CN107882284A - Composite thermal insulation decorative board - Google Patents
Composite thermal insulation decorative board Download PDFInfo
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- CN107882284A CN107882284A CN201711047495.3A CN201711047495A CN107882284A CN 107882284 A CN107882284 A CN 107882284A CN 201711047495 A CN201711047495 A CN 201711047495A CN 107882284 A CN107882284 A CN 107882284A
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- Prior art keywords
- decorative board
- thermal insulation
- composite thermal
- parts
- insulation decorative
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Finishing Walls (AREA)
- Laminated Bodies (AREA)
Abstract
This case is related to a kind of composite thermal insulation decorative board, including adiabator layer and etch resistant material layer, includes the raw material of following parts by weight by organic binder cemented fixation, described adiabator layer between them:30~50 parts of kaolin;20~30 parts of acrylic latex powder;8~16 parts of hollow silica ball;5~10 parts of fluoro polyphosphonitrile rubber;4~8 parts of hydrophober;5~8 parts of fireproof agent;2~5 parts of string;3~5 parts of humic acid.The present invention by insulation intermediate layer by being arranged to said components and proportioning, and the insulation intermediate layer soundproof effect produced is very remarkable, and high insulating effect;Technique is simple, and production cost is low, and fire rating is high, good corrosion resistance.
Description
Technical field
The present invention relates to building material field, more particularly to a kind of composite thermal insulation decorative board.
Background technology
Promoting ecological environmental protection is sustainable development theory important in modern society, and the construction and application of technical ability building are just
This point has been absolutely proved, has also produced positive effect for environmental protection and energy-saving and emission-reduction work.Exterior-wall heat insulation plate technique application
In being only capable of in building, the realization of building heat preservation engineering and its giving full play to for effect are promoted, even more realizes the pass of building energy conservation
Key requirement.External wall insulation is that have factory's centralized production, is then directly used for external wall in construction and bonds, has and protect
Temperature, the important materials of the effect of waterproof, even more architectural finish.The characteristics of external wall insulation, determines it in architectural engineering
Extensive use, but be intended to reach good construction effect, being ensured of for external wall heat-insulating board construction technology is essential,
It is the essential condition for developing modern architecture and energy saving building theory, has more ensured the architecture quality and service life of building, be society
The reasonable of meeting resource utilizes the guarantee lived safely with people.
Mainly based on organic heat-insulating plate, these organic heat-insulating plate heat-insulating properties disclosure satisfy that in the market Outwall thermal insulation board
It is required that but stability deficiency, easy to crack, soundproof effect is bad, can not especially solve the problems, such as security against fire.
The content of the invention
For technical problem present in prior art, this case provides a kind of composite thermal insulation decorative board.
To achieve the above object, this case is achieved through the following technical solutions:
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Preferably, described composite thermal insulation decorative board, wherein, the etch resistant material layer is polyurethane foam insulation
Plate.
Preferably, described composite thermal insulation decorative board, wherein, the organic binder bond is polyurethane adhesive or ureaformaldehyde
Resinoid bond.
Preferably, described composite thermal insulation decorative board, wherein, the hollow silica ball by following mass parts group
It is grouped into:
0.1-1 μm of 50~70wt% of hollow silica ball;
10-40 μm of 30~50wt% of hollow silica ball.
Preferably, described composite thermal insulation decorative board, wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is
300000-500000。
Preferably, described composite thermal insulation decorative board, wherein, the hydrophober is copper 8-quinolinolate.
Preferably, described composite thermal insulation decorative board, wherein, the string is wood fibre.
Preferably, described composite thermal insulation decorative board, wherein, the fireproof agent is in fishbone dust, calcium superphosphate
It is a kind of.
