CN107814998A - A kind of resist delamination incubator shell and its manufacture method - Google Patents

A kind of resist delamination incubator shell and its manufacture method Download PDF

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Publication number
CN107814998A
CN107814998A CN201710932517.8A CN201710932517A CN107814998A CN 107814998 A CN107814998 A CN 107814998A CN 201710932517 A CN201710932517 A CN 201710932517A CN 107814998 A CN107814998 A CN 107814998A
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CN
China
Prior art keywords
parts
incubator shell
incubator
resist delamination
shell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710932517.8A
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Chinese (zh)
Inventor
曾庆丽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polymer Rotomolding Co Ltd
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Polymer Rotomolding Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polymer Rotomolding Co Ltd filed Critical Polymer Rotomolding Co Ltd
Priority to CN201710932517.8A priority Critical patent/CN107814998A/en
Publication of CN107814998A publication Critical patent/CN107814998A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a kind of resist delamination incubator shell, it is made up of the raw material of following parts by weight:0.1 0.6 parts of 100 parts of substrate resin, the reinforcing agent of 35 45 mesh, 4 10 mesh and glass transition temperature are not less than 12 parts of the assisted resin of substrate resin, and manufacture method is:Raw material is disposably added in the rotational molding machine for installing mould in parts by weight, the 20min of rotational moulding 15 at 300 450 DEG C, the resist delamination incubator shell is obtained after cooling;Uneven on the inside of the shell, roughness is big, and bumps are evenly distributed everywhere, while the surface of incubator shell is still smooth;It is strong with polyurathamc adhesive force after filling-foam polyurethane;Increased weight outside turnout few, realize the lightweight of product;Shaping disposably feeds intake, and step is simple, and production efficiency is high.

