer, the nozzle of the second spraying layer are set downward, and the nozzle of the 3rd spraying layer is upward Set;Each spraying layer passes sequentially through air and liquid mixer, circulating pump, filtration apparatus and is connected with catch basin, the air and liquid mixer Also it is connected with pure air supply pump;The connector of the filtration apparatus and catch basin is arranged at the top of catch basin;
The gas inlet 3 is connected with exhaust gases passes, and hybrid hydrostatic case, the mixing are provided with the exhaust gases passes The exhaust gases passes of plenum chamber leading portion are mixing flue, and first high pressure perpendicular with airflow direction is provided with the mixing flue Air spray ring, the windward side of the first pressure-air spray ring are evenly arranged with multiple spiral nozzles, first pressure-air Spray ring is connected with high-pressure pump;
At least one spiral fan blade is provided with the middle part of the hybrid hydrostatic case, the hybrid hydrostatic case upper wall is provided with multiple Cleaning sprayer, the bottom of the hybrid hydrostatic case are provided with inclined floor, the lower end of the inclined floor by sewage draining valve with Dredge pump is connected;
The filtration apparatus includes filter screen, and the filter screen is towards scraper plate is provided with a side surface of catch basin, also Including the fixed rotating shaft positioned at filter screen center position and the setting of vertically passing screen surface, it is provided with the fixed rotating shaft First bevel gear, the fixed rotating shaft are fixedly connected with scraper plate, further include cleaning motor, the head of the output shaft for cleaning motor Portion is provided with the second bevel gear cooperated with each other with first bevel gear.
Further, the slurries supply pump is connected with limestone slurry liquid case, Limestone silo successively;The gypsum is drawn Pump be connected successively with gypsum cyclone, gypsum dehydration machine, the gypsum dehydration machine is connected with filtrate receiver, the filtrate receiver and Catch basin is connected.
Further, in the desulfurizing tower demister is provided with above the first spraying layer.
Further, further include control unit, described control unit respectively with Aeration fan, high-pressure pump, pure air Supply pump is connected.
Further, the quantity of the spiral fan blade is 3.
Further, it is also respectively provided with flow control valve on the connecting line of each spraying layer and air and liquid mixer.
Further, the second pressure-air spray ring being connected with high-pressure pump, the second pressure-air spray are further included Ring close on the first pressure-air spray ring set and it is parallel to each other with it, the front and rear sides of the second pressure-air spray ring are all provided with Multiple spiral nozzles are equipped with, the second pressure-air spray ring is arranged at the front portion of the first pressure-air spray ring.
In addition, in technical solution of the present invention, it is all not do what is illustrated, it can use the conventional hand in this area Section realizes the technical program.
The present invention has the following advantages:The present invention is realized by three kinds of different modes supplements air into flue gas, and cigarette Gas can sufficiently be mixed with air, desulfurization slurry, can be carried out sufficient oxidation reaction to calcium sulfite, be realized efficient Desulfurization.And the air capacity that different modes are pumped into can be adjusted in the setting of control unit, while oxidation effectiveness is ensured Operating cost can be reduced as far as possible.This is provided with filtration apparatus to the present invention, by setting filtration apparatus effectively to reduce The probability that nozzle is blocked, ensures the long-time steady operation of system.The present invention has dependable performance, oxidation efficiency height, operation The advantages that cost is low, desulfurization effect is preferable, is conducive to large-scale promotion application.
Brief description of the drawings
Fig. 1 is the structure diagram of the present invention;
Fig. 2 is the structure diagram of filtration apparatus of the present invention.
In figure:1st, desulfurizing tower;2nd, catch basin;3rd, gas inlet;4th, exhanst gas outlet;5th, hybrid hydrostatic case;6th, flue is mixed; 7th, the first pressure-air spray ring;8th, spiral nozzle;9th, high-pressure pump;10th, cleaning sprayer;11st, spiral fan blade;12nd, inclined floor; 13rd, sewage draining valve;14th, dredge pump;15th, the first spraying layer;16th, the second spraying layer;17th, the 3rd spraying layer;18th, circulating pump;19、 Filtration apparatus;20th, air and liquid mixer;21st, pure air supply pump;22nd, Limestone silo;23rd, limestone slurry liquid case;24th, slurries Supply pump;25th, agitating device;26th, aeration tube;27th, Aeration fan;28th, gypsum draws pump;29th, gypsum cyclone;30th, gypsum Dewaterer;31st, filtrate receiver;32nd, demister;33rd, filter screen;34th, scraper plate;35th, fixed rotating shaft, 36, cleaning motor, 37, output Axis, 38 first bevel gears;39th, second bevel gear.
