CN107903412A - A kind of Anti-static electricity color master batch that can improve colour stability - Google Patents
A kind of Anti-static electricity color master batch that can improve colour stability Download PDFInfo
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- CN107903412A CN107903412A CN201711125943.7A CN201711125943A CN107903412A CN 107903412 A CN107903412 A CN 107903412A CN 201711125943 A CN201711125943 A CN 201711125943A CN 107903412 A CN107903412 A CN 107903412A
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- master batch
- static electricity
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/223—Packed additives
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Abstract
The invention discloses a kind of Anti-static electricity color master batch that can improve colour stability, include the raw material of following mass percent：Masterbatch base material is 45 55%, brilliant potassium titanate is 5 10%, antistatic additive is 6 10%, compatilizer is 4 6%, composite antioxidant is 1.2 2.4%, metallic pigments master batch is 12 14%, catalyst is 2 4%, molybdenum disulfide is 0.2 1.2%, diatomite is 0.4 0.8% and the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is 6.6 14.2%, the antistatic additive inspires confidence in the mixture of antistatic additive and ACL antistatic additive for luxuriant growth power, the compatilizer is cyclic acid anhydride polymer, the composite antioxidant is didodecyl thiodipropionate and the mixture of butylated hydroxy anisole, the metallic pigments master batch is iron oxide red toner, titanium yellow toner or aluminium white powder.The present invention is economical and practical, and Anti-static electricity color master batch has preferable colour stability, and the antistatic property of Anti-static electricity color master batch is greatly improved.
Description
Technical field
The present invention relates to Anti-static electricity color master batch technical field, more particularly to a kind of it can improve the antistatic of colour stability
Masterbatch.
Background technology
With reform and opening-up, the development in an all-round way of China's economy, Anti-static electricity color master batch be widely used in household electrical appliances, electronic apparatus,
On automobile, electric tool and office furniture so that the demand of Anti-static electricity color master batch is continuously increased, in addition Anti-static electricity color master batch
Kind and quality also have increased significantly therewith, but the colour stability of Anti-static electricity color master batch is poor so that antistatic
Masterbatch easily changes colour during use, and then proposes a kind of antistatic color masterbatch that can improve colour stability
Grain.
The content of the invention
Based on technical problem existing for background technology, the present invention, which proposes, a kind of can improve the antistatic of colour stability
Masterbatch.
A kind of Anti-static electricity color master batch that can improve colour stability proposed by the present invention, including following mass percent
Raw material：Masterbatch base material is 45-55%, potassium titanate crystalline substance is 5-10%, antistatic additive 6-10%, compatilizer 4-6%, compound
Antioxidant is 1.2-2.4%, metallic pigments master batch is 12-14%, catalyst 2-4%, molybdenum disulfide 0.2-1.2%, silicon
Diatomaceous earth is 0.4-0.8% and the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is 6.6-14.2%.
Preferably, the antistatic additive inspires confidence in the mixture of antistatic additive and ACL antistatic additive for luxuriant growth power.
Preferably, the compatilizer is cyclic acid anhydride polymer.
Preferably, the composite antioxidant is didodecyl thiodipropionate and the mixture of butylated hydroxy anisole.
Preferably, the metallic pigments master batch is iron oxide red toner, titanium yellow toner or aluminium white powder.
Preferably, the polyphosphate sodium in the mixture of polyphosphate sodium and the organic multicomponent phosphonic acids and organic multicomponent phosphonic acids are pressed
According to 1:3 ratio mixing.
Preferably, the catalyst is the mixture of bismuth neodecanoate, laurate bismuth and isooctyl acid bismuth.
Beneficial effects of the present invention：Molybdenum disulfide, diatomite and polyphosphate sodium are added on the basis of original and are had
The mixture of machine polyphosphonic acid, and the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is as stabilizer, polyphosphate sodium and organic
The mixture of polyphosphonic acid greatly improves metallic pigments master batch on Masterbatch base material under diatomite and catalyst complex
Colour stability, in addition antistatic additive is using preserving power to inspire confidence in the mixture of antistatic additive and ACL antistatic additive so that antistatic color
The antistatic property of master batch is greatly improved, and the present invention is economical and practical, and Anti-static electricity color master batch has preferable colour stable
Property, and the antistatic property of Anti-static electricity color master batch is greatly improved.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment one
A kind of Anti-static electricity color master batch that can improve colour stability, including following quality percentage are proposed in the present embodiment
The raw material of ratio：Masterbatch base material is 45%, potassium titanate crystalline substance is 10%, antistatic additive 10%, compatilizer 6%, compound antioxygen
Agent is 2.4%, metallic pigments master batch is 14%, catalyst 4%, molybdenum disulfide 1.2%, diatomite are 0.8% and poly-
The mixture of sodium phosphate and organic multicomponent phosphonic acids is 6.6%.
