CN107754737A - A kind of chlorine dioxide synthetic reaction device - Google Patents
A kind of chlorine dioxide synthetic reaction device Download PDFInfo
- Publication number
- CN107754737A CN107754737A CN201711235290.8A CN201711235290A CN107754737A CN 107754737 A CN107754737 A CN 107754737A CN 201711235290 A CN201711235290 A CN 201711235290A CN 107754737 A CN107754737 A CN 107754737A
- Authority
- CN
- China
- Prior art keywords
- reaction
- level
- class
- pot
- chlorine dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0036—Flash degasification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/025—Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
A kind of chlorine dioxide synthetic reaction device, including the chlorine dioxide synthetic reaction device, including first class reaction pot and second order reaction tank, first class reaction pot, which is arranged at, to be placed in second order reaction tank；The upper end of first class reaction pot is provided with charging aperture, and the upper side of first class reaction pot is provided with one-level gas outlet and one-level leakage fluid dram；The top of second order reaction tank is provided with secondary inlet pipe and two level gas outlet, and the bottom of second order reaction tank is provided with tapping valve.During operation, reaction raw materials first flow to first class reaction pot, and the reaction product in first class reaction pot, which is entered back into second order reaction tank, to be continued to react, and reaction can be safely and reliably carried out continuously by repeating above procedure.The apparatus structure is simple, by the way of first class reaction pot is built in second order reaction tank, avoids reaction product leakage, saves arrangement space again.
Description
Technical field
The present invention relates to one kind to be used for chlorine dioxide synthesis device for making, belongs to chlorine dioxide synthesis technical field.
Background technology
Chlorine dioxide has very strong killing ability to bacterium, virus and fungal spore.Chlorine dioxide is usually to use salt
Acid is quantitatively injected into retort with sodium chlorate (or sodium chlorite), and chemical reaction generation occurs in case of heating for retort
Chlorine dioxide and chlorine.Certain density sodium chlorate aqueous solution (or certain density sodium chlorite aqueous solution) and finite concentration
Hydrochloric acid be quantitatively delivered in retort, the gas-liquid for generating chlorine dioxide and chlorine by aerated reaction at a certain temperature is mixed
Compound, certain density chlorine dioxide mixing thimerosal is made, then is added in sterilization water body or adds by water sprayer suction
Into the object for needing to sterilize, the effect such as concurrent disinfection, oxidation of chlorine dioxide and chlorine is completed.
The producing equipment of current chlorine dioxide respectively has feature.As disclosed in Chinese patent literature CN102701156A《One
Kind chlorine dioxide generating system》, disclosed in CN102502507A《The preparation facilities and its technique of chlorine dioxide》、
Disclosed in CN103334117A《A kind of chlorine dioxide generator of efficient electric solution》And disclosed in CN103922288A《Dioxy
Change chlorine generator improved structure》.These device structures are complicated, and power consumption is big, and mainly raw material reaction is incomplete, cause raw material unrestrained
Take, produce cost height, the chlorine dioxide purity of acquisition is not high, and reaction product has the danger of leakage, security
Can have much room for improvement.
The content of the invention
The problem of feed liquid hybrid reaction technology is present when the present invention produces for the synthesis of existing gaseous state, there is provided a kind of safety can
Lean on, chlorine dioxide synthetic reaction device easy to use.
The chlorine dioxide synthetic reaction device of the present invention, using following technical scheme：
The device, including the chlorine dioxide synthetic reaction device, including first class reaction pot and second order reaction tank, first order reaction
Tank, which is arranged at, to be placed in second order reaction tank；The upper end of first class reaction pot is provided with charging aperture, and the upper side of first class reaction pot is set
It is equipped with one-level gas outlet and one-level leakage fluid dram；The top of second order reaction tank is provided with secondary inlet pipe and two level gas outlet, two level
The bottom of retort is provided with tapping valve.