Embodiment
The present invention will be further described below in conjunction with the accompanying drawings.
Referring to Fig. 1-2, a kind of efficient oxidation wet desulfurization system, including desulfurizing tower 1, is provided with cigarette on the desulfurizing tower 1 Catch basin 2 is formed on gas import 3 and exhanst gas outlet 4, the bottom of the desulfurizing tower 1;Be provided with the catch basin agitating device 25, Aeration tube 26, the aeration tube 26 are connected with Aeration fan 27;The catch basin also draws with slurries supply pump 24, gypsum respectively Go out pump 28 to be connected.
1 top of desulfurizing tower is disposed with the first spraying layer 15, the second spraying layer 16, the 3rd spraying layer from up to down 17, the nozzle misalignment of each spraying layer is set, and the first spraying layer 15, the nozzle of the second spraying layer 16 are set downward, the 3rd spray The nozzle of layer 17 is set upward.By the nozzle for each spraying layer that is staggered, can strengthen spraying slurries to tower body inside Coverage rate.And the nozzle for setting the 3rd spraying layer 17 is upward, on the one hand expands and spray the moving regions of slurries, extend slurries with The incorporation time of flue gas, on the other hand makes the slurries of sprinkling mutually collide, and makes slurries more scattered, increase and the contact surface of flue gas Product, and then improve desulfuration efficiency.
Each spraying layer passes sequentially through air and liquid mixer 20, circulating pump 18, filtration apparatus 19 and is connected with catch basin 2, described Air and liquid mixer 20 is also connected with pure air supply pump 21;The connector of the filtration apparatus 19 and catch basin 2 is arranged at The top of catch basin 2.Compressed air is mixed with slurries by air and liquid mixer, on the one hand can be due to compressed air it is swollen Swollen effect, makes the drop smaller, thinner of the slurries of ejection, so as to expand the contact area and area coverage of slurries and flue gas, increases Big desulfuration efficiency;On the other hand the blocking probability of nozzle can be also reduced, finally, additionally it is possible to improve containing for flue gas in desulfurizing tower 1 Oxygen amount, improves the oxidation effectiveness of sulphite.
The gas inlet 3 is connected with exhaust gases passes, and hybrid hydrostatic case 5 is provided with the exhaust gases passes, described mixed The exhaust gases passes for closing 5 leading portion of plenum chamber are mixing flue 6, and the perpendicular with airflow direction is provided with the mixing flue 6 One pressure-air spray ring 7, the windward side of the first pressure-air spray ring 7 are evenly arranged with multiple spiral nozzles 8, and described first Pressure-air spray ring 7 is connected with high-pressure pump 9.
Air is injected into flue gas by the first pressure-air spray ring 7, and then improves the oxygen content of flue gas, the present invention first The anchor ring of pressure-air spray ring 7 and flue gas stream direction are perpendicular, and the side of the side windward of the first pressure-air spray ring 7 It is upper vertical, be uniformly provided with multiple spiral nozzles 8, so under the action of incoming flue gas, the high pressure that spiral nozzle 8 sprays is empty Air-flow is more disorderly, and then can greatly improve the mixed effect of flue gas and air.
As a preferred embodiment, further include the second pressure-air spray ring (not shown) being connected with high-pressure pump 9, institute State the second pressure-air spray ring and close on the first pressure-air spray ring 7 and set and, second pressure-air parallel to each other with it The front and rear sides of spray ring are both provided with multiple spiral nozzles, and the second pressure-air spray ring is arranged at the first pressure-air spray ring 7 front portion.Nozzle so on the inside of two pressure-air spray rings can interact, and the air-flow of ejection is mutually touched Hit, air stream is more spread, be conducive to the mixing of air and flue gas.
The middle part of hybrid hydrostatic case 5 is provided with least one spiral fan blade 11, and 5 upper wall of hybrid hydrostatic case is provided with Multiple cleaning sprayers 10, the bottom of the hybrid hydrostatic case 5 are provided with inclined floor 12, and the lower end of the inclined floor 12 passes through Sewage draining valve 13 is connected with dredge pump 14.
