CN107879548A - A kind of green active mineral matter Ecology treatment and purification method - Google Patents

A kind of green active mineral matter Ecology treatment and purification method Download PDF

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Publication number
CN107879548A
CN107879548A CN201710895531.5A CN201710895531A CN107879548A CN 107879548 A CN107879548 A CN 107879548A CN 201710895531 A CN201710895531 A CN 201710895531A CN 107879548 A CN107879548 A CN 107879548A
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CN
China
Prior art keywords
parts
mineral water
water
modifying agent
mineral
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Pending
Application number
CN201710895531.5A
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Chinese (zh)
Inventor
施建耀
潘威
施仲耀
高雪琴
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Zhejiang Haiyi Environmental Control Technology Co Ltd
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Zhejiang Haiyi Environmental Control Technology Co Ltd
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Priority to CN201710895531.5A priority Critical patent/CN107879548A/en
Publication of CN107879548A publication Critical patent/CN107879548A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)

Abstract

The invention discloses a kind of green active mineral matter Ecology treatment and purification method; detected again including mineral water detection, mineral water debugging, mineral water improvement and mineral water, wherein the modifying agent used in mineral water improvement includes 58 parts of 50 60 parts of zeolite, 15 20 parts of montmorillonite, 15 20 parts of sepiolite, 10 15 parts of dolomite, 20 25 parts of diatomite, 5 10 parts of titanium dioxide, 10 15 parts of hydrogel and graphene by weight.A kind of green active mineral matter Ecology treatment and purification method that the present invention obtains, can make the water quality of mineral water be improved, while the modifying agent in the present invention, have the characteristics of targetedly improving active mineral matter water, its adsorption capacity is strong, and effect is good.