In the present embodiment, for antistatic additive to preserve power to inspire confidence in the mixture of antistatic additive and ACL antistatic additive, compatilizer is ring-type
Anhydride polymer, composite antioxidant are didodecyl thiodipropionate and the mixture of butylated hydroxy anisole, and metallic pigments master batch is
Polyphosphate sodium in the mixture of iron oxide red toner, titanium yellow toner or aluminium white powder, polyphosphate sodium and organic multicomponent phosphonic acids and have
Machine polyphosphonic acid is according to 1:3 ratio mixing, catalyst is the mixture of bismuth neodecanoate, laurate bismuth and isooctyl acid bismuth, in original
The mixture of molybdenum disulfide, diatomite and polyphosphate sodium and organic multicomponent phosphonic acids, and polyphosphate sodium are added on the basis of coming
With the mixture of organic multicomponent phosphonic acids as stabilizer, the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is in diatomite and catalysis
Under agent coordinates, colour stability of the metallic pigments master batch on Masterbatch base material is greatly improved, in addition antistatic additive uses
Power is preserved to inspire confidence in the mixture of antistatic additive and ACL antistatic additive so that the antistatic property of Anti-static electricity color master batch has obtained greatly carrying
Height, the Anti-static electricity color master batch are widely used on household electrical appliances, electronic apparatus, automobile, electric tool and office furniture, and the present invention is economical
Practicality, Anti-static electricity color master batch has preferable colour stability, and the antistatic property of Anti-static electricity color master batch has obtained greatly carrying
It is high.
Embodiment two
A kind of Anti-static electricity color master batch that can improve colour stability, including following quality percentage are proposed in the present embodiment
The raw material of ratio：Masterbatch base material is 50%, potassium titanate crystalline substance is 7.5%, antistatic additive 8%, compatilizer 5%, compound antioxygen
Agent is 1.8%, metallic pigments master batch is 13%, catalyst 3%, molybdenum disulfide 0.7%, diatomite are 0.6% and poly-
The mixture of sodium phosphate and organic multicomponent phosphonic acids is 10.4%.
In the present embodiment, for antistatic additive to preserve power to inspire confidence in the mixture of antistatic additive and ACL antistatic additive, compatilizer is ring-type
Anhydride polymer, composite antioxidant are didodecyl thiodipropionate and the mixture of butylated hydroxy anisole, and metallic pigments master batch is
Polyphosphate sodium in the mixture of iron oxide red toner, titanium yellow toner or aluminium white powder, polyphosphate sodium and organic multicomponent phosphonic acids and have
Machine polyphosphonic acid is according to 1:3 ratio mixing, catalyst is the mixture of bismuth neodecanoate, laurate bismuth and isooctyl acid bismuth, in original
The mixture of molybdenum disulfide, diatomite and polyphosphate sodium and organic multicomponent phosphonic acids, and polyphosphate sodium are added on the basis of coming
With the mixture of organic multicomponent phosphonic acids as stabilizer, the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is in diatomite and catalysis
Under agent coordinates, colour stability of the metallic pigments master batch on Masterbatch base material is greatly improved, in addition antistatic additive uses
Power is preserved to inspire confidence in the mixture of antistatic additive and ACL antistatic additive so that the antistatic property of Anti-static electricity color master batch has obtained greatly carrying
Height, the Anti-static electricity color master batch are widely used on household electrical appliances, electronic apparatus, automobile, electric tool and office furniture, and the present invention is economical
Practicality, Anti-static electricity color master batch has preferable colour stability, and the antistatic property of Anti-static electricity color master batch has obtained greatly carrying
It is high.
Embodiment three
A kind of Anti-static electricity color master batch that can improve colour stability, including following quality percentage are proposed in the present embodiment
The raw material of ratio：Masterbatch base material is 55%, potassium titanate crystalline substance is 5%, antistatic additive 6%, compatilizer 4%, composite antioxidant
For 1.2%, metallic pigments master batch be 12%, catalyst 2%, molybdenum disulfide 0.2%, diatomite are 0.8% and poly- phosphorus
The mixture of sour sodium and organic multicomponent phosphonic acids is 14.2%.
In the present embodiment, for antistatic additive to preserve power to inspire confidence in the mixture of antistatic additive and ACL antistatic additive, compatilizer is ring-type
Anhydride polymer, composite antioxidant are didodecyl thiodipropionate and the mixture of butylated hydroxy anisole, and metallic pigments master batch is
Polyphosphate sodium in the mixture of iron oxide red toner, titanium yellow toner or aluminium white powder, polyphosphate sodium and organic multicomponent phosphonic acids and have
Machine polyphosphonic acid is according to 1:3 ratio mixing, catalyst is the mixture of bismuth neodecanoate, laurate bismuth and isooctyl acid bismuth, in original
The mixture of molybdenum disulfide, diatomite and polyphosphate sodium and organic multicomponent phosphonic acids, and polyphosphate sodium are added on the basis of coming
With the mixture of organic multicomponent phosphonic acids as stabilizer, the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is in diatomite and catalysis
Under agent coordinates, colour stability of the metallic pigments master batch on Masterbatch base material is greatly improved, in addition antistatic additive uses
Power is preserved to inspire confidence in the mixture of antistatic additive and ACL antistatic additive so that the antistatic property of Anti-static electricity color master batch has obtained greatly carrying
Height, the Anti-static electricity color master batch are widely used on household electrical appliances, electronic apparatus, automobile, electric tool and office furniture, and the present invention is economical
Practicality, Anti-static electricity color master batch has preferable colour stability, and the antistatic property of Anti-static electricity color master batch has obtained greatly carrying
It is high.
