CN107857475A - A kind of ceramic whiteware glaze - Google Patents
A kind of ceramic whiteware glaze Download PDFInfo
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- CN107857475A CN107857475A CN201711195798.XA CN201711195798A CN107857475A CN 107857475 A CN107857475 A CN 107857475A CN 201711195798 A CN201711195798 A CN 201711195798A CN 107857475 A CN107857475 A CN 107857475A
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- glaze
- ceramic whiteware
- whiteware glaze
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
A kind of ceramic whiteware glaze of the present invention, using properly mixed zirconium silicate and zinc oxide as the opacifiers of ceramic whiteware glaze, ceramic whiteware glaze production cost can be reduced, improves the whiteness and opacity of ceramic whiteware glaze, the viscosity of ceramic whiteware glaze, the convenient outer surface coated on ceramic whiteware base substrate can be effectively reduced simultaneously;The addition of ripe talcum can effectively improve the opacity of ceramic whiteware glaze;Glaze slip denseness can suitably be increased by adding appropriate kaolin, make the thickness of glaze layer moderate, and increase glaze reduces the generation of contracting glaze to the adhesive force of billet surface;Appropriate lithium carbonate, barium carbonate, Gaozhou county kaolin, silicon powder and spodumene are added, the glossiness of ceramic whiteware glaze glaze paint can be effectively improved, improves the quality of the ceramic whiteware glaze of output;Ceramic whiteware glaze is obtained by ball mill by wet process wet ball grinding, can be uniformly mixed the raw material of composition ceramic whiteware glaze, and being advantageous to acquisition physical and chemical performance tends to the slurry of uniformity, facilitates glazing.
Description
Technical field
The present invention relates to porcelain manufacture technology field, has and is related to a kind of ceramic whiteware glaze.
Background technology
Chinese porcelain makes with a long history, various in style.In addition to the blue and white and beautiful in colour faience of elegant.
Plain ceramic whiteware is also the kind that people like, although bright-colored decorative pattern and gorgeous color are looked no, in Piao
It is real without Central China, what it showed people is that natural day into U.S..Ceramic whiteware generally refers to porcelain body as white, and surface is clear frit
Porcelain.Ceramic whiteware has that base matter densification is transparent, and glazing, Cheng Taohuo degree are high, no water imbibition, sound is clear and the features such as rhythm is long.Because color and luster is clean
In vain, millet paste color and luster can be reflected, heat transfer, heat-insulating property are moderate, in addition riotous with colour, different modeling, can be rated as it in tea set
Treasure.
White glaze is this color glaze of porcelain.General china clay and glaze, all more or less contain some iron oxide, after implements are burnt
Necessarily show the different cyan of the depth.If the iron content in glaze is less than 0.75%, what is burnt will be white
Glaze.The making of ancient times ceramic whiteware, it is not that white photoghraphic coupler is added in glaze, but selects iron-holder less china clay and glaze
Processing and refining, iron-holder is set to be reduced to minimum degree.Pure clear frit is so imposed on pure white porcelain body, can just be fired
The very high ceramic whiteware of whiteness.Existing ceramic glaze is mainly made into by feldspar, quartz and raw clay, and the opacifiers of glaze mainly passes through
The processes such as tin oxide, zinc oxide, titanium dioxide, zirconium silicate have been gone through, because tin oxide is too high as the cost of opacifiers, making now
Dosage is fewer and fewer.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of glaze paint whiteness is high, glaze paint glossiness is good, raw
Produce a kind of low ceramic whiteware glaze of cost.
The present invention is realized by implementation below:
A kind of ceramic whiteware glaze, is made up of the component of following parts by weight:20 parts~22 parts of potassium stone, 15 parts~25 parts of albite, stone
14 parts~15 parts of English, 10 parts~12 parts of lime stone, 5 parts~10 parts of ripe talcum, 0.8 part~1.2 parts of zinc oxide, lithium carbonate 2 parts~4
Part, 2 parts~4 parts of barium carbonate, 5 parts~10 parts of kaolin, 1 part~3 parts of silicon powder, 2 parts~4 parts of spodumene, zirconium silicate 5 parts~15
Part.
Preferably, a kind of ceramic whiteware glaze, is made up of the component of following parts by weight:21 parts of potassium stone, 20 parts of albite, quartz
14.5 parts, 11 parts of lime stone, 8 parts of ripe talcum, 1.0 parts of zinc oxide, 3 parts of lithium carbonate, 3 parts of barium carbonate, 8 parts of kaolin, silicon powder 2
Part, 3 parts of spodumene, 10 parts of zirconium silicate.
