CN107793119A - A kind of novel silicate/phosphate nano inorganic compounding powder material - Google Patents
A kind of novel silicate/phosphate nano inorganic compounding powder material Download PDFInfo
- Publication number
- CN107793119A CN107793119A CN201610797404.7A CN201610797404A CN107793119A CN 107793119 A CN107793119 A CN 107793119A CN 201610797404 A CN201610797404 A CN 201610797404A CN 107793119 A CN107793119 A CN 107793119A
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- Prior art keywords
- nano
- phosphate
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- powder
- powder material
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
- C04B28/344—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition solely as one or more phosphates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00008—Obtaining or using nanotechnology related materials
Abstract
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, it is made up of the component of following mass fraction:15~55 parts of soluble phosphate, 15~55 parts of Portland clinker, 1~15 part of magnesia, 10~40 parts of nano-powder.Novel silicate/phosphate nano inorganic compounding powder material of the present invention has formula simple, excellent performance, easy to use and the characteristics of be widely used.
Description
Technical field
The present invention relates to nano composite material technical field, specially a kind of novel silicate/phosphate nano is inorganic multiple
Close powder body material.
Background technology
Composite is widely used in aviation boat due to its excellent combination property, the designability of particularly its performance
My god, national defence, traffic, field, the nano composite material such as physical culture be then that wherein most the part of attraction, nano composite material have
More excellent mechanical property, barrier property, heat endurance and fire resistance etc. than conventional composite materials.It is nano combined in recent years
Quickly, the development of nano composite material is all put into important position to Materials by the strategy of World Developed Countries new material development
Put.High-tech nano composite material is introduced into construction industry, multi-functional, high performance new building material is developed, to improve China
The technology competition strength of building trade, the market position of developing construction material at home and abroad.Solves high-performance using nanometer technology
The inexorable trend that building materials will develop as following building materials field, this produces significant impact to society, economic and national security.
Phosphate concrete is typically to be mixed by metal oxide and phosphoric acid or soluble phosphate, and additive, mineral
With material according to a certain percentage, the inorganic coagulation material using phosphate as Binder Phase is generated.Phosphate concrete has preferable
Mechanical property, adhesive property, good endurance, including freexing tolerance, weatherability fluctuation, permeability resistance etc..Therefore, phosphate cementious
Material has a very wide range of applications prospect.
Portland clinker is one kind by CaO, SiO2、Al2O3、Fe2O3Fine powder is worn into by appropriate proportioning for raw material, is burnt extremely
Partial melting, it is able to the product that calcium silicates is main mineral constituent.It is mainly used in cement preparation, it is necessary to add gypsum, mixes
Material etc., final cement products are made by combined grinding.
But single phosphate concrete, Portland clinker or nano material is because of the functional limitation of its own
Property, the application in terms of building materials is by serious restriction.
The content of the invention
It is an object of the invention to provide a kind of novel silicate/phosphate nano inorganic compounding powder material, has formula
Simply, excellent performance, easy to use and the characteristics of be widely used.
The present invention can be achieved through the following technical solutions:
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, by following mass fraction
Component composition:15~55 parts of soluble phosphate, 15~55 parts of Portland clinker, 1~15 part of magnesia, nano-powder
10~40 parts.
Further, novel silicate/phosphate nano inorganic compounding powder material by following mass fraction component group
Into:25~40 parts of soluble phosphate, 25~40 parts of Portland clinker, 2~10 parts of magnesia, nano-powder 15~35
Part.
Further, the soluble phosphate in potassium dihydrogen phosphate, sodium dihydrogen phosphate and ammonium dihydrogen phosphate extremely
Few one kind.
Further, the nano-powder is selected from nano silicon, nano titanium oxide, nano-cerium oxide, nano oxygen
Change at least one of zirconium, nano bismuth oxide.
Further, the particle diameter of nanometer powder is 50-300nm.
A kind of novel silicate/phosphate nano inorganic compounding powder material of the present invention, has following beneficial effect:
Firstth, formula is simple, whole material system only include soluble phosphate, Portland clinker, magnesia and
Nano-powder, inorganic coagulation material, construction material and nano material are combined together;
Secondth, excellent performance, inorganic coagulation material, construction material and nano material are combined together, obtain that there is height
Performance and multifunctional novel silicate/phosphate nano inorganic composite powder material, the composite nano-powder material have super
Strong cohesive, excellent covering property and shielding, intensity are up to 82.74 MPas, and impermeable, high temperature resistant, fire prevention was up to 3 hours
More than;
3rd, it is easy to use, inorganic coagulation material, construction material and nano material are combined together, obtain that there is height
Performance and multifunctional novel silicate/phosphate nano inorganic composite powder material, composite nano-powder material solidification speed
Degree is fast, safety energy-conserving environment protection;
4th, it is widely used, inorganic coagulation material, construction material and nano material is combined together, obtains that there is height
Performance and multifunctional novel silicate/phosphate nano inorganic composite powder material, can be widely applied to military project, naval vessel system
Make, the numerous areas such as steel building, new energy and fixed-end forces.
Embodiment
In order that those skilled in the art will better understand the technical solution of the present invention, with reference to embodiment and to this
Invention product is described in further detail.
Embodiment 1
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, by following mass fraction
Component composition:55 parts of soluble phosphate, 35 parts of Portland clinker, 1 part of magnesia, 40 parts of nano-powder.
In the present embodiment, the soluble phosphate is potassium dihydrogen phosphate;The nano-powder is nano silicon;
The particle diameter of nanometer powder is 50-300nm.
Embodiment 2
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, by following mass fraction
Component composition:35 parts of soluble phosphate, 15 parts of Portland clinker, 15 parts of magnesia, 25 parts of nano-powder.
