CN107793830A - A kind of quick-dry type environmental protection rotary ink and preparation method - Google Patents

A kind of quick-dry type environmental protection rotary ink and preparation method Download PDF

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Publication number
CN107793830A
CN107793830A CN201610781552.XA CN201610781552A CN107793830A CN 107793830 A CN107793830 A CN 107793830A CN 201610781552 A CN201610781552 A CN 201610781552A CN 107793830 A CN107793830 A CN 107793830A
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CN
China
Prior art keywords
ink
quick
environmental protection
oil
dry type
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Pending
Application number
CN201610781552.XA
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Chinese (zh)
Inventor
丁艳丽
黄雯
李昊翔
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TIANJIN ANGEL CHEMICALS GROUP CO Ltd
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TIANJIN ANGEL CHEMICALS GROUP CO Ltd
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Priority to CN201610781552.XA priority Critical patent/CN107793830A/en
Publication of CN107793830A publication Critical patent/CN107793830A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/06—Printing inks based on fatty oils
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/08—Printing inks based on natural resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention provides a kind of quick-dry type environmental protection rotary ink and preparation method, and ink raw materials include modified resin oil mixture, mineral oil solvent, pigment, ultrafine calcium and dispersant, and wherein modified resin oil mixture is the modified hybrid resin of butch flax oil.The beneficial effects of the invention are as follows：Rosin denaturation thermoplastic resin is thermosetting resin, can improve rapid draing performance；Butch flax oil and the advance of rosin denaturation thermoplastic resin combine processing, the mechanical performance of ink can be improved, make that ink adhesive force on newspaper is strong, film forming is hard, wearability is good, is not easy set-off, linseed oil can improve the mobility of ink again, in addition linseed oil platymiscium oil, substitute part petroleum solvent as diluent, resource can be saved, the market competitiveness is improved, can not only reduce the harm of ink print can also reduce the generation of harmful substance in ink manufacturing process, be easy to degrade.

