CN107857315A - A kind of de- chromium clean reagent in drinking water and preparation method thereof - Google Patents

A kind of de- chromium clean reagent in drinking water and preparation method thereof Download PDF

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Publication number
CN107857315A
CN107857315A CN201711181951.3A CN201711181951A CN107857315A CN 107857315 A CN107857315 A CN 107857315A CN 201711181951 A CN201711181951 A CN 201711181951A CN 107857315 A CN107857315 A CN 107857315A
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CN
China
Prior art keywords
parts
chromium
drinking water
water
calcium
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Withdrawn
Application number
CN201711181951.3A
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Chinese (zh)
Inventor
温九江
袁松平
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Guangxi Xiaocao Information Industry Co Ltd
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Guangxi Xiaocao Information Industry Co Ltd
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Priority to CN201711181951.3A priority Critical patent/CN107857315A/en
Publication of CN107857315A publication Critical patent/CN107857315A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • C02F2101/22Chromium or chromium compounds, e.g. chromates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/34Organic compounds containing oxygen
    • C02F2101/345Phenols

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

The present invention relates to a kind of de- chromium clean reagent in drinking water and preparation method thereof.The de- chromium clean reagent in drinking water, including following parts by weight of component:15 30 parts of calcium silicates aluminium, 10 30 parts of titanium dioxide, aoxidize 3 10 parts of magnalium, 15 40 parts of iron oxide, 10 30 parts of calcium carbonate, 57 parts of calcium stearate, 5 15 parts of sodium alginate, 5 15 parts of activated carbon.The heavy metal ion such as the chromium that technical scheme can be preferably gone in water removal, the flow velocity of water can will not be reduced again effectively from water except dechromising;Not only clean-up effect is reliable, cheap, easy to use, environment-friendly, and it can effectively increase de- chromium effect, the phenol contained can be effectively removed in water removal simultaneously, there is good clean-up effect for the drinking water containing chromium and phenol, along with its can be in make-up water source water trace element, make source water obtain effectively purifying while greatly increasing the quality of drinking water source.

