CN107805886A - A kind of graphene basalt fiber composite material and preparation method thereof - Google Patents
A kind of graphene basalt fiber composite material and preparation method thereof Download PDFInfo
- Publication number
- CN107805886A CN107805886A CN201711150791.6A CN201711150791A CN107805886A CN 107805886 A CN107805886 A CN 107805886A CN 201711150791 A CN201711150791 A CN 201711150791A CN 107805886 A CN107805886 A CN 107805886A
- Authority
- CN
- China
- Prior art keywords
- basalt fibre
- graphene
- basalt
- aqueous solution
- graphene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/005—Manufacture of flakes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/1095—Coating to obtain coated fabrics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/42—Coatings containing inorganic materials
- C03C25/44—Carbon, e.g. graphite
Abstract
The invention discloses a kind of graphene basalt fiber composite material and preparation method thereof, and the crosslinking to basalt fibre can be realized using the swelling and fusion of the graphite oxide ene coatings on basalt fibre surface.Graphene oxide, can be to the uniform coating of basalt fibre as sizing agent and crosslinking agent, and cross-linking process is quick and easy, and cross-link intensity is high.After further reduction, graphene oxide cross-linked layer is changed into graphene cross-linked layer, enhance the interaction between basalt fibre, reduce interfibrous contact resistance, so that basalt fibre shows excellent mechanical property and electrical and thermal conductivity, enhancing phase and differentiation fiber applications available for composite.It is this to be crosslinked the method for basalt fibre with very big researching value using graphene and be widely applied prospect.
Description
Technical field
The invention belongs to composite fibre field, more particularly to a kind of graphene-basalt fiber composite material and its preparation
Method.
Background technology
Basalt fibre is a kind of novel inorganic environment-friendly and green high performance fibre material, it be by silica, aluminum oxide,
The basalt building stones of the oxides such as calcium oxide, magnesia, iron oxide and titanium dioxide composition are fast by bushing after high-temperature fusion
Speed draws what is formed.Compared with glass fibre, basalt fibre not only has that mechanical strength is high, thermal conductivity factor is low and heatproof,
A series of excellent performances such as acid and alkali-resistance, heat-insulated, sound insulation, electric insulation, safe and non-toxic and own wt be light, but also with special
Use temperature range (- 260~700 DEG C).In addition, the production technology of basalt fibre determines that caused discarded object is few, it is right
Environmental pollution is small, and directly can be degraded in the environment after product abandonment, without any harm, thus is a kind of qualified green
Color, environment-friendly materials.China is classified as basalt fibre the big fiber of four given priority to, and (carbon fiber, aramid fiber, super high molecular weight are gathered
One of ethene, basalt fibre), realize industrialized production.Basalt continuous fiber is in fibre reinforced composites, friction
The many aspects such as material, shipbuilding materials, heat-barrier material, automobile industry, high temperature filtration fabric and protection field have obtained extensively
Application.However, the surface property of basalt fibre is poor, easy embrittlement, it is difficult to boundling and surface modification, and due to major part into
It is divided into silica, alkali resistance is bad, and application is poor when facing particular surroundings.
Graphene is a kind of two-dimentional carbon material with monoatomic layer thickness, has low-density, high mechanical strength, heat
Conductance and electrical conductivity and excellent corrosion resistance, and have preferable compatibility between basalt fibre, therefore utilize pure stone
Black alkene is crosslinked basalt fibre, and the boundling and non-woven fabrics of basalt fibre can be realized by non-melt means, can not only
The mechanical strength of maintenance basalt fibre, heat-resisting quantity, corrosion resistance well, and the electrical and thermal conductivity of material can be improved,
Overall proportion is reduced, can be used as the obturator of high-performance composite materials.
The profound of pure graphene crosslinking is prepared using graphene oxide swelling in a solvent and fusion in the present invention
Military rock fiber, the method compared to melting crosslinking can more preferably keep the intensity of basalt fibre in itself, compared to using other changes
Method crosslinking is more simple and easy, green.Due to graphene high conductivity in itself, high-termal conductivity, corrosion resistance etc.
Performance, after being coated to basalt fibre surface, basalt fibre electrical and thermal conductivity in itself and alkali resistance can be lifted, and
Due to the presence of graphene crosslinking, basalt fibre surface can form conductive and heat-conductive network, in the reinforcement for composite
Make more efficiently realize enhancing.