Description

A kind of green active mineral matter Ecology treatment and purification method
Technical field
The present invention relates to a kind of method for treating water, particularly a kind of green active mineral matter Ecology treatment and purification side Method.
Background technology
With the rapid development of economic construction, mankind's activity migration is frequent, and urbanization process is accelerated, and quantity of wastewater effluent is significantly Increase, large amount of sewage directly discharge lake, then add rainfall Surface Runoff, production sand and production dirt to cause China some areas river, lake Pool muddy water environmental aspect drastically deteriorates.
When natural water body deterioration or eutrophication, pollutant is mostly that organic matter or sludge float support thing in water body, now Surface is mostly negative electrical charge in water body, and because when pollutant bulk concentration is exceeded to a certain degree, interionic is only by reaction force and certainly It is difficult precipitation to be again.Therefore it is necessary to propose a kind of green active mineral matter Ecology treatment and purification method now.
The content of the invention
The invention aims to solve above-mentioned the deficiencies in the prior art and provide a kind of technique is simple, cost is low, effect A kind of high green active mineral matter Ecology treatment and purification method of rate.
To achieve these goals, a kind of green active mineral matter Ecology treatment and purification side designed by the present invention Method, comprise the following steps:
(1) mineral water detects, and mineral water is detected using detection means, wherein detection means includes pH value test side Mouth, DO values detection port and COD value detection port;
(2) mineral water is debugged, and launches acid-base buffer agent so that the pH stable of mineral water is between 6.9-7.1, wherein acid Alkali buffer includes sodium carbonate and saleratus by weight, and the weight ratio of the sodium carbonate and saleratus is 1-20:1-10;
(3) mineral water is improved, and will launch modifying agent in mineral water, the modifying agent include by weight zeolite 50-60 parts, Montmorillonite 15-20 parts, sepiolite 15-20 parts, dolomite 10-15 parts, diatomite 20-25 parts, titanium dioxide 5-10 parts, hydrogel 10-15 parts and graphene 5-8 parts;
(4) mineral water detects again, launches modifying agent and mineral water is detected again after 1 month, also with detection Device detects to mineral water.
The preparation method of the modifying agent is by weight after dispensing, first by zeolite 50-60 parts, montmorillonite 15-20 parts, sea Afrodite 15-20 parts, dolomite 10-15 parts, diatomite 20-25 parts, titanium dioxide 5-10 parts stir, and are then placed in heating furnace In heated, temperature be 150-200 DEG C, heat time 30min, mixed after cooling with hydrogel 10-15 parts and graphene 5-8 parts Close, stir and produce modifying agent.
In mineral water detection, mineral water is carried out using detection means pH value in detection water, DO values with And COD value, as primary data;
In mineral water debugs link, acid-base buffer agent, wherein sodium carbonate and saleratus, the sodium carbonate and carbonic acid are launched The weight ratio of hydrogen potassium is 1-20:1-10, above-mentioned acid-base buffer agent do not pollute for environment, and can effectively keep soda acid in water PH stable;
In mineral water improves link, modifying agent is launched, wherein zeolite is a kind of highly polar adsorbent, and its specific surface area is fitted In, generally 500 ~ 800m2/g;For its pore structure based on micropore, aperture is smaller, and general major bore is maximum to be no more than 2.5nm, and It is distributed homogeneous.Zeolite easily hydrone isopolarity molecule, and because itself alumina silica ratio is different with pore size, to opposed polarity point Son has selectivity, has the metal cation that can be exchanged in duct, there is special suction-operated to some specific moleculars.
Montmorillonite, sepiolite and dolomite are used as cation adsorbent, have some cations of sorption and anion And it is held in the characteristic of swap status;
Diatomite is used to adsorb the organic matter in water, and a good microorganism is constructed in water body at the same time as a carrier Growth attachment environment, wide metabolism value-added space is provided for beneficial microbe;
Main its bridge joint effect of titanium dioxide so that a stable connection can be played between inorganic molecule;
Hydrogel is used to coat above-mentioned active ingredient, it is slowly discharged in water;
Graphene can adsorb and the heavy metal in curing sludge, and with the reduction of mud water content, is free in water originally In the adsorbed precipitation of heavy metal ion.
In mineral water again detection, launch modifying agent and mineral water is detected again after 1 month, mineral The water quality of matter water is obviously improved, without obvious floating object.
A kind of green active mineral matter Ecology treatment and purification method that the present invention obtains, it is had the technical effect that through ore deposit The detection of material water, mineral water debugging, mineral water improvement and mineral water detect again, so that the water of mineral water Matter is improved, while the modifying agent in the present invention, has the characteristics of targetedly improving active mineral matter water, its adsorption capacity By force, effect is good.
Embodiment
With reference to embodiment, the present invention is further described.
Embodiment 1:
A kind of green active mineral matter Ecology treatment and purification method that the present embodiment provides, comprises the following steps:
(1) mineral water detects, and mineral water is detected using detection means, wherein detection means includes pH value test side Mouth, DO values detection port and COD value detection port;
(2) mineral water is debugged, and launches acid-base buffer agent so that the pH stable of mineral water is between 6.9-7.1, wherein acid Alkali buffer includes sodium carbonate and saleratus by weight, and the weight ratio of the sodium carbonate and saleratus is 3:1;
(3) mineral water is improved, and modifying agent will be launched in mineral water, and the modifying agent includes 50 parts of zeolite, covered by weight De- 15 parts of stone, 15 parts of sepiolite, 10 parts of dolomite, 20 parts of diatomite, 5 parts of titanium dioxide, 10 parts of hydrogel and graphene 5 Part;
(4) mineral water detects again, launches modifying agent and mineral water is detected again after 1 month, also with detection Device detects to mineral water.
The preparation method of the modifying agent is by weight after dispensing, first by 50 parts of zeolite, 15 parts of montmorillonite, sepiolite 15 5 parts of part, 10 parts of dolomite, 20 parts of diatomite, titanium dioxide parts stir, and are then placed in heating furnace and are heated, temperature For 150-200 DEG C, heat time 30min, mixed after cooling with 5 parts of 10 parts of hydrogel and graphene, stir and produce improvement Agent.
The water that the later water of 1 month modifying agent and before processing have been launched in the present embodiment is contrasted, its data is as follows:
Before processing:PH value is 7.0, turbidity(NTU)For 114.8 degree, suspended solid(SS)For 75.1mg/L, dissolved oxygen (DO) is 0.98 mg/L, COD value 76, total nitrogen content are 6.8 mg/L;
After processing:PH value is 6.9, turbidity(NTU)For 2.54 degree, suspended solid(SS)For 1.17mg/L, dissolved oxygen (DO) is 5.54 mg/L, COD value 2, total nitrogen content 2.07mg/L.
Embodiment 2:
A kind of green active mineral matter Ecology treatment and purification method that the present embodiment provides, its general steps and embodiment 1 is identical, but during specifically used, the modifying agent includes 60 parts of zeolite, 0 part of montmorillonite 2, sepiolite 20 by weight Part, 15 parts of dolomite, 25 parts of diatomite, 10 parts of titanium dioxide, 15 parts of hydrogel and 8 parts of graphene.
The water that the later water of 1 month modifying agent and before processing have been launched in the present embodiment is contrasted, its data is as follows:
Before processing:PH value is 7.0, turbidity(NTU)For 114.8 degree, suspended solid(SS)For 75.1mg/L, dissolved oxygen (DO) is 0.98 mg/L, COD value 76, total nitrogen content are 6.8 mg/L;
After processing:PH value is 6.9, turbidity(NTU)For 2.78 degree, suspended solid(SS)For 1.05mg/L, dissolved oxygen (DO) is 6.58 mg/L, COD value 2.3, total nitrogen content 1.57mg/L.
Embodiment 3:
A kind of green active mineral matter Ecology treatment and purification method that the present embodiment provides, its general steps and embodiment 1 is identical, but during specifically used, the modifying agent includes 55 parts of zeolite, 18 parts of montmorillonite, sepiolite 18 by weight Part, 18 parts of dolomite, 22 parts of diatomite, 8 parts of titanium dioxide, 10 parts of hydrogel and 8 parts of graphene.
The water that the later water of 1 month modifying agent and before processing have been launched in the present embodiment is contrasted, its data is as follows:
Before processing:PH value is 7.0, turbidity(NTU)For 114.8 degree, suspended solid(SS)For 75.1mg/L, dissolved oxygen (DO) is 0.98 mg/L, COD value 76, total nitrogen content are 6.8 mg/L;
After processing:PH value is 6.9, turbidity(NTU)For 3.06 degree, suspended solid(SS)For 0.95mg/L, dissolved oxygen (DO) is 7.72mg/L, COD value 1.5, total nitrogen content 2.15mg/L.

