CN107892420A - A kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions - Google Patents

A kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions Download PDF

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Publication number
CN107892420A
CN107892420A CN201711395955.1A CN201711395955A CN107892420A CN 107892420 A CN107892420 A CN 107892420A CN 201711395955 A CN201711395955 A CN 201711395955A CN 107892420 A CN107892420 A CN 107892420A
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CN
China
Prior art keywords
water
module
delivery port
organic carbon
water inlet
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Withdrawn
Application number
CN201711395955.1A
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Chinese (zh)
Inventor
付新
金达
凌杰
徐宁
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Zhejiang Kai Er Mechanical And Electrical Technology Co Ltd
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Zhejiang Kai Er Mechanical And Electrical Technology Co Ltd
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Priority to CN201711395955.1A priority Critical patent/CN107892420A/en
Publication of CN107892420A publication Critical patent/CN107892420A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/60Silicon compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/427Treatment of water, waste water, or sewage by ion-exchange using mixed beds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/04Non-contaminated water, e.g. for industrial water supply for obtaining ultra-pure water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/03Pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/23O3
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/40Liquid flow rate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)

Abstract

The present invention relates to a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions.The present invention includes electron level factory service water tank, pure water pump, flow control meter, self-cleaning temperature control check valve, self-cleaning temperature control module, uviol lamp and goes total organic carbon module, deoxidation module, other impurities to remove module, detection module diaphragm valve, detection module, water repellant barrier valve, water outlet diaphragm valve, return flow meter, first check-valve etc..The invention kills bacterium in pipeline and water purification module at different levels by being passed through heating gradient ultra-pure water, because the biomembrane of water purification module is the main attachment of bacteria breed, by the way that most bacterium can be removed to the sterilization with membrane module, and flowed by certain water circulation, save the consumption of heat energy, cost can be being saved to a certain degree, there is great application value so that water quality reaches the requirement of liquid immersion lithography ultra-pure water total organic carbon.

