CN107868576A - Ship deck surface anti-skidding wear-resistant coating and preparation method thereof - Google Patents

Ship deck surface anti-skidding wear-resistant coating and preparation method thereof Download PDF

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Publication number
CN107868576A
CN107868576A CN201711295544.5A CN201711295544A CN107868576A CN 107868576 A CN107868576 A CN 107868576A CN 201711295544 A CN201711295544 A CN 201711295544A CN 107868576 A CN107868576 A CN 107868576A
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China
Prior art keywords
parts
coating
deck surface
ship deck
titanium dioxide
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CN201711295544.5A
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CN107868576B (en
Inventor
徐玉福
彭玉斌
陈星�
吴若琪
周琪
胡献国
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Hefei University of Technology
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Hefei University of Technology
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of ship deck surface anti-skidding wear-resistant coating and preparation method thereof, the main component of the coating is made up of epoxy resin, graphene, Paeonol, carbon fiber powder, dibutyl phthalate, silica, titanium dioxide, carborundum, polyamide etc., and its preparation method includes several steps such as ball milling, scattered, roller coating.The coating of the present invention has that anti-skid wearable effect is good, stability is strong, preparation technology is easy, the more low advantage of cost, has good application prospect.

Description

Ship deck surface anti-skidding wear-resistant coating and preparation method thereof
First, technical field
The present invention relates to functional coating field, specifically a kind of ship deck surface anti-skidding wear-resistant coating and its preparation Method.
2nd, background technology
With China ocean power implementation, increasing large ship is put into use, particularly Liaoning warship Fall in lines and greatly strengthen China ocean military power.Different from inland environment, often there is high humidity, high salt fog ring in marine environment Border, therefore cause material surface easily to slide, wear aggravation, realize that anti-skid wearable of the naval vessel under marine environment is significant, Especially frequently ship deck surface anti-skidding is wear-resisting directly affects naval vessel efficiency for the operation of personnel activity and carrier-borne aircraft.Improve naval vessel Deck surface anti-skid wearable performance is the focus of association area scientific research personnel concern in recent years.
Due to advantages such as easy to operate, easy cares, it is mesh to form anti-skid wearable coating in ship deck external coating coating Preceding a kind of most-often used method.Applied as Chinese patent (notification number CN 102477248) discloses a kind of Hydroxylated acrylic resin Material, by titanium dioxide, carbon black, lubricant, thickener, anti-settling agent, diamond dust, toughener and Hydroxylated acrylic resin skid-proof paint paste, Curing agent forms.Chinese patent (notification number CN 102504679) discloses a kind of antiskid deck paint, mainly includes:Emulsion 30-45 parts, coalescents 2-5 parts, titanium dioxide 15-25 parts, filler 5-20 parts, wetting dispersing agent 0.2-1.0 parts, antilubricant 5-15 Part, defoamer 0.1-0.5 parts, age resistor 0.5-1.0 parts, thickener 0.5-2.0 parts, Antisepticize and mildew preventive 0.5-1.0 parts;Water 10- 25 parts.But these inventions do not obtain large-scale promotion application still.Although the serial and international paint companies of AST companies of U.S. MS Intershield coating series product is applied in type aircraft carrier deck, but because the factors such as secrecy, the formula of product have no public Open or report.Because coating forms the influence complicated, various components can be different to coating performance generation, therefore, having must Develop a kind of ship deck surface anti-skidding wear-resistant coating and preparation method thereof.
3rd, the content of the invention
The present invention is directed to state of the art, and purpose seeks to provide a kind of ship deck table with anti-skid wearable function Finishing coat and preparation method thereof.
The present invention is achieved through the following technical solutions:
A kind of ship deck surface anti-skidding wear-resistant coating, its parts by weight composition are:Epoxy resin 30-50 parts, graphene 0.0001-0.05 parts, Paeonol 0.001-0.01 parts, carbon fiber powder 0.01-0.8 parts, dibutyl phthalate 0.2-3 parts, Silica 2-24 parts, titanium dioxide 1-12 parts, carborundum 0.5-6 parts, polyamide 5-15 parts;Wherein described asphalt mixtures modified by epoxy resin alicyclic ring Oxygen value is 0.25-0.4, and graphene specific surface area is not less than 2500m2/ g, 5-10 μm of carbon fiber powder filament diameter, draw ratio 3:1- 6:1, silica, titanium dioxide and carborundum weight ratio are 4:2:1st, particle diameter is 20-80 μm.
The preparation method of above-mentioned ship deck surface anti-skidding wear-resistant coating is as described below to attach most importance to prepare according to the following steps Measure part:
(1) graphene 0.0001-0.05 parts, Paeonol 0.001-0.01 will be sequentially added in the epoxy resin of 30-50 parts Part, carbon fiber powder 0.01-0.8 parts, dibutyl phthalate 0.2-3 parts, stir and evenly mix, and then obtain material A;
(2) silica 2-24 parts, titanium dioxide 1-12 parts, carborundum 0.5-6 parts, polyamide 5-15 parts are collectively disposed at Particle diameter is milled in ball mill as 20-150 μm, obtains material B;
(3) material B is added in material A, at 40-60 DEG C, mixed with 500-800rpm speed stirring 30-50min Even, it is 20-3000 μm that roller coating to thickness is carried out to ship deck surface, dries and produces.
Compared with existing product, coating anti-skid wearable effect of the invention is good, and coefficient of friction is reachable under dry condition More than 0.8, wear rate significantly reduces, and has good protective effect to matrix material;The coating each component stability of the present invention It is good, synergistic action effect can be played between each component;The preparation method of the present invention is easy, is easy in ship deck surface large area Using cost is relatively low.
4th, specific embodiment
Epoxy resin epoxy value described in following examples is 0.25-0.4, and graphene specific surface area is not less than 2500m2/ g, 5-10 μm of carbon fiber powder filament diameter, draw ratio 3:1-6:1, silica, titanium dioxide and carborundum particle diameter are equal For 20-80 μm;As described below is parts by weight.
Embodiment 1:
To be sequentially added in 30 parts of epoxy resin 0.0002 part of graphene, 0.001 part of Paeonol, 0.2 part of carbon fiber powder, 1 part of dibutyl phthalate, is stirred and evenly mixed, and then obtains material A;By 0 part of silica 1,5 parts of titanium dioxide, carborundum 2.5 Part, polyamide 6 part, which are collectively disposed in ball mill, is milled to particle diameter as 30-50 μm, obtains material B;Material B is added in material A, 45 DEG C are mixed with 500rpm speed stirring 50min, and it is 100-120 μm that roller coating to thickness is carried out to ship deck surface, Dry and produce anti-skid wearable coating.
Embodiment 2:
0.01 part of graphene, 0.006 part of Paeonol, 0.6 part of carbon fiber powder, adjacent benzene are sequentially added in 40 parts of epoxy resin 2.2 parts of dibutyl carboxylic acid, is stirred and evenly mixed, and then obtains material A;By 2 parts of silica 1,6 parts of titanium dioxide, 3 parts of carborundum, 8 parts of polyamide, which is collectively disposed in ball mill, is milled to particle diameter as 50-70 μm, obtains material B;Material B is added in material A, 50 DEG C mixed with 800rpm speed stirring 30min, be 1000 μ to ship deck surface progress roller coating to thickness M, dry and produce anti-skid wearable coating.
Embodiment 3:
0.04 part of graphene, 0.01 part of Paeonol, 0.8 part of carbon fiber powder, neighbour will be sequentially added in 50 parts of epoxy resin 2 parts of dibatyl phithalate, is stirred and evenly mixed, and then obtains material A;By 22 parts of silica, 11 parts of titanium dioxide, carborundum 5.5 Part, 12 parts of polyamide, which are collectively disposed in ball mill, is milled to particle diameter as 60-80 μm, obtains material B;Material B is added in material A, At 55 DEG C, mixed with 600rpm speed stirring 40min, it is 2000 μm that roller coating to thickness is carried out to ship deck surface, Dry and produce anti-skid wearable coating.
By anti-skid wearable coating obtained by above-described embodiment 1-3, friction testing is done using 45 steel as to mill material, system is averagely rubbed It is respectively 0.82,0.86,0.84 to wipe coefficient, and compared with before non-coating, wear rate reduces by 85%, 76%, 81% respectively after coating, It can be seen that serve good anti-skid wearable effect.

