CN107892859A - A kind of nano-negative ion water-based interior paint and preparation method thereof - Google Patents
A kind of nano-negative ion water-based interior paint and preparation method thereof Download PDFInfo
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- CN107892859A CN107892859A CN201711185180.5A CN201711185180A CN107892859A CN 107892859 A CN107892859 A CN 107892859A CN 201711185180 A CN201711185180 A CN 201711185180A CN 107892859 A CN107892859 A CN 107892859A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
The present invention provides a kind of nano-negative ion water-based interior paint and preparation method thereof, is related to technical field of coatings.Nano-negative ion water-based interior paint of the present invention includes following raw material:Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler, auxiliary agent, deionized water.Nano-negative ion water-based interior paint of the present invention being capable of sustained release high-concentration anion after being used for interior wall film, by the effect such as electrically neutralizing, chemically reacting and adsorbing, dispel multiple pollutant, purify the air of a room, and anion of the present invention is made up of pure natural components, it is safe to use, have no toxic side effect, the water-based interior paint can discharge substantial amounts of anion and far infrared after being used for interior wall film, remove indoor harmful substance, be advantageous to health.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of nano-negative ion water-based interior paint and its preparation side
Method.
Background technology
The developing direction of modern dwelling is:Health, ecology, environmental protection and energy-conservation, this is also the healthy living that people pursue
Mode, because 68% disease origin is relevant with indoor pollution, 80% cancer is relevant with living environment, indoor hardware fitting and
Formaldehyde, benzene, the pernicious gas such as ammonia of furniture release are to cause IAQ to pollute and one of the main reason for human body diseases,
Their respiratory system, hematopoietic function, nervous system and reproductive systems to human body etc. have very serious toxic action;The one of people
The time for having 2/3rds is spent at home, builds a natural, pure and fresh, healthy, beautiful living environment, is each
The life goal that people pursues and yearned for;Possesses the interior decoration of certain function health environment-friendly functional paint nearly 2 years abroad
Achieve fast development.
Indoor environment is that people contact most frequent, most close place, according to statistics, it has been found that indoor air pollutants have
Kind more than 300, negative aeroion is the neutral molecule combination electronics in air and the gas ion with negative electrical charge that is formed.Work as sky
When negative ion concentration is higher in gas, the breeding of a variety of germs can be suppressed, reduced blood pressure and dispelling fatigue, promote growth in humans and Fa
Educate, thus people liken negative aeroion " vitamin in air " to.When people walk in forest, waterfall or seabeach
Wait, may feel that it is with fresh air, happy because these place negative ion concentrations are larger.In the prior art
There are many water negative ion interior wall paints, but needed the big competence exertion anion of raw material addition for producing anion to make
With it is high to produce the cost of material of anion, is unfavorable for being applied to public demand.
Therefore, it is few to be badly in need of a kind of raw material addition for producing anion, but can efficiently discharge the inexpensive of anion
Environmentally friendly anion water paint, the paint have toxic and harmful gas in environmental protection, sustained release anion, purification air, improve human body
The effect of immunity.
The content of the invention
For prior art produce anion raw material addition is high, technical problem that cost is high, provide one to be of the invention
Kind nano-negative ion water-based interior paint and preparation method thereof.
The present invention uses following technical scheme:
A kind of nano-negative ion water-based interior paint, the nano-negative ion water-based interior paint include the original of following parts by weight
Material:Water Soluble Compound nanometer anion powder 5-25 parts, modified tourmaline nano emulsion 6-12 parts, aqueous epoxy resin emulsion 15-
35 parts, filler 20-40 parts, auxiliary agent 2-10 parts, deionized water 10-20 parts.
Preferably, the nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nanometer is born
Ion powder 7-15 parts, modified tourmaline nano emulsion 7-10 parts, aqueous epoxy resin emulsion 20-30 parts, filler 25-35 parts, help
Agent 4-8 parts, deionized water 13-17 parts.
Preferably, the nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nanometer is born
10 parts of ion powder, modified tourmaline nano emulsion 8,25 parts of aqueous epoxy resin emulsion, 30 parts of filler, 5 parts of auxiliary agent, deionized water
15 parts.
Preferably, the particle diameter of the Water Soluble Compound nanometer anion powder is 5-20 μm.