The content of the invention
Due to being difficult to boundling, alkali resistance is poor, and electrical and thermal conductivity is poor, and the application of existing basalt fibre receives limit
System.The purpose of the present invention is to be directed to existing technical deficiency, there is provided a kind of graphene-basalt fiber composite material and its preparation
Method.
The purpose of the present invention is achieved through the following technical solutions：A kind of graphene-basalt fiber composite material, stone
Black alkene is coated on basalt fibre surface, and basalt fibre surface is connected with graphene film by Van der Waals force and hydrogen bond.The Black Warrior
Crosslinking is realized by being coated on the graphene on surface between rock fiber, forms zero twisted yarn, non-woven fabrics or chopped mat.
A kind of preparation method of graphene-basalt fiber composite material, comprises the following steps：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10~30min, remove surface size
And finish, drying.
(2) surface coating is carried out to basalt fibre using graphene oxide dispersion, obtaining surface after drying is coated with
The basalt fibre of graphene oxide.
(3) basalt fibre for coating graphene oxide is placed in progress surface swelling in solvent, then merged fiber
The zero twisted yarn is formed after drying, or fiber is mutually overlapped and forms the non-woven fabrics or chopped mat after drying, dries temperature
Degree is less than 100 degrees Celsius.
(4) graphene-basalt fiber composite material is obtained after reducing.
Further, the concentration of graphene oxide dispersion is 7mg/g in the step (2), and dispersant is water, N, N- bis-
It is NMF, DMAC N,N' dimethyl acetamide, ethanol, ethylene glycol, 1-METHYLPYRROLIDONE, tetrahydrofuran, dimethyl sulfoxide, two sweet
Alcohol, pyridine, dioxane, butanone, isopropanol etc..
Further, basalt fibre is repeatedly coated using graphene oxide dispersion in the step (2), often
Dried after secondary coating, final dried graphene oxide thickness degree is 3 μm.
Further, solvent is water, methanol, ethanol, isopropanol, ethylene glycol, glycerine, diethylene glycol (DEG) in the step (3)
Deng the organic acids such as alcohols, formic acid, acetic acid, propionic acid, butyric acid, valeric acid, ethanedioic acid, malonic acid, succinic acid, acrylic acid, acetone, fourth
Ketone, N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, tetrahydrofuran, dimethyl sulfoxide, 1-METHYLPYRROLIDONE, pyridine, two
The ring of oxygen six, the aqueous solution of sodium chloride, the aqueous solution of calcium chloride, the aqueous solution of sodium nitrate, the aqueous solution of calcium nitrate, the water of sodium phosphate
Solution, the aqueous solution of potassium chloride, the aqueous solution of ammonium chloride, the aqueous solution of potassium hydroxide, sodium hydroxide the aqueous solution or these are molten
The mixed liquor of liquid.
Further, restoring method is to use hydroiodic acid, hydrazine hydrate, Vitamin C, sodium borohydride etc. in the step (4)
Chemical reducing agent is reduced or 100~600 DEG C of thermal reductions.
The beneficial effects of the present invention are：
(1) pure graphene is uniform as basalt fibre surface distributed, and interface adhesive strength is high, and immersion does not take off in a solvent
Fall.
(2) pure graphene is high as the cross-linking agents intensity of basalt fibre.Using graphene oxide in a solvent
Swelling fusion realizes the crosslinking of basalt fibre, and method is simple, time saving, and the solvent environmental protection of use, cross-linking effect is good, compares
Other cross-linking methods have very big application value.
The excellent mechanical property of basalt fibre can be kept using this cross-linking method, and improves its electric conductivity, it is corrosion-resistant
Property, thermal conductivity, so as to further expand the application of basalt fiber material.
Brief description of the drawings
Fig. 1 is the schematic diagram of the basalt fibre non-woven fabrics through graphene of the present invention crosslinking.
Fig. 2 is the non-twist fine schematic diagram of basalt fibre being crosslinked through graphene of the present invention.
