CN107880496B - Regenerated disposable shopping bag - Google Patents

Regenerated disposable shopping bag Download PDF

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Publication number
CN107880496B
CN107880496B CN201711127907.4A CN201711127907A CN107880496B CN 107880496 B CN107880496 B CN 107880496B CN 201711127907 A CN201711127907 A CN 201711127907A CN 107880496 B CN107880496 B CN 107880496B
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Prior art keywords
parts
weight
shopping bag
regenerated
disposable shopping
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CN201711127907.4A
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Chinese (zh)
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CN107880496A (en
Inventor
陈道明
彭凯嘉
卢德
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Sichuan Plasking Sci Tech Co ltd
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Sichuan Plasking Sci Tech Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Packages (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The invention discloses a regenerated disposable shopping bag, which relates to environmental protection and is prepared from the following components:
Figure DDA0001468769650000011

Description

Regenerated disposable shopping bag
Technical Field
The invention relates to environmental protection, in particular to a regenerative disposable shopping bag.
Background
The polyester bottle has light weight and good sealing performance, and is widely applied to various industries, and the scrapped polyester bottle generally adopts an incineration method, so that the environment is polluted, and the development of industry and agriculture is not facilitated.
However, the recycled disposable shopping bag is only used for preparing clothes such as carpets and the like and cannot be used for preparing films because molecules are cut in recycling of polyester bottles.
Disclosure of Invention
The invention aims to provide a regenerated disposable shopping bag, and the prepared regenerated disposable shopping bag has the sealing strength of not less than 1.2Kg/15mm at the heat sealing temperature of 135 ℃.
The technical scheme is as follows: a regenerated disposable shopping bag is prepared from the following components:
70-75 parts by weight of polyester bottle chips
5-8 parts of MLLDPE
20-30 parts by weight of a high-pressure polyethylene resin and
5-10 parts by weight of methacrylic acid dehydrated glyceride.
Preferably, the
70 parts by weight of polyester bottle chips
MLLDPE 5 parts by weight
20 parts by weight of high-pressure polyethylene resin
5 parts of dehydrated glycerol methacrylate.
Preferably, the
Polyester bottle chips 72 parts by weight
MLLDPE 6 parts by weight
25 parts by weight of high-pressure polyethylene resin
7 parts of dehydrated glycerol methacrylate.
Preferably, the
75 parts by weight of polyester bottle chips
MLLDPE 8 parts by weight
30 parts by weight of high-pressure polyethylene resin
10 parts of dehydrated glycerol methacrylate.
Has the advantages that:
the sealing strength of the regenerated disposable shopping bag prepared by the invention is not lower than 1.2Kg/15mm at the heat sealing temperature of 135 ℃.
Detailed Description
In order to make those skilled in the art better understand the technical solutions in the present application, the technical solutions in the embodiments of the present application are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the scope of protection of the present application.
A regenerated disposable shopping bag is prepared by the following steps:
crushing the recovered polyester bottles into crushed particles with the average particle size of 0.3-0.4 mm, and removing impurities (metal particles and the like) which are not contained in the polyester bottles.
② 5-8 parts by weight of MLLDPE, 20-30 parts by weight of high-pressure polyethylene resin and 5-10 parts by weight of methacrylic acid dehydrated glyceride.
③ taking the crushed polyester bottle
Figure BDA0001468769640000031
Adding the components into a high-efficiency mixer in parts by weight, and simultaneously adding ②The homogeneous mass was mixed and then mixed for 20min with a stirring speed of 20 rpm.
And fourthly, feeding the mixture obtained in the third step into a kneading machine for kneading to prepare regenerated polyester granules, wherein the kneading machine is provided with a vacuum exhaust port for exhausting.
Fifthly, using the extrudate of the fourth step for preparing the regenerated disposable shopping bag, wherein the melting temperature of the resin in the expansion step is 150 ℃.
Example 1
A regenerated disposable shopping bag is prepared by the following steps:
crushing the recovered polyester bottles into crushed particles with the average particle size of 0.3-0.4 mm, and removing impurities (metal particles and the like) which are not contained in the polyester bottles.
② 5 parts by weight of MLLDPE, 20 parts by weight of high-pressure polyethylene resin and 5 parts by weight of methacrylic acid dehydrated glyceride.
And thirdly, adding 70 parts by weight of the crushed polyester bottle particles into a high-efficiency mixer, simultaneously adding the uniformly mixed substances in the step II, and then mixing for 20min at the stirring speed of 20 rpm.
And fourthly, feeding the mixture obtained in the third step into a kneading machine for kneading to prepare regenerated polyester granules, wherein the kneading machine is provided with a vacuum exhaust port for exhausting.
Fifthly, using the extrudate of the fourth step for preparing the regenerated disposable shopping bag, wherein the melting temperature of the resin in the expansion step is 150 ℃.
Example 2
A regenerated disposable shopping bag is prepared by the following steps:
crushing the recovered polyester bottles into crushed particles with the average particle size of 0.3-0.4 mm, and removing impurities (metal particles and the like) which are not contained in the polyester bottles.
② mixing 6 parts by weight of MLLDPE, 25 parts by weight of high-pressure polyethylene resin and 7 parts by weight of methacrylic acid dehydrated glyceride.
And thirdly, adding 72 parts by weight of the crushed polyester bottle particles into a high-efficiency mixer, simultaneously adding the uniformly mixed substances obtained in the step II, and then mixing for 20min at the stirring speed of 20 rpm.
And fourthly, feeding the mixture obtained in the third step into a kneading machine for kneading to prepare regenerated polyester granules, wherein the kneading machine is provided with a vacuum exhaust port for exhausting.
Fifthly, using the extrudate of the fourth step for preparing the regenerated disposable shopping bag, wherein the melting temperature of the resin in the expansion step is 150 ℃.
Example 3
A regenerated disposable shopping bag is prepared by the following steps:
crushing the recovered polyester bottles into crushed particles with the average particle size of 0.3-0.4 mm, and removing impurities (metal particles and the like) which are not contained in the polyester bottles.
② mixing 8 parts by weight of MLLDPE, 30 parts by weight of high-pressure polyethylene resin and 10 parts by weight of methacrylic acid dehydrated glyceride.
And thirdly, adding 75 parts by weight of the crushed polyester bottle particles into a high-efficiency mixer, simultaneously adding the uniformly mixed substances obtained in the third step, and then mixing for 20min at the stirring speed of 20 rpm.
And fourthly, feeding the mixture obtained in the third step into a kneading machine for kneading to prepare regenerated polyester granules, wherein the kneading machine is provided with a vacuum exhaust port for exhausting.
Fifthly, using the extrudate of the fourth step for preparing the regenerated disposable shopping bag, wherein the melting temperature of the resin in the expansion step is 150 ℃.
The regenerated disposable shopping bags prepared in examples 1 to 3 were sealed at a heat-sealing temperature of 135 ℃ with a sealing strength of not less than 1.2Kg/15 mm.
The above embodiments are disclosed as prior art unless otherwise specified.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (4)

