CN107880857A - A kind of pipe fire liquid and its application - Google Patents
A kind of pipe fire liquid and its application Download PDFInfo
- Publication number
- CN107880857A CN107880857A CN201610868461.XA CN201610868461A CN107880857A CN 107880857 A CN107880857 A CN 107880857A CN 201610868461 A CN201610868461 A CN 201610868461A CN 107880857 A CN107880857 A CN 107880857A
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- CN
- China
- Prior art keywords
- pipe fire
- liquid
- pipe
- fire
- fire liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The present invention relates to a kind of pipe fire liquid, the composition of following parts by weight is included：15~35 parts of antifreezing agent, 2~15 parts of fire retardant, 5~20 parts of antirust agent, 1~8 part of scale preventative, 0.1~10 part of preservative, 2~10 parts of buffer, 0.05~1 part of dyestuff, 30~60 parts of deionized water.The pipe fire liquid of the present invention has good antifreeze effect, and winter can effectively prevent pipeline bursting by freezing because of liquid icing；There is anti-rust action to pipeline, valve, contain anti-corrosion composition simultaneously, avoid cooperating microorganisms in liquid, service life is longer, while has certain flame retardant effect.
Description
Technical field
The invention belongs to chemical field, is related to pipe fire liquid, specifically, be related to one kind be filled in fire protection pipeline,
Prevent from freezing the liquid for causing frost crack pipe,.
Background technology
Fire protection pipeline is the pipeline for conveying fire-fighting fire extinguishing water or other firing-fighting mediums, according to material can be divided into cast iron pipe,
Copper pipe, compo pipe, plastic tube, composited pipe etc..Easily because liquid in pipe freezes bursting by freezing occurs for cold district winter, fire protection pipeline
Phenomenon, fire fighting supply safety is influenceed, causes potential safety hazard.Therefore adequate measures are taken to prevent that fire protection pipeline bursting by freezing from being very must
Want.
By fill pipe fire-fighting liquid anti-freezing method in pipeline, investment is small, and operating cost is relatively low.Domestic use special at present
It is less in the antifreeze fire-fighting liquid species of fire protection pipeline, and antirust, anti-corrosion, fire-retardant function are more short of, and have impact on fire-fighting liquid
Using effect.
The content of the invention
It is an object of the invention to provide a kind of frost-cracking-preventing performance is strong, while there is anti-corrosion, scale-deposit-preventing, prevent microorganism
Growth and the pipe fire liquid of flame retardant effect.
Pipe fire liquid provided by the invention, include the composition of following parts by weight：
Preferably, the pipe fire liquid includes the composition of following parts by weight：
In order to which the performance of the pipe fire liquid is further improved, specific choosing of the present invention to wherein each component
Select and be optimized.Specifically：
Antifreezing agent of the present invention is one kind in calcium chloride, magnesium chloride；Preferably calcium chloride.The antifreezing agent can be effective
Freezing point is reduced, prevents liquid from freezing at low temperature.
Fire retardant of the present invention is ammonium dihydrogen phosphate, diammonium hydrogen phosphate, phosphate, dibromo zinn glutaric alcohol, dibromo pungent penta
One or more in glycol phosphate；Preferably ammonium dihydrogen phosphate.The fire retardant can produce inhibitory action to burning, help
In stamping out a fire.
Antirust agent of the present invention is thiophosphate, alkylolamides, pentaerythritol ester, inositol hexaphosphate, 1,2-
One or more in diethoxy estersil base ethane；Preferably inositol hexaphosphate.The antirust agent can table in protective conduit
Face, prevent corrosion.
Scale preventative of the present invention is nitrogen epoxide trimethylene phosphonic, calgon, sodium tripolyphosphate, polyacrylic acid
One kind in salt, HPMA, ethylenediamine tetramethylene phosphonic acid, hydroxyethylidine di 2 ethylhexyl phosphonic acid；Preferably nitrogen epoxide three
Methylene phosphonic acid.The scale preventative can prevent water jet outlet caused by accumulating liquid fouling in pipeline from blocking.
Preservative of the present invention is one kind in chitosan, dimethyl fumarate, Kocide SD, copper sulphate.Preferably
Chitosan.The preservative can sterilizing, prevent pipeline accumulate liquid in cooperating microorganisms.