Preferably, the place of production of the potassium stone is Hubei, and the place of production of the albite is Hunan, and the quartzy place of production is osmanthus
Woods, the place of production of the lime stone is Beiliu City, and the place of production of the ripe talcum is Jiangxi, and the kaolinic place of production is Gaozhou county.
Preferably, the mass fraction of silica is more than 99.6% in the quartz, and the mass fraction of iron oxide is less than
0.004%。
Preferably, the ripe talcum is to have passed through the talcum powder after 1250 DEG C~1280 DEG C of high-temperature calcination, the ripe cunning
The whiteness of stone is more than 90 degree.
Preferably, the ceramic whiteware glaze is obtained by ball mill by wet process wet ball grinding.
A kind of ceramic whiteware glaze of the present invention, can using properly mixed zirconium silicate and zinc oxide as the opacifiers of ceramic whiteware glaze
Ceramic whiteware glaze production cost is reduced, improves the whiteness and opacity of ceramic whiteware glaze, while can effectively reduce the viscosity of ceramic whiteware glaze,
The convenient outer surface coated on ceramic whiteware base substrate;The addition of ripe talcum can effectively improve the opacity of ceramic whiteware glaze;Add in right amount
Kaolin can suitably increase glaze slip denseness, make the thickness of glaze layer moderate, and increase glaze reduces contracting glaze to the adhesive force of billet surface
Generation;Appropriate lithium carbonate, barium carbonate, Gaozhou county kaolin, silicon powder and spodumene are added, ceramic whiteware glaze glaze can be effectively improved
The glossiness in face, improve the quality of the ceramic whiteware glaze of output;Ceramic whiteware glaze is obtained by ball mill by wet process wet ball grinding, can make composition
The raw material of ceramic whiteware glaze is uniformly mixed, and being advantageous to acquisition physical and chemical performance tends to the slurry of uniformity, facilitates glazing.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1 prepares ceramic whiteware glaze
A kind of ceramic whiteware glaze, is made up of the component of following parts by weight:20 parts of potassium stone, 15 parts of albite, quartzy 14 parts, lime stone
10 parts, 5 parts of ripe talcum, 0.8 part of zinc oxide, 2 parts of lithium carbonate, 2 parts of barium carbonate, 5 parts of kaolin, 1 part of silicon powder, 2 parts of spodumene,
5 parts of zirconium silicate, the mass fraction of silica is more than the 99.6%, mass fraction of iron oxide and is less than 0.004% in the quartz, institute
It is that have passed through the talcum powder after 1250 DEG C of high-temperature calcination to state ripe talcum, and the whiteness of the ripe talcum is more than 90 degree.
The each component of above-mentioned composition ceramic whiteware glaze is put into ball mill by wet process, wet ball grinding obtains the ceramic whiteware glaze.
Embodiment 2 prepares ceramic whiteware glaze
A kind of ceramic whiteware glaze, is made up of the component of following parts by weight:22 parts of potassium stone, 25 parts of albite, quartzy 15 parts, stone
12 parts of lime stone, 10 parts of ripe talcum, 1.2 parts of zinc oxide, 4 parts of lithium carbonate, 4 parts of barium carbonate, 10 parts of kaolin, silicon powder 3
Part, 4 parts of spodumene, 15 parts of zirconium silicate, it is described quartz in silica mass fraction be more than 99.6%, the quality of iron oxide
Fraction is less than 0.004%, and the ripe talcum is to have passed through the talcum powder after 1280 DEG C of high-temperature calcination, the whiteness of the ripe talcum
More than 90 degree.
The each component of above-mentioned composition ceramic whiteware glaze is put into ball mill by wet process, wet ball grinding obtains the ceramic whiteware glaze.
Embodiment 3 prepares ceramic whiteware glaze
A kind of ceramic whiteware glaze, is made up of the component of following parts by weight:21 parts of potassium stone, 20 parts of albite, quartzy 14.5 parts, lime
11 parts of stone, 8 parts of ripe talcum, 1.0 parts of zinc oxide, 3 parts of lithium carbonate, 3 parts of barium carbonate, 8 parts of kaolin, 2 parts of silicon powder, spodumene 3
Part, 10 parts of zirconium silicate, the mass fraction of silica is more than 99.6% in the quartz, the mass fraction of iron oxide is less than
0.004%, the ripe talcum is to have passed through the talcum powder after 1260 DEG C of high-temperature calcination, and the whiteness of the ripe talcum is more than 90 degree.
