CN107858076A - A kind of propeller for vessels antifouling paint - Google Patents
A kind of propeller for vessels antifouling paint Download PDFInfo
- Publication number
- CN107858076A CN107858076A CN201711232985.0A CN201711232985A CN107858076A CN 107858076 A CN107858076 A CN 107858076A CN 201711232985 A CN201711232985 A CN 201711232985A CN 107858076 A CN107858076 A CN 107858076A
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- CN
- China
- Prior art keywords
- parts
- propeller
- vessels
- weight
- composite toughing
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of propeller for vessels antifouling paint, including material a and material b, material a and material b weight ratio are 1：0.2‑0.5；Wherein first component raw material includes by weight：100 140 parts of bisphenol-f type liquid resin, 10 20 parts of composite toughing agent, 8 14 parts of diatomite, 48 parts of tourmaline powder, 46 parts of germanite, 15 25 parts of inserts, 24 parts of dispersant, 24 parts of defoamer, 24 parts of wetting agent；Second component raw material includes by weight：6 12 parts of diethyl amino propylamine, 40 60 parts of water.The present invention is applied to various environment and temperature, and the defects of can avoiding epidermis tilting caused by poor adhesive force, come off, high with propeller surface adhesion intensity, water resistance is excellent, service life length.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of propeller for vessels antifouling paint.
Background technology
At present propeller for vessels material therefor mainly using stainless steel prepare, ship in the process of running, in the water of high speed
Stream is washed away with the presence of centrifugal force, and propeller surface will not produce sea marine organism pollution；When berthing, propeller is easy to that sea occurs
Biodeterioration.The sea marine organism pollution of propeller, particularly duricrust class sea marine organism pollution, ship resistance and the fuel oil of ship can be increased
Consumption, reduces the speed of a ship or plane, while can increase the surface roughness of propeller, reduces the delivery efficiency of propeller, accelerates propeller
Corrosion, ship is frequently lain up maintenance because propeller is stained problem, increase maintenance cost, reduction is sailed rate.State at present
It is inside and outside to have researched and developed a variety of methods for preventing sea marine organism pollution, typically pass through the antifouling painting of ability propeller external coating at present
Layer, but adhesive force is poor, it would be highly desirable to solve.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of propeller for vessels antifouling paint, is applicable
It is strong with propeller surface adhesion the defects of epidermis tilting caused by poor adhesive force can be avoided, come off in various environment and temperature
Degree is high, and water resistance is excellent, service life length.
A kind of propeller for vessels antifouling paint proposed by the present invention, including material a and material b, material a and material b
Weight ratio is 1：0.2-0.5；
Wherein first component raw material includes by weight：Bisphenol-f type liquid resin 100-140 parts, composite toughing agent 10-20
Part, diatomite 8-14 parts, tourmaline powder 4-8 parts, germanite 4-6 parts, inserts 15-25 parts, dispersant 2-4 parts, defoamer 2-4
Part, wetting agent 2-4 parts；
Second component raw material includes by weight：Diethyl amino propylamine 6-12 parts, water 40-60 parts.
Preferably, inserts includes by weight：Talcum powder 4-8 parts, weathered coal 3-6 parts, expanded perlite 3-6 parts are more
Wall carbon nano tube 2-4 parts.
Preferably, composite toughing agent is prepared using following technique：By ethylene-octene copolymer, end carboxyl nitrile (HTBN) rubber
Glue is mixed, and addition maleic anhydride, styrene are well mixed, and is added dibenzoyl peroxide and is well mixed, extrusion obtains compound increasing
Tough dose.
Preferably, in the preparation technology of composite toughing agent, ethylene-octene copolymer, carboxyl end of the liquid acrylonitrile-butadiene rubber, peroxide
The weight ratio for changing dibenzoyl is 20-30：10-18：0.04-0.1.
Preferably, in the preparation technology of composite toughing agent, maleic anhydride, styrene, the weight ratio of dibenzoyl peroxide
For 2-4：1-3：0.04-0.1.