Embodiment
The method for preparing graphene-basalt fiber composite material comprises the following steps：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10~30min, remove surface size
And finish, drying.(2) surface coating is carried out to basalt fibre using graphene oxide dispersion, surface painting is obtained after drying
It is covered with the basalt fibre of graphene oxide.The concentration of the graphene oxide dispersion is 7mg/g, and dispersant is water, N, N-
Dimethylformamide, DMAC N,N' dimethyl acetamide, ethanol, ethylene glycol, 1-METHYLPYRROLIDONE, tetrahydrofuran, dimethyl sulfoxide, two
Glycol, pyridine, dioxane, butanone, isopropanol etc..Basalt fibre is repeatedly applied using graphene oxide dispersion
Cover, dried every time after coating, drying temperature is about 25~200 DEG C, and final dried graphene oxide thickness degree is 3 μm.(3)
The basalt fibre for coating graphene oxide is placed in progress surface swelling in solvent, then fiber is merged and formed after drying
The zero twisted yarn, or fiber is mutually overlapped and forms the non-woven fabrics or chopped mat after drying, drying temperature is Celsius less than 100
Degree.The solvent is alcohols, formic acid, acetic acid, propionic acid, the fourths such as water, methanol, ethanol, isopropanol, ethylene glycol, glycerine, diethylene glycol (DEG)
The organic acids such as acid, valeric acid, ethanedioic acid, malonic acid, succinic acid, acrylic acid, acetone, butanone, N,N-dimethylformamide, N, N- bis-
Methylacetamide, tetrahydrofuran, dimethyl sulfoxide, 1-METHYLPYRROLIDONE, pyridine, dioxane, the aqueous solution of sodium chloride, chlorination
The aqueous solution of calcium, the aqueous solution of sodium nitrate, the aqueous solution of calcium nitrate, the aqueous solution of sodium phosphate, the aqueous solution of potassium chloride, ammonium chloride
The aqueous solution, the aqueous solution of potassium hydroxide, the mixed liquor of the aqueous solution of sodium hydroxide or these solution.(4) stone is obtained after reducing
Black alkene-basalt fiber composite material.The restoring method is to be changed using hydroiodic acid, hydrazine hydrate, Vitamin C, sodium borohydride etc.
Reducing agent is reduced or 100~600 DEG C of thermal reductions.
To realize the crosslinking of basalt fibre, graphene oxide is coated to basalt fibre surface by the present invention, aoxidizes stone
The hydroxyl of black alkene and basalt fibre forms hydrogen bond and van der Waals interaction, realizes uniformly firmly coating.Then make basalt fine
Dimension table layer graphene oxide is swelled in a solvent, and lamella obtains the larger free degree, when drying graphene oxide layer due to by
To the π-π active forces between the capillary force and lamella caused by solvent volatilization and spontaneous Close stack, therefore basalt fibre
It is cross-linked with each other, such as Fig. 1, shown in 2, finally gives graphene-basalt fiber composite material, including zero twisted yarn, non-woven fabrics or short
Cut felt etc..The basalt fibre of graphene crosslinking maintains the property such as the mechanical strength of basalt fibre itself, conduction, corrosion-resistant
Can, the thermal conductivity of basalt fibre is improved, there is very big actual application value.
The present invention is specifically described below by embodiment, the present embodiment is served only for doing further the present invention
It is bright, it is impossible to be interpreted as limiting the scope of the invention, those skilled in the art makes one according to the content of foregoing invention
A little nonessential changes and adjustment belong to protection scope of the present invention.
Non-woven fabrics tensile strength refers to national standard GBT 15232-1994.
Embodiment 1：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10min, remove surface size and oil
Agent, drying；
(2) the basalt fibre surface obtained using the aqueous dispersions of graphene oxide to step (1) is coated repeatedly
Dry, cycle-index is 15 times, obtains the basalt fibre that surface is coated with graphene oxide.Graphene oxide thickness degree is 3 μ
m；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in water and carries out surface swelling, then
Fiber is mutually overlapped and forms non-woven fabrics after drying, drying temperature is less than 100 degrees Celsius.
(4) the graphene oxide crosslinking basalt fibre that step (3) obtains is placed in the closed cauldron containing hydrazine hydrate, 80
Reduced 12 hours at DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, the unordered friendship of composite fibre are realized by being coated on the graphene on surface
It is folded to form nonwoven fabric construct, surface density 86.1g/m2, 6h intensity is soaked in fracture strength 3.24GPa, PH=12 alkali lye
Conservation rate is 89%, and conductance is 1.6 × 104S/m, thermal conductivity 29W/mK.