Buffer of the present invention is one kind in HEPES, Tricine, triethanolamine.The buffer can keep pipeline
Liquid pH value is stablized relatively, prevents performance change and corrosive pipeline caused by liquid pH value change.
Dyestuff of the present invention is basic fuchsin.The fuel can dye liquid, so that it is distinguished with running water, prevent
Eat misuse by mistake.
As a preferred embodiment of the present invention, the pipe fire liquid includes the composition of following parts by weight：
As a preferred embodiment of the present invention, the pipe fire liquid includes the composition of following parts by weight：
Compared to existing technology, pipe fire liquid of the invention has the advantage that and effect：
1st, there is good antifreeze effect, winter can effectively prevent pipeline bursting by freezing because of liquid icing；
2nd, there is anti-rust action to pipeline, valve, contains anti-corrosion composition simultaneously, avoid cooperating microorganisms in liquid, use
Last a long time；
3rd, contain flame-retardant composition, there is certain flame retardant effect.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
The pipe fire liquid that following embodiment provides, can be prepared using following methods：According to measure it is each into
Point, it is well mixed, produces at room temperature.
Embodiment 1
A kind of pipe fire liquid, consisting of：Calcium chloride 15g, phosphate 12g, thiophosphate 8g, sodium tripolyphosphate
6g, dimethyl fumarate 5g, HEPES 8g, basic fuchsin 0.5g, deionized water 45.5g.
Embodiment 2
A kind of pipe fire liquid, consisting of：Calcium chloride 21g, dibromo zinn glutaric alcohol 11g, alkylolamides 10g, season penta
Four alcohol ester 7g, HPMA 3g, Kocide SD 1g, Tricine7g, basic fuchsin 0.8g, deionized water 39.2g.
Embodiment 3
A kind of pipe fire liquid, consisting of：Calcium chloride 25g, dibromo zinn glutaric alcohol phosphate 8g, 1,2- diethoxy silicon
Ester group ethane 15g, ethylenediamine tetramethylene phosphonic acid 5g, copper sulphate 2g, triethanolamine 8g, basic fuchsin 0.4g, deionized water
36.6g。
Embodiment 4
A kind of pipe fire liquid, consisting of：Calcium chloride 30g, diammonium hydrogen phosphate 2g, phosphate 2g, inositol hexaphosphate
18g, nitrogen epoxide trimethylene phosphonic 6g, dimethyl fumarate 0.5g, HEPES 3g, basic fuchsin 0.1g, deionized water
38.4g。
Embodiment 5
A kind of pipe fire liquid, consisting of：Magnesium chloride 15g, ammonium dihydrogen phosphate 2g, inositol hexaphosphate 2g, thio phosphorus
Acid esters 2g, pentaerythritol ester 1g, calgon 3g, chitosan 10g, triethanolamine 4g, basic fuchsin 1g, deionized water 60g.
Embodiment 6
A kind of pipe fire liquid, consisting of：Magnesium chloride 20g, diammonium hydrogen phosphate 5g, phosphate 1g, alkylolamides
11g, hydroxyethylidine di 2 ethylhexyl phosphonic acid 3g, chitosan 0.1g, Tricine 5g, basic fuchsin 0.5g, deionized water 54.4g.
Embodiment 7
A kind of pipe fire liquid, consisting of：Magnesium chloride 27g, diammonium hydrogen phosphate 8g, inositol hexaphosphate 15g, nitrogen epoxide
Trimethylene phosphonic 5g, chitosan 1.9g, HEPES 8g, basic fuchsin 0.1g, deionized water 35g.
Experimental example 1：
To embodiment 1~7, the freezing point of the pipe fire liquid obtained by each embodiment, inspection are determined according to SH/T 0090 method
It is as shown in table 1 to survey result.
The pipe fire liquid freezing point testing result of table 1
Conclusion：Freezing-point test result shows that pipe fire liquid provided by the invention has excellent antifreeze ability；Winter energy
It is enough effectively to prevent pipeline bursting by freezing because of liquid icing.
Fire retardancy test result shows, pipe fire liquid provided by the invention is non-combustible without flash-point, has certain fire-retardant
Property.