The each component of above-mentioned composition ceramic whiteware glaze is put into ball mill by wet process, wet ball grinding obtains the ceramic whiteware glaze.
Embodiment 4 prepares ceramic whiteware glaze
A kind of ceramic whiteware glaze, is made up of the component of following parts by weight:21 parts of potassium stone, 20 parts of albite, quartzy 14.5 parts, lime
11 parts of stone, 8 parts of ripe talcum, 1.0 parts of zinc oxide, 3 parts of lithium carbonate, 3 parts of barium carbonate, 8 parts of kaolin, 2 parts of silicon powder, spodumene 3
Part, 10 parts of zirconium silicate, the place of production of the potassium stone is Hubei, and the place of production of the albite is Hunan, and the quartzy place of production is osmanthus
Woods, the place of production of the lime stone is Beiliu City, and the place of production of the ripe talcum is Jiangxi, and the kaolinic place of production is Gaozhou county, described
The mass fraction of silica is more than the 99.6%, mass fraction of iron oxide and is less than 0.004% in quartz, the ripe talcum be by
Talcum powder after 1270 DEG C of high-temperature calcination, the whiteness of the ripe talcum are more than 90 degree.
The each component of above-mentioned composition ceramic whiteware glaze is put into ball mill by wet process, wet ball grinding obtains the ceramic whiteware glaze.
Comparative example 1
Compared with Example 4, the ripe talcum in the Jiangxi of 8 parts by weight is substituted for the talcum of 8 parts by weight by the ceramic whiteware glaze formula of comparative example 1
Powder, remaining composition ceramic whiteware glaze each component parts by weight it is same as Example 4, prepare the step of ceramic whiteware glaze with implementation
Example 4 is identical.
The performance test results for the ceramic whiteware glaze that table 1 below is embodiment 1-4 and comparative example 1 prepares.
Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 |
Glaze paint whiteness value (W)/% | 75.3 | 75.5 | 75.3 | 75.9 | 75.2 |
Viscosity/(Pa.s) | 1.31×10-3 | 1.33×10-3 | 1.29×10-3 | 1.34×10-3 | 1.32×10-3 |
Glaze layer thin and thick | It is moderate | It is moderate | It is moderate | It is moderate | It is moderate |
Whether contracting glaze | It is no | It is no | It is no | It is no | It is no |
Glaze paint spot | Nothing | Nothing | Nothing | Nothing | It is less |
Glaze paint glossiness | Well | Well | Well | Well | Preferably |
Suspension | It is good | It is good | It is good | It is good | Difference |
The performance test results of the ceramic whiteware glaze prepared from upper table embodiment 1-4 and comparative example 1 find out, the present invention one
Kind ceramic whiteware glaze, the thickness of its glaze layer is moderate, and glaze paint whiteness value is high, and the glossiness of ceramic whiteware glaze glaze paint is good, ceramic whiteware glaze
Quality is high, and contracting glaze will not also occur for glaze paint immaculate.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (6)
- A kind of 1. ceramic whiteware glaze, it is characterised in that:It is made up of the component of following parts by weight:20 parts~22 parts of potassium stone, albite 15 parts~25 parts, quartz 14 parts~15 parts, 10 parts~12 parts of lime stone, 5 parts~10 parts of ripe talcum, zinc oxide 0.8 part~1.2 Part, 2 parts~4 parts of lithium carbonate, 2 parts~4 parts of barium carbonate, 5 parts~10 parts of kaolin, 1 part~3 parts of silicon powder, spodumene 2 parts~4 Part, 5 parts~15 parts of zirconium silicate.
- A kind of 2. ceramic whiteware glaze according to claim 1, it is characterised in that:It is made up of the component of following parts by weight:Potassium 21 parts of stone, 20 parts of albite, 14.5 parts of quartz, 11 parts of lime stone, 8 parts of ripe talcum, 1.0 parts of zinc oxide, 3 parts of lithium carbonate, carbonic acid 3 parts of barium, 8 parts of kaolin, 2 parts of silicon powder, 3 parts of spodumene, 10 parts of zirconium silicate.