In addition, graphene oxide concentration and coating layer thickness are the optimal results obtained through repetition test.It can be seen by table 1
Go out, coat under same number, when the concentration of graphene oxide is 7mg/ml, graphite oxide ene coatings are on basalt fibre surface
Thickness is 3 μm, fracture strength, conductance, the thermal conductivity highest of obtained basalt fibre non-woven fabrics, and cross-linking effect is best.Oxygen
The concentration of graphite alkene is smaller, and thickness of the graphene oxide on basalt fibre surface is smaller, obtained basalt fibre nonwoven
Fracture strength, conductance, the thermal conductivity of cloth are smaller, and cross-linking effect is poorer.The concentration of graphene oxide is higher, and graphene oxide exists
Basalt fibre surface thickness is bigger, and thickness distribution is uneven, and cross-link intensity declines, and obtained basalt fibre non-woven fabrics breaks
Resistance to spalling, conductance, thermal conductivity reduce.
Embodiment 2：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10min, remove surface size and oil
Agent, drying；
(2) the basalt fibre table obtained using the N,N-dimethylformamide dispersion liquid of graphene oxide to step (1)
Face is coated drying repeatedly, and cycle-index is 13 times, obtains the basalt fibre that surface is coated with graphene oxide.Aoxidize stone
Black alkene thickness degree is 3 μm；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in water and carries out surface swelling, then
Fiber is mutually overlapped and forms non-woven fabrics after drying, drying temperature is less than 100 degrees Celsius.
(4) the graphene oxide crosslinking basalt fibre that step (3) obtains is placed in the closed cauldron containing hydrazine hydrate, 80
Reduced 12 hours at DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, the unordered friendship of composite fibre are realized by being coated on the graphene on surface
It is folded to form nonwoven fabric construct, surface density 85.2g/m2, 6h intensity is soaked in fracture strength 3.21GPa, PH=12 alkali lye
Conservation rate is 87%, and conductance is 1.3 × 104S/m, thermal conductivity 28W/mK.
Embodiment 3：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10min, remove surface size and oil
Agent, drying；
(2) the basalt fibre surface obtained using the alcohol dispersion liquid of graphene oxide to step (1) is applied repeatedly
Drying is covered, cycle-index is 16 times, obtains the basalt fibre that surface is coated with graphene oxide.Graphene oxide thickness degree is
3μm；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in water and carries out surface swelling, then
Fiber is mutually overlapped and forms non-woven fabrics after drying, drying temperature is less than 100 degrees Celsius.
(4) the graphene oxide crosslinking basalt fibre that step (3) obtains is placed in the closed cauldron containing hydroiodic acid, 90
Reduced 18 hours at DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, the unordered friendship of composite fibre are realized by being coated on the graphene on surface
It is folded to form nonwoven fabric construct, surface density 84.6g/m2, 6h intensity is soaked in fracture strength 3.23GPa, PH=12 alkali lye
Conservation rate is 85%, and conductance is 2.1 × 104S/m, thermal conductivity 27W/mK.
Embodiment 4：
(1) basalt long fiber arranged in parallel is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 20min, remove table
Face size and finish, drying；
(2) the basalt fibre surface obtained using the ethylene glycol dispersion liquid of graphene oxide to step (1) is carried out repeatedly
Drying is coated, cycle-index is 12 times, and it is fine to obtain basalt fibre length of the surface coated with graphene oxide.Graphene oxide layer
Thickness is 3 μm；
(3) the long fibre of basalt fibre for the coating graphene oxide that step (2) obtains is placed in ethylene glycol and carries out surface
Swelling, then fiber is merged and forms the zero twisted yarn after drying, drying temperature is less than 100 degrees Celsius, ethylene glycol is volatilized.
(4) the graphene oxide crosslinking basalt fibre length fibre that step (3) obtains is placed in the closed cauldron containing hydroiodic acid
In, reduced 18 hours at 90 DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, composite fibre parallel are realized by being coated on the graphene on surface
Row form non-twist fine structure, and it is 85% that 6h strength retentions are soaked in fracture strength 3.42GPa, PH=12 alkali lye, conductive
Rate is 3.9 × 104S/m, thermal conductivity 31W/mK.
Embodiment 5：
(1) basalt long fiber arranged in parallel is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 20min, remove table
Face size and finish, drying；
(2) the basalt fibre surface obtained using the aqueous dispersions of graphene oxide to step (1) is coated repeatedly
Dry, cycle-index is 15 times, obtains the basalt fibre that surface is coated with graphene oxide.Graphene oxide thickness degree is 3 μ
m；
(3) basalt fibre for the coating graphene oxide that step (2) obtains is placed in progress surface swelling in ethylene glycol,
Then fiber is merged and forms the zero twisted yarn after drying, drying temperature is less than 100 degrees Celsius, ethylene glycol is volatilized.