Contrast the antistatic color masterbatch that can improve colour stability of conventional Anti-static electricity color master batch and embodiment one to three
Grain, the raising percentage such as following table of the Anti-static electricity color master batch that can improve colour stability of embodiment one to three：
From above table, the colour stable of the Anti-static electricity color master batch proposed by the present invention that colour stability can be improved
Performance and antistatic property, which are respectively provided with, to be significantly improved, and it is most preferred embodiment to implement two.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of Anti-static electricity color master batch that can improve colour stability, it is characterised in that include the original of following mass percent
Material：Masterbatch base material is 45-55%, potassium titanate crystalline substance is 5-10%, antistatic additive 6-10%, compatilizer 4-6%, compound anti-
Oxygen agent is 1.2-2.4%, metallic pigments master batch is 12-14%, catalyst 2-4%, molybdenum disulfide 0.2-1.2%, diatom
Soil is that the mixture of 0.4-0.8% and polyphosphate sodium and organic multicomponent phosphonic acids is 6.6-14.2%.
2. a kind of Anti-static electricity color master batch that can improve colour stability according to claim 1, it is characterised in that described
Antistatic additive inspires confidence in the mixture of antistatic additive and ACL antistatic additive for luxuriant growth power.
3. a kind of Anti-static electricity color master batch that can improve colour stability according to claim 1, it is characterised in that described
Compatilizer is cyclic acid anhydride polymer.
4. a kind of Anti-static electricity color master batch that can improve colour stability according to claim 1, it is characterised in that described
Composite antioxidant is didodecyl thiodipropionate and the mixture of butylated hydroxy anisole.
5. a kind of Anti-static electricity color master batch that can improve colour stability according to claim 1, it is characterised in that described
Metallic pigments master batch is iron oxide red toner, titanium yellow toner or aluminium white powder.
6. a kind of Anti-static electricity color master batch that can improve colour stability according to claim 1, it is characterised in that described
Polyphosphate sodium and organic multicomponent phosphonic acids in the mixture of polyphosphate sodium and organic multicomponent phosphonic acids is according to 1:3 ratio mixing.
7. a kind of Anti-static electricity color master batch that can improve colour stability according to claim 1, it is characterised in that described
Catalyst is the mixture of bismuth neodecanoate, laurate bismuth and isooctyl acid bismuth.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711125943.7A CN107903412A (en) | 2017-11-15 | 2017-11-15 | A kind of Anti-static electricity color master batch that can improve colour stability |
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| CN201711125943.7A CN107903412A (en) | 2017-11-15 | 2017-11-15 | A kind of Anti-static electricity color master batch that can improve colour stability |
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| CN107903412A true CN107903412A (en) | 2018-04-13 |
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| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
| CN104059275A (en) * | 2014-06-20 | 2014-09-24 | 北京化工大学 | Polyolefin color master batch with diatomite replacing part of pigments and preparation method of polyolefin color master batch |
| CN105839215A (en) * | 2016-04-11 | 2016-08-10 | 浙江纳美新材料股份有限公司 | A preparing method of a three-primary-color colorant used for preparing colored polyester fibres |
| CN106800752A (en) * | 2016-12-23 | 2017-06-06 | 苏州曙帆信电子科技有限公司 | A kind of fast light blast PET color master batch |
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| CN1492901A (en) * | 2001-02-22 | 2004-04-28 | �����ﰲ�ز���(Bvi)����˾ | Color improving stabilizing compositions comprising leucine |
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| CN104059275A (en) * | 2014-06-20 | 2014-09-24 | 北京化工大学 | Polyolefin color master batch with diatomite replacing part of pigments and preparation method of polyolefin color master batch |
| CN105839215A (en) * | 2016-04-11 | 2016-08-10 | 浙江纳美新材料股份有限公司 | A preparing method of a three-primary-color colorant used for preparing colored polyester fibres |
| CN106800752A (en) * | 2016-12-23 | 2017-06-06 | 苏州曙帆信电子科技有限公司 | A kind of fast light blast PET color master batch |
| CN106977807A (en) * | 2017-05-03 | 2017-07-25 | 马志明 | A kind of nanometer EVA Masterbatch |
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Address after: 215626 No. 1 Xingyu West Road, Hexing, Jinfeng Town, Zhangjiagang City, Suzhou City, Jiangsu Province Applicant after: JIANGSU BOLIN PLASTICS Co.,Ltd. Address before: 215626 No. 1 Xingyu West Road, Hexing, Jinfeng Town, Zhangjiagang City, Jiangsu Province Applicant before: BOILN PLASTICS CO.,LTD. |
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Application publication date: 20180413 |