Description

A kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions
Technical field
The present invention relates to a kind of ultra-pure water to remove organic carbon device, and being used for liquid immersion lithography more particularly, to one kind has automatically The ultrapure water preparation device of degerming functions.
Background technology
In 193nm ArF immersion lithographic systems, it is general using in optical projection system last object lens between silicon chip One layer of ultra-pure water is filled in gap as immersion liquid, photoetching resolution is improved with this.Due to one of this layer of ultra-pure water as light path Part, and directly contacted with silicon chip, therefore very high requirement is proposed to the water quality of the ultra-pure water.In order to prevent in ultra-pure water There is organic fine particles generation, it should go organic carbon to handle the ultra-pure water, however, in general, only using and removing organic carbon mould Block is inadequate, because the bacteria breed of pipeline causes organic carbon endlessly to be produced from internal system, causes organic carbon total Amount is constantly in higher state.If in addition, containing foreign body or particulate in the water for cleaning of IC photo-mask process, will lead Cause gate oxide film thickness uneven, defect occurs for product figure, and pressure-resistant function degenerates, therefore we should be as far as possible in system for a long time It is not used or does not carry out carrying out sterilization processing to device when sterilization is safeguarded for a long time.
All unit flows being related in ultrapure water production system are designed around quality requirement.However, ultra-pure water Often there is unexpected organic carbon pollutant to pollute water quality in making link.Illustrate herein, such as in purifier Upper formation biological membranous layer, then bacterium will be bred in a manner of violent, this may cause bacteria levels to steeply rise and cause water purification The device life-span declines.Once being contaminated in device, it is a stubborn problem that it, which recovers clean state, is because being produced in ultra-pure water In system, will not typically add the chemicals for sterilization, this device interior element can be caused it is huge infringement and generate other can not The pollution of control.
In large-scale semiconductor factory, the sterilization of the general source water using prime, but do not consider rear class water cleaning systems The ligotrophic of middle growth falls, the excreta of such bacterium, a significant source of remains also organic carbon.In this method In, by the way of hot pure water parallel connection enters system, by certain thermograde, kill except the bacterium in pipeline is without to device Internal filter damages.
The content of the invention
The invention discloses a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions.
The present invention includes electron level factory service water tank, pure water pump, flow control meter, self-cleaning temperature control check valve, self-cleaning Temperature control module, uviol lamp go total organic carbon module, deoxidation module, other impurities to remove module, detection module diaphragm valve, water quality inspection Survey module, water repellant barrier valve, with water diaphragm valve, return flow meter and check-valves.
The first water inlet is provided with electron level factory service water tank, electron level factory service water tank delivery port meets entering for pure water pump The mouth of a river, pure water pump delivery port connect the water inlet of flow control meter.Flow control meter delivery port connects uviol lamp and goes total organic carbon module Water inlet, uviol lamp goes the delivery port of total organic carbon module to connect the water inlet of degassing module, and the delivery port for the module that deaerates connects it The water inlet of his impurity treatment module.The delivery port of other impurities processing module is divided into two-way:Pass through water quality detection module all the way The water inlet of diaphragm valve water receiving quality detection module;Another way connects with the water inlet of water repellant barrier valve, with the water inlet of water diaphragm valve Connect the water inlet for being followed by return flow meter.The delivery port of water quality detection module run in water diaphragm valve delivery port after be used as draining Mouthful.The delivery port of return flow meter enters water by what check-valves was connected on the delivery port of flow control meter and total organic carbon removing module Between mouthful.Water nozzle is used as by the use of the delivery port of water diaphragm valve.Self-cleaning temperature control module is connected on stream by self-cleaning temperature control check valve Between the delivery port of amount control meter and the water inlet of total organic carbon removing module;Second is provided with self-cleaning temperature control module and enters water Mouthful.
Pure water pump is used to control intake pressure and flow velocity, and self-cleaning temperature control module is used to carry out pipeline in device and device Sterilization treatment;Return flow meter is used to control circling water flow rate, and the anti-non-return water of check-valves flows backwards.Uviol lamp goes total organic carbon module to use Total organic carbon and some bacteriums in ultra-pure water are removed.Deoxidation module be used for remove ozone remaining in ultra-pure water and Uviol lamp go total organic carbon module caused by carbon dioxide, prevent impurity introduce post-module.Pass through other impurities processing module Other impurities are removed, water quality detection module is monitored in real time to water quality.
Water temperature is regulated and controled using self-cleaning temperature control module, gradient is heated to be slowly heated 28 with 2-3 DEG C per minute DEG C ultra-pure water circulates 80-85 DEG C of hot ultra-pure water 30-60 minute, to device interior conduit until reach 80-85 DEG C in device afterwards Sterilization processing is carried out with other filter films, afterwards with 2-3 DEG C per minute of the Slow cooling ultra-pure water of falling temperature gradient 23 to 28 DEG C, After water temperature recovers 28 DEG C, preparation is supplied water 10 minutes.
Described uviol lamp goes total organic carbon module to include ozone source, multiple uviol lamps, multiple flow controllers and every Film valve.
Described degassing module includes nitrogen access source, multiple electromagnetism magnetic valve, gas pressure regulator and degassing films.
Described other impurities, which remove module, to include deionization mixed bed, removes single of silicon and end-filtration.
Described defects inspecting module includes total organic carbon table, ozone table, resistivity table.
Present invention employs self-cleaning temperature control module to regulate and control to water temperature, to kill in pipeline and water purification module at different levels Bacterium, because the biomembrane of water purification module is the main attachment of bacteria breed, by the way that the sterilization with film module can remove a bit to this Most bacterium is gone, and is flowed by certain water circulation, the consumption of heat energy is saved, is saving cost to a certain degree, have There is great application value.
Brief description of the drawings
Fig. 1 is the overall structure diagram of the present invention.
Embodiment
