CN107863542A - Applied to fuel cell generation or the burning reformer of production hydrogen machine - Google Patents

Applied to fuel cell generation or the burning reformer of production hydrogen machine Download PDF

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Publication number
CN107863542A
CN107863542A CN201711158863.1A CN201711158863A CN107863542A CN 107863542 A CN107863542 A CN 107863542A CN 201711158863 A CN201711158863 A CN 201711158863A CN 107863542 A CN107863542 A CN 107863542A
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China
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transfer zone
heat transfer
heat exchange
exchange coil
burning
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CN201711158863.1A
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CN107863542B (en
Inventor
赵青
朱云浩
韩显寿
苏铭传
简调源
王厚翔
吴荣生
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Ningbo Shenjiang Technology Co Ltd
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Ningbo Shenjiang Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074Heat exchange unit structures specially adapted for fuel cell
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)

Abstract

The present invention relates to a kind of burning reformer for being applied to fuel cell generation or producing hydrogen machine, waste heat recoverer and burning recombining reaction device including interconnection, central dividing plate in waste heat recoverer will be divided into the first heat transfer zone and the second heat transfer zone inside waste heat recoverer, burning recombining reaction device includes the 3rd heat exchange coil being nested with successively from inside to outside, it is catalyzed combustion chamber, recombining reaction inner chamber, recombining reaction exocoel and combustion product gases chamber, 3rd heat exchange coil and recombining reaction intracavity inter-connection, recombining reaction inner chamber is connected with recombining reaction exocoel, first heat transfer zone is connected by external connecting pipe with recombining reaction exocoel can provide one-level preheating to recombinate tail gas to the first heat transfer zone;Catalysis combustion chamber is connected with combustion product gases chamber, and the second heat transfer zone is connected by external connecting pipe with combustion product gases chamber can provide two level preheating with combustion tail gas to the second heat transfer zone.Compact-sized, heat utilization efficiency of the invention and recombination efficiency are high, it is rapider to start.