1. A regenerated disposable shopping bag is prepared from the following components:
70-75 parts by weight of polyester bottle chips
5-8 parts of MLLDPE
20-30 parts by weight of a high-pressure polyethylene resin and
5-10 parts by weight of methacrylic acid dehydrated glyceride.
2. A recyclable disposable shopping bag according to claim 1, characterized in that: the above-mentioned
70 parts by weight of polyester bottle chips
MLLDPE 5 parts by weight
20 parts by weight of high-pressure polyethylene resin
5 parts of dehydrated glycerol methacrylate.
3. A recyclable disposable shopping bag according to claim 1, characterized in that: the above-mentioned
Polyester bottle chips 72 parts by weight
MLLDPE 6 parts by weight
25 parts by weight of high-pressure polyethylene resin
7 parts of dehydrated glycerol methacrylate.
4. A recyclable disposable shopping bag according to claim 1, characterized in that: the above-mentioned
75 parts by weight of polyester bottle chips
MLLDPE 8 parts by weight
30 parts by weight of high-pressure polyethylene resin
10 parts of dehydrated glycerol methacrylate.
CN201711127907.4A 2017-11-15 2017-11-15 Regenerated disposable shopping bag Active CN107880496B (en)

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Publication number Priority date Publication date Assignee Title
US11746219B2 (en) * 2022-04-06 2023-09-05 Exxonmobil Chemical Patents Inc. Blends of recycled resins with metallocene-catalyzed polyolefins

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011079892A (en) * 2009-10-05 2011-04-21 Okura Packs Kk Composition containing pet resin, method for preparing the same and method for producing film

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103224693B (en) * 2013-05-22 2016-12-28 北京市第五建筑工程集团有限公司 Polyester/polyethylealloy alloy material and preparation method thereof
CN106634007A (en) * 2016-12-11 2017-05-10 钦州市康绿宝农业有限公司 Plastic package for fish and shrimp live transportation and preparation method of plastic package

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011079892A (en) * 2009-10-05 2011-04-21 Okura Packs Kk Composition containing pet resin, method for preparing the same and method for producing film

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Inventor after: Chen Daoming

Inventor after: Peng Kaijia

Inventor after: Lu Deming

Inventor before: Chen Daoming

Inventor before: Peng Kaijia

Inventor before: Lu De