(4) the graphene oxide crosslinking basalt fibre length fibre that step (3) obtains is placed in the closed cauldron containing hydroiodic acid
In, reduced 18 hours at 90 DEG C.
Through above step, graphene coated passes through model on basalt fibre surface, basalt fibre surface with graphene film
De Huali connects with hydrogen bond.Between basalt fibre crosslinking, composite fibre parallel are realized by being coated on the graphene on surface
Row form non-twist fine structure, and it is 84% that 6h strength retentions are soaked in fracture strength 3.45GPa, PH=12 alkali lye, conductive
Rate is 4.4 × 104S/m, thermal conductivity 26W/mK.
Claims (6)
1. a kind of graphene-basalt fiber composite material, it is characterised in that graphene coated is profound on basalt fibre surface
Military rock fiber surface is connected with graphene film by Van der Waals force and hydrogen bond.By being coated on the stone on surface between basalt fibre
Black alkene realizes crosslinking, forms zero twisted yarn, non-woven fabrics or chopped mat.
2. a kind of preparation method of graphene-basalt fiber composite material, it is characterised in that comprise the following steps：
(1) basalt fibre is placed in toluene and is heated to 250 DEG C, be cleaned by ultrasonic 10~30min, remove surface size and oil
Agent, drying.
(2) surface coating is carried out to basalt fibre using graphene oxide dispersion, surface is obtained after drying coated with oxidation
The basalt fibre of graphene.
(3) basalt fibre for coating graphene oxide is placed in progress surface swelling in solvent, then merged fiber through dry
The zero twisted yarn is formed after dry, or fiber is mutually overlapped and forms the non-woven fabrics or chopped mat after drying, drying temperature is low
In 100 degrees Celsius.
(4) graphene-basalt fiber composite material is obtained after reducing.
3. according to the method for claim 2, it is characterised in that the concentration of graphene oxide dispersion in the step (2)
For 7mg/g, dispersant is water, DMF, DMA, ethanol, ethylene glycol, N- crassitudes
Ketone, tetrahydrofuran, dimethyl sulfoxide, diethylene glycol (DEG), pyridine, dioxane, butanone, isopropanol etc..
4. according to the method for claim 2, it is characterised in that graphene oxide dispersion pair is used in the step (2)
Basalt fibre is repeatedly coated, and is dried every time after coating, and final dried graphene oxide thickness degree is 3 μm.
5. according to the method for claim 2, it is characterised in that solvent is water, methanol, ethanol, isopropyl in the step (3)
The alcohols such as alcohol, ethylene glycol, glycerine, diethylene glycol (DEG), formic acid, acetic acid, propionic acid, butyric acid, valeric acid, ethanedioic acid, malonic acid, succinic acid,
The organic acids such as acrylic acid, acetone, butanone, N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, tetrahydrofuran, dimethyl sulfoxide,
1-METHYLPYRROLIDONE, pyridine, dioxane, the aqueous solution of sodium chloride, the aqueous solution of calcium chloride, the aqueous solution of sodium nitrate, nitre
The aqueous solution of sour calcium, the aqueous solution of sodium phosphate, the aqueous solution of potassium chloride, the aqueous solution of ammonium chloride, the aqueous solution of potassium hydroxide, hydrogen
The mixed liquor of the aqueous solution of sodium oxide molybdena or these solution.