As shown in figure 1, a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions, including electronics Level factory service water tank 1, pure water pump 2, flow control meter 3, self-cleaning temperature control check valve 4, self-cleaning temperature control module 5, uviol lamp are gone Total organic carbon module 6, deoxidation module 7, other impurities remove module 8, detection module diaphragm valve 9, water quality detection module 10, draining Diaphragm valve 11, with water diaphragm valve 12, return flow meter 13 and check-valves 14.
Electron level factory service water water inlet (the first water inlet), electron level factory service water are provided with electron level factory service water tank 1 The delivery port of water tank 1 connects the water inlet of pure water pump, and the delivery port of pure water pump 2 connects the water inlet of flow control meter 3.Flow control meter 3 goes out The mouth of a river connects the water inlet that uviol lamp goes total organic carbon module 6, and uviol lamp goes the delivery port of total organic carbon module 6 to connect degassing module 7 Water inlet, the delivery port of degassing module 7 connects the water inlet of other impurities processing module 8.The water outlet of other impurities processing module 8 Mouth is divided into two-way:Pass through the water inlet of the water receiving quality detection module 10 of detection module diaphragm valve 9 all the way;Another way and water repellant barrier valve 11 water inlet, the water inlet for being followed by return flow meter 13 is connected with the water inlet of water diaphragm valve 12.Water quality detection module 10 Delivery port run in water diaphragm valve 11 delivery port after be used as discharge outlet.The delivery port of return flow meter 13 is connected on stream by check-valves Between the delivery port of amount control meter 3 and the water inlet of total organic carbon removing module.By the use of the delivery port of water diaphragm valve 12 as using water Mouthful.Self-cleaning temperature control module 5 is connected on the delivery port and total organic carbon removing of flow control meter 3 by self-cleaning temperature control check valve 4 Between the water inlet of module;Electron level factory service water water inlet (the second water inlet) is provided with self-cleaning temperature control module 5.
Pure water pump 2 is used to control intake pressure and flow velocity, and self-cleaning temperature control module 5 is used to enter pipeline in device and device Row sterilization treatment;Return flow meter 13 is used to control circling water flow rate, and 14 anti-non-return water of check-valves flows backwards.Uviol lamp removes total organic carbon Module 6 is used to be removed the total organic carbon in ultra-pure water and some bacteriums.Deoxidation module 7 is used to remove remaining in ultra-pure water Ozone and uviol lamp go total organic carbon module 6 caused by carbon dioxide, prevent impurity introduce post-module.Pass through other impurities Processing module 8 is removed to some other impurity, including metallic element, dissolved oxygen etc., finally by water quality detection module 10 pairs of water quality are monitored in real time.
Uviol lamp goes total organic carbon module 6 to include ozone source, multiple uviol lamps, multiple flow controllers and diaphragm valve. The module 7 that deaerates includes nitrogen access source, multiple electromagnetism magnetic valve, gas pressure regulator and degassing films.Other impurities remove Module 8 includes deionization mixed bed, removes single of silicon and end-filtration.Defects inspecting module 9 includes total organic carbon table, ozone table, electricity Resistance rate table.
The present invention uses self-cleaning temperature control module to regulate and control water temperature with the sensitive filters in protection device, while complete Into the sterilization processing of interior conduit He other filter films.Specially:Gradient is heated with 2-3 DEG C per minute to be slowly heated 28 DEG C Ultra-pure water is until reach 80-85 DEG C, if wherein temperature rises too fast, meeting oxidation damage rear end filter, it is therefore desirable to very Strict temperature control, 80-85 DEG C of hot ultra-pure water 30-60 minute is circulated in device afterwards, afterwards with 2-3 DEG C per minute of drop For warm gradient Slow cooling ultra-pure water to 28 DEG C, its effect is identical with method and slow heating process, and recovers 28 DEG C in water temperature Afterwards, preparation, which is supplied water 10 minutes, allows device inner member to carry out certain Acclimation temperature.
The course of work:The present invention shares three states, is service position, preparation service position and sterilizing state respectively:When When being in service position, the first water inlet can be opened, and the second water inlet is closed, and water nozzle magnetic valve is opened, discharge outlet electromagnetism Valve is closed, and electron level factory service water is passed through from the first water inlet.When program is in prepared service position, the first water inlet can be beaten Open, the second water inlet is closed, water nozzle closed electromagnetic valve, and discharge outlet magnetic valve is opened, wherein being passed through electronics from the first water inlet Level factory service water.When program is in sterilizing state, the first water inlet can be closed, and the second water inlet is opened, water nozzle magnetic valve Close, discharge outlet magnetic valve is opened, and the electron level factory service water with temperature control is passed through from the second water inlet.Do not cleaned for a long time in device Or after being not used for a long time, by opening system sterilizing state, the ultra-pure water of certain temperature is passed through into the second water inlet introgressive line In system, total organic carbon module, deoxidation module and other impurities are gone to remove filter screen or biomembrane in module to pipeline and uviol lamp Carry out sterilization;And parameters are detected by water quality detection module.Simultaneously by the regulation to return flow meter, Circling water flow rate is controlled, improves the degerming efficiency of system and for the ultra-pure water demand with water, and reduce self-cleaning temperature control mould The energy resource consumption of block, while by discharge outlet to System drainage.
During the non-bacterial heap of also not qualified but pipeline or rear class instruction of supplying water is not initiated, open system ready in water quality and supply water State, by electron level factory service water by the first water inlet import system, by interior circulation regulating water quality, and by discharge outlet to being System carries out draining.When water quality is qualified and rear class supplies water instructs initiation, system water supply state is opened, electron level factory service water is passed through First water inlet import system, by water nozzle, level supplies water backward.
Water repellant barrier valve and one can only be opened in the same time with water diaphragm valve, its delivery port is respectively as waste water draining Outlet and ultra-pure water water out.
Circling water flow rate control meter provides corresponding flow according to water demand dynamic, ensures the supply to rear class, leads to simultaneously Cross the temperature of feedback stability water spot, pressure, flow value, each element in protection device inside.
Above-mentioned embodiment is used for illustrating the present invention, rather than limits the invention, the present invention's In spirit and scope of the claims, to any modifications and changes of the invention made.

