CN107758616A - A kind of heat exchange of energy-conserving and environment-protective and condenser system - Google Patents

A kind of heat exchange of energy-conserving and environment-protective and condenser system Download PDF

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Publication number
CN107758616A
CN107758616A CN201610664030.1A CN201610664030A CN107758616A CN 107758616 A CN107758616 A CN 107758616A CN 201610664030 A CN201610664030 A CN 201610664030A CN 107758616 A CN107758616 A CN 107758616A
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China
Prior art keywords
pipeline
passes
heat
preheater
heat exchanger
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CN201610664030.1A
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Inventor
李可根
李卓谦
李忠俐
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CHENGDU ZHUOLI RUIXING TECH Co
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CHENGDU ZHUOLI RUIXING TECH Co
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Priority to CN201610664030.1A priority Critical patent/CN107758616A/en
Publication of CN107758616A publication Critical patent/CN107758616A/en
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

A kind of heat exchange of energy-conserving and environment-protective and condenser system, belong to power-saving technology and environmental protection equipment field, be related to gas converting heat technology, suitable for there are all condenser systems caused by condensate liquid, suitable for all chemical industries, especially methanol decomposition hydrogen manufacturing industry.The present invention is formed by connecting by equipment such as raw material flow container, preheater, heat exchanger, vaporizer, converter, water cooler and Liquid level adjusting valves by pipeline, the system is by changing gas inlet and outlet direction and improving fluid passage, the separation of gas and condensate liquid is realized well, improve the coefficient of heat transfer, reduce the heating load of whole system, reduce circulation water consumption, reduce heat exchange area, utility is reclaimed, it is incomplete to solve heat recovery in Chemical Manufacture, the problem of energy expenditure is excessive, the purpose of energy-conserving and environment-protective is reached.

Description

A kind of heat exchange of energy-conserving and environment-protective and condenser system
Technical field
This project belongs to power-saving technology and environmental protection equipment field, belongs to energy-conserving and environment-protective technology and product, is related to gas converting heat Technology, suitable for there is all condenser systems caused by condensate liquid, suitable for all chemical industries, especially methanol decomposition hydrogen manufacturing row Industry.
Background technology
From the point of view of present circumstances, China's water resource and the energy are all at full stretch, and energy-conservation is known as water, coal, oil, natural " the 5th energy " outside gas, and the energy waste phenomenon being related at present in all kinds of chemical industry engineerings and equipment is extremely serious, Energy recovery is incomplete, and cooling water demand is big, and cooling water is directly discharged with water can cause thermal pollution, economy and the wasting of resources, Save water and energy turns into urgent problem.
The main function of heat exchange and condenser system is to reclaim the heat in hot fluid, while the medium for needing to cool down is obtained Cooling.The heat energy of GOOD TASTE will be reclaimed wherein heat energy by the cold medium with needing to heat in usual heat source gas, low product Position thermal source is then that cooling agent takes away heat by water or air, realizes the cooling of heat source gas.
Heat exchanger is the big and various in style product of an amount, and the investigation to external condenser system market shows, shell-and-tube Condenser system market still accounts for 64%.Although the competitiveness of various board-like condenser systems is rising, shell-and-tube condenser system bears height There is great advantage in terms of pressure and High Pressure Difference, leading position will be occupied.
Hydrogen industrially has extensive purposes.In recent years, due to fine chemistry industry, anthraquinone producing hydrogen peroxide, powder smelting Gold, oil hydrogenation, forestry product and agriculture product hydrogenation, bioengineering, petroleum refining hydrogenation and hydrogen fuel cleaning vehicle etc. it is rapid Development, rapidly increases pure hydrogen demand.To not facilitating the area of hydrogen source, if used traditional with petroleum-type, natural gas Or coal be raw material gas making come separating and preparing hydrogen need it is huge investment-- " equivalent to half synthesis ammonia ", be only applicable to large-scale consumer. Hydrogen can be conveniently made in middle-size and small-size user's electrolysis water, but energy consumption is very big, and every cubic metre of hydrogen power consumption reaches 6 degree, and hydrogen is pure Spend undesirable, impurity is more, while scale is also restrained, therefore many originals are carried out one after another with the producer of water electrolysis hydrogen production in recent years Technological transformation, use the new process route of preparing hydrogen by methanol vapour transformation instead.
