CN107807475A - Quantum feature board and preparation method thereof - Google Patents

Quantum feature board and preparation method thereof Download PDF

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Publication number
CN107807475A
CN107807475A CN201711075227.2A CN201711075227A CN107807475A CN 107807475 A CN107807475 A CN 107807475A CN 201711075227 A CN201711075227 A CN 201711075227A CN 107807475 A CN107807475 A CN 107807475A
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CN
China
Prior art keywords
quantum dot
polystyrene
quantum
substrate
feature board
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711075227.2A
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Chinese (zh)
Inventor
黄海涛
黄敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Rrich New Materials Ltd By Share Ltd
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Nantong Rrich New Materials Ltd By Share Ltd
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Publication date
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Priority to CN201711075227.2A priority Critical patent/CN107807475A/en
Publication of CN107807475A publication Critical patent/CN107807475A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/133614Illuminating devices using photoluminescence, e.g. phosphors illuminated by UV or blue light

Abstract

The invention discloses a kind of quantum feature board and preparation method thereof, quantum feature board includes substrate, and substrate is provided with coating layer;The coating layer is the cured layer after the epoxy glue coating of polystyrene and quantum dot;The substrate is three-decker form, and to be co-extruded in mould, baseplate material is transparent organic polymer plastic material, the three-decker, wherein added with diffusion particle or similar functionality material in one layer.Preparation method includes polystyrene and the colloid mixture of quantum dot makes, prepares the steps such as substrate, coating.Present invention lifting backlight packaging efficiency, promotes backlight mechanization assembling, saves cost.