In the present embodiment, the soluble phosphate is sodium dihydrogen phosphate;The nano-powder is nano titanium oxide;
The particle diameter of nanometer powder is 50-300nm.
Embodiment 3
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, by following mass fraction
Component composition:15 parts of soluble phosphate, 55 parts of Portland clinker, 8 parts of magnesia, 10 parts of nano-powder.
In the present embodiment, the soluble phosphate is ammonium dihydrogen phosphate;The nano-powder is nano-cerium oxide;Institute
It is 50-300nm to state particle diameter of nanometer powder.
Embodiment 4
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, by following mass fraction
Component composition:40 parts of soluble phosphate, 25 parts of Portland clinker, 10 parts of magnesia, 15 parts of nano-powder.
In the present embodiment, the soluble phosphate is sodium dihydrogen phosphate and ammonium dihydrogen phosphate;The nano-powder is
Nano silicon and nano titanium oxide;The particle diameter of nanometer powder is 50-300nm.
Embodiment 5
The invention discloses a kind of novel silicate/phosphate nano inorganic compounding powder material, by following mass fraction
Component composition:25 parts of soluble phosphate, 40 parts of Portland clinker, 2 parts of magnesia, 35 parts of nano-powder.
In the present embodiment, the soluble phosphate is in potassium dihydrogen phosphate, sodium dihydrogen phosphate and ammonium dihydrogen phosphate;Institute
Nano-powder is stated as in nano silicon, nano titanium oxide, nano-cerium oxide, nano zircite and nano bismuth oxide;Institute
It is 50-300nm to state particle diameter of nanometer powder.
The foregoing is only a preferred embodiment of the present invention, not makees any formal limitation to the present invention;It is all
The those of ordinary skill of the industry can be shown in by specification and described above and swimmingly implement the present invention;It is but all familiar
Professional and technical personnel without departing from the scope of the present invention, makes using disclosed above technology contents
A little variation, modification and evolution equivalent variations, be the present invention equivalent embodiment;Meanwhile all realities according to the present invention
Variation, modification and evolution of any equivalent variations that matter technology is made to above example etc., still fall within the technology of the present invention
Within the protection domain of scheme.
Claims (5)
1. a kind of novel silicate/phosphate nano inorganic compounding powder material, it is characterised in that by the group of following mass fraction
It is grouped into:15~55 parts of soluble phosphate, 15~55 parts of Portland clinker, 1~15 part of magnesia, nano-powder 10~
40 parts.
2. novel silicate according to claim 1/phosphate nano inorganic compounding powder material, it is characterised in that:By
The component composition of following mass fraction:25~40 parts of soluble phosphate, 25~40 parts of Portland clinker, magnesia 2~
10 parts, 15~35 parts of nano-powder.
3. novel silicate according to claim 1 or 2/phosphate nano inorganic compounding powder material, it is characterised in that:
The soluble phosphate is selected from least one of potassium dihydrogen phosphate, sodium dihydrogen phosphate and ammonium dihydrogen phosphate.
4. novel silicate according to claim 3/phosphate nano inorganic compounding powder material, it is characterised in that:Institute
Nano-powder is stated in nano silicon, nano titanium oxide, nano-cerium oxide, nano zircite, nano bismuth oxide
It is at least one.
5. novel silicate according to claim 4/phosphate nano inorganic compounding powder material, it is characterised in that:Institute
It is 50-300nm to state particle diameter of nanometer powder.
Priority Applications (1)
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CN201610797404.7A CN107793119A (en) | 2016-08-31 | 2016-08-31 | A kind of novel silicate/phosphate nano inorganic compounding powder material |
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CN201610797404.7A CN107793119A (en) | 2016-08-31 | 2016-08-31 | A kind of novel silicate/phosphate nano inorganic compounding powder material |
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CN107793119A true CN107793119A (en) | 2018-03-13 |
Family
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CN201610797404.7A Pending CN107793119A (en) | 2016-08-31 | 2016-08-31 | A kind of novel silicate/phosphate nano inorganic compounding powder material |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU929673A1 (en) * | 1981-03-27 | 1982-05-23 | Научно-Исследовательская Лаборатория Физико-Химической Механики Материалов И Технологических Процессов Главмоспромстройматериалов | Composition of protective coating |
CN1207087A (en) * | 1995-12-08 | 1999-02-03 | 罗狄亚化学公司 | Novel binding phase for phosphorus-magnesium cements and use thereof |
CN101124178A (en) * | 2005-03-25 | 2008-02-13 | 创新生物陶瓷公司 | Hydraulic cement compositions and methods of making and using the same |
CN104926238A (en) * | 2015-06-18 | 2015-09-23 | 张家港市山牧新材料技术开发有限公司 | Nano cement paste |
-
2016
- 2016-08-31 CN CN201610797404.7A patent/CN107793119A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU929673A1 (en) * | 1981-03-27 | 1982-05-23 | Научно-Исследовательская Лаборатория Физико-Химической Механики Материалов И Технологических Процессов Главмоспромстройматериалов | Composition of protective coating |
CN1207087A (en) * | 1995-12-08 | 1999-02-03 | 罗狄亚化学公司 | Novel binding phase for phosphorus-magnesium cements and use thereof |
CN101124178A (en) * | 2005-03-25 | 2008-02-13 | 创新生物陶瓷公司 | Hydraulic cement compositions and methods of making and using the same |
CN104926238A (en) * | 2015-06-18 | 2015-09-23 | 张家港市山牧新材料技术开发有限公司 | Nano cement paste |
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Application publication date: 20180313 |