Nowadays, schizolysis hydrogen production plant with methanol is widely used, and its basic skills is:First alcohol and water is mixed according to a certain percentage Close, after being pressurizeed with pump, exchanged heat through heat exchanger, then enter converter after vaporizing, being superheated to the temperature needed for reaction, turning Change in device in the presence of catalyst, methanol resolves into hydrogen, carbon monoxide first, and carbon monoxide generates hydrogen with steam reaction again Gas, carbon dioxide etc. convert gas, and conversion gas carries in heat exchanger with entering after condensed device cools down again after material benzenemethanol, water heat exchange Pure process carries out purification processes;In the flow, about 230 DEG C or so of the conversion temperature degree reflected, in heat exchanger with original Material first alcohol and water carries out after heat exchange cooling that condensed device is cooled to less than 40 DEG C by recirculated cooling water again, is converting air cooling process In, gas phase water vapour is constantly condensed out, and is formed biphase gas and liquid flow with gas, is influenceed condenser thermal transfer coefficient, temperature is not easy Lower, when typically entering condenser, convert the temperature of gas at 130 DEG C or so, and required heat exchange area is big, cost of investment Height, heat recovery is not ideal enough, and required cooling water amount is big.
The content of the invention
The defects of present invention exists for above-mentioned background technology provides heat exchange and the condenser system of a kind of energy-conserving and environment-protective, should System establishes new technological process, realization is changed by changing original heat exchange and the number of devices and device structure of condenser system Gas-liquid separation in hot systems, the heat transfer coefficient of medium is improved, thermal source is entered into the medium temperature of water cooling system as far as possible Ground will be low, maximumlly reclaims heat therein, reduces the heating load of vaporization superheater, reduces the cooling water of water cooling system Dosage, total heat exchange area of whole system is reduced, save equipment investment.
To reach this purpose, the invention discloses a kind of heat exchange of energy-conserving and environment-protective and condenser system, it is by passing through pipeline The equipment such as connected raw material flow container, preheater, heat exchanger, vaporizer, converter, water cooler and Liquid level adjusting valve form.
Material liquid is entered preheater shell side after buffered, inhaled in preheater by out-of-bounds entering raw material flow container by pipeline Receive conversion gas heat to be preheated, enter back into after heat exchanger shell pass carries out second of heat exchange with conversion gas and enter vaporization overheat Device, cracked being vaporized and being superheated to needed for reaction in vaporizing superheater into converter after temperature and conversion reaction, The conversion gas of high temperature is generated, reaction cracking needs to absorb heat, and conversion reaction can discharge heat, vaporize needed for superheater and converter Heat is by out-of-bounds heat supply;Conversion gas is exchanged heat into heat exchanger tube pass after being come out from converter with material liquid, cooling, now The generation of partial condensation liquid is had, two phase flow is produced to avoid gas from being mixed with condensate liquid, heat transfer efficiency is influenceed, in heat exchanger tube pass The port of export shunts to gas-liquid, and condensate liquid is drawn through into Liquid level adjusting valve from exchanger base returns to raw material flow container, by it The unreacted material and heat carried all directly returns to raw material flow container, is no longer participate in the cooling of next step, gas is then from heat exchange Go out to enter preheater tube side at the top of device, exchanged heat again with material liquid, the condensate liquid being now condensed out from gas phase is again The secondary Liquid level adjusting valve that is drawn through returns to raw material flow container, and gas enters water cooler shell side after preheater Base top contact, until Go out system to out-of-bounds after being cooled to normal temperature, now temperature difference is big, and a large amount of unreacted material liquids are condensed, directly from shell side Liquid level adjusting valve is discharged to below and returns to raw material flow container, and the condensate liquid drawn from preheater, heat exchanger and water cooler passes through;Water Cooling medium is recirculated cooling water or chilled brine.