- A kind of 3. ceramic whiteware glaze according to claim 1 or 2, it is characterised in that:The place of production of the potassium stone is Hubei, described The place of production of albite is Hunan, and the quartzy place of production is Guilin, and the place of production of the lime stone is Beiliu City, the production of the ripe talcum Ground is Jiangxi, and the kaolinic place of production is Gaozhou county.
- A kind of 4. ceramic whiteware glaze according to claim 1, it is characterised in that:The mass fraction of silica in the quartz More than 99.6%, the mass fraction of iron oxide is less than 0.004%.
- A kind of 5. ceramic whiteware glaze according to claim 1, it is characterised in that:The ripe talcum be have passed through 1250 DEG C~ Talcum powder after 1280 DEG C of high-temperature calcination, the whiteness of the ripe talcum are more than 90 degree.
- A kind of 6. ceramic whiteware glaze according to claim 1, it is characterised in that:The ceramic whiteware glaze is by ball mill by wet process wet method Ball milling obtains.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109020212A (en) * | 2018-09-20 | 2018-12-18 | 河南省钧艺照明灯具有限公司 | It is a kind of to watch lamps and lanterns and preparation method thereof suitable for outdoor ceramics |
CN109369017A (en) * | 2018-12-12 | 2019-02-22 | 禹州市神后镇永春瓷业有限公司 | A kind of white pottery glaze |
CN109502980A (en) * | 2019-01-21 | 2019-03-22 | 德化县英发陶瓷有限公司 | A kind of high reinforcing white pottery glaze and preparation, application method |
CN111517647A (en) * | 2020-05-08 | 2020-08-11 | 广西南山瓷器有限公司 | Glaze material for moistening glaze and preparation method thereof |
CN113666713A (en) * | 2021-08-20 | 2021-11-19 | 德化县顺尔美工艺品有限公司 | Soda-fired molten glaze ceramic and preparation method thereof |
CN116395964A (en) * | 2023-04-11 | 2023-07-07 | 福建省德化新圣美陶瓷有限公司 | White porcelain glaze and method for preparing ceramic product by using same |
CN116514528A (en) * | 2023-03-27 | 2023-08-01 | 湖南兴诚电瓷电器有限公司 | Ceramic insulator for isolating switch and preparation process thereof |
CN116854373A (en) * | 2023-07-25 | 2023-10-10 | 景德镇乐华陶瓷洁具有限公司 | Low-zirconium ceramic sanitary ware opacifying glaze, ceramic sanitary ware and preparation method thereof |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109020212A (en) * | 2018-09-20 | 2018-12-18 | 河南省钧艺照明灯具有限公司 | It is a kind of to watch lamps and lanterns and preparation method thereof suitable for outdoor ceramics |
CN109369017A (en) * | 2018-12-12 | 2019-02-22 | 禹州市神后镇永春瓷业有限公司 | A kind of white pottery glaze |
CN109502980A (en) * | 2019-01-21 | 2019-03-22 | 德化县英发陶瓷有限公司 | A kind of high reinforcing white pottery glaze and preparation, application method |
CN111517647A (en) * | 2020-05-08 | 2020-08-11 | 广西南山瓷器有限公司 | Glaze material for moistening glaze and preparation method thereof |
CN111517647B (en) * | 2020-05-08 | 2022-08-16 | 广西南山瓷器有限公司 | Glaze material for moistening glaze and preparation method thereof |
CN113666713A (en) * | 2021-08-20 | 2021-11-19 | 德化县顺尔美工艺品有限公司 | Soda-fired molten glaze ceramic and preparation method thereof |
CN116514528A (en) * | 2023-03-27 | 2023-08-01 | 湖南兴诚电瓷电器有限公司 | Ceramic insulator for isolating switch and preparation process thereof |
CN116514528B (en) * | 2023-03-27 | 2024-04-12 | 湖南兴诚电瓷电器有限公司 | Ceramic insulator for isolating switch and preparation process thereof |
CN116395964A (en) * | 2023-04-11 | 2023-07-07 | 福建省德化新圣美陶瓷有限公司 | White porcelain glaze and method for preparing ceramic product by using same |
CN116854373A (en) * | 2023-07-25 | 2023-10-10 | 景德镇乐华陶瓷洁具有限公司 | Low-zirconium ceramic sanitary ware opacifying glaze, ceramic sanitary ware and preparation method thereof |
CN116854373B (en) * | 2023-07-25 | 2024-02-23 | 景德镇乐华陶瓷洁具有限公司 | Low-zirconium ceramic sanitary ware opacifying glaze, ceramic sanitary ware and preparation method thereof |
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