CN107858147B - 一种具有促根作用的土壤磷素活化剂 - Google Patents
一种具有促根作用的土壤磷素活化剂 Download PDFInfo
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- CN107858147B CN107858147B CN201711079801.1A CN201711079801A CN107858147B CN 107858147 B CN107858147 B CN 107858147B CN 201711079801 A CN201711079801 A CN 201711079801A CN 107858147 B CN107858147 B CN 107858147B
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- acid
- soil
- phosphorus
- root
- parts
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- 239000011574 phosphorus Substances 0.000 title claims abstract description 86
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 86
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 239000002689 soil Substances 0.000 title claims abstract description 79
- 239000012190 activator Substances 0.000 title claims abstract description 33
- 230000001737 promoting effect Effects 0.000 title claims abstract description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 66
- 108010020346 Polyglutamic Acid Proteins 0.000 claims abstract description 26
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 26
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims abstract description 22
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 22
- 229920000805 Polyaspartic acid Polymers 0.000 claims abstract description 22
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 108010064470 polyaspartate Proteins 0.000 claims abstract description 22
- 239000000600 sorbitol Substances 0.000 claims abstract description 22
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 12
- RBFWXVHGJQDSGG-UHFFFAOYSA-N [7-borono-9,9-bis(2-ethylhexyl)fluoren-2-yl]boronic acid Chemical compound C1=C(B(O)O)C=C2C(CC(CC)CCCC)(CC(CC)CCCC)C3=CC(B(O)O)=CC=C3C2=C1 RBFWXVHGJQDSGG-UHFFFAOYSA-N 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- 238000007873 sieving Methods 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 10
- 238000001694 spray drying Methods 0.000 claims description 9
- OXIKLRTYAYRAOE-CMDGGOBGSA-N (e)-3-(1-benzyl-3-pyridin-3-ylpyrazol-4-yl)prop-2-enoic acid Chemical group N1=C(C=2C=NC=CC=2)C(/C=C/C(=O)O)=CN1CC1=CC=CC=C1 OXIKLRTYAYRAOE-CMDGGOBGSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims 1
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 abstract description 24
- 230000003213 activating effect Effects 0.000 abstract description 10
- 239000003795 chemical substances by application Substances 0.000 abstract description 10
- 239000002686 phosphate fertilizer Substances 0.000 abstract description 10
- 230000002786 root growth Effects 0.000 abstract description 3
- 150000001413 amino acids Chemical class 0.000 abstract description 2
- 235000015816 nutrient absorption Nutrition 0.000 abstract description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract description 2
- 229920001184 polypeptide Polymers 0.000 abstract description 2
- 108090000765 processed proteins & peptides Proteins 0.000 abstract description 2
- 102000004196 processed proteins & peptides Human genes 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 26
- 230000000694 effects Effects 0.000 description 17
- 235000015097 nutrients Nutrition 0.000 description 12
- IAYJZWFYUSNIPN-KFRZSCGFSA-N (2s,3r,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-(4-nitrophenoxy)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](OC=2C=CC(=CC=2)[N+]([O-])=O)[C@H](O)[C@H]1O IAYJZWFYUSNIPN-KFRZSCGFSA-N 0.000 description 9
- 240000006915 Petasites Species 0.000 description 8
- XLXMYOUBZINZAX-UHFFFAOYSA-N bis(11-methyldodecyl) dodecanedioate Chemical compound CC(C)CCCCCCCCCCOC(=O)CCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C XLXMYOUBZINZAX-UHFFFAOYSA-N 0.000 description 7
- 241000227653 Lycopersicon Species 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- MFYMCCBGVQYQIX-UHFFFAOYSA-L P.[Cl-].[Cl-].Cl.Cl.Cl.[Ca+2] Chemical compound P.[Cl-].[Cl-].Cl.Cl.Cl.[Ca+2] MFYMCCBGVQYQIX-UHFFFAOYSA-L 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 240000003296 Petasites japonicus Species 0.000 description 2