Preferably, composite toughing agent is prepared using following technique：By ethylene-octene copolymer, end carboxyl nitrile (HTBN) rubber
Glue is mixed, and addition maleic anhydride, styrene are well mixed, and is added dibenzoyl peroxide and is well mixed, extrusion obtains compound increasing
Tough dose, extrusion temperature is 230-250 DEG C.
The present invention is applied to various environment and temperature, the defects of epidermis tilting caused by poor adhesive force can be avoided, come off,
High with propeller surface adhesion intensity, water resistance is excellent, service life length.
In the composite toughing agent of the present invention, ethylene-octene copolymer, carboxyl end of the liquid acrylonitrile-butadiene rubber compounding, Malaysia is added
Acid anhydrides, styrene are grafting agent, using dibenzoyl peroxide as initiator, improve polar functional group in composite toughing agent and contain
Amount；Composite toughing agent coordinates with bisphenol-f type liquid resin, and mutual combination degree is high, and after film-forming, film is close
Real, good toughness, adhesive force is extremely strong, and diatomite, tourmaline powder, germanite coordinate, and can effectively suppress mould, and anti-corrosive properties are good, coordinates
Talcum powder, weathered coal, expanded perlite, multi-walled carbon nanotube effect are added, excellent adsorption, water proofing property is strong, and hardness is high, coordinates multiple
Toughener effect is closed, on the premise of hardness is ensured, good toughness, film is easy to crack.
Up to more than 180 μm, salt water resistance soaks 6 months one-pass film-forming thickness of the present invention, does not ftracture, be non-foaming, not falling off,
Adhesive force is extremely strong, and propeller surface is smooth, corrosion-free, no sea organism attachment, by evaluate estimated antifouling phase imitate up to 6 months with
On, suitable for propellers such as naval vessels, large ship, fishing boats.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of propeller for vessels antifouling paint, including material a and material b, material a and material b weight ratio are 1：
0.2；
Wherein first component raw material includes by weight：140 parts of bisphenol-f type liquid resin, 10 parts of composite toughing agent, diatomite
14 parts, 4 parts of tourmaline powder, 6 parts of germanite, 15 parts of inserts, 4 parts of dispersant, 2 parts of defoamer, 4 parts of wetting agent；
Second component raw material includes by weight：6 parts of diethyl amino propylamine, 60 parts of water.
Inserts includes：4 parts of talcum powder, 6 parts of weathered coal, 3 parts of expanded perlite, 4 parts of multi-walled carbon nanotube.
Composite toughing agent is prepared using following technique：By 20 parts of ethylene-octene copolymers, 18 parts of end carboxyl nitrile (HTBN) rubbers
Glue is mixed, and 2 parts of maleic anhydrides of addition, 3 parts of styrene are well mixed, and is added 0.04 part of dibenzoyl peroxide and is well mixed, squeezes
Go out to obtain composite toughing agent, extrusion temperature is 250 DEG C.
Embodiment 2
A kind of propeller for vessels antifouling paint, including material a and material b, material a and material b weight ratio are 1：
0.5；
Wherein first component raw material includes by weight：100 parts of bisphenol-f type liquid resin, 20 parts of composite toughing agent, diatomite
8 parts, 8 parts of tourmaline powder, 4 parts of germanite, 25 parts of inserts, 2 parts of dispersant, 4 parts of defoamer, 2 parts of wetting agent；
Second component raw material includes by weight：12 parts of diethyl amino propylamine, 40 parts of water.
Inserts includes：8 parts of talcum powder, 3 parts of weathered coal, 6 parts of expanded perlite, 2 parts of multi-walled carbon nanotube.
Composite toughing agent is prepared using following technique：By 30 parts of ethylene-octene copolymers, 10 parts of end carboxyl nitrile (HTBN) rubbers
Glue is mixed, and 4 parts of maleic anhydrides of addition, 1 part of styrene are well mixed, and is added 0.1 part of dibenzoyl peroxide and is well mixed, extrudes
Composite toughing agent is obtained, extrusion temperature is 230 DEG C.