Description

A kind of quick-dry type environmental protection rotary ink and preparation method
Technical field
The invention belongs to ink print field, more particularly, to a kind of quick-dry type environmental protection rotary ink and preparation method.
Background technology
Printing-ink is made up of pigment, link stuff and auxiliary agent etc., is mainly used in books and periodicals, packing and decorating, building decoration etc. Various printings, as social demand increases, ink kind and yield also respective extension and growth.The U.S. is maximum ink in the world Producing country and country of consumption, Japan take second place, and Germany the 3rd, China occupies the 4th.With economic development, the flourishing band of press-packaging industry The manufacturing Fast Growth of ink is moved, current domestic ink industry size is just maintained sustained and rapid growth with more than 10% speed. The solvent-based ink used in heat cure offset lithographic rotary press that China introduces contains up to 35-42% petroleum solvents, this A little solvents are mainly made up of alkane and 10-30% aromatic hydrocarbons, and the hazardous solvent concentration that can cause to print place exceedes permitting deformation, Hair is also sent out exceeded by printed matter surface hazardous solvent residual quantity；In addition, traditional solvent-based ink is mostly the components such as phenolic aldehyde, alkyd For resin as main link stuff, such product can discharge harmful gas such as harmful phenol, formaldehyde in printing process Body.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of quick-dry type environmental protection rotary ink and preparation method.
The technical solution adopted by the present invention is：A kind of quick-dry type environmental protection rotary ink, ink raw materials include modified resin oil Mixture, mineral oil solvent, pigment, ultrafine calcium and dispersant.
Preferably, modified resin oil mixture is the modified hybrid resin of butch flax oil, the compound tree that butch flax oil is modified Fat preparation method is：Butch flax oil is preheating to 110 DEG C, phenolic resin is added and KH-570 continues to be uniformly mixed, mix Add rosin denaturation thermoplastic resin after uniformly to continue to be uniformly mixed, obtained well mixed solution is butch flax oil Modified hybrid resin.
Preferably, phenolic resin addition is 17-24%.
Preferably, KH-570 additions are 1-5%.
Preferably, rosin denaturation thermoplastic resin addition is 28-40%.
A kind of preparation method of quick-dry type environmental protection rotary ink, each component mass fraction are：Modified resin oil mixture 55- 62 parts, mineral oil solvent 5-10 parts, pigment 15-20 parts, ultrafine calcium 20-25 parts, dispersant 1-2 parts, preparation method is as follows：
Modified resin oil mixture and mineral oil solvent are added in pill tank by step 1, normal temperature stirring at low speed 60- 90min, stand 30min；
Step 2 adds pigment, ultrafine calcium and dispersant, stirs while heat up, during one section of keeping temperature stirring at low speed Between after stir while being cooled to room temperature；
Step 3 grinds the material of mixing with sand mill, and quick-dry type environmental protection rotary ink is made.
Preferably, 75-90 DEG C is warming up in step 2, is kept stirring for 35-40min.
Preferably, obtained quick-dry type environmental protection rotary ink measure viscosity is 25-40sec/25 DEG C, release property >=2.5ml/ 2g, pH value 8.5-9.0.
The present invention has the advantages and positive effects of：Rosin denaturation thermoplastic resin is thermoplastic resin, can be improved Rapid draing performance；The advance mechanicalness for combining processing, ink being improved of butch flax oil and rosin denaturation thermoplastic resin Can, make that ink adhesive force on newspaper is strong, film forming is hard, wearability is good, is not easy set-off, linseed oil can improve ink again Mobility, linseed oil platymiscium oil, substitutes part petroleum solvent as diluent, can save resource, it is competing to improve market in addition Power is striven, can not only reduce the harm of ink print can also reduce the generation of harmful substance in ink manufacturing process, be easy to degrade.
Embodiment
The present invention provides a kind of quick-dry type environmental protection rotary ink and preparation method.
Quick-dry type environmental protection rotary ink each component and mass fraction are as follows：
Modified resin oil mixture 55-62 parts, the hybrid resin that modified resin oil mixture is modified for butch flax oil, flax The modified hybrid resin preparation method of mustard oil is：Butch flax oil is preheating to 110 DEG C, adds 17-24% phenolic resin and 1-5% KH-570 continues to be uniformly mixed, and 28-40% rosin denaturation thermoplastic resin is added after well mixed and continues to be stirred Even, obtained well mixed solution is the modified hybrid resin of butch flax oil；
Mineral oil solvent 5-10 parts, selected low fragrant solvent D110 kerosene to replace common rotation, 310# kerosene and 23# it is molten Agent oil, to reduce arene content, meet the requirement of environmental protection；
Pigment 15-20 parts；
Ultrafine calcium 20-25 parts, ultrafine calcium use 1000-3000 mesh；
Dispersant 1-2 parts, using A4300；
Ink preparation method is as follows：
Modified resin oil mixture and mineral oil solvent are added in pill tank by step 1, normal temperature stirring at low speed 60- 90min, stand 30min；
Step 2 adds pigment, ultrafine calcium and dispersant, stirs while be warming up to 75-90 DEG C, keeping temperature low speed Stirred after stirring 35-40min while being cooled to room temperature；
