CN107833987A - A kind of lithium ion battery insulating heat-conductive film - Google Patents
A kind of lithium ion battery insulating heat-conductive film Download PDFInfo
- Publication number
- CN107833987A CN107833987A CN201711101372.3A CN201711101372A CN107833987A CN 107833987 A CN107833987 A CN 107833987A CN 201711101372 A CN201711101372 A CN 201711101372A CN 107833987 A CN107833987 A CN 107833987A
- Authority
- CN
- China
- Prior art keywords
- parts
- conductive film
- insulating heat
- lithium ion
- ion battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 17
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 claims abstract description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 Negel Chemical compound 0.000 claims abstract description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 229920000570 polyether Polymers 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 6
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 6
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 6
- 150000008064 anhydrides Chemical class 0.000 claims abstract description 5
- 238000009413 insulation Methods 0.000 claims abstract description 4
- 229940048086 sodium pyrophosphate Drugs 0.000 claims abstract description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 3
- NCZCAFWTDIRZFT-UHFFFAOYSA-N [K+].[K+].OB(O)O.OB(O)O.OB(O)O.OB([O-])[O-] Chemical class [K+].[K+].OB(O)O.OB(O)O.OB(O)O.OB([O-])[O-] NCZCAFWTDIRZFT-UHFFFAOYSA-N 0.000 claims description 3
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims 1
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 abstract description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- JPSKCQCQZUGWNM-UHFFFAOYSA-N 2,7-Oxepanedione Chemical compound O=C1CCCCC(=O)O1 JPSKCQCQZUGWNM-UHFFFAOYSA-N 0.000 description 1
- 206010068052 Mosaicism Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 210000003765 sex chromosome Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Cell Separators (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
The invention discloses a kind of lithium ion battery insulating heat-conductive film, the insulating heat-conductive film is used to coat battery body surface, and the insulating heat-conductive film is composed of the following components:Polysiloxane polyether copolymer, oxidation of alkyl amine APEO, dipotassium tetraborate, lauryl sodium sulfate, Negel, sodium pyrophosphate, anhydride maleique, carborundum, methyl laurate, methyl methacrylate.Insulating heat-conductive film of the present invention has the double attribute of insulation and heat conduction, the insulating heat-conductive film coated battery body surface, can effectively improve the security performance of battery.
Description
Technical field
The present invention relates to a kind of lithium ion battery insulating heat-conductive film.
Background technology
Lithium ion battery has that energy density is big, power output is high, discharge and recharge long lifespan, pollution-free, operating temperature range
Many advantages, such as wide and self discharge is small.It is as new high-energy chemistry power supply, towards solving human environment pollution and the energy
During crisis is advanced, challenge the hugest, i.e. safety problem are encountered.Lithium ion battery can be because of overcurrent, internal branch
Crystalline substance causes internal short-circuit or the abuse conditions such as overcharges, and causes the heat accumulation of inside, when thermal accumlation to a certain extent when, meeting
Trigger electrolyte, positive pole and internal other materials that heat release chain reaction occurs, ultimately result in lithium battery and thermal runaway occurs.
The approach for solving the problems, such as lithium ion battery security at present mainly includes two aspects.On the one hand it is by using maintenance
Or Added Management ensures its security.Lithium ion battery short circuit is such as prevented by lithium ion battery management system, overcharges and surpasses
Temperature etc..On the other hand it is then to improve the security of lithium ion battery itself by improving lithium battery material or optimization design.Such as
By improving positive electrode stability, the additive such as fire-retardant and anti-overcharge is added in the electrolytic solution, using new types of diaphragm(Such as ceramics
Barrier film)Etc. mode.But the above method can not fundamentally solve the peace of lithium ion battery at present because of the limitation of various factors
Full sex chromosome mosaicism.
The content of the invention
It is an object of the invention to provide a kind of lithium ion battery insulating heat-conductive film, the insulating heat-conductive film has exhausted
Edge and the double attribute of heat conduction, the insulating heat-conductive film coated battery body surface, the security performance of battery can be effectively improved.
To achieve the above object, should the technical scheme is that designing a kind of lithium ion battery insulating heat-conductive film
Insulating heat-conductive film is used to coat battery body surface, and the insulating heat-conductive film is composed of the following components:Silicone polyether is total to
Polymers, oxidation of alkyl amine APEO, dipotassium tetraborate, lauryl sodium sulfate, Negel, sodium pyrophosphate, butylene
Dicarboxylic anhydride, carborundum, methyl laurate, methyl methacrylate.