Claims (2)

  1. A kind of 1. green active mineral matter Ecology treatment and purification method, it is characterised in that comprise the following steps:
    (1) mineral water detects, and mineral water is detected using detection means, wherein detection means includes pH value test side Mouth, DO values detection port and COD value detection port;
    (2) mineral water is debugged, and launches acid-base buffer agent so that the pH stable of mineral water is between 6.9-7.1, wherein acid Alkali buffer includes sodium carbonate and saleratus by weight, and the weight ratio of the sodium carbonate and saleratus is 1-20:1-10;
    (3) mineral water is improved, and will launch modifying agent in mineral water, the modifying agent include by weight zeolite 50-60 parts, Montmorillonite 15-20 parts, sepiolite 15-20 parts, dolomite 10-15 parts, diatomite 20-25 parts, titanium dioxide 5-10 parts, hydrogel 10-15 parts and graphene 5-8 parts;
    (4) mineral water detects again, launches modifying agent and mineral water is detected again after 1 month, also with detection Device detects to mineral water.
  2. A kind of 2. green active mineral matter Ecology treatment and purification method according to claim 1, it is characterised in that: The preparation method of the modifying agent is by weight after dispensing, first by zeolite 50-60 parts, montmorillonite 15-20 parts, sepiolite 15- 20 parts, dolomite 10-15 parts, diatomite 20-25 parts, titanium dioxide 5-10 parts stir, be then placed in heating furnace and carry out Heating, temperature are 150-200 DEG C, heat time 30min, mix, stir with hydrogel 10-15 parts and graphene 5-8 parts after cooling Mix and uniformly produce modifying agent.
CN201710895531.5A 2017-09-28 2017-09-28 A kind of green active mineral matter Ecology treatment and purification method Pending CN107879548A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108910971A (en) * 2018-07-10 2018-11-30 奚永乐 A kind of purifying domestic sewage agent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101049984A (en) * 2007-03-29 2007-10-10 陶韬 Purified filtering agent for seawater desalination by using natural mineral
CN101219371A (en) * 2007-01-08 2008-07-16 北京化工大学 Photocatalysis oxidation treated high concentration organic trade waste
CN104276670A (en) * 2014-09-30 2015-01-14 希望环保(福建)有限公司 Sewage treating agent containing natural mineral substances and preparation method thereof
CN106986408A (en) * 2017-05-03 2017-07-28 西安航空学院 A kind of high efficiency sewage treating agent and preparation method thereof
CN107176686A (en) * 2017-05-04 2017-09-19 浙江清天地环境工程有限公司 A kind of salt-tolerant plant is biological floating bed and its applies

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101219371A (en) * 2007-01-08 2008-07-16 北京化工大学 Photocatalysis oxidation treated high concentration organic trade waste
CN101049984A (en) * 2007-03-29 2007-10-10 陶韬 Purified filtering agent for seawater desalination by using natural mineral
CN104276670A (en) * 2014-09-30 2015-01-14 希望环保(福建)有限公司 Sewage treating agent containing natural mineral substances and preparation method thereof
CN106986408A (en) * 2017-05-03 2017-07-28 西安航空学院 A kind of high efficiency sewage treating agent and preparation method thereof
CN107176686A (en) * 2017-05-04 2017-09-19 浙江清天地环境工程有限公司 A kind of salt-tolerant plant is biological floating bed and its applies

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108910971A (en) * 2018-07-10 2018-11-30 奚永乐 A kind of purifying domestic sewage agent and preparation method thereof

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Address after: 315334 Ningbo, Cixi, Zhejiang (Cixi) green agricultural products processing base (Chung Shou town)

Applicant after: Zhejiang Hai Yi ring Academy Limited

Address before: 315334 Ningbo, Cixi, Zhejiang Ningbo (Cixi) green agricultural products processing base (Chung Shou town)

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Application publication date: 20180406