Preferably, the Water Soluble Compound nanometer anion powder is opal light shale, quartz, vermiculite, medical stone, electricity
In gas stone at least two through nano-milled manufactured nanometer grade composit powder body.
Preferably, each parts by weight of raw materials proportioning is nanoprotein stone lightweight page in the Water Soluble Compound nanometer anion powder
Rock:Nanometer silica flour:Nanometer vermiculite powder:Nano medical stone:Nano-tourmaline=4.5:4:3:4:6.
Preferably, the modified tourmaline nano emulsion is that tourmaline nano powder is dispersed in fluoro-resin emulsion to obtain
Arrive.
Preferably, the auxiliary agent includes 0.3-1 parts wetting agent, 0.2-0.5 parts dispersant, 0.2-1.5 parts defoamer, 0.5-
2 parts of stabilizers, 0.2-2 parts levelling agent, 0.5-2 parts antiseptic, 0.1-1 part thickeners.
A kind of preparation method of nano-negative ion water-based interior paint, comprises the following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler,
In deionized water input mixer, stirring 10-20min is reported with rotating speed 500-2000r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 300-500r/min, stirs 5-
15min, you can.
A kind of nano-negative ion water-based interior paint of the present invention and preparation method thereof, compared with prior art, its spy protruded
Point and excellent effect are:
Nano-negative ion water-based interior paint of the present invention be used for interior wall film after can sustained release high-concentration anion, pass through
Electrically neutralize, chemical reaction and absorption etc. effect, dispel multiple pollutant, purify the air of a room, and anion of the present invention by
Pure natural components are formed, safe to use, are had no toxic side effect, and the water-based interior paint can discharge substantial amounts of bear after being used for interior wall film
Ion and far infrared, indoor harmful substance is removed, be advantageous to health, and the interior wall paint appearance of film surfacing light
Slide, water-tolerant, good corrosion resistance, adhesive force is strong;
Water Soluble Compound nanometer anion powder of the present invention from opal light shale, quartz, vermiculite, medical stone, electrically
Stone, wherein opal light shale are the non-metallic ores for possessing natural nano level microcellular structure precious in nature, albumen
Stone light shale, quartz, vermiculite, medical stone, tourmaline are provided with extremely strong absorption property, and water absorption rate can be inhaled more than 70%
Minute dust and unnecessary moisture in toxic and harmful gas and peculiar smell, absorption Indoor Air in attached room, possess and persistently release
Put the function of anion;
When the addition of Water Soluble Compound nanometer anion powder of the present invention is 5 parts and 25 parts, release negative ion amount is suitable, adopts
It is water-soluble with Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, the collective effect of aqueous epoxy resin emulsion
The addition of composite Nano negative ion powder can also discharge a large amount of anion fine-purification room airs less, and then reduce cost, have
Beneficial to being applied to public demand.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following examples, the present invention is carried out
It is further described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit
The present invention.
In embodiment, the particle diameter of Water Soluble Compound nanometer anion powder is 5-20 μm;Modified tourmaline nano emulsion be by
Tourmaline nano powder, which is dispersed in fluoro-resin emulsion, to be obtained.
Embodiment 1
The present embodiment nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nano-negative ion
5 parts of powder, modified 6 parts of tourmaline nano emulsion, 15 parts of aqueous epoxy resin emulsion, 20 parts of filler, 2 parts of auxiliary agent, deionized water 10
Part;
Wherein, Water Soluble Compound nanometer anion powder is opal light shale, quartz, vermiculite, medical stone, tourmaline warp
Nanometer grade composit powder body made of nano-milled, each parts by weight of raw materials proportioning is nanometer egg in Water Soluble Compound nanometer anion powder
White stone light shale:Nanometer silica flour:Nanometer vermiculite powder:Nano medical stone:Nano-tourmaline=4.5:4:3:4:6;Auxiliary agent bag
Include 0.3 part of wetting agent, 0.2 part of dispersant, 0.2 part of defoamer, 0.5 part of stabilizer, 0.2 part of levelling agent, 0.5 part of antiseptic, 0.1
Part thickener.
The preparation method of the present embodiment nano-negative ion water-based interior paint, comprises the following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler,
In deionized water input mixer, stirring 10min is reported with rotating speed 500r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 300r/min, stirs 5min, i.e.,
Can.