Description

A kind of de- chromium clean reagent in drinking water and preparation method thereof
Technical field
The invention belongs to new energy and environmental protection and energy saving technical field, more particularly to a kind of de- chromium clean reagent in drinking water and its system Preparation Method.
Background technology
With the fast development of economic society, industry, agricultural and water pollution problem caused by resident living are increasingly Seriously, the pollution of drinking water and the short supply of purifying drinking water are also more and more troubling.Drinking water by it is harmful it is inorganic from Son and heavy metal pollution, heavy metal poisoning can cause lung cancer, kidney wing, Guang cancer and cutaneum carcinoma and other skin diseases, and phenol Poisoning can cause phenol tooth disease or phenol bone disease.Therefore drink water purifying turns into one of topic most popular at present.Conventional art It is that the chromium compounds and phenolate in water are removed using magnesia, but because magnesia generates pasty state or pulpous state when being contacted with water Magnesium hydroxide, make water flow velocity reduce in addition make water stop flowing, to a certain extent as drinking water treatment technology develop Bottleneck.Also column purification, counter-infiltration and hydroxide precipitation etc. purification techniques, but all there is it is respective the shortcomings that or deficiency.
The content of the invention
In view of the problems of prior art, it is an object of the invention to provide it is a kind of being capable of effective purifying drinking water Cleanser.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:A kind of de- chromium clean reagent in drinking water, including it is following heavy Measure part component:Calcium silicates aluminium 15-25 parts, titanium dioxide 20-40 parts, aoxidize magnalium 5-15 parts, iron oxide 20-50 parts, calcium carbonate 10-30 parts, calcium stearate 5-7 parts, sodium alginate 5-15 parts, activated carbon 5-15 parts, polyvinyl alcohol 15-30 parts, limonite are 10-30 parts
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the de- chromium clean reagent in drinking water includes following parts by weight of component:15 parts of calcium silicates aluminium, 20 part two Titanium oxide, 5 parts of oxidation magnaliums, 20 parts of iron oxide, 10 parts of calcium carbonate, 5 parts of calcium stearates, 5 parts of sodium alginates, 5 parts of activated carbons, 15 parts of polyvinyl alcohol, 10 parts of limonites.
Further, the de- chromium clean reagent in drinking water includes following parts by weight of component:25 parts of calcium silicates aluminium, 40 part two Titanium oxide, 15 parts of oxidation magnaliums, 50 parts of iron oxide, 30 parts of calcium carbonate, 7 parts of calcium stearates, 15 parts of sodium alginates, 15 parts of activity 30 parts of polyvinyl alcohol of charcoal, 30 parts of limonites..
Further, the de- chromium clean reagent in drinking water includes following parts by weight of component:20 parts of calcium silicates aluminium, 30 part two Titanium oxide, 10 parts of oxidation magnaliums, 30 parts of iron oxide, 30 parts of calcium carbonate, 6 parts of calcium stearates, 8 parts of sodium alginates, 10 parts of activity Charcoal, 20 parts of polyvinyl alcohol, 20 parts of limonites.
Present invention also offers a kind of preparation method of de- chromium clean reagent in drinking water, comprise the following steps:Match somebody with somebody by weight Than weighing following components:Calcium silicates aluminium, titanium dioxide, magnalium is aoxidized, iron oxide, calcium carbonate, calcium stearate, sodium alginate, is lived Property charcoal, said components is dried at 120-150 DEG C processing, crushes and be well mixed.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
The invention provides a kind of de- chromium clean reagent in drinking water, including following parts by weight of component:Calcium silicates aluminium 15-25 parts, Titanium dioxide 20-40 parts, aoxidize magnalium 5-15 parts, iron oxide 20-50 parts, calcium carbonate 10-30 parts, calcium stearate 5-7 parts, sea Mosanom 5-15 parts, activated carbon 5-15 parts, polyvinyl alcohol 15-30 parts, limonite are 10-30 parts.
Technical scheme is by reasonably matching and the combination of each component is with the effect that significantly purifies water Fruit and it is easily manufactured, purification is quick;, can be effectively from water except dechromising and benzene using the clean reagent in drinking water of the present invention Phenol ion, the flow velocity of water will not be reduced again;Using the present invention clean reagent in drinking water, not only clean-up effect it is reliable, it is cheap, It is easy to use, environment-friendly, and can effectively increase de- chromium and take off phenol effect, have for the drinking water containing chromium and phenol De- chromium well and take off phenol effect.Overcome conventional water purification agent and be not easy the shortcomings that well mixed, and using effect is excellent, day Right nontoxic, tasteless, excellent in physical and chemical performance, available for drinking water caused by deep treatment for drinking water or sudden water pollution event Emergent pretreatment, it is environmentally friendly, it is pollution-free.
Activated carbon has the advantages that porous, specific surface area is big, and adsorption capacity is strong again, can not only adsorb impurities in water, again Adsorbable a certain amount of heavy metal ion;Reserves are big in nature for the two, and price is low, and production cost is low, and flow is short, operation letter Just, it is adapted to industrialized production.Chromium and phenol in drinking water are significantly reduced using cleanser of the present invention, Cr in source water can be made The clearance of (chromium) 77.76%~95.83%, phenol clearance up to 87.77%~97.73%;Along with it can be mended The trace element filled in source water, source water is set to have obtained effectively purifying while greatly increasing the quality of drinking water source.
It is introduced below by specific embodiment.
Embodiment 1
Following components is weighed by weight:15 parts of calcium silicates aluminium, 20 parts of titanium dioxide, 5 parts of oxidation magnaliums, 20 parts of oxidations Iron, 10 parts of calcium carbonate, 5 parts of calcium stearates, 5 parts of sodium alginates, 5 parts of activated carbons, 15 parts of polyvinyl alcohol, 10 parts of limonites will be upper State component and processing is dried at 120-150 DEG C, crush and be well mixed, the de- chromium clean reagent in drinking water is made.
Embodiment 2
Following components is weighed by weight:25 parts of calcium silicates aluminium, 40 parts of titanium dioxide, 15 parts of oxidation magnaliums, 50 parts of oxidations Iron, 30 parts of calcium carbonate, 7 parts of calcium stearates, 15 parts of sodium alginates, 15 parts of activated carbons, 30 parts of polyvinyl alcohol, 30 parts of limonites will be upper State component and processing is dried at 120-150 DEG C, crush and be well mixed, the de- chromium clean reagent in drinking water is made.
Embodiment 3
Following components is weighed by weight:20 parts of calcium silicates aluminium, 30 parts of titanium dioxide, 10 parts of oxidation magnaliums, 30 parts of oxidations Iron, 30 parts of calcium carbonate, 6 parts of calcium stearates, 8 parts of sodium alginates, 10 parts of activated carbons, 20 parts of polyvinyl alcohol, 20 parts of limonites will Processing is dried in said components at 120-150 DEG C, crushes and is well mixed, and the de- chromium clean reagent in drinking water is made.
Measure of merit
Embodiment 1-3 clean reagent in drinking water 1g and commercially available clean reagent in drinking water 1g (comparative example) are added to respectively In the pending drinking water of 100ml, stir and evenly mix, be precipitated to clarification, take supernatant liquor to be detected.Testing result is shown in Table 1.
Test result is as shown in table 1.
Table 1
Chromium clearance (%) Phenol clearance (%)
Embodiment 1 93 87
Embodiment 2 95 88
Embodiment 3 91 92
Comparative example 1 64 70
Data in table 1 can be seen that the huge sum of money such as chromium that technical scheme can be preferably gone in water removal Belong to ion, can will not reduce the flow velocity of water again effectively from water except dechromising;Not only clean-up effect it is reliable, it is cheap, make It with convenient, environment-friendly, and can effectively increase de- chromium effect, while can effectively remove in water removal the phenol contained, Have good clean-up effect for the drinking water containing chromium and phenol, along with its can be in make-up water source water micro member Element, source water is set to have obtained effectively purifying while greatly increasing the quality of drinking water source.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that come for one of ordinary skill in the art Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should will be defined by appended right.