The setting of hybrid hydrostatic case 5, especially sets spiral fan blade 11, can greatly promote flue gas and air inside it Mixing, to be ready in advance to the oxidation of calcium sulfite in desulfurizing tower.And since hybrid hydrostatic case 5 works long hours Inside will necessarily gather many flue dust, therefore be provided with cleaning sprayer 10, and inclined floor 12 dips down along flow of flue gas direction Tiltedly, very easily hybrid hydrostatic case 5 can be cleaned, and last blowdown work.
The filtration apparatus 19 includes filter screen 33, and the filter screen 33 is towards being provided with a side surface of catch basin 2 Scraper plate 34, further includes the fixed rotating shaft 35 positioned at filter screen center position and the setting of vertically passing screen surface, the fixation First bevel gear 38 is provided with shaft 35, the fixed rotating shaft 35 is fixedly connected with scraper plate 34, is further included and is cleaned motor 36, institute The head for stating the output shaft 37 for cleaning motor 36 is provided with the second bevel gear 39 cooperated with each other with first bevel gear 38.Cross The setting of strainer 33 can effectively reduce the blocking probability of spraying layer nozzle, and set the components such as motor and scraper plate, can be timely Cleaning is blocked in lime white, calcium plaster coagulation on filter screen 33, can ensure the long-time steady operation of filtration apparatus 19.
As a preferred embodiment, the slurries supply pump 24 is connected with limestone slurry liquid case 23, Limestone silo 22 successively;Institute State gypsum extraction pump 28 successively with gypsum cyclone 29, gypsum dehydration machine 30 to be connected, the gypsum dehydration machine 30 and filtrate receiver 31 are connected, and the filtrate receiver 31 is connected with catch basin 2.It is provided with the desulfurizing tower 1 positioned at the top of the first spraying layer 15 Demister 32.
Further include control unit, described control unit respectively with Aeration fan 27, high-pressure pump 9, pure air supply pump 21 are connected.By setting control unit, the oxidization condition of calcium sulfite, in time control can be adjusted according in desulfurizing tower 1 The air capacity that Aeration fan 27, high-pressure pump 9, pure air supply pump 21 supply, so that reaching the premise of oxidation requirements Under, the air capacity being pumped into flue gas is minimum, the minimum effect of operating cost.
The quantity of the spiral fan blade 11 is 3.Each spraying layer with also setting respectively on the connecting line of air and liquid mixer 20 It is equipped with flow control valve.By setting flow control valve, the pressure of each spraying layer can be adjusted, and then spraying effect is made Adjustment.
As being well known that, in order to be controlled to the current in each connecting line, in attached drawing 1 although it is not shown, but It is that multiple shut-off valves, flow valve, booster pump etc. can be set according to the actual requirements in each pipeline, does not go to live in the household of one's in-laws on getting married further herein State.
Finally it should be noted that:The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although The present invention is described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that:It still may be used To modify to the technical solution described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic; And these modification or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical solution spirit and Scope.

Claims (7)

1. a kind of efficient oxidation wet desulfurization system, including desulfurizing tower, it is provided with gas inlet on the desulfurizing tower and flue gas goes out Mouthful, catch basin is formed on the bottom of the desulfurizing tower;Be provided with agitating device, aeration tube in the catch basin, the aeration tube with Aeration fan is connected;The catch basin also draws pump with slurries supply pump, gypsum respectively and is connected;It is characterized in that:
The desulfurizing tower top is disposed with the first spraying layer, the second spraying layer, the 3rd spraying layer, each spraying layer from up to down Nozzle misalignment set, and the first spraying layer, the nozzle of the second spraying layer are set downward, and the nozzle of the 3rd spraying layer is set upward Put;Each spraying layer passes sequentially through air and liquid mixer, circulating pump, filtration apparatus and is connected with catch basin, and the air and liquid mixer is also It is connected with pure air supply pump;The connector of the filtration apparatus and catch basin is arranged at the top of catch basin;
The gas inlet is connected with exhaust gases passes, and hybrid hydrostatic case, the hybrid hydrostatic are provided with the exhaust gases passes The exhaust gases passes of case leading portion are mixing flue, and first pressure-air perpendicular with airflow direction is provided with the mixing flue Spray ring, the windward side of the first pressure-air spray ring are evenly arranged with multiple spiral nozzles, the first pressure-air spray ring It is connected with high-pressure pump;
At least one spiral fan blade is provided with the middle part of the hybrid hydrostatic case, the hybrid hydrostatic case upper wall is provided with multiple cleanings Nozzle, the bottom of the hybrid hydrostatic case are provided with inclined floor, and the lower end of the inclined floor passes through sewage draining valve and blowdown Pump is connected;
The filtration apparatus includes filter screen, and the filter screen is further included towards scraper plate is provided with a side surface of catch basin Positioned at filter screen center position and the fixed rotating shaft of vertically passing screen surface setting, first is provided with the fixed rotating shaft Bevel gear, the fixed rotating shaft are fixedly connected with scraper plate, further include cleaning motor, and the head of the output shaft for cleaning motor is set It is equipped with the second bevel gear cooperated with each other with first bevel gear.