Corrosion test result shows that pipe fire liquid provided by the invention is good to the rust-proof effect of metal cast iron and copper,
Effectively corrosion protection can be provided to cast iron pipe, copper pipe and metal valve.
Although above the present invention is made to retouch in detail with general explanation, embodiment and experiment
State, but on the basis of the present invention, it can be made some modifications or improvements, this is apparent to those skilled in the art
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, are belonged to claimed
Scope.
Claims (10)
1. a kind of pipe fire liquid, it is characterised in that include the composition of following parts by weight：
2. pipe fire liquid according to claim 1, it is characterised in that include the composition of following parts by weight：
3. pipe fire liquid according to claim 1 or 2, it is characterised in that the antifreezing agent is in calcium chloride, magnesium chloride
One kind；Preferably calcium chloride.
4. the pipe fire liquid according to claims 1 to 3 any one, it is characterised in that the fire retardant is di(2-ethylhexyl)phosphate
One or more in hydrogen ammonium, diammonium hydrogen phosphate, phosphate, dibromo zinn glutaric alcohol, dibromo zinn glutaric alcohol phosphate；Preferably phosphorus
Acid dihydride ammonium.
5. the pipe fire liquid according to Claims 1 to 4 any one, it is characterised in that the antirust agent is inositol six
One or more in phosphate, thiophosphate, alkylolamides, pentaerythritol ester, 1,2- diethoxy estersil base ethane；
Preferably inositol hexaphosphate.
6. the pipe fire liquid according to Claims 1 to 5 any one, it is characterised in that the scale preventative is nitrogen epoxide
Trimethylene phosphonic, calgon, sodium tripolyphosphate, polyacrylate, HPMA, ethylenediamine tetramethylene phosphine
One kind in acid, hydroxyethylidine di 2 ethylhexyl phosphonic acid；Preferably nitrogen epoxide trimethylene phosphonic.
7. the pipe fire liquid according to claim 1~6 any one, it is characterised in that the preservative be chitosan,
One kind in dimethyl fumarate, Kocide SD, copper sulphate.Preferably chitosan.
8. the pipe fire liquid according to claim 1~7 any one, it is characterised in that the buffer be HEPES,
One kind in Tricine, triethanolamine；
Or/and the dyestuff is basic fuchsin.
9. a kind of pipe fire liquid, it is characterised in that include the composition of following parts by weight：
Preferably, the composition of following parts by weight is included：
It is further preferred that include the composition of following parts by weight：
10. the application of pipe fire liquid described in claim 1~9 any one, it is characterised in that be filled in the fire-fighting liquid
In fire protection pipeline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610868461.XA CN107880857A (en) | 2016-09-29 | 2016-09-29 | A kind of pipe fire liquid and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610868461.XA CN107880857A (en) | 2016-09-29 | 2016-09-29 | A kind of pipe fire liquid and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107880857A true CN107880857A (en) | 2018-04-06 |
Family
ID=61769685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610868461.XA Pending CN107880857A (en) | 2016-09-29 | 2016-09-29 | A kind of pipe fire liquid and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107880857A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020247780A1 (en) * | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
| US10960249B2 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11395934B2 (en) | 2020-12-15 | 2022-07-26 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11554280B2 (en) | 2019-06-07 | 2023-01-17 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11819723B2 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| WO2020247780A1 (en) * | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
| US11607570B2 (en) | 2019-06-07 | 2023-03-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US10960249B2 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11344760B2 (en) | 2019-06-07 | 2022-05-31 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11819722B1 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| EP3980140A4 (en) * | 2019-06-07 | 2023-06-14 | FRS Group, LLC | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11534643B2 (en) | 2019-06-07 | 2022-12-27 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11554279B2 (en) | 2019-06-07 | 2023-01-17 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US10960250B2 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11041063B2 (en) | 2019-06-07 | 2021-06-22 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
| US10960251B1 (en) | 2019-06-07 | 2021-03-30 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11628324B2 (en) | 2020-12-15 | 2023-04-18 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11420084B2 (en) | 2020-12-15 | 2022-08-23 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11395934B2 (en) | 2020-12-15 | 2022-07-26 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11602658B2 (en) | 2020-12-15 | 2023-03-14 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11865391B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11865392B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11883703B2 (en) | 2020-12-15 | 2024-01-30 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
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Application publication date: 20180406 |