In summary, the system has following characteristics:
In preheater, heat exchanger and water cooler, gas is discharged from heat exchanger top exit, and condensate liquid is from exchanger base Discharge, gas phase and liquid phase shunting are realized, gas-liquid two-phase is avoided the formation of, improves the coefficient of heat transfer, enhance exchange capability of heat.
Condensate liquid is no longer participate in cooling procedure below, passes through pipeline after preheater, heat exchanger, water cooler, bottom discharge Raw material flow container is directly returned, heat has directly been taken back to material liquid system, has reclaimed condensate heat.
Condensate liquid returns to raw material flow container by pipeline, directly reclaimed after preheater, heat exchanger, water cooler, bottom discharge Unreacted material, realizes the zero-emission of condensate liquid, has good environmental protection effect.
Water cooler walks tube side using cooling water, and gas phase walks the mode of shell side, in time by condensate liquid from heat exchanger shell pass bottom Discharge, improve heat transfer coefficient.
One air chamber is set at the top of heat exchanger, there are enough vaporization spaces after being raised so as to material liquid temperature.
Condensate liquid is to a Liquid level adjusting valve is mounted with the pipeline of raw material flow container, to convert gas when ensureing and being arranged outside condensate liquid It will not discharge.
Brief description of the drawings
Figure of description Fig. 1 is the flow chart of patent of the present invention, and 1 enters raw material flow container for out-of-bounds material liquid in figure(101)Pipe Road, 2 be connection raw material flow container(101)With preheater(102)Pipeline, 3 for connection preheater(102)With heat exchanger(103)'s Material liquid pipeline, 4 be connection heat exchanger(103)With vaporizer(104)Material liquid pipeline, 5 for connection vaporizer(104)With turning Change device(105)Unstrpped gas pipeline, 6 be connection converter and heat exchanger(103)Conversion feed channel, 7 for connection heat exchanger (103)With preheater(102)Conversion feed channel, 8 for connection preheater(102)With water cooler(106)Conversion feed channel, 9 To export to the conversion feed channel outside battery limit (BL) from water cooler, 10 be heat exchanger(103)To the condensate liquid pipeline of Liquid level adjusting valve, 11 For preheater(102)It is water cooler to the condensate liquid pipeline of Liquid level adjusting valve, 12(106)To the condensate line of Liquid level adjusting valve Road, 13 be into the heat conducting oil pipe for vaporizing superheater, and 14 is vaporize superheater to the heat conducting oil pipe of converter, and 15 be converter The heat conducting oil pipe of outlet, 16 be the recirculated cooling water inlet channel of water cooler, and 17 be the circulating cooling water outlet pipe of water cooler Road.
Embodiment
For the feature of patent of the present invention, technological means and the specific purposes reached, function can be further appreciated that, with reference to attached Patent of the present invention is described in further detail with embodiment for figure.
Accompanying drawing 1 is referred to, the device is the heat recovery and utilization and conversion gas of a set of 6000Nm3/h hydrogen production units by carbinol Cooling system, the operating pressure are 1.8MPa, and material liquid is by first alcohol and water each 50%(w/w)Composition, water is excessive, vaporization temperature Spend for 170 DEG C.
