CN107903787A - A kind of concrete penetrating colorants and its application - Google Patents
A kind of concrete penetrating colorants and its application Download PDFInfo
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- CN107903787A CN107903787A CN201711354092.3A CN201711354092A CN107903787A CN 107903787 A CN107903787 A CN 107903787A CN 201711354092 A CN201711354092 A CN 201711354092A CN 107903787 A CN107903787 A CN 107903787A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention relates to a kind of concrete penetrating colorants and its application, including organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent, silane coupling agent and diluent.Concrete penetrating colorants have stronger permeability, can effectively it infiltrate into concrete surface layer, chemically reacted with concrete substrate, generate the color concrete overall structure that tone is stablized, it is easy to operate, it is easy to use, it is rich in color, a conventional color kind up to more than 20, also voluntarily mixes other required colors using existing color kind；Wherein, there are golden yellow, the orange, colour of camel's hair, brown, coffee color, orange, purplish red, bright red, sauce red, purple, bright green, emerald green, blackish green, grey blue, gorgeous blue, peacock blue, the dark blue, light gray of water, middle grey, just black etc. tone in conventional color kind, can two-by-two be mixed according to these colors afterwards or a variety of be mixed to form other tones.
Description
Technical field
The present invention relates to a kind of concrete coloring agent, more particularly to a kind of concrete penetrating colorants and its application.
Background technology
It is glued construction material, such as concrete largely uses in the whole world；By varying component used in splicing pre-composition
Ratio, can obtain the concrete of many types, since this kind of splicing concrete has quick-hardening and the characteristic solidified so that its
Certain degree of hardness and the material that can be walked on the top can be solidified out into the short period of time, it is generally desirable to draw in the process
Enter the aesthetic effect that color improves construction material.
The concrete colouring method being currently known mainly includes following three kinds：
1. with the acid solution washing surface containing metal salt, and after color formation, add add again after neutralizer it is transparent
Protectiveness polymer seal coat；
2. being washed with acid solution, under the corrosiveness of acid solution, make the concrete surface after laying coarse, then with dyeing
Agent or paint colour for surface, and clear coat is finally coated in upper surface to protect；
3. after corrosion or lapped face, on its surface, coating gelatin substance forms bonding layer, with the acid solution containing metal salt
Dye bonding layer.
But be required to use the acid solution with compared with severe corrosive in above several method, thus these coloring agents with
And construction is all more dangerous.
In development course afterwards, but successively occur it is several be used for dyeing to concrete method, such as pass through to
It is hydrated in pre-composition and adds inorganic pigment such as iron oxide etc., inorganic pigment preparation is mixed with a small amount of machine oil or vegetable oil, compressed shape
It is used for concrete coloring into the material that particle diameter is 0.2-2mm.
Such as a kind of concrete coloring agent disclosed in the Chinese patent that application publication number is " CN107108354A ", this coloring
Agent is a kind of flowable aerosol type microparticle formulation, mainly including polycarboxylic acids, hydroxylated amine, polyethylene glycol and several inorganic face
Material.
In recent years, as people's the accelerating rhythm of life and the automated process of technological process are accelerated, this kind of construction
Simple and easily operated material emerges in multitude, thus the concrete that we provide a kind of use simply herein and health is harmless
Toner.
The content of the invention
The object of the present invention is to provide a kind of concrete penetrating colorants, its concrete floor to indoor laying has preferably
Degree of staining.
The present invention above-mentioned technical purpose technical scheme is that：A kind of concrete infiltration coloring
Agent, including organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent, silane coupling agent and diluent.