The upper end of the first class reaction pot is provided with one-level air inlet pipe, and first order reaction pot bottom is provided with one-level air distribution head,
One-level air distribution head is connected with one-level air inlet pipe.Two level stripping is carried out to reaction liquid by compressed air, increases first class reaction pot
Interior reaction rate.
The top of the second order reaction tank is provided with secondary inlet pipe, and second order reaction pot bottom is provided with two level air distribution head,
Two level air distribution head is connected with secondary inlet pipe.Two level stripping is carried out to reaction liquid by compressed air, increases second order reaction tank
Interior reaction rate.
The second order reaction pot bottom is provided with gas distribution grid.
The second order reaction tank top is provided with liquid-level switch.
Reaction raw materials first flow to first class reaction pot, and the reaction product in first class reaction pot, which is entered back into second order reaction tank, to be continued
Reaction, reaction can be safely and reliably carried out continuously by repeating above procedure.
The present invention is simple in construction, by the way of first class reaction pot is built in second order reaction tank, avoids reaction product
Leakage, saves arrangement space again.
Brief description of the drawings
Fig. 1 is the principle schematic diagram of chlorine dioxide synthetic reaction device of the present invention.
Wherein：1. one-level air distribution head, 2. first class reaction pots, 3. tapping valves, 4. two level air distribution heads, 5. gas distribution grids, 6. liquid
Bit switch, 7. second order reaction tanks, 8. one-level leakage fluid drams, 9. one-level gas outlets, 10. charging apertures, 11. one-level air inlet pipe, 12. two levels
Air inlet pipe, 13. gas outlets.
Embodiment
As shown in figure 1, the chlorine dioxide synthetic reaction device of the present invention is a kind of reactor with two-stage reaction tank body,
Including first class reaction pot 2 and second order reaction tank 7, first class reaction pot 2 is built in second order reaction tank 7, the upper end of first class reaction pot 2
It is provided with charging aperture 10 (a kind of corresponding charging aperture of raw material) and one-level air inlet pipe 11, the top side of first class reaction pot 2 is set
It is equipped with one-level gas outlet 9 and one-level leakage fluid dram 8.The inner bottom part of first class reaction pot 2 is provided with one-level air distribution head 1, one-level air distribution head 1
It is connected with one-level air inlet pipe 11.The top of second order reaction tank 7 is provided with secondary inlet pipe 12 and two level gas outlet 13.Second order reaction
The bottom of tank 7 is provided with tapping valve 3, and the inner bottom part of second order reaction tank 7 is provided with two level air distribution head 4 and gas distribution grid 5, two level cloth
Gas first 4 is connected with secondary inlet pipe 12.Liquid-level switch 6 is provided with second order reaction tank 7.
Reaction raw materials first flow to first class reaction pot 2, and second order reaction tank is directly entered by the reaction product in first class reaction pot 2
In 7, it is arranged apart to be different from two tanks, you can avoid reaction product from leaking, save arrangement space again.Respectively to two-stage during reaction
Appropriate compressed air is passed through in retort, two level stripping is carried out to reaction liquid, and then considerably increase reaction rate.
Two kinds of material liquids (hydrochloric acid and sodium chlorate, or hydrochloric acid and sodium chlorite) in exterior line successively pass through two
Charging aperture 10 flows into the bottom of first class reaction pot 2, and at the same time the appropriate compressed air from exterior line is by one-level air inlet pipe
11 blow to the liquid of the inner bottom part of first class reaction pot 2 through one-level air distribution head 1, carry out gas mixing, carry out two level stripping to reaction liquid, enter
And reaction rate is considerably increased, synthetically produced chlorine dioxide.Caused chlorine dioxide is by upper in first class reaction pot 2
The one-level gas outlet 9 in portion enters in second order reaction tank 7, and the two level gas outlet 13 through the top of second order reaction tank 7 is discharged, and entrance is external
In pipeline.With the inflow of two kinds of raw materials in first class reaction pot 2, liquid level gradually rises up to the one-level leakage fluid dram of first class reaction pot 2
8, feed liquid flows to the bottom of second order reaction tank 7 through one-level leakage fluid dram 8, appropriate compressed air is passed through by secondary inlet pipe 12, through two
Level air distribution head 4 blows to the liquid of the bottom of second order reaction tank 7, carries out gas mixing to liquid, increases reaction rate, continues reaction synthesis production
Raw chlorine dioxide.The chlorine dioxide of synthesis, the top of second order reaction tank 7 is flowed to through gas distribution grid 5 in second order reaction tank 7
Two level gas outlet 13, into external pipeline.