Description

Quantum feature board and preparation method thereof
Technical field
The present invention relates to a kind of quantum feature board and preparation method thereof.
Background technology
The quantum film being conventionally used in backlight technology, typically uniformly mixes a certain proportion of quantum with specific glue Point, while levels are by Obstruct membrane(Main material is PET)Cladding fitting forms.Quantum dot is by a limited number of atom group Into three dimensions are in nanometer scale.Quantum dot is generally spherical or spherical, and stable diameter is received 2~20 nm's Rice corpuscles.It is the aggregate of atom on nanoscale and molecule, can be both made up of a kind of semi-conducting material, such as by IIB. Group VIA element or IIIA.VA races element composition, can also be made up of two or more semi-conducting material.Because of quantum dot It can not expose in atmosphere(Need to obstruct water and oxygen), cause the mode cost for being fabricated to film higher.Using to LCD TV In backlight module, while also need to and other optical modules(Diffuser plate/light guide plate, optical film)Carry out collocation use.
The content of the invention
It is an object of the invention to provide a kind of quantum function of lifting backlight packaging efficiency, promote backlight mechanization assembling Plate and preparation method thereof.
The present invention technical solution be:
A kind of quantum feature board, it is characterized in that:Including substrate, substrate is provided with coating layer;The coating layer be polystyrene and Cured layer after the epoxy glue coating of quantum dot;The substrate is three-decker form, and to be co-extruded in mould, baseplate material is Transparent organic polymer plastic material, the three-decker, wherein added with diffusion particle or similar functionality material in one layer;
Cured layer after the epoxy glue coating of the polystyrene and quantum dot is made up of following method:
The epoxy glue of the polystyrene made and quantum dot is passed through and is coated work into coating head/applicator roll for colloid system Industry, uniformly it is attached to substrate surface and forms a thin layer, substrate surface is then solidificated in by UV illumination or baking oven system.
The transparent organic polymer plastic material is PMMA, PS, PC, MS, PET, PP or its associated polymer.
The diffusion particle or similar functionality material are organosilicon, PMMA microballons or nanosized SiO_2/TiO2.
The three-decker does difference in functionality layer using different refractivity material, using the light law of refraction, to optical link Certain angle distribution is done in footpath, obtains the light of specific needs.
A kind of preparation method of quantum feature board, it is characterized in that:Comprise the following steps:
(1)The colloid mixture of polystyrene and quantum dot makes:
A) polystyrene microsphere is added into solvent, stirring swelling;Unsupported quantum dot is added, continues stirring and reaches uniform point Dissipate;After removing solvent using correlation techniques such as revolvings, the quantum dot of PS loads is obtained, is placed in mortar or grinder and is ground into powder End;
B) granules of polystyrene is dissolved in styrene monomer, and dissolving is stirred simultaneously, obtains viscous solution;
C) the quantum dot powder of PS loads is added into viscous solution, initiator is continuously added, is uniformly mixing to obtain colloid mixture;
(2)Prepare substrate:Substrate is three-decker, to be co-extruded in mould, is worked simultaneously by three extruders, three extrusions The material of molten condition is compound in mould in machine and then is extruded as an entirety by die orifice;
(3)The colloid mixture made passes through is coated operation for colloid system into coating head/applicator roll, is uniformly attached to substrate Surface forms a thin layer, is then solidificated in substrate surface by UV illumination or baking oven system.
Step(1)A) solvent described in is dichloromethane or toluene;The mass ratio of polystyrene microsphere and solvent is:0.5- 1:2;The addition of unsupported quantum dot is the 5 ~ 10% of above-mentioned polystyrene microsphere and solvent gross mass;Step(1)B) gather in The mass ratio of styrene pellets and styrene monomer is 0.5-1:1;Step(1)C) dosage for the quantum dot powder that PS is loaded is in The 10 ~ 15% of the viscous solution quality;The dosage of initiator is the 3 ~ 5% of the viscous solution quality;Initiator be 184, 907th, BP or TPO.
Advantages of the present invention:
1st, backlight packaging efficiency is lifted, diffuser plate and quantum film need to clean assembling respectively in down straight aphototropism mode set;
2nd, backlight mechanization assembling is promoted, the hardness property endured that backing material plate is brought makes quantum feature board completely can mechanical arm operation;
3rd, cost is saved, saves the Obstruct membrane cost that quantum film application is brought.
With reference to embodiment, the invention will be further described.
Embodiment
A kind of preparation method of quantum feature board, comprises the following steps:
(1)The colloid mixture of polystyrene and quantum dot makes:
A) polystyrene microsphere is added into solvent, stirring swelling;Unsupported quantum dot is added, continues stirring and reaches uniform point Dissipate;After removing solvent using correlation techniques such as revolvings, the quantum dot of PS loads is obtained, is placed in mortar or grinder and is ground into powder End;
B) granules of polystyrene is dissolved in styrene monomer, and dissolving is stirred simultaneously, obtains viscous solution;
C) the quantum dot powder of PS loads is added into viscous solution, initiator is continuously added, is uniformly mixing to obtain colloid mixture;
(2)Prepare substrate:Substrate is three-decker, to be co-extruded in mould, is worked simultaneously by three extruders, three extrusions The material of molten condition is compound in mould in machine and then is extruded as an entirety by die orifice;
(3)The colloid mixture made passes through is coated operation for colloid system into coating head/applicator roll, is uniformly attached to substrate Surface forms a thin layer, is then solidificated in substrate surface by UV illumination or baking oven system.
Step(1)A) solvent described in is dichloromethane or toluene;The mass ratio of polystyrene microsphere and solvent is:0.5- 1:2;The addition of unsupported quantum dot is the 5 ~ 10% of above-mentioned polystyrene microsphere and solvent gross mass;Step(1)B) gather in The mass ratio of styrene pellets and styrene monomer is 0.5-1:1;Step(1)C) dosage for the quantum dot powder that PS is loaded is in The 10 ~ 15% of the viscous solution quality;The dosage of initiator is the 3 ~ 5% of the viscous solution quality;Initiator be 184, 907th, BP or TPO.
Backing material plate mainly haves three layers structure, molten in 3 machines to be co-extruded in mould, it is necessary to 3 extruders while work The material for melting state is compound in mould and then be extruded as an entirety by die orifice.
Material in the 3-tier architecture, mainly it is made up of organic polymer plastic material, such material main performance requirements has: Water white transparency, impact resistance, very property, certain weatherability, such as currently used PMMA, PS, PC, MS, PET, PP material or its Associated polymer
Each layer embodies different features in 3-tier architecture, wherein one layer will add certain diffusion particle or the thing of similar functionality Matter, make have certain change to the opticpath of light emitting source during application, to reach certain effect covered with uniform light extraction.It is as usual The particle for the diffusion function seen:Organosilicon, PMMA microballons, nanosized SiO_2/TiO2 etc..
3-tier architecture can also do difference in functionality layer using different refractivity material, using the light law of refraction, to optical link Certain angle distribution is done in footpath, obtains the light of specific needs.Such as, low-index material is under, and high-index material is upper, under Surface, which enters angle of the light of light when from upper surface light extraction, to diminish, and can reach the effect of front optically focused, otherwise scattering process.
The Base Material of 3-tier architecture be may be the same or different, and thickness can be adjusted according to being actually needed.
The quantum dot being distributed in glue does not limit a certain system quantum dot, then design requirement is can reach after pretreatment It is defined.
This feature board can be extensively using in backlight and illuminating product.

Claims (6)