- 235000003823 Petasites japonicus Nutrition 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000012258 culturing Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 229940023569 palmate Drugs 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- ZMBXDLZXSVSXOQ-UHFFFAOYSA-N P(Cl)(Cl)Cl.[Ca] Chemical compound P(Cl)(Cl)Cl.[Ca] ZMBXDLZXSVSXOQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-L dodecanedioate(2-) Chemical compound [O-]C(=O)CCCCCCCCCCC([O-])=O TVIDDXQYHWJXFK-UHFFFAOYSA-L 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002367 phosphate rock Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
编号 | 处理g/L | 无机磷提升率% |
实施例1 | 0.4 | 24% |
实施例2 | 0.4 | 30% |
实施例3 | 0.4 | 31% |
实施例4 | 0.4 | 30% |
实施例5 | 0.4 | 31% |
对比例1 | 0.4 | 11% |
对比例2 | 0.4 | 12% |
编号 | 处理g/Kg | Olsen-P提升率% |
实施例1 | 5 | 12% |
实施例2 | 5 | 17% |
实施例3 | 5 | 18% |
实施例4 | 5 | 17% |
实施例5 | 5 | 18% |
对比例1 | 5 | 3% |
对比例2 | 5 | 4% |
编号 | 处理g/Kg | 根长提升率% |
实施例1 | 0.4 | 12% |
实施例2 | 0.4 | 16% |
实施例3 | 0.4 | 16% |
实施例4 | 0.4 | 17% |
实施例5 | 0.4 | 16% |
对比例1 | 0.4 | 4% |
对比例2 | 0.4 | 5% |
编号 | 处理g/Kg | 根干重提升率% |
实施例1 | 0.4 | 20% |
实施例2 | 0.4 | 25% |
实施例3 | 0.4 | 24% |
实施例4 | 0.4 | 24% |
实施例5 | 0.4 | 25% |
对比例1 | 0.4 | 13% |
对比例2 | 0.4 | 12% |
Claims (1)
Priority Applications (1)
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CN201711079801.1A CN107858147B (zh) | 2017-11-06 | 2017-11-06 | 一种具有促根作用的土壤磷素活化剂 |
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Application Number | Priority Date | Filing Date | Title |
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CN201711079801.1A CN107858147B (zh) | 2017-11-06 | 2017-11-06 | 一种具有促根作用的土壤磷素活化剂 |
Publications (2)
Publication Number | Publication Date |
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CN107858147A CN107858147A (zh) | 2018-03-30 |
CN107858147B true CN107858147B (zh) | 2020-10-20 |
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CN201711079801.1A Active CN107858147B (zh) | 2017-11-06 | 2017-11-06 | 一种具有促根作用的土壤磷素活化剂 |
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Country | Link |
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CN (1) | CN107858147B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109265286B (zh) * | 2018-09-29 | 2021-09-10 | 中国农业大学 | 一种提高土壤磷利用的生物激活剂及其制备方法和应用 |
CN109293444A (zh) * | 2018-12-05 | 2019-02-01 | 史丹利农业集团股份有限公司 | 一种石灰性土壤的磷素活化剂及其制备方法与应用 |
CN110014032B (zh) * | 2019-04-28 | 2022-04-12 | 北京建工环境修复股份有限公司 | 一种农田土壤重金属污染的修复方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6444614B2 (en) * | 2000-04-12 | 2002-09-03 | Lidochem Inc. | Aspartic acid derivative-containing compositions and use thereof in stimulating and/or regulating plant and plant precursor growth |
CN102276364B (zh) * | 2011-05-09 | 2013-04-24 | 南京工业大学 | 一种含γ-聚谷氨酸的抗旱保水种衣剂及其制备方法 |
CN104010510B (zh) * | 2011-12-21 | 2016-10-12 | 巴斯夫欧洲公司 | 含有氨基-/多氨基羧化物和有机磷酸化物、膦酸化物或亚磷酸化物的配制剂及其在农业中的用途 |
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Publication number | Publication date |
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CN107858147A (zh) | 2018-03-30 |
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TR01 | Transfer of patent right |
Effective date of registration: 20210419 Address after: 618413 Deyang, Sichuan City, Shifang Province, South springs town and Hing Village Patentee after: SICHUAN ANDA CHEMICALS Co.,Ltd. Address before: 100193 new teaching building, No. 2, West Road, Old Summer Palace, Haidian District, Beijing Patentee before: CHINA AGRICULTURAL University |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A soil phosphorus activator with root promoting effect Effective date of registration: 20210625 Granted publication date: 20201020 Pledgee: Sichuan Shifang rural commercial bank Limited by Share Ltd. Pledgor: SICHUAN ANDA CHEMICALS Co.,Ltd. Registration number: Y2021510000131 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210913 Granted publication date: 20201020 Pledgee: Sichuan Shifang rural commercial bank Limited by Share Ltd. Pledgor: SICHUAN ANDA CHEMICALS Co.,Ltd. Registration number: Y2021510000131 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A soil phosphorus activator with root promoting effect Effective date of registration: 20210926 Granted publication date: 20201020 Pledgee: Sichuan Shifang rural commercial bank Limited by Share Ltd. Pledgor: SICHUAN ANDA CHEMICALS Co.,Ltd. Registration number: Y2021510000235 |
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