Claims (2)

1. a kind of ship deck surface anti-skidding wear-resistant coating, it is characterised in that parts by weight, which form, is:Epoxy resin 30-50 parts, stone Black alkene 0.0001-0.05 parts, Paeonol 0.001-0.01 parts, carbon fiber powder 0.01-0.8 parts, dibutyl phthalate 0.2-3 Part, silica 2-24 parts, titanium dioxide 1-12 parts, carborundum 0.5-6 parts, polyamide 5-15 parts;Wherein described asphalt mixtures modified by epoxy resin Alicyclic ring oxygen value is 0.25-0.4, and graphene specific surface area is not less than 2500m2/ g, 5-10 μm of carbon fiber powder filament diameter, draw ratio 3:1-6:1, silica, titanium dioxide and carborundum weight ratio are 4:2:1st, particle diameter is 20-80 μm.
2. ship deck surface anti-skidding wear-resistant coating according to claim 1, it is characterised in that prepare according to the following steps, As described below is parts by weight:
(1) graphene 0.0001-0.05 parts, Paeonol 0.001-0.01 parts, carbon will be sequentially added in the epoxy resin of 30-50 parts Fiber powder 0.01-0.8 parts, dibutyl phthalate 0.2-3 parts, stir and evenly mix, and then obtain material A;
(2) silica 2-24 parts, titanium dioxide 1-12 parts, carborundum 0.5-6 parts, polyamide 5-15 parts are collectively disposed at ball milling Particle diameter is milled in machine as 20-150 μm, obtains material B;
(3) material B is added in material A, at 40-60 DEG C, mixed with 500-800rpm speed stirring 30-50min, it is right It is 20-3000 μm that ship deck surface, which carries out roller coating to thickness, dries and produces.
CN201711295544.5A 2017-12-08 2017-12-08 Anti-skid wear-resistant coating on surface of ship deck and preparation method thereof Active CN107868576B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108784710A (en) * 2018-06-27 2018-11-13 常州市第人民医院 A kind of blood oxygen saturation monitoring instrument based on Radio Transmission Technology
CN109044655A (en) * 2018-06-25 2018-12-21 常州市第二人民医院 A kind of multi-functional disposition bed of Emergence
CN109401531A (en) * 2018-09-14 2019-03-01 浙江万华不锈钢有限公司 High-cleanness stainless steel cable and its processing method
CN110499097A (en) * 2019-07-31 2019-11-26 浙江意可味厨具制造有限公司 A kind of super wear-resistant unsticky coating and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194578A (en) * 2014-08-21 2014-12-10 青岛优维奥信息技术有限公司 Elastic anti-skid deck coating
CN105348980A (en) * 2015-09-25 2016-02-24 洛阳暖盈电子技术有限公司 Wear-resistant ceramic coating
CN105949946A (en) * 2016-05-17 2016-09-21 中国科学院宁波材料技术与工程研究所 Wear-resistant and anti-corrosion coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104194578A (en) * 2014-08-21 2014-12-10 青岛优维奥信息技术有限公司 Elastic anti-skid deck coating
CN105348980A (en) * 2015-09-25 2016-02-24 洛阳暖盈电子技术有限公司 Wear-resistant ceramic coating
CN105949946A (en) * 2016-05-17 2016-09-21 中国科学院宁波材料技术与工程研究所 Wear-resistant and anti-corrosion coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109044655A (en) * 2018-06-25 2018-12-21 常州市第二人民医院 A kind of multi-functional disposition bed of Emergence
CN108784710A (en) * 2018-06-27 2018-11-13 常州市第人民医院 A kind of blood oxygen saturation monitoring instrument based on Radio Transmission Technology
CN109401531A (en) * 2018-09-14 2019-03-01 浙江万华不锈钢有限公司 High-cleanness stainless steel cable and its processing method
CN110499097A (en) * 2019-07-31 2019-11-26 浙江意可味厨具制造有限公司 A kind of super wear-resistant unsticky coating and preparation method thereof

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