Preferably, the organic pigment is metal azo pigments, heterocyclic pigment, condensed ring ketone pigment, phthalocyanines face
It is a kind of or any several in material；The solvent is dimethylformamide, tetrahydrofuran, glycerine, propane diols, ethylene glycol, second two
One kind or any several in alcohol monobutyl ether acetate；The wetting agent is polyether silicone, lauryl sodium sulfate, dialkyl group fourth
One kind or any several in two acid esters sodium sulfonates；The bleeding agent is neopelex；The silane coupling agent is
One kind or any several in isobutyl triethoxy silane, methacryloxypropyl silane, amino silane or vinyl silanes；
The emulsifying agent is alkylphenol polyoxyethylene ether, Diphenethyl answers phenol polyethenoxy ether, one kind of amino alcohol fatty acid derivatives
It is or any several；The diluent is water.
Preferably, 5-40 parts of organic pigment
20-60 parts of solvent
1-10 parts of bleeding agent
1-10 parts of silane coupling agent
1-30 parts of emulsifying agent.
Preferably, further include following material：
1-5 parts of light stabilizer
1-5 parts of heat stabilizer
0.5-10 parts of defoamer.
Preferably, the light stabilizer is using 2- hydroxyl -4- methoxyl group -5- diphenylsulfones ketone, benzotriazole, bigcatkin willow
One kind or any several in acid esters；The heat stabilizer is using D-sorbite, one kind in calcium stearate zinc or any several；
The defoamer uses organic silicon defoamer.
Preferably, further include following material：
1-5 parts of dispersant
1-5 parts of adhesive.
Preferably, following component is by weight：
10-30 parts of organic pigment
30-50 parts of solvent
1-5 parts of bleeding agent
0.5-10 parts of wetting agent
1-10 parts of silane coupling agent
5-30 parts of emulsifying agent
10-30 parts of diluent
2-3.5 parts of dispersant
2-3.5 parts of adhesive.
Preferably, following component is by weight：
10-30 parts of organic pigment
30-50 parts of solvent
1-5 parts of bleeding agent
1-10 parts of silane coupling agent
5-30 parts of emulsifying agent.
Preferably, following component is by weight：
10-30 parts of organic pigment
30-50 parts of solvent
1-5 parts of bleeding agent
0.5-10 parts of wetting agent
0.5-10 parts of defoamer
1-10 parts of silane coupling agent
5-30 parts of emulsifying agent
1-5 parts of light stabilizer
1-5 parts of heat stabilizer
10-30 parts of diluent.
The object of the present invention is to provide a kind of application of concrete penetrating colorants, its concrete floor to indoor laying
There is preferable degree of staining.
The present invention above-mentioned technical purpose technical scheme is that：A kind of above-mentioned concrete infiltration
Colouring agent, the indoor terrace coloring being laid with for concrete.
In conclusion the invention has the advantages that：
（1）Concrete penetrating colorants have stronger permeability, can effectively infiltrate into concrete surface layer, with concrete substrate
Chemically react, the color concrete overall structure that generation tone is stablized, easy to operate, application method is rich in color, up to
A conventional color kind more than 20, also voluntarily mixes other required colors using existing color kind；Wherein, often
There is golden yellow, the orange, colour of camel's hair, brown, coffee color, orange, purplish red, bright red, sauce red, purple, bright green, emerald green, black in rule color kind
Green, grey blue, gorgeous blue, peacock blue, the dark blue, light gray of water, middle grey, just black etc. tone, can be mixed two-by-two according to these colors afterwards or
It is a variety of to be mixed to form other tones；
（2）In above-mentioned concrete penetrating colorants, solvent is used to dissolve other materials, since other materials are organic matter mostly
Matter, thus solvent is organic solvent herein, can use cheap and nontoxic organic liquid as solvent, such as diformazan
Base formamide（DMF）, tetrahydrofuran（HTF）And glycerine, this three classes solvent are also known as alembroth, most of organic matter
Matter may be dissolved in wherein, this same three classes material can be dissolved each other with water with arbitrary proportion again, thus diluent is mixed into wherein
When can reduce the concentration of colouring agent, increase the mobility of colouring agent, increase the uniformity of coloring；Wetting agent and bleeding agent collaboration are made