Claims (6)

1. a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions, including electron level factory service water water Case, pure water pump, flow control meter, self-cleaning temperature control check valve, self-cleaning temperature control module, uviol lamp go total organic carbon module, taken off Oxygen module, other impurities remove module, detection module diaphragm valve, detection module, water repellant barrier valve, with water diaphragm valve, backwater stream Gauge and check-valves;It is characterized in that:
The first water inlet is provided with described electron level factory service water tank, electron level factory service water tank delivery port connects pure water pump Water inlet, pure water pump delivery port connect the water inlet of flow control meter;Flow control meter delivery port connects uviol lamp and removes total organic carbon mould The water inlet of block, uviol lamp go the delivery port of total organic carbon module to connect the water inlet of degassing module, and the delivery port for the module that deaerates connects The water inlet of other impurities processing module;The delivery port of other impurities processing module is divided into two-way:All the way by detection module every Film valve connects the water inlet that other impurities remove module;Another way and water inlet, the water inlet with water diaphragm valve of water repellant barrier valve Connection is followed by the water inlet of return flow meter;Other impurities remove module delivery port run in water diaphragm valve delivery port after conduct Discharge outlet;The delivery port of return flow meter is connected on the delivery port and total organic carbon removing module of flow control meter by check-valves Between water inlet;Water nozzle is used as by the use of the delivery port of water diaphragm valve;Self-cleaning temperature control module is connect by self-cleaning temperature control check valve Between the delivery port of flow control meter and the water inlet of total organic carbon removing module;Second is provided with self-cleaning temperature control module Water inlet.
Pure water pump is used to control intake pressure and flow velocity, and self-cleaning temperature control module is used to sterilize to pipeline in device and device Processing;Return flow meter is used to control circling water flow rate, and the anti-non-return water of check-valves flows backwards;Uviol lamp go total organic carbon module be used for pair Total organic carbon and some bacteriums in ultra-pure water are removed;Deoxidation module is used to remove ozone remaining in ultra-pure water and ultraviolet Lamp go total organic carbon module caused by carbon dioxide, prevent impurity introduce post-module;By other impurities processing module to it He is removed impurity, and detection module is monitored in real time to water quality.
2. a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions as claimed in claim 1, its It is characterised by:Water temperature is regulated and controled using self-cleaning temperature control module, gradient is heated to be slowly heated 28 with 2-3 DEG C per minute DEG C ultra-pure water circulates 80-85 DEG C of hot ultra-pure water 30-60 minute, to device interior conduit until reach 80-85 DEG C in device afterwards Sterilization processing is carried out with other filter films, afterwards with 2-3 DEG C per minute of the Slow cooling ultra-pure water of falling temperature gradient 23 to 28 DEG C, After water temperature recovers 28 DEG C, preparation is supplied water 10 minutes.
3. a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions as claimed in claim 1, its It is characterised by:Described uviol lamp goes total organic carbon module to include ozone source, multiple uviol lamps, multiple flow controllers and every Film valve.
4. a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions as claimed in claim 1, its It is characterised by:Described degassing module includes nitrogen access source, multiple electromagnetism magnetic valve, gas pressure regulator and degassings Film.
5. a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions as claimed in claim 1, its It is characterised by:Described other impurities, which remove module, to include deionization mixed bed, removes single of silicon and end-filtration.
6. a kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions as claimed in claim 1, its It is characterised by:Described defects inspecting module includes total organic carbon table, ozone table, resistivity table.
CN201711395955.1A 2017-12-21 2017-12-21 A kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions Withdrawn CN107892420A (en)

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CN201711395955.1A CN107892420A (en) 2017-12-21 2017-12-21 A kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions

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Application Number Priority Date Filing Date Title
CN201711395955.1A CN107892420A (en) 2017-12-21 2017-12-21 A kind of ultrapure water preparation device for liquid immersion lithography with automatic degerming functions

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CN107892420A true CN107892420A (en) 2018-04-10

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01148387A (en) * 1987-12-02 1989-06-09 Daicel Chem Ind Ltd Thermal sterilization of final filter for preparing extremely pure water
CN103172185A (en) * 2013-04-02 2013-06-26 浙江大学 Ultrapure water preparation device with outlet water quality regulating mechanism

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01148387A (en) * 1987-12-02 1989-06-09 Daicel Chem Ind Ltd Thermal sterilization of final filter for preparing extremely pure water
CN103172185A (en) * 2013-04-02 2013-06-26 浙江大学 Ultrapure water preparation device with outlet water quality regulating mechanism

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