Description

Applied to fuel cell generation or the burning reformer of production hydrogen machine
Technical field
The present invention relates to field of fuel cell technology, more particularly to one kind using methanol-water as fuel applications in fuel cell Electricity generation system or the burning reformer for producing hydrogen machine.
Background technology
By Effect of Natural Disaster, the simple power system for relying on centralization can not ensure the continual and steady fortune of visual plant Turn, in addition to daily life is influenceed, more likely therefore jeopardize the safety of lives and properties, battery can not be long-acting as non-firm power Power supply, and battery recycling and problem of environmental pollution are still difficult to solve.Electric power infrastructure can not reach remote districts and Island, at present still using diesel generation as main power source, but its noise is big, seriously polluted, frequency of maintenance is high, power supply is elastic It is low.The renewable source of energy generation such as solar energy, wind-force technology is had a great influence by sunshine, region and weather, can not still be carried out at present effectively Stable power-supplying.Fuel cell generation has the advantages of high stability, low-maintenance, long-acting operating, low emission, plus can be with The polynary renewable sources of energy, which are integrated, is used as the reliable power source of local resident, is to be presently considered to extremely potential generating Technology.
Fuel cell be it is a kind of without combustion process directly in a manner of electrochemical reaction by fuel and the chemistry of oxidant The efficient generating apparatus of electric energy can be changed into, its high conversion efficiency, almost without pollutant emission, using fuel cell as power Electricity generation system not only with environmental protection but also can solve the matter of great urgency.But hydrogen belongs to flammable and explosive substance, liquefaction compression is difficult Spend high, storage and transport difficult.
But problem is, the operating temperature of reformer is higher, and reacting needs absorption substantial amounts of hot, typically utilizes two After reformer is warming up to operating temperature by primary cell or civil power using electrical heating, reformer is set to start working, but the method opens The problem of dynamic reformer needs to expend extra electric power, but also the presence startup time is longer, passes through chemistry so also having now The mode of burning substitute it is traditional use electric energy heat production, on the one hand can be with such as typically using methanol and air burning release heat Power consumption is reduced, on the other hand can shorten and start the time, still, reformer is started using the heat energy of chemical combustion release Requirement to equipment is higher, and in general device structure is complicated, and heat utilization efficiency is relatively low.Such as Japanese Laid-Open Patent No.2004-31280 It is disclosed a kind of using a burner laser heating fuel reformer and the device of shift-converter, when using heating fuel weight During the burner heating shift-converter of group device, shift-converter is positioned apart with burner, it is necessary to for a long time could be conversion Temperature of reactor is increased to operating temperature, complicated, and the thermal efficiency is low.
The content of the invention
In view of the above-mentioned state of the art, the technical problems to be solved by the invention be to provide one kind be simple to manufacture, Compact-sized, heat utilization efficiency and recombination efficiency are high, start more rapidly applied to fuel cell generation or production hydrogen machine Burning reformer.
Technical scheme is used by the present invention solves above-mentioned technical problem:One kind be applied to fuel cell generation or Person produces the burning reformer of hydrogen machine, including the waste heat recoverer of interconnection and burning recombining reaction device, the waste heat recoverer Central dividing plate is inside additionally provided with, the central dividing plate will be divided into the first heat transfer zone and the second heat transfer zone, the combustion inside waste heat recoverer It is anti-to burn the 3rd heat exchange coil, catalysis combustion chamber, recombining reaction inner chamber, restructuring that recombining reaction device includes being nested with successively from inside to outside Answer exocoel and combustion product gases chamber, the 3rd heat exchange coil and recombining reaction intracavity inter-connection, the recombining reaction inner chamber with again Group reaction exocoel is connected, and first heat transfer zone is connected to recombinate thick hydrogen by external connecting pipe with recombining reaction exocoel The first heat transfer zone can be given to provide one-level preheating;The catalysis combustion chamber is connected with combustion product gases chamber, second heat transfer zone Two level preheating can be provided with combustion tail gas to the second heat transfer zone by being connected by external connecting pipe with combustion product gases chamber.