With making concrete coloring agent preferably colour, wherein wetting agent allows the water to open up by reducing surface tension, the interfacial tension of object
Its surface is opened in fixed surface of material or penetrated, the surface of solids is soaked, and the concrete that bleeding agent contributes to after sprinkling
Toner permeates downwards, avoids coloring from floating on and comes to the surface and easily come off, both make concrete coloring agent preferably be dispersed at cooperation
Concrete block surface and under ooze and make uniform coloring and stabilization；
（3）Above material is likely to result in some minute bubbles and is suspended in more than liquid level, defoamer can be reduced in whipping process
The minute bubbles generated in whipping process；Emulsifying agent is can to improve the surface tension respectively formed in liquid between phase, is allowed to be formed
Uniform and stable dispersion, silane coupling agent are also used as a kind of surface conditioning agent while can increasing the intensity of material；Will
It is used in concrete penetrating colorants, and the concrete surface after coloring can be made smooth glossy, and strong with certain structure
Degree and certain anti-fight act on；
（4）Heat stabilizer, light stabilizer can be used for stablizing the concrete surface after coloring, strengthen it to ultraviolet, illumination, heat etc.
Stability；Dispersant and adhesive are used to making colouring agent dispersed in concrete surface and gluing is in concrete road surface,
Avoid it from coming off；
（5）When concrete penetrating colorants after this compounding are sprayed on mattess, colouring agent is in mattess
On disperse around, and permeated downwards during scattered；Organic pigment is used to paint during this, bleeding agent and wetting agent
The surface tension that synergistic effect reduces concrete penetrating colorants makes it preferably be flowed on concrete road surface and covers around
Lid, defoamer, which eliminates bubble therein, makes colouring agent be attached on concrete road surface, and silane coupling agent increase is dried mixed
The surface texture intensity and glossiness of solidifying soil penetrating colorants.
Embodiment
This specific embodiment is only explanation of the invention, it is not limitation of the present invention, people in the art
Member as needed can make the present embodiment the modification of no creative contribution after this specification is read, but as long as at this
All protected in the right of invention be subject to Patent Law.
Embodiment 1：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, the adoptable species of solvent is more, such as tetrahydrofuran, ethylene glycol, propane diols, glycerine, diformazan
Yl acetamide and 2-Butoxyethyl acetate；Organic pigment uses metal azo pigments in the present embodiment, and solvent uses dimethyl
Formamide, wetting agent use polyether silicone, and bleeding agent uses neopelex, and silane coupling agent uses isobutyl group three
Ethyl oxysilane, emulsifying agent use alkylphenol polyoxyethylene ether, and diluent uses water.
Clean container is taken, 20 parts of solvents and 10 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 5 parts of organic pigments are added thereto, are stirred evenly；1 part of bleeding agent, 1 part of emulsifying agent and 0.5 part of wetting agent are mixed afterwards
After be poured slowly into container and uniformly mix.
Embodiment 2：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, the adoptable species of solvent are more such as tetrahydrofuran, ethylene glycol, propane diols, glycerine, dimethyl
Acetamide and 2-Butoxyethyl acetate；Organic pigment uses heterocyclic pigment in the present embodiment, and solvent uses tetrahydrofuran, profit
Humectant uses polyether silicone, and bleeding agent uses neopelex, and silane coupling agent uses happy festival time acryloyl-oxy ethene
Ether, emulsifying agent use Diphenethyl phenol polyvinylether, and diluent uses water.
Clean container is taken, 60 parts of solvents and 30 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 40 parts of organic pigments are added thereto, are stirred evenly；10 parts of bleeding agents, 30 parts of emulsifying agents and 10 parts of wetting agents are mixed afterwards
It is poured slowly into after conjunction in container and uniformly mixes.