1. a kind of quantum feature board, it is characterized in that:Including substrate, substrate is provided with coating layer;The coating layer is polystyrene With the cured layer after the epoxy glue coating of quantum dot;The substrate is three-decker form, to be co-extruded in mould, baseplate material For transparent organic polymer plastic material, the three-decker, wherein added with diffusion particle or similar functionality thing in one layer Matter;
Cured layer after the epoxy glue coating of the polystyrene and quantum dot is made up of following method:
The epoxy glue of the polystyrene made and quantum dot is passed through and is coated work into coating head/applicator roll for colloid system Industry, uniformly it is attached to substrate surface and forms a thin layer, substrate surface is then solidificated in by UV illumination or baking oven system.
2. quantum feature board according to claim 1, it is characterized in that:The transparent organic polymer plastic material is PMMA, PS, PC, MS, PET, PP or its associated polymer.
3. quantum feature board according to claim 1 or 2, it is characterized in that:The diffusion particle or similar functionality material For organosilicon, PMMA microballons or nanosized SiO_2/TiO2.
4. quantum feature board according to claim 1 or 2, it is characterized in that:The three-decker utilizes different refractivity material Material does difference in functionality layer, and using the light law of refraction, certain angle distribution is done to opticpath, obtains the light of specific needs.
5. a kind of preparation method of the quantum feature board described in claim 1, it is characterized in that:Comprise the following steps:
(1)The colloid mixture of polystyrene and quantum dot makes:
A) polystyrene microsphere is added into solvent, stirring swelling;Unsupported quantum dot is added, continues stirring and reaches uniform point Dissipate;After removing solvent, the quantum dot of PS loads is obtained, is placed in mortar or grinder and smashes;
B) granules of polystyrene is dissolved in styrene monomer, and dissolving is stirred simultaneously, obtains viscous solution;
C) the quantum dot powder of PS loads is added into viscous solution, initiator is continuously added, is uniformly mixing to obtain colloid mixture;
(2)Prepare substrate:Substrate is three-decker, to be co-extruded in mould, is worked simultaneously by three extruders, three extrusions The material of molten condition is compound in mould in machine and then is extruded as an entirety by die orifice;
(3)The colloid mixture made passes through is coated operation for colloid system into coating head/applicator roll, is uniformly attached to substrate Surface forms a thin layer, is then solidificated in substrate surface by UV illumination or baking oven system.
6. the preparation method of quantum feature board according to claim 5, it is characterized in that:Step(1)A) solvent is described in Dichloromethane or toluene;The mass ratio of polystyrene microsphere and solvent is:0.5-1:2;The addition of unsupported quantum dot is Above-mentioned polystyrene microsphere and the 5 ~ 10% of solvent gross mass;Step(1)B) quality of granules of polystyrene and styrene monomer in Than for 0.5-1:1;Step(1)C) dosage for the quantum dot powder that PS is loaded is the 10 ~ 15% of the viscous solution quality in;Draw The dosage for sending out agent is the 3 ~ 5% of the viscous solution quality;Initiator is 184,907, BP or TPO.
CN201711075227.2A 2017-11-06 2017-11-06 Quantum feature board and preparation method thereof Pending CN107807475A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711075227.2A CN107807475A (en) 2017-11-06 2017-11-06 Quantum feature board and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201711075227.2A CN107807475A (en) 2017-11-06 2017-11-06 Quantum feature board and preparation method thereof

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CN107807475A true CN107807475A (en) 2018-03-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295045A (en) * 2018-03-23 2019-10-01 陈学仕 High efficiency light conversion material
CN114755861A (en) * 2022-06-15 2022-07-15 广东欧迪明光电科技股份有限公司 High-efficiency quantum dot optical substrate and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020164271A1 (en) * 2001-05-02 2002-11-07 Ho Winston Z. Wavelength-coded bead for bioassay and signature recogniton
CN1616342A (en) * 2004-12-09 2005-05-18 上海交通大学 Method for preparing fluorescent spectrum adjustable quantum dot nano composite particle
KR20110012246A (en) * 2009-07-30 2011-02-09 엘지이노텍 주식회사 Backlight unit
CN105259601A (en) * 2015-11-10 2016-01-20 合肥乐凯科技产业有限公司 Multi-layer quantum dot film and backlight module group
CN107115830A (en) * 2017-03-28 2017-09-01 南京林业大学 A kind of method that polymer microsphere is prepared based on high-pressure electrostatic ultrasonic atomizatio
CN107219684A (en) * 2017-07-26 2017-09-29 南通创亿达新材料股份有限公司 A kind of quantum feature board and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020164271A1 (en) * 2001-05-02 2002-11-07 Ho Winston Z. Wavelength-coded bead for bioassay and signature recogniton
CN1616342A (en) * 2004-12-09 2005-05-18 上海交通大学 Method for preparing fluorescent spectrum adjustable quantum dot nano composite particle
KR20110012246A (en) * 2009-07-30 2011-02-09 엘지이노텍 주식회사 Backlight unit
CN105259601A (en) * 2015-11-10 2016-01-20 合肥乐凯科技产业有限公司 Multi-layer quantum dot film and backlight module group
CN107115830A (en) * 2017-03-28 2017-09-01 南京林业大学 A kind of method that polymer microsphere is prepared based on high-pressure electrostatic ultrasonic atomizatio
CN107219684A (en) * 2017-07-26 2017-09-29 南通创亿达新材料股份有限公司 A kind of quantum feature board and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110295045A (en) * 2018-03-23 2019-10-01 陈学仕 High efficiency light conversion material
CN110295045B (en) * 2018-03-23 2022-03-15 陈学仕 High efficiency light conversion material
CN114755861A (en) * 2022-06-15 2022-07-15 广东欧迪明光电科技股份有限公司 High-efficiency quantum dot optical substrate and preparation method thereof
CN114755861B (en) * 2022-06-15 2023-01-06 广东欧迪明光电科技股份有限公司 High-efficiency quantum dot optical substrate and preparation method thereof

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Application publication date: 20180316