Preferably, the first heat exchange coil, the second heat exchange coil and preheating straight tube are provided with the waste heat recoverer, it is described First heat exchange coil is connected with the second heat exchange coil and is placed on outside the preheating straight tube, and first heat exchange coil is positioned at the In one heat transfer zone, second heat exchange coil is located in the second heat transfer zone, and the preheating straight tube changes through the first heat transfer zone, second Hot-zone, the preheating straight tube are connected by external connecting pipe with the catalysis combustion chamber.
Preferably, the central dividing plate and waste heat recoverer inwall, the first heat exchange coil outer wall, outside the second heat exchange coil Wall, the junction welded seal for preheating straight tube outer wall, ensure that the first heat transfer zone, the second heat transfer zone are mutually isolated and seal.
Preferably, it is filled with the catalyst for being used for being catalyzed burning in the catalysis combustion chamber.
Preferably, the preheating straight tube extends downwardly and is connected with air intlet pipe, first is connected with the air intlet pipe Alcohol inlet tube.
Preferably, second heat transfer zone is provided with combustion product gases outlet at central dividing plate.
Preferably, first heat exchange coil is outward extended with methanol-water fuel inlet, second heat exchange coil to The outer outlet for being extended with connection external connecting pipe, the 3rd heat exchange coil are outward extended with the import of connection external connecting pipe Pipe.
Preferably, the recombining reaction exocoel is outwards provided with the recombinant gas outlet of connection external connecting pipe, it is described First heat transfer zone is provided with recombinant gas inlet tube at central dividing plate, and the bottom of first heat transfer zone is provided with thick hydrogen outlet.
Compared with prior art, the advantage of the invention is that:Recombining reaction chamber is divided into inner chamber and exocoel by the present invention, effectively Increase heat exchange area and heat exchange shell side, catalysis combustion chamber be arranged in intracavitary in recombining reaction, improve heat transfer effect.By Three heat exchange coils are arranged in catalysis combustion chamber so that can be absorbed during methanol-water fuel preheating caused by a part of methanol burning Heat, be unlikely to so that be catalyzed that combustion chamber temperature is too high and burning apparatus, while and can makes more uniform temperature in catalysis combustion chamber. In addition, waste heat recoverer is divided into the first heat transfer zone and the second heat transfer zone by central dividing plate so that combustion tail gas can change second Hot-zone is supplied to methanol-water fuel, the preheating of methanol air two level so that restructuring tail gas can be supplied to first in the first heat transfer zone Alcohol water fuel, the preheating of methanol air one-level.The present invention using catalysis combustion system progress heat supply come starter, it is and compact-sized Rationally, reaching the steady running condition time only needs 0.5h, very fast;Multi-stage heat exchanger pattern is used simultaneously, realizes energy Cascade utilization, burning recombination efficiency and heat utilization efficiency are effectively increased, many places use three fluid heat transfer patterns, reduce heat exchanger number Amount, the complexity of device structure is enormously simplify, reduce volume, more compact structure.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the sectional view of the present invention;
As illustrated, 1 waste heat recoverer, the heat exchange coils of 1a first, 1b preheating straight tubes, the heat exchange coils of 1c second, among 1d Dividing plate, the heat transfer zones of 1e first, the heat transfer zones of 1f second, 2 burning recombining reaction devices, the heat exchange coils of 2a the 3rd, 2b catalysis combustion chambers, 2c Recombining reaction inner chamber, 2d recombining reaction exocoels, 2e combustion product gases chambers, 3 methanol inlet tubes, 4 air intlet pipes, 5 methanol-water fuel Import, 6 outlets, 7 inlet tubes, 8 recombinant gas outlets, 9 recombinant gas inlet tubes, 10 thick hydrogen outlets, the outlet of 11 combustion product gases Pipe, 12 external connecting pipes.
Embodiment
As shown in Figure 1-2, a kind of burning reformer for being applied to fuel cell generation or producing hydrogen machine, including it is mutual The waste heat recoverer 1 and burning recombining reaction device 2 of connection, waste heat recoverer 1 is interior to be provided with the first heat exchange coil 1a, the second heat exchange disk Pipe 1c and preheating straight tube 1b, the first heat exchange coil 1a and the second heat exchange coil 1c are connected and are placed on outside preheating straight tube 1b, are given up Central dividing plate 1d is additionally provided with heat regenerator 1, central dividing plate 1d will be divided into the first heat transfer zone 1e and inside waste heat recoverer 1 Two heat transfer zone 1f, the first heat exchange coil 1a are located in the first heat transfer zone 1e, and the second heat exchange disk 1c pipes are located in the second heat transfer zone 1f, Straight tube 1b is preheated through the first heat transfer zone 1e, the second heat transfer zone 1f, central dividing plate 1d and the inwall of waste heat recoverer 1, the first heat exchange Coil pipe 1a outer walls, the second heat exchange coil 1c outer walls, the junction welded seal for preheating straight tube 1b outer walls, ensure the first heat transfer zone 1e, the second heat transfer zone 1f are mutually isolated and seal.
