CN107805315A - A kind of plastics after plastic processing methods and processing - Google Patents
A kind of plastics after plastic processing methods and processing Download PDFInfo
- Publication number
- CN107805315A CN107805315A CN201710961309.0A CN201710961309A CN107805315A CN 107805315 A CN107805315 A CN 107805315A CN 201710961309 A CN201710961309 A CN 201710961309A CN 107805315 A CN107805315 A CN 107805315A
- Authority
- CN
- China
- Prior art keywords
- inorganic ceramic
- coating
- processing methods
- frosting
- plastic processing
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 44
- 239000004033 plastic Substances 0.000 title claims abstract description 44
- 238000003672 processing method Methods 0.000 title claims abstract description 16
- 238000012545 processing Methods 0.000 title claims abstract description 6
- 238000005524 ceramic coating Methods 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000000919 ceramic Substances 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 239000003973 paint Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 238000003618 dip coating Methods 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- 238000007761 roller coating Methods 0.000 claims description 4
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000005488 sandblasting Methods 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- 235000019589 hardness Nutrition 0.000 description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000009832 plasma treatment Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
The present invention relates to the plastics after a kind of plastic processing methods and processing, plastic processing methods A, in the frosting coating nanometer inorganic ceramic paint.Nano inorganic ceramic coating has inorganic ceramic performance, can significantly improve the shortcomings of frosting hardness is low, not wear-resisting, UV resistant is poor, the resistance to temperature difference, solvent resistant difference.Ceramic plastic material after preparation had both had the characteristics of low common plastic cost, in light weight, toughness, shock resistance is good, Corrosion Protection is excellent, ornamental high, had the advantages of inorganic ceramic coating hardness is high, weather resistance is good, solvent resistant and chemicals performance are good, wearability is good again.
Description
Technical field
The invention belongs to plastics, coating application field, and in particular to the plastics after a kind of plastic processing methods and processing.
Background technology
Plastics are the materials commonly used in modern industry, and the shell of such as many industrial products is manufactured from plastic, but due to
The shortcomings of case hardnesses of plastics is low, not wear-resisting, UV resistant is poor, the resistance to temperature difference, solvent resistant difference, therefore, its application is also by one
Fixed limitation, if require high to hardness, wear-resisting, UV resistant, heatproof, solvent resistant etc., plastic production cannot be used.
The content of the invention
The present invention provides plastic processing methods, and to solve, existing frosting hardness is low, not wear-resisting, UV resistant is poor, resistance to
The technical problem of the temperature difference, solvent resistant difference.
In order to solve the above technical problems, the present invention adopts the technical scheme that：
A kind of plastic processing methods, it is characterized in that, A, in the frosting coating nanometer inorganic ceramic paint.
Also followed the steps below before the step A is carried out：A, the frosting is handled, in order to described
Nano inorganic ceramic coating is coated to the frosting.
Processing is carried out to the frosting includes plasma treatment, mechanical-physical surface sand-blasting, grinding process.
The thickness of the nano inorganic ceramic coating is 10-100um, and the application pattern is spraying, roller coating or dip-coating.
After the completion of the step A, also follow the steps below：B, to being coated to the nano inorganic ceramic coating of frosting
Coating is solidified.
The solidification temperature is normal temperature or 50-200 DEG C.
The mixing nano inorganic ceramic coating is obtained by mixing and curing nano inorganic ceramic coating.
The nano inorganic ceramic coating is selected from：By silica or by silica and aluminum oxide, carborundum, oxygen
Change the mixture of one or more compositions composition in zirconium, polyester, acrylic resin.
The nano inorganic ceramic coating constituent is：Silica 30-100%, aluminum oxide 0-50%, carborundum 0-
30%, zirconium oxide 0-30%, polyester 0-30%, acrylic resin 0-30%.
The present invention also provides a kind of plastics, it is characterized in that, it is provided with the frosting at any of the above-described method
Manage obtained mixing nano inorganic ceramic coating layer.
After above-mentioned technical proposal is employed, due in the frosting coating nanometer inorganic ceramic paint.Inorganic pottery
Porcelain coating has many unique performances, for example, high-weatherability, has excellent ultravioletlight screening, the long Kubo of gloss of film
Hold, be not efflorescence, non-degradable；Property easy to clean, surface is smooth, is produced without electrostatic, therefore is not easy to adsorb dust, and a small amount of dust rainwater is
It is flushable clean；Excellent adhesive force, there is good attachment on inorganic, metal and part organic substrate, produce firmization
Learn key；High temperature resistant and non-flammability, coating structure are inorganic, are mainly crosslinked film forming with inorganic chemistry key, can for a long time resistance to 600
DEG C and keep stable, while meet fire and do not burn, no toxic gas produces；Corrosion of chemicals-resistant and chemical solvent etc., each
State-owned wide purposes, such as communal facility, household electrical appliance, ship, military project and chemical anticorrosion field.Except above advantage without
Machine ceramic coating has excellent case hardness, and film forming matter is mainly inorganic nanometer oxide, and it is hard can to significantly improve frosting
Spend the shortcomings of low, not wear-resisting, UV resistant is poor, the resistance to temperature difference, solvent resistant difference.Solve existing frosting hardness it is low, it is not wear-resisting,
UV resistant is poor, the technical problem of the resistance to temperature difference, solvent resistant difference.