Embodiment 2
The present embodiment nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nano-negative ion
25 parts of powder, modified 12 parts of tourmaline nano emulsion, 35 parts of aqueous epoxy resin emulsion, 40 parts of filler, 10 parts of auxiliary agent, deionized water
20 parts;
Wherein, Water Soluble Compound nanometer anion powder is opal light shale, quartz, vermiculite, medical stone, tourmaline warp
Nanometer grade composit powder body made of nano-milled, each parts by weight of raw materials proportioning is nanometer egg in Water Soluble Compound nanometer anion powder
White stone light shale:Nanometer silica flour:Nanometer vermiculite powder:Nano medical stone:Nano-tourmaline=4.5:4:3:4:6;Auxiliary agent bag
Include 1 part of wetting agent, 0.5 part of dispersant, 1.5 parts of defoamers, 2 parts of stabilizers, 2 parts of levelling agents, 2 parts of antiseptics, 1 part of thickener.
The preparation method of the present embodiment nano-negative ion water-based interior paint, comprises the following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler,
In deionized water input mixer, stirring 20min is reported with rotating speed 2000r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 500r/min, stirs 15min, i.e.,
Can.
Embodiment 3
The present embodiment nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nano-negative ion
10 parts of powder, modified tourmaline nano emulsion 8,25 parts of aqueous epoxy resin emulsion, 30 parts of filler, 5 parts of auxiliary agent, deionized water 15
Part;
Wherein, Water Soluble Compound nanometer anion powder is opal light shale, quartz through nano-milled manufactured nanometer
Level composite granule;Auxiliary agent includes 1 part of wetting agent, 0.3 part of dispersant, 0.5 part of defoamer, 1 part of stabilizer, 0.7 part of levelling agent, 1
Part antiseptic, 0.5 part of thickener.
The preparation method of the present embodiment nano-negative ion water-based interior paint, comprises the following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler,
In deionized water input mixer, stirring 15min is reported with rotating speed 1700r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 400r/min, stirs 10min, i.e.,
Can.
Embodiment 4
The present embodiment nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nano-negative ion
7 parts of powder, modified 7 parts of tourmaline nano emulsion, 20 parts of aqueous epoxy resin emulsion, 25 parts of filler, 4 parts of auxiliary agent, deionized water 13
Part;
Wherein, Water Soluble Compound nanometer anion powder is that opal light shale, vermiculite, tourmaline are made through nano-milled
Nanometer grade composit powder body;Each parts by weight of raw materials proportioning is nanoprotein stone lightweight page in Water Soluble Compound nanometer anion powder
Rock:Nanometer vermiculite powder:Nano-tourmaline=2:3:2.5;Auxiliary agent include 0.4 part of wetting agent, 0.3 part of dispersant, 1 part of defoamer,
0.5 part of stabilizer, 0.5 part of levelling agent, 1 part of antiseptic, 0.3 part of thickener.
The preparation method of the present embodiment nano-negative ion water-based interior paint, comprises the following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler,
In deionized water input mixer, stirring 12min is reported with rotating speed 1000r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 350r/min, stirs 7min, i.e.,
Can.
Embodiment 5
The present embodiment nano-negative ion water-based interior paint includes the raw material of following parts by weight:Water Soluble Compound nano-negative ion
15 parts of powder, modified 10 parts of tourmaline nano emulsion, 30 parts of aqueous epoxy resin emulsion, 35 parts of filler, 8 parts of auxiliary agent, deionized water
17 parts;
Wherein, Water Soluble Compound nanometer anion powder is that opal light shale, quartz, vermiculite, medical stone are ground through nanometer
The nanometer grade composit powder body being milled into;Each parts by weight of raw materials proportioning is light for nanoprotein stone in Water Soluble Compound nanometer anion powder
Matter shale:Nanometer silica flour:Nanometer vermiculite powder:Nano medical stone=4.5:4:3:4;Auxiliary agent include 0.5 part of wetting agent, 0.5 part
Dispersant, 0.5 part of defoamer, 2 parts of stabilizers, 2 parts of levelling agents, 2 parts of antiseptics, 0.5 part of thickener.