Embodiment 3
A kind of propeller for vessels antifouling paint, including material a and material b, material a and material b weight ratio are 1：
0.3；
Wherein first component raw material includes by weight：130 parts of bisphenol-f type liquid resin, 12 parts of composite toughing agent, diatomite
12 parts, 5 parts of tourmaline powder, 5.5 parts of germanite, 18 parts of inserts, 3.5 parts of dispersant, 2.5 parts of defoamer, 3.5 parts of wetting agent；
Second component raw material includes by weight：8 parts of diethyl amino propylamine, 55 parts of water.
Inserts includes：5 parts of talcum powder, 5 parts of weathered coal, 4 parts of expanded perlite, 3.5 parts of multi-walled carbon nanotube.
Composite toughing agent is prepared using following technique：By 22 parts of ethylene-octene copolymers, 16 parts of end carboxyl nitrile (HTBN) rubbers
Glue is mixed, and 2.5 parts of maleic anhydrides of addition, 2.5 parts of styrene are well mixed, and it is equal to add 0.06 part of dibenzoyl peroxide mixing
Even, extrusion obtains composite toughing agent, and extrusion temperature is 245 DEG C.
Embodiment 4
A kind of propeller for vessels antifouling paint, including material a and material b, material a and material b weight ratio are 1：
0.4；
Wherein first component raw material includes by weight：110 parts of bisphenol-f type liquid resin, 18 parts of composite toughing agent, diatomite
10 parts, 7 parts of tourmaline powder, 4.5 parts of germanite, 22 parts of inserts, 2.5 parts of dispersant, 3.5 parts of defoamer, 2.5 parts of wetting agent；
Second component raw material includes by weight：10 parts of diethyl amino propylamine, 45 parts of water.
Inserts includes：7 parts of talcum powder, 4 parts of weathered coal, 5 parts of expanded perlite, 2.5 parts of multi-walled carbon nanotube.
Composite toughing agent is prepared using following technique：By 28 parts of ethylene-octene copolymers, 12 parts of end carboxyl nitrile (HTBN) rubbers
Glue is mixed, and 3.5 parts of maleic anhydrides of addition, 1.5 parts of styrene are well mixed, and it is equal to add 0.08 part of dibenzoyl peroxide mixing
Even, extrusion obtains composite toughing agent, and extrusion temperature is 235 DEG C.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
- A kind of 1. propeller for vessels antifouling paint, it is characterised in that including material a and material b, material a and material b weight Than for 1：0.2-0.5；Wherein first component raw material includes by weight：Bisphenol-f type liquid resin 100-140 parts, composite toughing agent 10-20 parts, silicon Diatomaceous earth 8-14 parts, tourmaline powder 4-8 parts, germanite 4-6 parts, inserts 15-25 parts, dispersant 2-4 parts, defoamer 2-4 parts, wetting Agent 2-4 parts；Second component raw material includes by weight：Diethyl amino propylamine 6-12 parts, water 40-60 parts.
- 2. propeller for vessels antifouling paint according to claim 1, it is characterised in that inserts includes by weight：It is sliding Stone flour 4-8 parts, weathered coal 3-6 parts, expanded perlite 3-6 parts, multi-walled carbon nanotube 2-4 parts.
- 3. propeller for vessels antifouling paint according to claim 1 or claim 2, it is characterised in that composite toughing agent is using as follows It is prepared by technique：Ethylene-octene copolymer, carboxyl end of the liquid acrylonitrile-butadiene rubber are mixed, add maleic anhydride, styrene mixing It is even, add dibenzoyl peroxide and be well mixed, extrusion obtains composite toughing agent.
- 4. propeller for vessels antifouling paint according to claim 3, it is characterised in that the preparation technology of composite toughing agent In, ethylene-octene copolymer, carboxyl end of the liquid acrylonitrile-butadiene rubber, the weight ratio of dibenzoyl peroxide are 20-30：10-18： 0.04-0.1。
- 5. according to the propeller for vessels antifouling paint of claim 3 or 4, it is characterised in that the preparation work of composite toughing agent In skill, maleic anhydride, styrene, the weight ratio of dibenzoyl peroxide are 2-4：1-3：0.04-0.1.