The 3rd heat exchange coil 2a that the recombining reaction device 2 that wherein burns includes being nested with successively from inside to outside, catalysis combustion chamber 2b, Recombining reaction inner chamber 2c, recombining reaction exocoel 2d and combustion product gases chamber 2e, catalysis combustion chamber 2b are connected with combustion product gases chamber 2e, It is catalyzed catalyst (methanol oxidation combustion catalyst or H2, CO the catalysis burning for being filled with combustion chamber 2b and being used to be catalyzed burning Catalyst), recombining reaction inner chamber 2c is connected with recombining reaction exocoel 2d, the 3rd heat exchange coil 2a and recombining reaction inner chamber 2c phases Connection, preheating straight tube 1b are connected by external connecting pipe 12 with catalysis combustion chamber 2b, and the second heat transfer zone 1f passes through external connecting pipe 12 are connected with combustion product gases chamber 2e, and the second heat exchange coil 1c is connected by external connecting pipe 12 with the 3rd heat exchange coil 2a, and first Heat transfer zone 1e is connected by external connecting pipe 12 with recombining reaction exocoel 2d, and preheating straight tube 1b, which is extended downwardly, is connected with air intlet Pipe 4, methanol inlet tube 3 is connected with the air intlet pipe 4, the second heat transfer zone 1f is provided with combustion product gases at central dividing plate 1d Outlet 11, the first heat exchange coil 1a are outward extended with methanol-water fuel inlet 5, and the second heat exchange coil 1c is outward extended with connection The outlet 6 of external connecting pipe, the 3rd heat exchange coil 2a are outward extended with the inlet tube 7 of connection external connecting pipe, recombining reaction Exocoel 2d is outwards provided with the recombinant gas outlet 8 of connection external connecting pipe, and the first heat transfer zone 1e is set at central dividing plate 1d There is recombinant gas inlet tube 9, the first heat transfer zone 1e bottom is provided with thick hydrogen outlet 10.
During work, methanol enters from methanol inlet tube 3, and air enters from air intlet pipe 4, and preheating straight tube is entered after mixing 1b, entered by external connecting pipe 12 in the interior catalyst combustion chamber 2b of burning recombining reaction device 2, under the catalytic action of catalyst Methanol air starts to burn, and the heat of methanol air burning release starts to preheat and heat up to device, remaining high-temp combustion cigarette Gas is discharged by combustion product gases chamber 2e, is entered by external connecting pipe 12 in second heat transfer zone 1f of waste heat recoverer 1, straight with preheating Methanol air in pipe 1b is discharged after being exchanged heat from combustion product gases outlet 11, and temperature reaches 500 in combustion chamber 2b to be catalyzed DEG C when, start to be passed through the methanol-water fuel of total amount 35% from methanol-water fuel inlet 5, methanol-water fuel is in the second heat transfer zone 1f The high-temperature flue gas discharged with burning carries out the 3rd heat exchange entered after heat exchange heating by external connecting pipe 12 in reforming reactor 2 Coil pipe 2a, enter after catalysis combustion chamber 2b is preheated and heated up again in reforming reaction inner chamber 2c and reforming reaction exocoel 2d Reforming reaction is carried out, the heat that the heat wherein absorbed required for reforming reaction is catalyzed burning release by methanol air provides, instead High temperature reformation raw hydrogen body caused by after answering is carried out from recombinant gas outlet 8 by external connecting pipe 12 and recombinant gas inlet tube 9 It is tightly connected into the first heat transfer zone 1e of waste heat recoverer 1, it is straight with the methanol-water fuel in the first heat exchange coil 1a, preheating Methanol air in pipe 1b is discharged after being exchanged heat from thick hydrogen outlet 10.When the second heat transfer zone 1f temperature reaches 200 DEG C, increase The dosage of big methanol-water after device stable operation, uses to predetermined value for fuel cell system or production hydrogen machine.
Only highly preferred embodiment of the present invention is described above, but is not to be construed as limiting the scope of the invention.This Invention is not only limited to above example, and its concrete structure allows to change.All protection models in independent claims of the present invention Interior made various change is enclosed to all fall in the scope of protection of the present invention.