Description

A kind of resist delamination incubator shell and its manufacture method
Technical field
The present invention relates to a kind of incubator, particularly a kind of incubator shell and its manufacture method.
Background technology
Plastic Foam Box is made by being filled in as the polyurathamc of insulation material in polyethylene sheath.Because of incubator Volume is larger, and polyethylene sheath is frequently with rotation molding, but rotation molding can cause shell inside and outside both side surface flat smooth, and Because polyurethane is polar material, polyethylene is non-polar material, thus polyurathamc is not strong to the adhesive force of polyethylene, is held Incubator finished product delamination is easily caused, i.e. polyethylene sheath separates with the polyurathamc of filling.
Plastic Foam Box shell of the prior art is in order to solve delamination problems, after polyethylene sheath rotation molding and still When uncolled, to the interior side spray LLDPE little particle of polyethylene sheath, thus obtained incubator housing exterior Face still flat smooth, and inner side becomes coarse because LLDPE little particle is fixed with, to a certain extent Polyurathamc is increased to the adhesive force on the inside of polyethylene sheath.But this method has the disadvantages that:(1), the amount dusted compared with Greatly, dusting operation can not realize the lightweight of product to weightening more than 30% outside turnout.(2), add the process dusted, Secondary batching, reduce production efficiency.(3), be difficult to ensure that in dusting operation and dust uniformly, dust it is excessive and it is very few all can be unfavorable Polyethylene sheath is clinged in polyurathamc.(4), using dusting change manufactured insulation after roughness on the inside of polyethylene sheath Case, polyurathamc be not still high to adhesive force on the inside of polyethylene sheath, and delamination is still present, and product disqualification rate is high.
The content of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of smooth in appearance and inner side is coarse, and manufacturing step letter Single, reduction product weightening, the coarse resist delamination incubator shell being evenly distributed and its manufacture method.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of resist delamination incubator shell, is made up of the raw material of following parts by weight:100 parts of substrate resin, the reinforcing agent of 35-45 mesh 0.1-0.6 parts, 4-10 mesh and glass transition temperature are not less than assisted resin 1-2 parts of the substrate resin.
The substrate resin is high density polyethylene (HDPE).
The reinforcing agent is selected from barium sulfate, calcium carbonate, one or both of sodium sulphate and two or more arbitrary proportions Mixture.
The assisted resin is selected from one or both of PLA, makrolon, polyamide and two or more any ratios The mixture of example.
A kind of manufacture method of described resist delamination incubator shell, this method is, by the raw material one of above-mentioned parts by weight Secondary property is added in the rotational molding machine for installing mould, the rotational moulding 15-20min at 300-450 DEG C, and the resist delamination insulation is obtained after cooling Case shell.
The beneficial effects of the invention are as follows:The present invention adds substrate resin, reinforcing agent and particle diameter ratio base material tree with once feeding intake Fat is greatly and glass transition temperature is not less than the assisted resin of substrate resin, and the incubator shell inner side obtained after rotation molding is recessed Convex injustice, roughness is big, and bumps are evenly distributed everywhere, while the surface of incubator shell is still smooth;Filling-foam gathers It is strong with polyurathamc adhesive force after urethane;Increased weight outside turnout few, realize the lightweight of product;Shaping disposably feeds intake, and walks Rapid simple, production efficiency is high.
Embodiment
A kind of resist delamination incubator shell, is made up of the raw material of following parts by weight:100 parts of the substrate resin of 35-45 mesh, increase Strong agent 0.1-0.6 parts, 4-10 mesh and glass transition temperature are not less than assisted resin 1-2 parts of the substrate resin.
The substrate resin is high density polyethylene (HDPE).
The reinforcing agent is selected from barium sulfate, calcium carbonate, one or both of sodium sulphate and two or more arbitrary proportions Mixture.
The assisted resin is selected from one or both of PLA, makrolon, polyamide and two or more any ratios The mixture of example.
Increase explanation:In rotation molding, the small substrate resin part of particle diameter is taken the lead in, and the hot mould of contact is heated to be melted Melt to be adhered on mould and form the smooth outer surface of incubator shell, assisted resin is because its particle diameter is bigger than substrate resin, vitrifying Transition temperature is not less than substrate resin, thus melting is slower, uniformly mixes and is collectively forming outside incubator with remaining substrate resin The inner side of shell, assisted resin melting is incomplete, but is fixed by substrate resin, has benefited from this, and the inner side of incubator shell is concavo-convex Injustice, formation is millimetre-sized rugged, plus assisted resin using thermoplastic polars such as PLA, makrolon, polyamide Resin, with being all that to contact adhesive force strong for the polyurathamc of polar material, make obtained incubator that delamination not occur.Add auxiliary After resin, contrast and use substrate resin merely originally, mechanical property can change mends, it is necessary to add a small amount of reinforcing agent By force.
Embodiment 1
Resist delamination incubator shell is fabricated by the raw material of following weight proportion:Substrate resin selects the high-density polyethylene of 35 mesh 100 parts of alkene, reinforcing agent select 0.5 part of barium sulfate, and assisted resin selects 2 parts of the PLA of 6 mesh.
The manufacture method of the resist delamination incubator shell of embodiment 1 is disposably to add the raw material of above-mentioned parts by weight In the rotational molding machine for installing mould, the rotational moulding 16min at 400 DEG C, the resist delamination incubator shell is obtained after cooling.
Embodiment 2
Resist delamination incubator shell is fabricated by following raw materials in part by weight:Substrate resin selects the high density polyethylene (HDPE) of 45 mesh 100 parts, reinforcing agent selects 1 part of PLA, the poly- carbon of 2 purposes of 10 mesh from 0.1 part of calcium carbonate, 0.1 part of calcium carbonate, assisted resin 0.5 part of acid esters.
The manufacture method of the resist delamination incubator shell of embodiment 2 is disposably to add the raw material of above-mentioned parts by weight In the rotational molding machine for installing mould, the rotational moulding 20min at 390 DEG C, the resist delamination incubator shell is obtained after cooling.
Embodiment 3
Resist delamination incubator shell is fabricated by following raw materials in part by weight:Substrate resin selects the high density polyethylene (HDPE) of 40 mesh 100 parts, reinforcing agent is from 0.5 part of barium sulfate, 0.1 part of sodium sulphate, and assisted resin is from 0.5 part of polyamide, makrolon 0.5 Part.
The manufacture method of the resist delamination incubator shell of embodiment 3 is disposably to add the raw material of above-mentioned parts by weight In the rotational molding machine for installing mould, the rotational moulding 18min at 420 DEG C, the resist delamination incubator shell is obtained after cooling.
Each component in the various embodiments described above is product generally in the art, is not particularly limited, and is commercially available.
Experiment is compared:
Continuously made with the method for prior art, embodiment 1, embodiment 2 and embodiment 3, each method respectively by skilled worker worker Three incubator shells are made, record total time used in each method, and weigh high density polyethylene (HDPE) used in each incubator shell Charged material weight and gained incubator containment weight, calculate the percentage that additionally increases weight.
Pressure injecting glue is carried out to totally 12 incubator shells produced above, full polyurathamc is filled, waits to be solidified 24 After hour, incubator product is obtained.Divide fourth class branch with the width of gained incubator, by the vertical incubator of the fourth class branch Width cut, each incubator thus be divided into 4 pieces, obtain 6 face inner sections.It is poly- with foaming to all inner section inside holding case shells The engagement edge of urethane is observed, if incubator shell occur and being more than or equal to 2.00cm with polyurathamc separation length Judge that the part is bad, the quantity at bad place obtained by statistics each method.
Acquired results are as follows:
From experimental result, the incubator shell manufacture efficiency of the invention is high, and additionally weightening is few for the product of gained, can realize The lightweight of product, and delamination does not occur after filling-foam polyurethane.