Claims (5)

1. a kind of de- chromium clean reagent in drinking water, it is characterised in that including following parts by weight of component:Calcium silicates aluminium 15-25 parts, dioxy Change titanium 20-40 parts, aoxidize magnalium 5-15 parts, iron oxide 20-50 parts, calcium carbonate 10-30 parts, calcium stearate 5-7 parts, sodium alginate 5-15 parts, activated carbon 5-15 parts, polyvinyl alcohol 15-30 parts, limonite are 10-30 parts.
2. a kind of de- chromium clean reagent in drinking water according to claim 1, it is characterised in that including following parts by weight of component:15 Part calcium silicates aluminium, 20 parts of titanium dioxide, 5 parts of oxidation magnaliums, 20 parts of iron oxide, 10 parts of calcium carbonate, 5 parts of calcium stearates, 5 portions of marine algas Sour sodium, 5 parts of activated carbons, 15 parts of polyvinyl alcohol, 10 parts of limonites.
3. a kind of de- chromium clean reagent in drinking water according to claim 1, it is characterised in that including following parts by weight of component:25 Part calcium silicates aluminium, 40 parts of titanium dioxide, 15 parts of oxidation magnaliums, 50 parts of iron oxide, 30 parts of calcium carbonate, 7 parts of calcium stearates, 15 parts of seas Mosanom, 15 parts of activated carbons, 30 parts of polyvinyl alcohol, 30 parts of limonites.
4. a kind of de- chromium clean reagent in drinking water according to claim 1, it is characterised in that including following parts by weight of component:20 Part calcium silicates aluminium, 30 parts of titanium dioxide, 10 parts of oxidation magnaliums, 30 parts of iron oxide, 30 parts of calcium carbonate, 6 parts of calcium stearates, 8 parts of seas Mosanom, 10 parts of activated carbons, 20 parts of polyvinyl alcohol, 20 parts of limonites.
A kind of 5. preparation method that chromium clean reagent in drinking water is taken off as described in any one of Claims 1-4, it is characterised in that including Following steps:Following components is weighed by weight ratio:Calcium silicates aluminium, titanium dioxide, oxidation magnalium, iron oxide, calcium carbonate, firmly Resin acid calcium, sodium alginate, activated carbon, processing is dried in said components at 120-150 DEG C, crushes and is well mixed.
CN201711181951.3A 2017-11-23 2017-11-23 A kind of de- chromium clean reagent in drinking water and preparation method thereof Withdrawn CN107857315A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114269450A (en) * 2019-07-31 2022-04-01 勒瓦研究开发股份有限公司 Filter material for water treatment
CN114790015A (en) * 2021-05-07 2022-07-26 浙江施维康生物医学材料有限公司 Slow-release sustained-effect water purifying agent and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114269450A (en) * 2019-07-31 2022-04-01 勒瓦研究开发股份有限公司 Filter material for water treatment
CN114269450B (en) * 2019-07-31 2024-04-02 勒瓦研究开发股份有限公司 Filter material for water treatment
CN114790015A (en) * 2021-05-07 2022-07-26 浙江施维康生物医学材料有限公司 Slow-release sustained-effect water purifying agent and preparation method thereof
CN114790015B (en) * 2021-05-07 2023-10-20 浙江施维康生物医学材料有限公司 Sustained-release and sustained-effect water purifying agent and preparation method thereof

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