Claims (8)

  1. A kind of 1. burning reformer for being applied to fuel cell generation or producing hydrogen machine, it is characterised in that:Including mutually interconnecting The waste heat recoverer (1) and burning recombining reaction device (2) connect, the waste heat recoverer (1) is interior to be additionally provided with central dividing plate (1d), should Central dividing plate (1d) will be divided into the first heat transfer zone (1e) and the second heat transfer zone (1f), the burning weight inside waste heat recoverer (1) Group reactor (2) includes the 3rd heat exchange coil (2a), catalysis combustion chamber (2b), recombining reaction inner chamber being nested with successively from inside to outside (2c), recombining reaction exocoel (2d) and combustion product gases chamber (2e), the 3rd heat exchange coil (2a) and recombining reaction inner chamber (2c) It is connected, the recombining reaction inner chamber (2c) is connected with recombining reaction exocoel (2d), and first heat transfer zone (1e) is by outer Portion's connecting tube connected with recombining reaction exocoel (2d) with allow recombinate thick hydrogen to the first heat transfer zone (1e) provide one-level preheating; The catalysis combustion chamber (2b) is connected with combustion product gases chamber (2e), and second heat transfer zone (1f) passes through external connecting pipe and combustion Flue gas chamber (2e) connection is burnt to allow combustion tail gas to provide two level preheating to the second heat transfer zone (1f).
  2. 2. the burning reformer according to claim 1 for being applied to fuel cell generation or producing hydrogen machine, its feature It is:The first heat exchange coil (1a), the second heat exchange coil (1c) and preheating straight tube (1b) are provided with the waste heat recoverer (1), First heat exchange coil (1a) connects with the second heat exchange coil (1c) and to be placed on the preheating straight tube (1b) outside, and described the One heat exchange coil (1a) is located in the first heat transfer zone (1e), and second heat exchange coil (1c) is located in the second heat transfer zone (1f), The preheating straight tube (1b) runs through the first heat transfer zone (1e), the second heat transfer zone (1f), and the preheating straight tube (1b) is connected by outside Adapter connects with the catalysis combustion chamber (2b).
  3. 3. the burning reformer according to claim 2 for being applied to fuel cell generation or producing hydrogen machine, its feature It is, the central dividing plate (1d) and waste heat recoverer (1) inwall, the first heat exchange coil (1a) outer wall, the second heat exchange coil (1c) outer wall, the junction welded seal for preheating straight tube (1b) outer wall.
  4. 4. the burning reformer according to claim 1 for being applied to fuel cell generation or producing hydrogen machine, its feature It is, the catalyst for being used for being catalyzed burning is filled with the catalysis combustion chamber (2b).
  5. 5. the burning reformer according to claim 2 for being applied to fuel cell generation or producing hydrogen machine, its feature It is, the preheating straight tube (1b), which extends downwardly, is connected with air intlet pipe (4), and methanol is connected with the air intlet pipe (4) Inlet tube (3).
  6. 6. the burning reformer according to claim 1 for being applied to fuel cell generation or producing hydrogen machine, its feature It is, second heat transfer zone (1f) is provided with combustion product gases outlet (11) close to central dividing plate (1d) place.
  7. 7. the burning reformer according to claim 2 for being applied to fuel cell generation or producing hydrogen machine, its feature It is, first heat exchange coil (1a) is outward extended with methanol-water fuel inlet (5), and second heat exchange coil (1c) is outside The outlet (6) of connection external connecting pipe is extended with, the 3rd heat exchange coil (2a) is outward extended with connection external connecting pipe Inlet tube (7).
  8. 8. the burning reformer according to claim 1 for being applied to fuel cell generation or producing hydrogen machine, its feature It is, the recombining reaction exocoel (2d) is outwards provided with the recombinant gas outlet (8) of connection external connecting pipe, and described first changes Hot-zone (1e) is provided with recombinant gas inlet tube (9) close to central dividing plate (1d) place, and the bottom of first heat transfer zone (1e) is provided with slightly Hydrogen outlet (10).
CN201711158863.1A 2017-11-20 2017-11-20 Combustion reformer applied to fuel cell power generation system or hydrogen generator Active CN107863542B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112194099A (en) * 2020-10-30 2021-01-08 摩氢科技有限公司 Methanol-water preheating device
CN112707370A (en) * 2020-12-28 2021-04-27 宁波申江科技股份有限公司 Electric heating methanol reformer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1990379A (en) * 2005-12-30 2007-07-04 三星Sdi株式会社 Hydrogen generator having double burners and method of operating the same
CN101222975A (en) * 2005-06-28 2008-07-16 赫多特普索化工设备公司 Compact reforming reactor
US20150280263A1 (en) * 2012-10-09 2015-10-01 Honda Motor Co., Ltd. Fuel cell module
CN106784940A (en) * 2016-12-27 2017-05-31 宁波索福人能源技术有限公司 A kind of solid oxide fuel cell power generating system
CN207624815U (en) * 2017-11-20 2018-07-17 宁波申江科技股份有限公司 Applied to fuel cell generation or the burning reformer of production hydrogen machine

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101222975A (en) * 2005-06-28 2008-07-16 赫多特普索化工设备公司 Compact reforming reactor
CN1990379A (en) * 2005-12-30 2007-07-04 三星Sdi株式会社 Hydrogen generator having double burners and method of operating the same
US20150280263A1 (en) * 2012-10-09 2015-10-01 Honda Motor Co., Ltd. Fuel cell module
CN106784940A (en) * 2016-12-27 2017-05-31 宁波索福人能源技术有限公司 A kind of solid oxide fuel cell power generating system
CN207624815U (en) * 2017-11-20 2018-07-17 宁波申江科技股份有限公司 Applied to fuel cell generation or the burning reformer of production hydrogen machine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112194099A (en) * 2020-10-30 2021-01-08 摩氢科技有限公司 Methanol-water preheating device
CN112707370A (en) * 2020-12-28 2021-04-27 宁波申江科技股份有限公司 Electric heating methanol reformer

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