Embodiment 3：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, the adoptable species of solvent are more such as tetrahydrofuran, ethylene glycol, propane diols, glycerine, dimethyl
Acetamide and 2-Butoxyethyl acetate；Organic pigment uses condensed ring ketone pigment or phthalocyanine pigment, solvent in the present embodiment
Using tetrahydrofuran, wetting agent uses dialkyl group Succinate sodium sulfonate, and bleeding agent uses neopelex, and silane is even
Connection agent uses happy festival time acryloyl-oxy vinethene, and emulsifying agent uses amino alcohol fatty acid derivatives, and diluent uses water.
Clean container is taken, 40 parts of solvents and 20 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 20 parts of organic pigments are added thereto, are stirred evenly；After 5 parts of bleeding agents, 5 parts of emulsifying agents and 6 parts of wetting agents are mixed afterwards
It is poured slowly into container and uniformly mixes.
Embodiment 4：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, further include dispersant and adhesive, and the adoptable species of solvent is more such as tetrahydrofuran, second two
Alcohol, propane diols, glycerine, dimethylacetylamide and 2-Butoxyethyl acetate；Organic pigment uses phthalocyanines in the present embodiment
Pigment, solvent use glycerine, and wetting agent uses dialkyl group Succinate sodium sulfonate, and bleeding agent uses dodecyl benzene sulfonic acid
Sodium, silane coupling agent use vinyl silanes, and emulsifying agent uses alkylphenol polyoxyethylene ether, and diluent uses water, and dispersant can
Using polyethylene pyrrole network alkanone, ethyl acetate, cetyl trimethylammonium bromide, adhesive can use gum arabic, polyamides
Amine, alkyd resin.
Clean container is taken, 30 parts of solvents and 10 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 10 parts of organic pigments are added thereto, are stirred evenly；1 part of bleeding agent, 5 parts of emulsifying agents and 0.5 part of wetting agent are mixed afterwards
After be poured slowly into container and uniformly mix, finally add 2 parts of dispersants and 2 parts of adhesives thereto.
Embodiment 5：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, further include dispersant and adhesive, and the adoptable species of solvent is more such as tetrahydrofuran, second two
Alcohol, propane diols, glycerine, dimethylacetylamide and 2-Butoxyethyl acetate；Organic pigment uses phthalocyanines in the present embodiment
Pigment, solvent use glycerine, and wetting agent uses dialkyl group Succinate sodium sulfonate, and bleeding agent uses dodecyl benzene sulfonic acid
Sodium, silane coupling agent use vinyl silanes, and emulsifying agent uses alkylphenol polyoxyethylene ether, and diluent uses water, and dispersant can
Using polyethylene pyrrole network alkanone, ethyl acetate, cetyl trimethylammonium bromide, adhesive can use gum arabic, polyamides
Amine, alkyd resin.
Clean container is taken, 50 parts of solvents and 30 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 30 parts of organic pigments are added thereto, are stirred evenly；5 parts of bleeding agents, 30 parts of emulsifying agents and 10 parts of wetting agents are mixed afterwards
After be poured slowly into container and uniformly mix, finally add 3.5 parts of dispersants and 3.5 parts of adhesives thereto.
Embodiment 6：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, further include dispersant and adhesive, and the adoptable species of solvent is more such as tetrahydrofuran, second two
Alcohol, propane diols, glycerine, dimethylacetylamide and 2-Butoxyethyl acetate；Organic pigment uses metal pair in the present embodiment
Nitrogen class pigment, solvent use dimethyl formyl, and wetting agent uses polyether silicone, and bleeding agent uses neopelex,
Silane coupling agent uses isobutyl triethoxy silane, and emulsifying agent uses alkyl phenol polyvinylether, and diluent uses water, dispersant
Polyethylene pyrrole network alkanone, ethyl acetate, cetyl trimethylammonium bromide can be used, adhesive can use gum arabic, gather
Acid amides, alkyd resin.