When the liquid of the bottom of second order reaction tank 7 is gradually risen to the position of liquid-level switch 6, triggering liquid-level switch 6 closes,
The closure signal of liquid-level switch 6 is sent to control system, opens tapping valve 3 by system feedback, the liquid in second order reaction tank 7 is by arranging
Liquid valve is expelled in next stage retort.Reaction can be safely and reliably carried out continuously by repeating above procedure.
Claims (5)
1. a kind of chlorine dioxide synthetic reaction device, it is characterized in that：Including first class reaction pot and second order reaction tank, first class reaction pot
It is arranged at and is placed in second order reaction tank；The upper end of first class reaction pot is provided with charging aperture, and the upper side of first class reaction pot is set
There are one-level gas outlet and one-level leakage fluid dram；The top of second order reaction tank is provided with secondary inlet pipe and two level gas outlet, and two level is anti-
The bottom of tank is answered to be provided with tapping valve.
2. chlorine dioxide synthetic reaction device according to claim 1, it is characterized in that：The upper end of the first class reaction pot is set
One-level air inlet pipe is equipped with, first order reaction pot bottom is provided with one-level air distribution head, and one-level air distribution head is connected with one-level air inlet pipe.Pass through
Compressed air carries out two level stripping to reaction liquid, increases the reaction rate in first class reaction pot.
3. chlorine dioxide synthetic reaction device according to claim 1, it is characterized in that：The top of the second order reaction tank is set
Secondary inlet pipe is equipped with, second order reaction pot bottom is provided with two level air distribution head, and two level air distribution head is connected with secondary inlet pipe.Pass through
Compressed air carries out two level stripping to reaction liquid, increases the reaction rate in second order reaction tank.
4. chlorine dioxide synthetic reaction device according to claim 1, it is characterized in that：The second order reaction pot bottom is set
There is gas distribution grid.
5. chlorine dioxide synthetic reaction device according to claim 1, it is characterized in that：The second order reaction tank top is set
There is liquid-level switch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711235290.8A CN107754737A (en) | 2017-11-29 | 2017-11-29 | A kind of chlorine dioxide synthetic reaction device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711235290.8A CN107754737A (en) | 2017-11-29 | 2017-11-29 | A kind of chlorine dioxide synthetic reaction device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107754737A true CN107754737A (en) | 2018-03-06 |
Family
ID=61276797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711235290.8A Withdrawn CN107754737A (en) | 2017-11-29 | 2017-11-29 | A kind of chlorine dioxide synthetic reaction device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107754737A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110732302A (en) * | 2019-11-19 | 2020-01-31 | 济南科琳宝环境科技有限公司 | Pure chlorine dioxide gas tube type preparation device |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2220467Y (en) * | 1994-10-06 | 1996-02-21 | 黄君礼 | Practical chlorine dioxide generator |
| CN201158590Y (en) * | 2008-01-17 | 2008-12-03 | 回东冰 | Chlorine dioxide generator |
| CN201857295U (en) * | 2010-08-21 | 2011-06-08 | 王永仪 | Chlorine dioxide generator with residual liquid separator |
| CN205527737U (en) * | 2016-03-16 | 2016-08-31 | 四川齐力绿源水处理科技有限公司 | Chlorine dioxide's apparatus for producing |