6. according to the method for claim 2, it is characterised in that restoring method is to use hydroiodic acid, water in the step (4)
The chemical reducing agents such as conjunction hydrazine, Vitamin C, sodium borohydride are reduced or 100~600 DEG C of thermal reductions.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711150791.6A CN107805886A (en) | 2017-11-18 | 2017-11-18 | A kind of graphene basalt fiber composite material and preparation method thereof |
| US16/617,531 US11542411B2 (en) | 2017-05-27 | 2018-03-13 | Method for preparing composites on basis of graphene bonding |
| PCT/CN2018/078765 WO2018219008A1 (en) | 2017-05-27 | 2018-03-13 | Method for preparing composites on basis of graphene bonding |
| JP2019565907A JP6952134B2 (en) | 2017-05-27 | 2018-03-13 | Method of manufacturing composite material based on graphene adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711150791.6A CN107805886A (en) | 2017-11-18 | 2017-11-18 | A kind of graphene basalt fiber composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107805886A true CN107805886A (en) | 2018-03-16 |
Family
ID=61589597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711150791.6A Withdrawn CN107805886A (en) | 2017-05-27 | 2017-11-18 | A kind of graphene basalt fiber composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107805886A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108947376A (en) * | 2018-08-16 | 2018-12-07 | 北京天维宝辰化学产品有限公司 | A kind of cement mortar and preparation method thereof |
| CN109502996A (en) * | 2018-12-10 | 2019-03-22 | 中国科学院新疆理化技术研究所 | A kind of basalt fibre size and preparation method with conducting function |
| CN109825098A (en) * | 2019-01-29 | 2019-05-31 | 刘建军 | Modified heavy traffic paving asphalt and preparation method thereof |
| CN110372300A (en) * | 2019-07-26 | 2019-10-25 | 北京工业大学 | Make the finely dispersed fiber concrete preparation method of basalt fibre |
| CN110835844A (en) * | 2019-11-19 | 2020-02-25 | 中国第二重型机械集团德阳万航模锻有限责任公司 | Composite fiber cloth for forging of large press and preparation method and application thereof |
| CN113845756A (en) * | 2021-11-04 | 2021-12-28 | 西南石油大学 | Preparation method of basalt fiber composite material |
| CN113896470A (en) * | 2021-11-29 | 2022-01-07 | 安徽瑞联节能科技股份有限公司 | Cement-based thin felt for composite board and production process thereof |
| CN114658191A (en) * | 2022-04-08 | 2022-06-24 | 德阳聪源光电科技股份有限公司 | Flame-retardant heat-conducting wood floor with flame-retardant heat-conducting enhancement layer |
| CN116023046A (en) * | 2023-02-24 | 2023-04-28 | 中国科学院新疆理化技术研究所 | Organic-inorganic nano hybridization basalt fiber sizing agent and preparation method thereof |
| CN117264401A (en) * | 2023-11-22 | 2023-12-22 | 西南石油大学 | Preparation method of basalt fiber composite material with damage self-sensing and temperature-sensitive behaviors |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591551A (en) * | 2015-01-16 | 2015-05-06 | 东华大学 | Preparation method of graphene-coated glass fiber composite material |
| CN106948165A (en) * | 2017-04-28 | 2017-07-14 | 浙江大学 | A kind of graphene fiber of fusion certainly and preparation method thereof |
| CN107200867A (en) * | 2017-06-15 | 2017-09-26 | 中北大学 | Basalt fibre nano surface coats the preparation method and application of multi-scale reinforcing body |
| CN107254066A (en) * | 2017-06-15 | 2017-10-17 | 中北大学 | It is a kind of to prepare the method that graphene oxide is grafted basalt fibre multi-scale reinforcing body |
-
2017
- 2017-11-18 CN CN201711150791.6A patent/CN107805886A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591551A (en) * | 2015-01-16 | 2015-05-06 | 东华大学 | Preparation method of graphene-coated glass fiber composite material |
| CN106948165A (en) * | 2017-04-28 | 2017-07-14 | 浙江大学 | A kind of graphene fiber of fusion certainly and preparation method thereof |
| CN107200867A (en) * | 2017-06-15 | 2017-09-26 | 中北大学 | Basalt fibre nano surface coats the preparation method and application of multi-scale reinforcing body |
| CN107254066A (en) * | 2017-06-15 | 2017-10-17 | 中北大学 | It is a kind of to prepare the method that graphene oxide is grafted basalt fibre multi-scale reinforcing body |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108947376A (en) * | 2018-08-16 | 2018-12-07 | 北京天维宝辰化学产品有限公司 | A kind of cement mortar and preparation method thereof |
| CN109502996A (en) * | 2018-12-10 | 2019-03-22 | 中国科学院新疆理化技术研究所 | A kind of basalt fibre size and preparation method with conducting function |
| CN109825098B (en) * | 2019-01-29 | 2021-04-27 | 常德金牛通达沥青有限公司 | Modified heavy traffic asphalt and preparation method thereof |