- 6. according to any one of the claim 3-5 propeller for vessels antifouling paints, it is characterised in that composite toughing agent uses It is prepared by following technique：Ethylene-octene copolymer, carboxyl end of the liquid acrylonitrile-butadiene rubber are mixed, add maleic anhydride, styrene mixing Uniformly, add dibenzoyl peroxide to be well mixed, extrusion obtains composite toughing agent, and extrusion temperature is 230-250 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711232985.0A CN107858076A (en) | 2017-11-30 | 2017-11-30 | A kind of propeller for vessels antifouling paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711232985.0A CN107858076A (en) | 2017-11-30 | 2017-11-30 | A kind of propeller for vessels antifouling paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107858076A true CN107858076A (en) | 2018-03-30 |
Family
ID=61704050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711232985.0A Withdrawn CN107858076A (en) | 2017-11-30 | 2017-11-30 | A kind of propeller for vessels antifouling paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN107858076A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108676393A (en) * | 2018-05-30 | 2018-10-19 | 陈建峰 | A kind of preparation method of anti-reflection film coating liquid |
| CN111925720A (en) * | 2020-08-24 | 2020-11-13 | 江苏华夏制漆科技有限公司 | Waterborne organic fluorine-silicon modified ship coating and preparation method thereof |
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| CN103589263A (en) * | 2013-10-30 | 2014-02-19 | 溧阳市哈大成果转化中心有限公司 | Coating-containing anti-icing propeller blade leading-edge assembly |
| US20140127017A1 (en) * | 2011-07-05 | 2014-05-08 | Hafmex Invest Oy | The surface structure of windmill rotors for special circumstances |
| CN104559728A (en) * | 2014-12-12 | 2015-04-29 | 中国航空工业集团公司北京航空材料研究院 | Corrosion-resistant anti-cavitation coating and preparation method thereof |
| CN105482619A (en) * | 2015-12-18 | 2016-04-13 | 广东华科新材料研究院有限公司 | Method for preparing wear-resistant and corrosion-resistant coating |
| CN106883725A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of double-component propeller antifouling paint |
| CN106893481A (en) * | 2015-12-17 | 2017-06-27 | 中国科学院金属研究所 | A kind of anti-cavitation corrosion coating of vinal-fluoride polyurethane and preparation method thereof |
| CN107380404A (en) * | 2017-07-28 | 2017-11-24 | 安徽卓尔航空科技有限公司 | A kind of advanced composite material (ACM) propeller |
-
2017
- 2017-11-30 CN CN201711232985.0A patent/CN107858076A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140127017A1 (en) * | 2011-07-05 | 2014-05-08 | Hafmex Invest Oy | The surface structure of windmill rotors for special circumstances |
| CN103589263A (en) * | 2013-10-30 | 2014-02-19 | 溧阳市哈大成果转化中心有限公司 | Coating-containing anti-icing propeller blade leading-edge assembly |
| CN104559728A (en) * | 2014-12-12 | 2015-04-29 | 中国航空工业集团公司北京航空材料研究院 | Corrosion-resistant anti-cavitation coating and preparation method thereof |
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| CN106883725A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of double-component propeller antifouling paint |
| CN107380404A (en) * | 2017-07-28 | 2017-11-24 | 安徽卓尔航空科技有限公司 | A kind of advanced composite material (ACM) propeller |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108676393A (en) * | 2018-05-30 | 2018-10-19 | 陈建峰 | A kind of preparation method of anti-reflection film coating liquid |
| CN111925720A (en) * | 2020-08-24 | 2020-11-13 | 江苏华夏制漆科技有限公司 | Waterborne organic fluorine-silicon modified ship coating and preparation method thereof |
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Application publication date: 20180330 |
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| WW01 | Invention patent application withdrawn after publication |