Step 3 grinds the material of mixing with sand mill, and quick-dry type environmental protection rotary ink is made.
Obtained quick-dry type environmental protection rotary ink measure viscosity is 25-40sec/25 DEG C, release property >=2.5ml/2g, pH value For 8.5-9.0.
Rosin denaturation thermoplastic resin can improve rapid draing performance；Butch flax oil and rosin are denatured thermoplastic resin Processing is combined in advance, can improve the mechanical performance of ink, makes that ink adhesive force on newspaper is strong, film forming is hard, wearability is good Well, set-off being not easy, linseed oil can improve the mobility of ink again,
Other linseed oil platymiscium oil, substitutes part petroleum solvent as diluent, so as to reduce the volatilization of printing-ink Property organic matter component, reduce the pollution to atmospheric environment, and resource can be saved, improve the market competitiveness, can not only reduce The harm of ink print can also reduce the generation of harmful substance in ink manufacturing process, and ink made of linseed oil easily takes off Ink, and be easily degraded by microorganisms, and its lubricity is good, relative to traditional ink, beans oil-based ink should in environmental protection and printing There is multinomial technical advantage with aspect.
Embodiment 1：
A kind of quick-dry type environmental protection rotary ink and preparation method.
Quick-dry type environmental protection rotary ink each component and mass fraction are：55 parts of modified resin oil mixture, mineral oil solvent 5 Part, 15 parts of pigment, 20 parts of ultrafine calcium, 1 part of dispersant.
Modified resin oil mixture preparation method is：Butch flax oil is preheating to 110 DEG C, add 17% phenolic resin and 1%KH-570 continues to be uniformly mixed, and 28% rosin denaturation thermoplastic resin is added after well mixed and continues to be stirred Even, obtained well mixed solution is the modified hybrid resin of butch flax oil.
Ink preparation method is as follows：
Modified resin oil mixture and mineral oil solvent are added in pill tank by step 1, normal temperature stirring at low speed 60min, Stand 30min；
Step 2 adds pigment, ultrafine calcium and dispersant, stirs while be warming up to 75 DEG C, keeping temperature stirring at low speed Stirred after 35min while being cooled to room temperature；
Step 3 grinds the material of mixing with sand mill, and quick-dry type environmental protection rotary ink is made.
Obtained quick-dry type environmental protection rotary ink measure viscosity is 25sec/25 DEG C, release property >=2.5ml/2g, and pH value is 8.5。
Embodiment 2：
A kind of quick-dry type environmental protection rotary ink and preparation method.
Quick-dry type environmental protection rotary ink each component and mass fraction are：62 parts of modified resin oil mixture, mineral oil solvent 10 parts, 20 parts of pigment, 25 parts of ultrafine calcium, 2 parts of dispersant.
Modified resin oil mixture preparation method is：Butch flax oil is preheating to 110 DEG C, add 24% phenolic resin and 5%KH-570 continues to be uniformly mixed, and 40% rosin denaturation thermoplastic resin is added after well mixed and continues to be stirred Even, obtained well mixed solution is the modified hybrid resin of butch flax oil.
Ink preparation method is as follows：
Modified resin oil mixture and mineral oil solvent are added in pill tank by step 1, normal temperature stirring at low speed 90min, Stand 30min；
Step 2 adds pigment, ultrafine calcium and dispersant, stirs while be warming up to 90 DEG C, keeping temperature stirring at low speed Stirred after 40min while being cooled to room temperature；
Step 3 grinds the material of mixing with sand mill, and quick-dry type environmental protection rotary ink is made.
Obtained quick-dry type environmental protection rotary ink measure viscosity is 40sec/25 DEG C, release property >=2.5ml/2g, and pH value is 9.0。
Embodiment 3：
A kind of quick-dry type environmental protection rotary ink and preparation method.
Quick-dry type environmental protection rotary ink each component and mass fraction are：60 parts of modified resin oil mixture, mineral oil solvent 8 Part, 18 parts of pigment, 22 parts of ultrafine calcium, 1.5 parts of dispersant.
Modified resin oil mixture preparation method is：Butch flax oil is preheating to 110 DEG C, add 20% phenolic resin and 3%KH-570 continues to be uniformly mixed, and 35% rosin denaturation thermoplastic resin is added after well mixed and continues to be stirred Even, obtained well mixed solution is the modified hybrid resin of butch flax oil.
Ink preparation method is as follows：
Modified resin oil mixture and mineral oil solvent are added in pill tank by step 1, normal temperature stirring at low speed 80min, Stand 30min；
Step 2 adds pigment, ultrafine calcium and dispersant, stirs while be warming up to 85 DEG C, keeping temperature stirring at low speed Stirred after 38min while being cooled to room temperature；
Step 3 grinds the material of mixing with sand mill, and quick-dry type environmental protection rotary ink is made.
Obtained quick-dry type environmental protection rotary ink measure viscosity is 32sec/25 DEG C, release property >=2.5ml/2g, and pH value is 8.8。
One embodiment of the present of invention is described in detail above, but the content is only the preferable implementation of the present invention Example, it is impossible to be considered as the practical range for limiting the present invention.All equivalent changes made according to the present patent application scope and improvement Deng, all should still belong to the present invention patent covering scope within.