Clean container is taken, 40 parts of solvents and 20 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 20 parts of organic pigments are added thereto, are stirred evenly；3 parts of bleeding agents, 18 parts of emulsifying agents and 6 parts of wetting agents are mixed afterwards
After be poured slowly into container and uniformly mix, finally add 2.8 parts of dispersants and 2.8 parts of adhesives thereto.
Embodiment 7：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, further include light stabilizer and heat stabilizer, and the adoptable species of solvent is more such as tetrahydrofuran, second
Glycol, propane diols, glycerine, dimethylacetylamide and 2-Butoxyethyl acetate；Organic pigment uses metal in the present embodiment
Azo pigment, solvent use dimethyl formyl, and wetting agent uses polyether silicone, and bleeding agent uses dodecyl benzene sulfonic acid
Sodium, silane coupling agent use isobutyl triethoxy silane, and emulsifying agent uses alkyl phenol polyvinylether, and diluent uses water, light
Stabilizer can use 2- hydroxyl -4- methoxyl group -5- diphenylsulfones ketone, benzotriazole, and heat stabilizer can use D-sorbite, disappear
Infusion uses organic silicon defoamer.
Clean container is taken, 30 parts of solvents and 10 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 10 parts of organic pigments are added thereto, are stirred evenly；Afterwards by 1 part of bleeding agent, 5 parts of emulsifying agents, 0.5 part of defoamer and 0.5
It is poured slowly into container after part wetting agent mixing and uniformly mixes, finally adds 1 part of heat stabilizer thereto and 1 part of light is stablized
Agent.
Embodiment 8：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, further include light stabilizer and heat stabilizer, and the adoptable species of solvent is more such as tetrahydrofuran, second
Glycol, propane diols, glycerine, dimethylacetylamide and 2-Butoxyethyl acetate；Organic pigment uses metal in the present embodiment
Azo pigment, solvent use dimethyl formyl, and wetting agent uses polyether silicone, and bleeding agent uses dodecyl benzene sulfonic acid
Sodium, silane coupling agent use isobutyl triethoxy silane, and emulsifying agent uses alkyl phenol polyvinylether, and diluent uses water, light
Stabilizer can use 2- hydroxyl -4- methoxyl group -5- diphenylsulfones ketone, benzotriazole, and heat stabilizer can use D-sorbite, disappear
Infusion uses organic silicon defoamer.
Clean container is taken, 40 parts of solvents and 20 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 20 parts of organic pigments are added thereto, are stirred evenly；3 parts of bleeding agents, 18 parts of emulsifying agents and 6 parts of wetting agents are mixed afterwards
After be poured slowly into container and uniformly mix, finally add 2.5 parts of light stabilizers and 2.5 parts of heat stabilizers thereto.
Embodiment 9：
A kind of concrete penetrating colorants, mainly including following material：Organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent,
Silane coupling agent and diluent, further include light stabilizer and heat stabilizer, and the adoptable species of solvent is more such as tetrahydrofuran, second
Glycol, propane diols, glycerine, dimethylacetylamide and 2-Butoxyethyl acetate；Organic pigment uses metal in the present embodiment
Azo pigment, solvent use dimethyl formyl, and wetting agent uses polyether silicone, and bleeding agent uses dodecyl benzene sulfonic acid
Sodium, silane coupling agent use isobutyl triethoxy silane, and emulsifying agent uses alkyl phenol polyvinylether, and diluent uses water, light
Stabilizer can use 2- hydroxyl -4- methoxyl group -5- diphenylsulfones ketone, benzotriazole, and heat stabilizer can use D-sorbite, disappear
Infusion uses organic silicon defoamer.
Clean container is taken, 40 parts of solvents and 20 parts of diluents is added thereto, both is uniformly dissolved mutually and disperse it
Afterwards, 30 parts of organic pigments are added thereto, are stirred evenly；Afterwards by 5 parts of bleeding agents, 30 parts of emulsifying agents, 10 parts of defoamers, 10 parts
It is poured slowly into container after wetting agent mixing and uniformly mixes, finally adds 5 parts of light stabilizers and 5 parts of heat stabilizers thereto.