| CN106986307A (en) * | 2017-05-19 | 2017-07-28 | 贾文敬 | Portable chlorine dioxide gas jet device |
| KR101793957B1 (en) * | 2017-04-05 | 2017-11-06 | 주식회사 더존이엔티 | Apparatus and method for generating chlorine dioxide gas |
| CN207605717U (en) * | 2017-11-29 | 2018-07-13 | 济南科琳宝环境科技有限公司 | A kind of chlorine dioxide synthetic reaction device |
-
2017
- 2017-11-29 CN CN201711235290.8A patent/CN107754737A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2220467Y (en) * | 1994-10-06 | 1996-02-21 | 黄君礼 | Practical chlorine dioxide generator |
| CN201158590Y (en) * | 2008-01-17 | 2008-12-03 | 回东冰 | Chlorine dioxide generator |
| CN201857295U (en) * | 2010-08-21 | 2011-06-08 | 王永仪 | Chlorine dioxide generator with residual liquid separator |
| CN205527737U (en) * | 2016-03-16 | 2016-08-31 | 四川齐力绿源水处理科技有限公司 | Chlorine dioxide's apparatus for producing |
| KR101793957B1 (en) * | 2017-04-05 | 2017-11-06 | 주식회사 더존이엔티 | Apparatus and method for generating chlorine dioxide gas |
| CN106986307A (en) * | 2017-05-19 | 2017-07-28 | 贾文敬 | Portable chlorine dioxide gas jet device |
| CN207605717U (en) * | 2017-11-29 | 2018-07-13 | 济南科琳宝环境科技有限公司 | A kind of chlorine dioxide synthetic reaction device |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110732302A (en) * | 2019-11-19 | 2020-01-31 | 济南科琳宝环境科技有限公司 | Pure chlorine dioxide gas tube type preparation device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20160250365A1 (en) | An Unpowered Pressurized Chlorine Dioxide Automatic Generating and Mixing Disinfection Device | |
| CN207605717U (en) | A kind of chlorine dioxide synthetic reaction device | |
| CN205886628U (en) | Aquatic pipe formation of ozone and ozone water generation device | |
| CN105130046A (en) | Plasma and ultrasonic and catalysis combined cascading style water treatment device | |
| CN107754737A (en) | A kind of chlorine dioxide synthetic reaction device | |
| CN106986307A (en) | Portable chlorine dioxide gas jet device | |
| CN107902627A (en) | A kind of high purity chlorine dioxide generator | |
| KR102349309B1 (en) | Apparatus for production of chlorine dioxide solution | |
| CN206350834U (en) | Spray appliance is produced in a kind of movable chlorine dioxide synthesis | |
| CN201686487U (en) | High-purity chlorine dioxide generator | |
| CN205275204U (en) | Multi -functional disinfection by chlorine dioxide machine | |
| CN207608320U (en) | A kind of high purity chlorine dioxide generator | |
| CN206751390U (en) | Portable chlorine dioxide gas jet device | |
| CN208318107U (en) | A kind of device for making of high-pure chlorinedioxide thimerosal | |
| CN105540546B (en) | A kind of Multifunctional chlorine dioxide disinfection machine | |
| CN105712296A (en) | Anti-scald safe, low-pressure and environment-friendly hydrogen machine and gas preparation method | |
| JP2013094747A (en) | Ozone liquid generator and ozone liquid generation method | |
| CN205892749U (en) | Full -automatic chlorine dioxide generator of integral type | |
| CN201529522U (en) | Device for manufacturing disinfectant | |
| CN207605570U (en) | A kind of ClO 2 solution, which is produced, uses absorption tower | |
| CN204400608U (en) | A kind of high-pure chlorinedioxide generator | |
| CN207694776U (en) | A kind of chlorine dioxide with high purity reactor | |
| CN207531771U (en) | A kind of chlorine dioxide disinfection liquid preparation system | |
| CN207608322U (en) | A kind of chlorine dioxide with high purity gas producing equipment | |
| CN201362589Y (en) | Chlorine dioxide generator with safety valve |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180306 |