Claims (8)

  1. A kind of 1. quick-dry type environmental protection rotary ink, it is characterised in that：Ink raw materials include modified resin oil mixture, and mineral oil is molten Agent, pigment, ultrafine calcium and dispersant.
  2. A kind of 2. quick-dry type environmental protection rotary ink according to claim 1, it is characterised in that：The modified resin oil mixing Thing is the modified hybrid resin of butch flax oil, and the modified hybrid resin preparation method of the butch flax oil is：By the butch flax Oil is preheating to 110 DEG C, adds phenolic resin and KH-570 continues to be uniformly mixed, and rosin denaturation thermoplastic is added after being well mixed Property resin continue to be uniformly mixed, obtained well mixed solution is the modified hybrid resin of butch flax oil.
  3. A kind of 3. quick-dry type environmental protection rotary ink according to claim 2, it is characterised in that：The phenolic resin addition For 17-24%.
  4. A kind of 4. quick-dry type environmental protection rotary ink according to claim 2, it is characterised in that：The KH-570 additions are 1-5%.
  5. A kind of 5. quick-dry type environmental protection rotary ink according to claim 2, it is characterised in that：The rosin is denatured thermoplasticity Resin content is 28-40%.
  6. 6. according to the preparation method of any quick-dry type environmental protection rotary ink in claim 1-5, it is characterised in that：Each component Mass fraction is：Modified resin oil mixture 55-62 parts, mineral oil solvent 5-10 parts, pigment 15-20 parts, ultrafine calcium 20-25 Part, dispersant 1-2 parts, preparation method are as follows：
    Modified resin oil mixture and mineral oil solvent are added in pill tank by step 1, normal temperature stirring at low speed 60-90min, Stand 30min；
    Step 2 adds pigment, ultrafine calcium and dispersant, stirs while heating up, keeping temperature stirring at low speed is for a period of time Stir afterwards while being cooled to room temperature；
    Step 3 grinds the material of mixing with sand mill, and the quick-dry type environmental protection rotary ink is made.
  7. A kind of 7. quick-dry type environmental protection rotary ink preparation method according to claim 6, it is characterised in that：The step 2 In be warming up to 75-90 DEG C, be kept stirring for 35-40min.
  8. A kind of 8. quick-dry type environmental protection rotary ink preparation method according to claim 6, it is characterised in that：It is obtained described Quick-dry type environmental protection rotary ink measure viscosity is 25-40sec/25 DEG C, release property >=2.5ml/2g, pH value 8.5-9.0.
CN201610781552.XA 2016-08-31 2016-08-31 A kind of quick-dry type environmental protection rotary ink and preparation method Pending CN107793830A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116535898A (en) * 2023-06-05 2023-08-04 张家港市黎明化工有限公司 Modified printing ink for lithography and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101302376A (en) * 2008-01-31 2008-11-12 天津东洋油墨有限公司 Preparation of web offset ink
CN101717598A (en) * 2009-11-30 2010-06-02 天津东洋油墨有限公司 Preparation method of high-viscoelasticity coupling material for non-fragrant soybean oil thermosetting web offset ink
CN103173065A (en) * 2013-04-19 2013-06-26 浙江科信油墨有限公司 Offset ink and preparation method thereof
CN104194482A (en) * 2014-08-15 2014-12-10 江苏中润油墨有限公司 Environment-friendly offset ink and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101302376A (en) * 2008-01-31 2008-11-12 天津东洋油墨有限公司 Preparation of web offset ink
CN101717598A (en) * 2009-11-30 2010-06-02 天津东洋油墨有限公司 Preparation method of high-viscoelasticity coupling material for non-fragrant soybean oil thermosetting web offset ink
CN103173065A (en) * 2013-04-19 2013-06-26 浙江科信油墨有限公司 Offset ink and preparation method thereof
CN104194482A (en) * 2014-08-15 2014-12-10 江苏中润油墨有限公司 Environment-friendly offset ink and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116535898A (en) * 2023-06-05 2023-08-04 张家港市黎明化工有限公司 Modified printing ink for lithography and preparation method thereof

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Application publication date: 20180313