Concrete penetrating colorants in embodiment 1- embodiments 9 are sprayed to concrete surface, and by by same material
Uncolored concrete block measures the concrete crushing strength after sprinkling colours 7 days, 14 days, 28 days and 60 days as a comparison case
（Unit：MPa）, and it is recorded in table 1：
| Compression strength（7 days） | Compression strength（14 days） | Compression strength（28 days） | Compression strength（60 days） | |
| Embodiment 1 | 39.7 | 49.6 | 51.3 | 52.6 |
| Embodiment 2 | 40.0 | 49.5 | 51.7 | 52.4 |
| Embodiment 3 | 39.7 | 49.3 | 51.3 | 52.5 |
| Embodiment 4 | 39.2 | 49.6 | 51.6 | 52.1 |
| Embodiment 5 | 39.4 | 49.9 | 51.9 | 52.6 |
| Embodiment 6 | 39.9 | 49.7 | 51.8 | 52.8 |
| Embodiment 7 | 39.6 | 49.8 | 52.0 | 52.2 |
| Embodiment 8 | 39.1 | 49.0 | 51.5 | 52.3 |
| Embodiment 9 | 39.5 | 49.1 | 51.1 | 52.7 |
| Comparative example | 39.0 | 49.3 | 51.2 | 52.3 |
Conclusion can be obtained according to upper table：Spraying this concrete penetrating colorants does not influence the structural strength of concrete.
The depth oozed under concrete penetrating colorants are measured into concrete, and table 2 is recorded in, after visually observing coloring
Uniform coloring degree and bleaching level of the concrete after 90 days, 120 days and 150 days are equally recorded in table 2：
| Under ooze depth（mm） | 90 days | 120 days | 150 days | |
| Embodiment 1 | 3.31 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 2 | 3.36 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 3 | 3.30 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 4 | 3.34 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 5 | 3.37 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 6 | 3.32 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 7 | 3.40 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 8 | 3.33 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
| Embodiment 9 | 3.38 | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon | Uniform coloring, no decoloration phenomenon |
Claims (10)
- A kind of 1. concrete penetrating colorants, it is characterised in that：Including organic pigment, solvent, bleeding agent, wetting agent, emulsifying agent, Silane coupling agent and diluent.
- A kind of 2. concrete penetrating colorants according to claim 1, it is characterised in that：The organic pigment is metal pair It is a kind of or any several in nitrogen pigment, heterocyclic pigment, condensed ring ketone pigment, phthalocyanine pigment；The solvent is dimethyl methyl One kind or any several in acid amides, tetrahydrofuran, glycerine, propane diols, ethylene glycol, 2-Butoxyethyl acetate；The profit Humectant is polyether silicone, lauryl sodium sulfate, one kind in dialkyl group Succinate sodium sulfonate or any several；It is described to ooze Saturating agent is neopelex；The silane coupling agent for isobutyl triethoxy silane, methacryloxypropyl silane, One kind or any several in amino silane or vinyl silanes；The emulsifying agent is alkylphenol polyoxyethylene ether, Diphenethyl One kind or any several of multiple phenol polyethenoxy ether, amino alcohol fatty acid derivatives；The diluent is water.
- 3. a kind of concrete penetrating colorants according to claim 1, it is characterised in that following component is by weight：5-40 parts of organic pigment20-60 parts of solvent1-10 parts of bleeding agent1-10 parts of silane coupling agent1-30 parts of emulsifying agent10-30 parts of diluent0.5-10 parts of wetting agent.
- 4. a kind of concrete penetrating colorants according to claim 3, it is characterised in that further include following material：1-5 parts of light stabilizer1-5 parts of heat stabilizer0.5-10 parts of defoamer.