The beneficial effects of the invention are as follows:
(1) by the way that hollow silica ball will be added in insulation intermediate layer, integral heat insulation performance is not only increased, using two
Kind specification, make the regular ordered arrangement of hollow spheres, properties of product are stable, and comprehensive strength is high, also composite plate is provided with very
Good sound-absorbing and sound insulation function, the decorative panel can play its superior sound absorption qualities in the range of 250~1000Hz;
(2) by adding acrylic latex powder, raising product compression strength and tensile strength and adhesion strength, while again
Significantly increase the viscosity and fire line of product;
(3) heat endurance and anti-flammability of product are improved by adding fluoro polyphosphonitrile rubber, copper 8-quinolinolate, which is used as, hates
Aqua and stabilizer improve the heat endurance of product with fluoro polyphosphonitrile rubber coordinative role, so as to improve the fire resistance of product;
(4) technique is simple, and production cost is low, and fire rating is high, good corrosion resistance.
Embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification
Word can be implemented according to this.
The presence of some oxygen-containing functional groups in humic acid, make humic acid that there is the various adsorptions of colloid property one, ion
Exchange, complexing, shock-absorbing capacity.The oxygen-containing functional group of humus mainly has carboxyl (COOH), phenolic hydroxyl group (Phenolic-
OH), ketone group (Ketolic-C=O) and methoxyl group (- OCH3), furthermore, it is also possible to contain quinonyl (Quinonid-C=O) and alcohol
Hydroxyl (Alcoholic-OH).The process of humic acid adsorbing metal ions includes ion exchange and the aspect of ligand complex two, humic
The main acidic functionality of acid is benzene carboxyl and phenolic hydroxyl group, because they are different from the link position of phenyl ring, in the structure mainly
Show as two types:Salicylic acid type and O-phthalic acid type;Kaolin is a kind of day with complicated aluminosilicate structure
Right mineral, its surface of solids contain substantial amounts of hydroxyl, kaolinic surface-active and permanent charge surface position and variable charge table
Both main surface action groups of face position are relevant.Mostly occur ion-exchange reactions on the position of permanent charge surface, and surface
The formation of complex compound is usually the result being bonded with surface hydroxyl.Humic acid is to metal ion electrostatic adsorption, or surface
Ligand complex, so as to strengthen the mechanical property of adiabator layer and heat-insulating property.
Acrylic latex powder can improve product compression strength and tensile strength and adhesion strength, while and can substantially increases
The viscosity and fire line of product.
Fluoro polyphosphonitrile rubber is that a kind of be interweaved with P and N has excellent for the inorganic fluorine-containing polymer of main chain, main chain P=N
Heat endurance and anti-flammability more, and it is very soft;Contain fluoride on side chain.Therefore addition fluoro polyphosphonitrile rubber has excellent
Different oil resistivity, high-temperature stability and compression strength.Copper 8-quinolinolate can improve fluorination phosphonitrile as hydrophober and stabilizer
The heat endurance of rubber, so as to improve the fire resistance of product.
Hollow silica ball makes the regular ordered arrangement of hollow spheres, makes interior tissue by using two kinds of specifications
Uniformly, properties of product are stable, and comprehensive strength is high, can effectively reduce noise.
Embodiment 1
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate.
Wherein, the organic binder bond is polyurethane adhesive.
Wherein, the hollow silica ball is made up of the component of following mass parts:
0.1-1 μm of hollow silica ball 70wt%;
10-40 μm of hollow silica ball 30wt%.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is fishbone dust.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
45min is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and polyurethane foam
Foam warming plate is adhesively fixed by polyurethane adhesive.
Embodiment 2
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate;The organic binder bond bonds for Lauxite
Agent.
The hollow silica ball is made up of the component of following mass parts:
0.1-1 μm of hollow silica ball 50wt%;
10-40 μm of hollow silica ball 50wt%.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is calcium superphosphate.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
1h is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and expanded polystyrene
Foam heat-insulating board is adhesively fixed by urea-formaldehyde binder.
Comparative example 1:
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate.
Wherein, the organic binder bond is polyurethane adhesive.
Wherein, the hollow silica ball is made up of the component of following mass parts:
0.1-1 μm of hollow silica ball 70wt%;
10-40 μm of hollow silica ball 30wt%.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is fishbone dust.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
45min is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and polyurethane foam
Foam warming plate is adhesively fixed by polyurethane adhesive.