The preparation method of the present embodiment nano-negative ion water-based interior paint, comprises the following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler,
In deionized water input mixer, stirring 18min is reported with rotating speed 1500r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 450r/min, stirs 12min, i.e.,
Can.
The nano-negative ion water-based interior paint of above-mentioned preparation, according to standard GB/T/T23999-2009 and HG/T4109-
2009 anion function coating, the detection of technical performance is carried out to it, testing result is shown in Tables 1 and 2.
The technical performance testing result of the nano-negative ion water-based interior paint of table 1
Sample | Technical indicator | Embodiment 1 | Embodiment 2 | Embodiment 3 |
Appearance of film | - | Surfacing is smooth | Surfacing is smooth | Surfacing is smooth |
Adhesive force (the right spacing 2m/ levels of body) | ≦3 | 1 | 2 | 1 |
Water resistance (24h) | It is without exception | It is without exception | It is without exception | It is without exception |
Boiling water resistance (15min) | It is without exception | It is without exception | It is without exception | It is without exception |
Alkali resistance (50g/L NaHCO3) | It is without exception | It is without exception | It is without exception | It is without exception |
Volatile organic matter (VOC) | ≦300 | 10g/L | 8g/L | 9g/L |
Dissoluble lead (mg/kg) | 90 | Do not detect | Do not detect | Do not detect |
Soluble chromium (mg/kg) | 60 | Do not detect | Do not detect | Do not detect |
Soluble mercury (mg/kg) | 60 | Do not detect | Do not detect | Do not detect |
Anion discharges number, individual/cm3 | ≧350 | 5500 | 6000 | 6000 |
The technical performance testing result of the nano-negative ion water-based interior paint of table 2
Sample | Technical indicator | Embodiment 4 | Embodiment 5 |
Appearance of film | - | Surfacing is smooth | Surfacing is smooth |
Adhesive force (the right spacing 2m/ levels of body) | ≦3 | 1 | 1 |
Water resistance (24h) | It is without exception | It is without exception | It is without exception |
Boiling water resistance (15min) | It is without exception | It is without exception | It is without exception |
Alkali resistance (50g/L NaHCO3) | It is without exception | It is without exception | It is without exception |
Volatile organic matter (VOC) | ≦300 | 10g/L | 9g/L |
Dissoluble lead (mg/kg) | 90 | Do not detect | Do not detect |
Soluble chromium (mg/kg) | 60 | Do not detect | Do not detect |
Soluble mercury (mg/kg) | 60 | Do not detect | Do not detect |
Anion discharges number, individual/cm3 | ≧350 | 5800 | 5900 |
Found out by data in Tables 1 and 2, the smooth light of appearance surfaces after nano-negative ion water-based interior paint film of the present invention
Slide, water-tolerant, good corrosion resistance, adhesive force is strong;Embodiment 1 and embodiment 2, Water Soluble Compound nanometer anion powder add
Dosage is respectively 5 parts and 25 parts, and release negative ion amount is suitable, and the addition of Water Soluble Compound nanometer anion powder of the present invention is less
A large amount of anion fine-purification room airs can be discharged, and then reduce cost, are advantageous to be applied to public demand.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although ginseng
The present invention is described in detail according to previous embodiment, it will be understood by those within the art that:It still can be with
Technical scheme described in foregoing embodiments is modified, or equivalent substitution is carried out to which part technical characteristic;And
These modifications are replaced, and the essence of appropriate technical solution is departed from the spirit and model of various embodiments of the present invention technical scheme
Enclose.
Claims (9)
1. a kind of nano-negative ion water-based interior paint, it is characterised in that the nano-negative ion water-based interior paint includes following heavy
Measure the raw material of part:Water Soluble Compound nanometer anion powder 5-25 parts, modified tourmaline nano emulsion 6-12 parts, aqueous epoxy resins
Emulsion 15-35 parts, filler 20-40 parts, auxiliary agent 2-10 parts, deionized water 10-20 parts.
2. nano-negative ion water-based interior paint according to claim 1, it is characterised in that in the nano-negative ion is water-based
Wall paint includes the raw material of following parts by weight:Water Soluble Compound nanometer anion powder 7-15 parts, modified tourmaline nano emulsion 7-10
Part, aqueous epoxy resin emulsion 20-30 parts, filler 25-35 parts, auxiliary agent 4-8 parts, deionized water 13-17 parts.