Secondly as also followed the steps below before the step A is carried out：A, the frosting is handled,
In order to which the nano inorganic ceramic coating is coated to the frosting, it can greatly increase between coating and plastics and adhere to
Power.
Embodiment
Embodiment one
A kind of hardening technology of frosting ceramic, specifically completed according to following steps：
First, plastics are surface-treated.
2nd, mix and cure nano inorganic ceramic coating.
3rd, frosting ceramic, i.e., in frosting coating nanometer inorganic ceramic paint.
4th, curing of coatings coating thickness is 10-100 microns.
Application pattern can be spraying, roller coating or dip-coating.Present embodiment can significantly improve frosting hardness it is low, intolerant to
The shortcomings of mill, UV resistant are poor, the resistance to temperature difference, solvent resistant difference.
Embodiment two
The difference of present embodiment and embodiment one is：Being directed at inorganic ceramic paint described in step 1
Surface treatment mode before reason plastics includes：Plasma treatment, mechanical-physical surface sand-blasting, polishing mode.Other and specific reality
It is identical to apply mode one
Embodiment three
Present embodiment is with one of embodiment one or two difference：Coating described in step 2 is in the market
The inorganic ceramic paint of two-component or more components.Other are identical with embodiment one or two.
Embodiment four
Present embodiment is with one of embodiment one to three difference：Inorganic ceramic paint described in step 2
Composition is silica 30-100%, aluminum oxide 0-50%, zirconium oxide 0-30%, carborundum 0-30%, polyester 0-30%, propylene
Acid resin 0-30%.Other are identical with embodiment one to three.
Embodiment five
Present embodiment is with one of embodiment one to four difference：In step 3 before inorganic ceramic paint use
After several components must being mixed into curing, frosting is coated in by modes such as spraying, roller coating, brushing or dip-coatings.Other with
Embodiment one to four is identical.
Embodiment six
Present embodiment is with one of embodiment one to five difference：Step 4 kind solidification temperature be normal temperature or
Film-forming at 50-200 DEG C.Other are identical with embodiment one to five.
The present invention is described in further detail with reference to specific embodiment, but it is not as a limitation of the invention.
Specific embodiment 1：ABS plastic surface hardening.Specifically operate according to the following steps.
First, ABS plastic surface is subjected to plasma treatment.
2nd, nano inorganic ceramic coating is mixed evenly.
3rd, after plasma treatment within two hours, nano inorganic ceramic coating is coated in by way of aerial spraying
ABS surface.
4th, after the curing be complete, coating thickness is 50 microns.
Specific embodiment 2：PC plastic surface hardening.Specifically operate according to the following steps.
First, PC plastic surface is subjected to mechanical-physical blasting treatment.
2nd, nano inorganic ceramic coating is mixed evenly.
3rd, nano inorganic ceramic coating is coated in frosting by way of dip-coating.
4th, after the curing be complete, coating thickness is 30 microns.
Specific embodiment 3：PBT plastic surface hardening.Specifically operate according to the following steps.
First, PBT plastic surface is subjected to grinding process.
2nd, nano inorganic ceramic coating is mixed evenly.
3rd, the nano inorganic ceramic coating mixed is coated in frosting by way of spraying.
4th, after the curing be complete, coating thickness is 80 microns.
Using following verification experimental verifications effect of the present invention
The surface ceramic deposition plastics of the ABS plastic surface hardening being applied to obtained in specific embodiment 1, its experimental method
And performance is as listed by table one：
Table one
The surface ceramic deposition plastics applied to PC plastic surface hardening obtained in specific embodiment 2, its experimental method and
Performance is as listed by table two：
Table two
The surface ceramic deposition plastics applied to PBT plastic surface hardening obtained in specific embodiment 3, its experimental method and
Performance is as listed by table three：
Table three
Test result understands that the hardness of three kinds of plastics plastics increases after surface ceramic deposition, while the wearability of plastics
It can significantly improve, the adhesive force of coating is preferable, and heatproof is water-based, resistance to xylene solvent immersion and resistance to butanone are cleaned.