Claims (5)

1. a kind of resist delamination incubator shell, it is characterised in that be made up of the raw material of following parts by weight:The substrate resin of 35-45 mesh 100 parts, reinforcing agent 0.1-0.6 parts, 4-10 mesh and glass transition temperature are not less than the assisted resin 1-2 of the substrate resin Part.
2. resist delamination incubator shell according to claim 1, it is characterised in that the substrate resin is high-density polyethylene Alkene.
3. resist delamination incubator shell according to claim 1, it is characterised in that the reinforcing agent is selected from barium sulfate, carbonic acid The mixture of one or both of calcium, sodium sulphate and two or more arbitrary proportions.
4. resist delamination incubator shell according to claim 1, it is characterised in that the assisted resin is selected from PLA, gathered The mixture of one or both of carbonic ester, polyamide and two or more arbitrary proportions.
A kind of 5. manufacture method of resist delamination incubator shell as described in claim 1-4 is any, it is characterised in that this method The raw material of above-mentioned parts by weight disposably to be added in the rotational molding machine for installing mould, the rotational moulding 15- at 300-450 DEG C 20min, the resist delamination incubator shell is obtained after cooling.
CN201710932517.8A 2017-10-10 2017-10-10 A kind of resist delamination incubator shell and its manufacture method Pending CN107814998A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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CN107814998A true CN107814998A (en) 2018-03-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109334141A (en) * 2018-09-12 2019-02-15 中山波利马塑胶科技有限公司 A kind of plate construction of incubator and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001012714A1 (en) * 1999-08-12 2001-02-22 The Dow Chemical Company Improved thermoplastic compositions for durable goods applications
WO2005115753A1 (en) * 2004-05-20 2005-12-08 Arkema Inc. Multi-layer rotational moulding
CN1713987A (en) * 2002-11-21 2005-12-28 托塔尔石油化学产品研究弗吕公司 Multilayer rotational moulding
CN100503195C (en) * 2006-08-28 2009-06-24 杭新宇 Manufacturing method of multilayer composite plastic storage tank

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001012714A1 (en) * 1999-08-12 2001-02-22 The Dow Chemical Company Improved thermoplastic compositions for durable goods applications
CN1713987A (en) * 2002-11-21 2005-12-28 托塔尔石油化学产品研究弗吕公司 Multilayer rotational moulding
WO2005115753A1 (en) * 2004-05-20 2005-12-08 Arkema Inc. Multi-layer rotational moulding
CN100503195C (en) * 2006-08-28 2009-06-24 杭新宇 Manufacturing method of multilayer composite plastic storage tank

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
郑春满: "《有机与高分子化学实验》", 31 May 2014 *
韦春: "《有机高分子材料实验教程》", 31 January 2009 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109334141A (en) * 2018-09-12 2019-02-15 中山波利马塑胶科技有限公司 A kind of plate construction of incubator and preparation method thereof
CN109334141B (en) * 2018-09-12 2023-11-10 中山波利马塑胶科技有限公司 Plate structure of insulation box and preparation method thereof

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Application publication date: 20180320