- A kind of 5. concrete penetrating colorants according to claim 4, it is characterised in that：The light stabilizer uses 2- hydroxyls Base -4- methoxyl group -5- diphenylsulfones ketone, benzotriazole, one kind in salicylate or any several；The heat stabilizer is adopted With one kind in D-sorbite, calcium stearate zinc or any several；The defoamer uses organic silicon defoamer.
- 6. a kind of concrete coloring agent according to claim 1, it is characterised in that further include following material：1-5 parts of dispersant1-5 parts of adhesive.
- 7. a kind of concrete penetrating colorants according to claim 3 or 6, it is characterised in that following component is by weight：10-30 parts of organic pigment30-50 parts of solvent1-5 parts of bleeding agent0.5-10 parts of wetting agent1-10 parts of silane coupling agent5-30 parts of emulsifying agent10-30 parts of diluent2-3.5 parts of dispersant2-3.5 parts of adhesive.
- 8. a kind of concrete penetrating colorants according to claim 1, it is characterised in that following component is by weight：10-30 parts of organic pigment30-50 parts of solvent1-5 parts of bleeding agent1-10 parts of silane coupling agent5-30 parts of emulsifying agent.
- 9. a kind of concrete penetrating colorants according to claim 3 or 5, it is characterised in that following component is by weight：10-30 parts of organic pigment30-50 parts of solvent1-5 parts of bleeding agent0.5-10 parts of wetting agent0.5-10 parts of defoamer1-10 parts of silane coupling agent5-30 parts of emulsifying agent1-5 parts of light stabilizer1-5 parts of heat stabilizer10-30 parts of diluent.
- A kind of 10. concrete penetrating colorants in claim 1-9 described in any one, it is characterised in that：For concrete The indoor terrace coloring of laying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711354092.3A CN107903787A (en) | 2017-12-15 | 2017-12-15 | A kind of concrete penetrating colorants and its application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711354092.3A CN107903787A (en) | 2017-12-15 | 2017-12-15 | A kind of concrete penetrating colorants and its application |
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| Publication Number | Publication Date |
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| CN107903787A true CN107903787A (en) | 2018-04-13 |
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| CN201711354092.3A Pending CN107903787A (en) | 2017-12-15 | 2017-12-15 | A kind of concrete penetrating colorants and its application |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109250949A (en) * | 2018-07-23 | 2019-01-22 | 广东广洁科技有限公司 | A kind of permeable concrete terrace coloring agent and preparation method thereof |
| CN110078411A (en) * | 2019-05-06 | 2019-08-02 | 济南大学 | It is a kind of suitable for the colorant and its application method of 3D printing plain boiled water cement-based material and application |
| CN111779227A (en) * | 2020-06-12 | 2020-10-16 | 广州名丰建材有限公司 | Concrete dyeing terrace construction method |
| CN114456645A (en) * | 2022-02-17 | 2022-05-10 | 山西磊鑫环境科技有限公司 | Superstrong-penetration type terrace colorant and preparation method thereof |
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| CN109250949A (en) * | 2018-07-23 | 2019-01-22 | 广东广洁科技有限公司 | A kind of permeable concrete terrace coloring agent and preparation method thereof |
| CN110078411A (en) * | 2019-05-06 | 2019-08-02 | 济南大学 | It is a kind of suitable for the colorant and its application method of 3D printing plain boiled water cement-based material and application |
| CN110078411B (en) * | 2019-05-06 | 2022-03-25 | 济南大学 | Coloring agent suitable for 3D printing white cement-based material and use method and application thereof |
| CN111779227A (en) * | 2020-06-12 | 2020-10-16 | 广州名丰建材有限公司 | Concrete dyeing terrace construction method |
| CN114456645A (en) * | 2022-02-17 | 2022-05-10 | 山西磊鑫环境科技有限公司 | Superstrong-penetration type terrace colorant and preparation method thereof |
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Application publication date: 20180413 |