Disclosed above is only several specific embodiments of the present invention, but the present invention is not limited to this, any ability
What field technique personnel can think change should all fall into protection scope of the present invention.
Claims (10)
1. a kind of plastic processing methods, it is characterized in that, A, in the frosting coating nanometer inorganic ceramic paint.
2. plastic processing methods according to claim 1, it is characterized in that, also carried out before the step A is carried out following
Step：A, the frosting is handled, in order to which the nano inorganic ceramic coating is coated to the frosting.
3. plastic processing methods according to claim 2, it is characterized in that, the frosting is carried out processing include grade from
Subprocessing, mechanical-physical surface sand-blasting, grinding process.
4. plastic processing methods according to claim 2, it is characterized in that, the thickness of the nano inorganic ceramic coating is
10-100um, the application pattern are spraying, roller coating or dip-coating.
5. according to the plastic processing methods described in claim 1 or 2 or 3, it is characterized in that, after the completion of the step A, also carry out
Following steps：B, the nano inorganic ceramic coating coating for being coated to frosting is solidified.
6. plastic processing methods according to claim 4, it is characterized in that, the solidification temperature is normal temperature or 50-200
℃。
7. according to the plastic processing methods described in claim 1 or 2 or 3, it is characterized in that, the mixing nano inorganic ceramic coating
Obtained by mixing and curing nano inorganic ceramic coating.
8. plastic processing methods according to claim 6, it is characterized in that, the nano inorganic ceramic coating is selected from：By
Silica or by silica and aluminum oxide, carborundum, zirconium oxide, polyester, acrylic resin it is one or more into
The mixture being grouped.
9. plastic processing methods according to claim 7, it is characterized in that, the nano inorganic ceramic coating constituent
For：Silica 30-100%, aluminum oxide 0-50%, carborundum 0-30%, zirconium oxide 0-30%, polyester 0-30%, acrylic acid
Resin 0-30%.
10. a kind of plastics, it is characterized in that, either method described in claim 1-8 is provided with the frosting and is handled
Obtained mixing nano inorganic ceramic coating layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710961309.0A CN107805315A (en) | 2017-10-17 | 2017-10-17 | A kind of plastics after plastic processing methods and processing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710961309.0A CN107805315A (en) | 2017-10-17 | 2017-10-17 | A kind of plastics after plastic processing methods and processing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107805315A true CN107805315A (en) | 2018-03-16 |
Family
ID=61591516
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710961309.0A Pending CN107805315A (en) | 2017-10-17 | 2017-10-17 | A kind of plastics after plastic processing methods and processing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107805315A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535461A (en) * | 2018-11-30 | 2019-03-29 | 成都其其小数科技有限公司 | A kind of preparation method of the gradient flame retardant coating for frosting |
| CN112644132A (en) * | 2020-12-24 | 2021-04-13 | 嘉兴领科材料技术有限公司 | High-hardness and high-weather-resistance polycarbonate composite board with excellent impact resistance and preparation method thereof |
| CN112691873A (en) * | 2020-12-09 | 2021-04-23 | 东莞仁海科技股份有限公司 | Plastic surface ceramic technology |
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| JP2002322389A (en) * | 2001-04-24 | 2002-11-08 | Sumio Tanabe | Manufacturing method for multifunctional ceramic coating film-forming material curable at low temperature and forming method for multifunctional ceramic coating film curable at low temperature |
| CN1664023A (en) * | 2004-03-04 | 2005-09-07 | 李力锋 | Preparation of vitreous far-infrared ceramic film coating |
| CN106349926A (en) * | 2016-09-30 | 2017-01-25 | 陈业新 | Water-based nano ceramic composite coating and coating method thereof |
| CN106583204A (en) * | 2016-12-14 | 2017-04-26 | 佛山市宜用新材料科技有限公司 | Inorganic fireproof plate and surface treatment method thereof |
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2017
- 2017-10-17 CN CN201710961309.0A patent/CN107805315A/en active Pending
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| JP2002322389A (en) * | 2001-04-24 | 2002-11-08 | Sumio Tanabe | Manufacturing method for multifunctional ceramic coating film-forming material curable at low temperature and forming method for multifunctional ceramic coating film curable at low temperature |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535461A (en) * | 2018-11-30 | 2019-03-29 | 成都其其小数科技有限公司 | A kind of preparation method of the gradient flame retardant coating for frosting |
| CN112691873A (en) * | 2020-12-09 | 2021-04-23 | 东莞仁海科技股份有限公司 | Plastic surface ceramic technology |
| CN112644132A (en) * | 2020-12-24 | 2021-04-13 | 嘉兴领科材料技术有限公司 | High-hardness and high-weather-resistance polycarbonate composite board with excellent impact resistance and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180316 |
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