Comparative example 2
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate.
Wherein, the organic binder bond is polyurethane adhesive.
Wherein, the hollow silica ball is made up of the component of following mass parts:
0.1-1 μm of hollow silica ball 70wt%;
10-40 μm of hollow silica ball 30wt%.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is fishbone dust.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
45min is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and polyurethane foam
Foam warming plate is adhesively fixed by polyurethane adhesive.
Comparative example 3
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate.
Wherein, the organic binder bond is polyurethane adhesive.
Wherein, the hollow silica ball is made up of the component of following mass parts:
0.1-1 μm of hollow silica ball 70wt%;
10-40 μm of hollow silica ball 30wt%.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is fishbone dust.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
45min is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and polyurethane foam
Foam warming plate is adhesively fixed by polyurethane adhesive.
Comparative example 4:
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate.
Wherein, the organic binder bond is polyurethane adhesive.
Wherein, the hollow silica ball particle diameter is 0.1-1 μm.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is fishbone dust.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
45min is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and polyurethane foam
Foam warming plate is adhesively fixed by polyurethane adhesive.
Comparative example 5:
A kind of composite thermal insulation decorative board, wherein, including adiabator layer and etch resistant material layer, by organic between them
Binding agent is adhesively fixed,
Described adiabator layer includes the raw material of following parts by weight:
Wherein, the etch resistant material layer is polyurethane foam insulation plate.
Wherein, the organic binder bond is polyurethane adhesive.
Wherein, the hollow silica ball particle diameter is 10-40 μm.
Wherein, the fluoro polyphosphonitrile rubber mean molecule quantity is 300000-500000;The hydrophober is 8-hydroxyquinoline
Copper;The string is wood fibre;The fireproof agent is fishbone dust.
Composite thermal insulation decorative board preparation method:
Adiabator layer weighs raw material mixing by above-mentioned parts by weight, is put into mixer plus water stirring is until well mixed;
By glass fibre cloth pad in die surface, gained mixture, which is poured into mould, to be press-formed;It is 90 DEG C to set oven temperature, is put into
45min is dried in baking oven;Take out shaped heat insulation material, it is to be cooled completely after, by the insulation material being prepared and polyurethane foam
Foam warming plate is adhesively fixed by polyurethane adhesive.
The composite thermal insulation decorative board performance test of the embodiment of table 1 and comparative example:
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited
In specific details.
Claims (8)
1. a kind of composite thermal insulation decorative board, it is characterised in that pass through including adiabator layer and etch resistant material layer, between them
Organic binder cemented fixation,
Described adiabator layer includes the raw material of following parts by weight:
2. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the etch resistant material layer is polyurethane foam
Warming plate.
3. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the organic binder bond is polyurethane adhesive
Or urea-formaldehyde binder.
4. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the hollow silica ball is by following quality
The component composition of part:
0.1-1 μm of 50~70wt% of hollow silica ball;
10-40 μm of 30~50wt% of hollow silica ball.
5. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the fluoro polyphosphonitrile rubber mean molecule quantity is
300000-500000。
6. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the hydrophober is copper 8-quinolinolate.
7. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the string is wood fibre.
8. composite thermal insulation decorative board as claimed in claim 1, it is characterised in that the fireproof agent is selected from fishbone dust, peroxophosphoric acid
One kind in calcium.
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CN201711047495.3A CN107882284A (en) | 2017-10-31 | 2017-10-31 | Composite thermal insulation decorative board |
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CN201711047495.3A CN107882284A (en) | 2017-10-31 | 2017-10-31 | Composite thermal insulation decorative board |
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Family
ID=61783235
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Cited By (2)
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CN108559187A (en) * | 2018-05-09 | 2018-09-21 | 合肥永泰新型建材有限公司 | A kind of novel environment-friendly insulating construction material and preparation method thereof |
CN110982028A (en) * | 2019-12-03 | 2020-04-10 | 江苏科趣新材料科技有限公司 | Heat insulation material for refrigeration house |
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Publication number | Priority date | Publication date | Assignee | Title |
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