3. nano-negative ion water-based interior paint according to claim 1, it is characterised in that in the nano-negative ion is water-based
Wall paint includes the raw material of following parts by weight:10 parts of Water Soluble Compound nanometer anion powder, it is modified tourmaline nano emulsion 8, is water-based
25 parts of epoxy resin latex, 30 parts of filler, 5 parts of auxiliary agent, 15 parts of deionized water.
4. according to the nano-negative ion water-based interior paint described in claim 1-3 any one, it is characterised in that the water solubility
The particle diameter of composite Nano negative ion powder is 5-20 μm.
5. according to the nano-negative ion water-based interior paint described in claim 1-3 any one, it is characterised in that:The water solubility
Composite Nano negative ion powder is opal light shale, at least two in quartz, vermiculite, medical stone, tourmaline grind through nanometer
The nanometer grade composit powder body being milled into.
6. nano-negative ion water-based interior paint according to claim 5, it is characterised in that the Water Soluble Compound nanometer is born
Each parts by weight of raw materials proportioning is nanoprotein stone light shale in ion powder:Nanometer silica flour:Nanometer vermiculite powder:Nanometer wheat meal
Stone:Nano-tourmaline=4.5:4:3:4:6.
7. according to the nano-negative ion water-based interior paint described in claim 1 or 2 or 3, it is characterised in that:The modified Tourmaline
Nanoemulsions are that tourmaline nano powder is dispersed in fluoro-resin emulsion to obtain.
8. according to the nano-negative ion water-based interior paint described in claim 1 or 2 or 3, it is characterised in that:The auxiliary agent includes
0.3-1 parts wetting agent, 0.2-0.5 parts dispersant, 0.2-1.5 parts defoamer, 0.5-2 parts stabilizer, 0.2-2 parts levelling agent,
0.5-2 parts antiseptic, 0.1-1 part thickeners.
A kind of 9. preparation method of the nano-negative ion water-based interior paint as described in claim 1-8 is any, it is characterised in that including
Following steps:
S1, according to parts by weight weigh each raw material;
S2, by Water Soluble Compound nanometer anion powder, modified tourmaline nano emulsion, aqueous epoxy resin emulsion, filler, go from
In sub- water input mixer, stirring 10-20min is reported with rotating speed 500-2000r/min, obtains mixed emulsion;
Auxiliary agent is added in S3, the mixed emulsion prepared to step S2, mixer rotating speed is 300-500r/min, stirs 5-15min,
.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110698916A (en) * | 2019-11-05 | 2020-01-17 | 金华纳维新材料科技有限公司 | Environment-friendly color ink |
CN113105812A (en) * | 2021-04-13 | 2021-07-13 | 江苏旌翔建材科技有限公司 | Negative ion environment-friendly coating and preparation method thereof |
CN113462240A (en) * | 2021-07-27 | 2021-10-01 | 梁作霖 | Preparation process and use method of negative ion releasing coating |
CN113969087A (en) * | 2021-10-11 | 2022-01-25 | 安徽朗凯奇防水科技股份有限公司 | Nano negative ion interior wall latex paint and preparation method thereof |
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CN107163667A (en) * | 2016-03-07 | 2017-09-15 | 许继胜 | Negative oxygen ion emulsion auxiliary agent |
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CN105153830A (en) * | 2015-10-28 | 2015-12-16 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional interior-wall latex paint and preparing method thereof |
CN107163667A (en) * | 2016-03-07 | 2017-09-15 | 许继胜 | Negative oxygen ion emulsion auxiliary agent |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110698916A (en) * | 2019-11-05 | 2020-01-17 | 金华纳维新材料科技有限公司 | Environment-friendly color ink |
CN113105812A (en) * | 2021-04-13 | 2021-07-13 | 江苏旌翔建材科技有限公司 | Negative ion environment-friendly coating and preparation method thereof |
CN113462240A (en) * | 2021-07-27 | 2021-10-01 | 梁作霖 | Preparation process and use method of negative ion releasing coating |
CN113969087A (en) * | 2021-10-11 | 2022-01-25 | 安徽朗凯奇防水科技股份有限公司 | Nano negative ion interior wall latex paint and preparation method thereof |
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