Preferably, insulating heat-conductive film by weight is composed of the following components:
4.2 parts of polysiloxane polyether copolymers,
3.1 parts of oxidation of alkyl amine APEOs,
1.2 parts of dipotassium tetraborates,
2.5 parts of lauryl sodium sulfate,
2.7 parts of Negels,
1.3 parts of sodium pyrophosphates,
2.4 parts of anhydride maleiques,
3.7 parts of carborundum,
4.9 parts of methyl laurates,
5.7 parts of methyl methacrylates.
The advantages of the present invention are:A kind of lithium ion battery insulating heat-conductive film is provided, the insulation is led
Hot film has the double attribute of insulation and heat conduction, the insulating heat-conductive film coated battery body surface, can effectively improve battery
Security performance.
Embodiment
With reference to embodiment, the embodiment of the present invention is further described.Following examples are only used for more
Add and clearly demonstrate technical scheme, and can not be limited the scope of the invention with this.
The technical scheme that the present invention is embodied is:
A kind of lithium ion battery insulating heat-conductive film, the insulating heat-conductive film are used to coat battery body surface, by weight
It is composed of the following components to count insulating heat-conductive film:
4.2 parts of polysiloxane polyether copolymers,
3.1 parts of oxidation of alkyl amine APEOs,
1.2 parts of dipotassium tetraborates,
2.5 parts of lauryl sodium sulfate,
2.7 parts of Negels,
1.3 parts of sodium pyrophosphates,
2.4 parts of anhydride maleiques,
3.7 parts of carborundum,
4.9 parts of methyl laurates,
5.7 parts of methyl methacrylates.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (2)
1. a kind of lithium ion battery insulating heat-conductive film, the insulating heat-conductive film is used to coat battery body surface, its feature
It is, the insulating heat-conductive film is composed of the following components:Polysiloxane polyether copolymer, oxidation of alkyl amine APEO, four
Potassium borate, lauryl sodium sulfate, Negel, sodium pyrophosphate, anhydride maleique, carborundum, methyl laurate, methyl
Methyl acrylate.
2. lithium ion battery according to claim 1 insulating heat-conductive film, it is characterised in that insulation is led by weight
Hot film is composed of the following components:
4.2 parts of polysiloxane polyether copolymers,
3.1 parts of oxidation of alkyl amine APEOs,
1.2 parts of dipotassium tetraborates,
2.5 parts of lauryl sodium sulfate,
2.7 parts of Negels,
1.3 parts of sodium pyrophosphates,
2.4 parts of anhydride maleiques,
3.7 parts of carborundum,
4.9 parts of methyl laurates,
5.7 parts of methyl methacrylates.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711101372.3A CN107833987A (en) | 2017-11-10 | 2017-11-10 | A kind of lithium ion battery insulating heat-conductive film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711101372.3A CN107833987A (en) | 2017-11-10 | 2017-11-10 | A kind of lithium ion battery insulating heat-conductive film |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107833987A true CN107833987A (en) | 2018-03-23 |
Family
ID=61654931
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201711101372.3A Pending CN107833987A (en) | 2017-11-10 | 2017-11-10 | A kind of lithium ion battery insulating heat-conductive film |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107833987A (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101333314A (en) * | 2007-06-25 | 2008-12-31 | 晟茂(青岛)先进材料有限公司 | Heat conducting insulating film material and method for manufacturing same |
CN101735563A (en) * | 2009-12-04 | 2010-06-16 | 郎玉龙 | Composite heat-conducting insulated film and method for manufacturing same |
CN204391174U (en) * | 2015-01-21 | 2015-06-10 | 合肥国轩高科动力能源股份公司 | A kind of aluminum electrokinetic cell module |
-
2017
- 2017-11-10 CN CN201711101372.3A patent/CN107833987A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101333314A (en) * | 2007-06-25 | 2008-12-31 | 晟茂(青岛)先进材料有限公司 | Heat conducting insulating film material and method for manufacturing same |
CN101735563A (en) * | 2009-12-04 | 2010-06-16 | 郎玉龙 | Composite heat-conducting insulated film and method for manufacturing same |
CN204391174U (en) * | 2015-01-21 | 2015-06-10 | 合肥国轩高科动力能源股份公司 | A kind of aluminum electrokinetic cell module |
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PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180323 |
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RJ01 | Rejection of invention patent application after publication |