2. efficient oxidation wet desulfurization system according to claim 1, it is characterised in that:The slurries supply pump successively with Limestone slurry liquid case, Limestone silo are connected;The gypsum draws pump and is connected successively with gypsum cyclone, gypsum dehydration machine, The gypsum dehydration machine is connected with filtrate receiver, and the filtrate receiver is connected with catch basin.
3. efficient oxidation wet desulfurization system according to claim 1 or 2, it is characterised in that:It is located in the desulfurizing tower Demister is provided with above first spraying layer.
4. efficient oxidation wet desulfurization system according to any one of claim 1-3, it is characterised in that:Further include control Unit, described control unit are connected with Aeration fan, high-pressure pump, pure air supply pump respectively.
5. the efficient oxidation wet desulfurization system according to any one of claim 1-4, it is characterised in that:The spiral wind The quantity of leaf is 3.
6. the efficient oxidation wet desulfurization system according to any one of claim 1-5, it is characterised in that:Each spraying layer with Flow control valve is also respectively provided with the connecting line of air and liquid mixer.
7. the efficient oxidation wet desulfurization system according to any one of claim 1-5, it is characterised in that:Further include and height The second pressure-air spray ring that compression pump is connected, the second pressure-air spray ring are closed on the first pressure-air spray ring and are set simultaneously And it is parallel to each other with it, the front and rear sides of the second pressure-air spray ring are both provided with multiple spiral nozzles, and described second is high Pressure air spray ring is arranged at the front portion of the first pressure-air spray ring.
CN201711224457.0A 2017-11-28 2017-11-28 A kind of efficient oxidation wet desulfurization system Pending CN107930374A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2510149Y (en) * 2001-12-06 2002-09-11 杨振坤 Double helical-blade guiding dust-collection and desulfurization apparatus
CN204034551U (en) * 2014-07-30 2014-12-24 浙江天洁环境科技股份有限公司 A kind of flue gas desulfurization device
CN205164488U (en) * 2015-10-22 2016-04-20 中国石油化工股份有限公司 Mixed flue gas wet flue gas desulfurization device of fire coal - catalysis
CN105749725A (en) * 2016-05-14 2016-07-13 张波 Desulfurizing tower system with oxidation device of improved structure
CN206199003U (en) * 2016-11-17 2017-05-31 大唐环境产业集团股份有限公司 A kind of wet desulphurization absorption tower carries effect device
CN208287797U (en) * 2017-11-28 2018-12-28 江苏民生重工有限公司 A kind of efficient oxidation wet desulfurization system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2510149Y (en) * 2001-12-06 2002-09-11 杨振坤 Double helical-blade guiding dust-collection and desulfurization apparatus
CN204034551U (en) * 2014-07-30 2014-12-24 浙江天洁环境科技股份有限公司 A kind of flue gas desulfurization device
CN205164488U (en) * 2015-10-22 2016-04-20 中国石油化工股份有限公司 Mixed flue gas wet flue gas desulfurization device of fire coal - catalysis
CN105749725A (en) * 2016-05-14 2016-07-13 张波 Desulfurizing tower system with oxidation device of improved structure
CN206199003U (en) * 2016-11-17 2017-05-31 大唐环境产业集团股份有限公司 A kind of wet desulphurization absorption tower carries effect device
CN208287797U (en) * 2017-11-28 2018-12-28 江苏民生重工有限公司 A kind of efficient oxidation wet desulfurization system

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