The device is by the raw material flow container that is connected by pipeline(101), preheater(102), heat exchanger(103), vaporizer (104), converter(105), water cooler(106)And Liquid level adjusting valve V1 is formed, the connection between each part is all connected using pipeline, Its technical process is as follows:
Material liquid from the external world passes through pipeline(1)Into raw material flow container(101)After buffering, pass through pipeline(2)Into preheater (102)Shell side, in preheater(102)In with conversion gas carry out heat exchange carry out tentatively preheat after pass through pipeline(3)Into heat exchange Device(103)After shell side carries out second of heat exchange heating with conversion gas, then pass through pipeline(4)Into vaporization superheater(104), In vaporization superheater(104)In be vaporized and be superheated to needed for reaction and pass through pipeline after temperature(5)Into converter(105)Enter Row cracking and conversion reaction, the conversion gas of high temperature is generated, convert gas from converter(105)Through pipeline after out(6)Into heat exchange Device(103)Tube side is exchanged heat with material liquid, cooling, the generation of partial condensation liquid is now had, to avoid gas from being mixed with condensate liquid Close and produce two phase flow, heat transfer efficiency is influenceed, in heat exchanger(103)The tube side port of export shunts to gas-liquid, by condensate liquid from changing Hot device bottom is drawn through pipeline(10)And Liquid level adjusting valve(V1)Raw material flow container (101) is returned to, what is carried is unreacted Material and heat all directly return to raw material flow container(101), the cooling of next step is no longer participate in, gas is then from heat exchanger(103)Top Go out to pass through pipeline in portion(8)Into preheater(102)Tube side, exchanged heat with material liquid, be now condensed from gas phase again The condensate liquid gone out passes through pipeline(11)It is drawn through Liquid level adjusting valve and returns to raw material flow container(101), gas is from preheater(102)Top Portion is drawn through pipeline(9)Into water cooler(106)Shell side, pass through pipeline after being cooled to normal temperature(9)Discharge system is to boundary Outside, now temperature difference is big, and a large amount of unreacted material liquids are condensed, directly from water cooler(106)Shell side is below by pipe Road(12)And Liquid level adjusting valve(V1)Return to raw material flow container (101), water cooler(106)Cooling medium be recirculated cooling water; In this technological process, the heat required for vaporizing superheater and converter is supplied by the conduction oil out-of-bounds to come.
After heat exchange and condenser system by a kind of energy-conserving and environment-protective of patent of the present invention, experimental data is ideal, main body Present the following aspects:
Conversion gas enters water cooler(106)Temperature fall below less than 80 DEG C, and conventional heat transfer systems can only drop to 110 DEG C.
Heat required for material liquid vaporization is 2,410,000 kilocalories, and the heat required for the vaporization of conventional system material liquid is 2660000 kilocalories.
Total heat exchange area is 338 ㎡, and conventional condenser heat exchange area is up to 520 ㎡.
24.7 tons of cooling water amount of condenser, and routine consumes cooling water up to 38 tons.
Example described above only expresses a kind of embodiment of patent of the present invention, and its description is more specific and detailed, but Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that the ordinary skill people for this area For member, on the premise of inventional idea of the present invention is not departed from, various modifications and improvements can be made, these belong to this hair The protection domain of bright patent.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (8)

1. heat exchange and the condenser system of a kind of energy-conserving and environment-protective, including raw material flow container, preheater, heat exchanger, vaporizer, converter, The equipment such as water cooler and Liquid level adjusting valve, feed conduit(1)With raw material flow container(101)Import is connected;Raw material flow container(101)Outlet Pass through pipeline(2)With preheater(102)Material liquid import is connected;Preheater(102)Material liquid exports and heat exchanger(103)It is former Liquor inlet passes through pipeline(3)It is connected;Heat exchanger(103)Material liquid outlet passes through pipeline(4)With vaporizing superheater(104)Material Entrance point is connected;Vaporize superheater(104)Material vaporization brings out mouth and passes through pipeline(5)With converter(105)Import is connected, conversion Device(105)Outlet passes through pipeline(6)With heat exchanger(103)The import of hot side end is connected, heat exchanger(103)Hot side brings out mouth and passes through pipe Road(7)With preheater(102)The import of hot side end is connected, preheater(102)The hot side end port of export passes through pipeline(8)With water cooler (106)Hot side import end is connected, from water cooler(106)Hot side brings out mouth and passes through pipeline(9)Reacting gas after cooling is conveyed To out-of-bounds;Heat exchanger(103)Tube side condensate liquid outlet passes through pipeline(10)With Liquid level adjusting valve(V1)It is connected;Preheater (102)Tube side condensate liquid outlet passes through pipeline(11)With Liquid level adjusting valve(V1)It is connected;Water cooler(106)Shell side condensate liquid is arranged Outlet passes through pipeline(12)With Liquid level adjusting valve(V1)It is connected;Liquid level adjusting valve(V1)Liquid import is returned by pipeline and raw material flow container It is connected;Conduction oil passes through pipeline(13)With vaporizing superheater(104)Heat conductive oil inlet end connects;Vaporize superheater(104)Heat conduction Oil export passes through pipeline(14)With converter(105)Heat conductive oil inlet end is connected, converter(105)Conduction oil outlet end passes through pipe Road(15)By conduction oil conveying output out-of-bounds.
2. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Heat exchanger(103)Tube side gas Discharged respectively from the different mouths of pipe from condensate liquid, gas is discharged from heat exchanger top, and condensate liquid is from heat exchanger(103)Discharge bottom.
3. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Preheater(102)Tube side gas Discharged respectively from the different mouths of pipe from condensate liquid, gas is discharged from preheater top, and condensate liquid is from preheater(102)Discharge bottom.
4. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Water cooler(106)Middle circulation is cold But water walks tube side, and shell side is made in conversion leave with rage.
5. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Heat exchanger(103)That discharges is cold Lime set passes through Liquid level adjusting valve(V1)It is discharged into raw material flow container(101).
6. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Preheater(102)That discharges is cold Lime set passes through Liquid level adjusting valve(V1)It is discharged into raw material flow container(101).
7. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Water cooler(106)That discharges is cold Lime set passes through Liquid level adjusting valve(V1)It is discharged into raw material flow container(101).
8. according to the heat exchange new technology of the energy-conserving and environment-protective described in claim 1, it is characterised in that:Heat exchanger(103)Top is set One steam chest.
CN201610664030.1A 2016-08-15 2016-08-15 A kind of heat exchange of energy-conserving and environment-protective and condenser system Pending CN107758616A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103910329A (en) * 2013-12-30 2014-07-09 成都科特瑞兴科技有限公司 High-efficiency energy-saving heat exchange novel technology
RU144911U1 (en) * 2014-03-11 2014-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский государственный энергетический университет" (ФГБОУ ВПО "КГЭУ") HEAT ELECTRIC STATION
CN104555922A (en) * 2015-01-23 2015-04-29 成都科特瑞兴科技有限公司 New technology for producing hydrogen by conversion of methyl alcohol and water vapor
CN105037109A (en) * 2015-08-11 2015-11-11 鹤壁宝发能源科技股份有限公司 Mid temperature-low temperature cascaded dimethyl ether production method
CN105517682A (en) * 2013-09-06 2016-04-20 株式会社大赛璐 Method and plant for using recompressed vapor
CN105713113A (en) * 2014-12-05 2016-06-29 中国石油天然气股份有限公司 Method for recovering heat of gas-phase material in condensation kettle
CN206069360U (en) * 2016-08-15 2017-04-05 成都科特瑞兴科技有限公司 A kind of heat exchange of energy-conserving and environment-protective and condenser system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105517682A (en) * 2013-09-06 2016-04-20 株式会社大赛璐 Method and plant for using recompressed vapor
CN103910329A (en) * 2013-12-30 2014-07-09 成都科特瑞兴科技有限公司 High-efficiency energy-saving heat exchange novel technology
RU144911U1 (en) * 2014-03-11 2014-09-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский государственный энергетический университет" (ФГБОУ ВПО "КГЭУ") HEAT ELECTRIC STATION
CN105713113A (en) * 2014-12-05 2016-06-29 中国石油天然气股份有限公司 Method for recovering heat of gas-phase material in condensation kettle
CN104555922A (en) * 2015-01-23 2015-04-29 成都科特瑞兴科技有限公司 New technology for producing hydrogen by conversion of methyl alcohol and water vapor
CN105037109A (en) * 2015-08-11 2015-11-11 鹤壁宝发能源科技股份有限公司 Mid temperature-low temperature cascaded dimethyl ether production method
CN206069360U (en) * 2016-08-15 2017-04-05 成都科特瑞兴科技有限公司 A kind of heat exchange of energy-conserving and environment-protective and condenser system

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