| CN109825098A (en) * | 2019-01-29 | 2019-05-31 | 刘建军 | Modified heavy traffic paving asphalt and preparation method thereof |
| CN110372300B (en) * | 2019-07-26 | 2021-09-17 | 北京工业大学 | Preparation method of fiber concrete capable of uniformly dispersing basalt fibers |
| CN110372300A (en) * | 2019-07-26 | 2019-10-25 | 北京工业大学 | Make the finely dispersed fiber concrete preparation method of basalt fibre |
| CN110835844A (en) * | 2019-11-19 | 2020-02-25 | 中国第二重型机械集团德阳万航模锻有限责任公司 | Composite fiber cloth for forging of large press and preparation method and application thereof |
| CN113845756A (en) * | 2021-11-04 | 2021-12-28 | 西南石油大学 | Preparation method of basalt fiber composite material |
| CN113845756B (en) * | 2021-11-04 | 2023-09-05 | 西南石油大学 | Preparation method of basalt fiber composite material |
| CN113896470A (en) * | 2021-11-29 | 2022-01-07 | 安徽瑞联节能科技股份有限公司 | Cement-based thin felt for composite board and production process thereof |
| CN114658191A (en) * | 2022-04-08 | 2022-06-24 | 德阳聪源光电科技股份有限公司 | Flame-retardant heat-conducting wood floor with flame-retardant heat-conducting enhancement layer |
| CN116023046A (en) * | 2023-02-24 | 2023-04-28 | 中国科学院新疆理化技术研究所 | Organic-inorganic nano hybridization basalt fiber sizing agent and preparation method thereof |
| CN116023046B (en) * | 2023-02-24 | 2024-03-01 | 中国科学院新疆理化技术研究所 | Organic-inorganic nano hybridization basalt fiber sizing agent and preparation method thereof |
| CN117264401A (en) * | 2023-11-22 | 2023-12-22 | 西南石油大学 | Preparation method of basalt fiber composite material with damage self-sensing and temperature-sensitive behaviors |
| CN117264401B (en) * | 2023-11-22 | 2024-01-23 | 西南石油大学 | Preparation method of basalt fiber composite material with damage self-sensing and temperature-sensitive behaviors |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107805886A (en) | A kind of graphene basalt fiber composite material and preparation method thereof | |
| CN107761249A (en) | A kind of Graphene glass fibrous composite and preparation method thereof | |
| US11542411B2 (en) | Method for preparing composites on basis of graphene bonding | |
| US11486086B2 (en) | Self-fused graphene fiber and method of preparing the same | |
| Wu et al. | Silane modified MXene/polybenzazole nanocomposite aerogels with exceptional surface hydrophobicity, flame retardance and thermal insulation | |
| CN104211056B (en) | A kind of preparation method of high strength graphite alkene film | |
| CN113816720B (en) | PBO fiber product composite aerogel high-performance heat-insulating material and preparation method thereof | |
| CN105819426A (en) | Alkali lignin carbon nanometer microsphere as well as preparation method and application thereof | |
| CN107675488A (en) | A kind of graphene carbon SiClx fibrous composite and preparation method thereof | |
| CN111057266A (en) | Aramid nanofiber/nanocellulose aerogel and preparation method thereof | |
| CN113150337A (en) | Regenerated cellulose membrane based on phosphoric acid solution and preparation method thereof | |
| CN103174053A (en) | Production method for aramid fiber 1414 paper substrate material | |
| CN107815789A (en) | A kind of graphene quartz fibre composite and preparation method thereof | |
| CN107151919A (en) | Fire-retardant cord fabric of graphene and preparation method thereof | |
| Sun et al. | Micron down feather fibers reinforced cellulose composite aerogel with excellent acoustic and thermal insulation | |
| CN110130101B (en) | Method for modifying surface function of meta-aramid fabric | |
| CN107858777A (en) | A kind of graphene alumina fibre composite and preparation method thereof | |
| CN106757526A (en) | A kind of polyether sulfone strengthens special basalt fibre and preparation method thereof | |
| CN105968622A (en) | Lightweight high-strength polyvinyl chloride foam tube | |
| CN107869047A (en) | A kind of graphene boron-nitride fibre composite and preparation method thereof | |
| CN113583270A (en) | High-electric-conductivity and high-heat-conductivity bacterial cellulose/graphene composite paper and preparation method thereof | |
| CN107936804A (en) | A kind of cold lead ingot granulator surface coating | |
| CN105968607A (en) | Polyvinyl chloride foam tube with long service life | |
| CN108864780A (en) | A kind of crack resistence inorganic sealing hole agent | |
| CN111635128A (en) | Preparation method of high-strength cold-resistant modified glass wool fiber material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180316 |